Photocatalysis in a nanocup

Guest web-writer Geoff Nelson blogs about using Au-coated nano-cups of anatase TiO2 as photocatalysts.

Written by Geoff Nelson, web writer.

Nanocups of anatase TiO2 coated with Au nanoparticles are efficient photocatalysts, as reported in a recent ChemComm article by Chemical Science and Chem Soc Rev Advisory Board member Jinlong Gong and  his group at Tianjin University, China.

This new shape promises to increase reactive surface area by exposing the normally inaccessible surface of hollow spheres.  Compared to TiO2 hollow spheres, TiO2 nanocup particles increase the rate of the photocatalytic degradation of methylene blue in the visible light region by 46%.

This performance and the ease of nanocup synthesis are reasons to promote further research.  Thus, we may expect nanocups made from other metal oxides and inorganic materials to be incorporated into solar, photochemical, and catalytic applications in the future.

In addition, the ability of nanocups to confine small amounts of reactants may find utility in nanofluidic devices.

Gong et al.‘s work has recently been highlighted as part of a C&EN article on novel nanostructures.

Read this ChemComm article in full:

Mesoporous anatase TiO2 nanocups with plasmonic metal decoration for highly active visible-light photocatalysis

Jianwei Lu, Peng Zhang, Ang Li, Fengli Su, Tuo Wang, Yuan Liu and Jinlong Gong
Chem. Commun., 2013, Advance Article
DOI: 10.1039/C3CC42029A

Geoff Nelson is a guest web-writer for ChemComm.  He currently works as a post-doctoral research associate in Dr David Payne’s research group in the Department of Materials at Imperial College, London.  Geoff’s current research concerns the synthesis and characterization of post-transition metal oxides for use in the energy sector.  His other research interests include carbon-based materials, biophysical chemistry, and surface science.

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HOT ChemComm articles for May

Here are this month’s referee-recommended HOT ChemComm articles– download them for FREE for a limited time!

Glucose-triggered release using enzyme-gated mesoporous silica nanoparticles
Elena Aznar, Reynaldo Villalonga, Cristina Giménez, Felix Sancenón, María Dolores Marcos, Ramon Martinez-Manez, Paula Díez, Jose M Pingarron and Pedro Amoros del Torro
Chem. Commun., 2013, Accepted Manuscript
DOI:10.1039/C3CC42210K

Free to access until 23rd June 2013


Cover and uncover: chiral switching exploiting templating and layer by layer grafting
Mahadeo Halhalli and Börje Sellergren
Chem. Commun., 2013, Accepted Manuscript
DOI: 10.1039/C3CC41989D

Free to access until 23rd June 2013


Target-selective photo-degradation of verotoxin-1 and reduction of its cytotoxicity to Vero cells using porphyrin-globotriose hybrids
Atsushi Okochi, Shuho Tanimoto, Daisuke Takahashi and Kazunobu Toshima
Chem. Commun., 2013, Accepted Manuscript
DOI:10.1039/C3CC42957A

Free to access until 23rd June 2013


1,1,n,n-tetramethyl[n](2,11)teropyrenophanes (n=7–9): a series of armchair SWCNT segments
Graham J. Bodwell, Kiran Sagar Unikela, Louise Nicole Dawe, David W Thompson and Bradley Lawrence Merner
Chem. Commun., 2013, Accepted Manuscript
DOI: 10.1039/C3CC43268H

Free to access until 23rd June 2013

Click here for more free HOT ChemComm articles for May!

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Jonathan Steed on why he likes ChemComm (video)

“A short, snappy format… a single message… you can read a ChemComm within a few moments and get an idea [of] a new, fresh idea…” – Jon Steed

Watch as our Associate Editor Jonathan Steed explains what he likes most about ChemComm.

Jonathan Steed accepts submissions to ChemComm in the area of supramolecular chemistry.  His research interests are in anion sensing, soft materials chemistry, particularly supramolecular gels, crystal growth, structural chemistry and crystal engineering.

Submit your best new, urgent, original research to Jonathan Steed’s Editorial Office.

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Why publish with the RSC?(video)

Watch this video and find out why the world’s leading scientists choose to publish with the RSC.  Keep an eye out for ChemComm Associate Editor Jon Steed (1:37), as well as ChemComm Advisory Board members Polly Arnold (2:39) and David Smith (6:00).

Polly Arnold also sits on the Chemical Science Advisory Board, together with Ben Feringa (3:10) and Seong Keun Kim (3:52).

Also appearing in the video is Chem Soc Rev Editorial Board member Zijian Guo (2:58).

Submit your best work to ChemComm, Chem Sci, and Chem Soc Rev!   

Find out more about RSC Publishing: http://rsc.li/11ki0Uo

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ChemComm Emerging Investigator Lectureship 2013: Winners Announced

louise

Louise Berben

On behalf of the ChemComm Editorial Board we are delighted to announce the winners of the ChemComm Emerging Investigator Lectureship 2013.

Marina Kuimova

Marina Kuimova

This year we received a high number of excellent nominations and therefore the Editorial Board have decided to award two Emerging Investigator Lectureships in 2013. The winners are Professor Louise A. Berben (University of California Davis, USA) and Dr Marina Kuimova (Imperial College London).

This annual lectureship recognises an emerging scientist in the early stages of their independent academic career.

The Editorial Board commended Louise’s contributions to the field of synthetic and physical inorganic chemistry, and Marina was awarded the lectureship for her excellent work within biophysical chemistry. Further details of the two Lectureships, including lecture locations, will be announced soon.

To find out more about the winners’ research, read some of their latest articles in ChemComm:

Redox active aluminium(III) complexes convert CO2 into MgCO3 or CaCO3 in a synthetic cycle using Mg or Ca metal
Thomas W. Myers and Louise A. Berben
Chem. Commun., 2013, DOI: 10.1039/C2CC37208H

Simple routes to bulky silyl-substituted acetylide ligands and examples of V(III), Fe(II), and Mn(II) complexes
Gereon M. Yee, Kristin Kowolik, Shuhei Manabe, James C. Fettinger and Louise A. Berben
Chem. Commun., 2011,47, 11680-11682, DOI: 10.1039/C1CC14758G

Reactive oxygen species in photochemistry of the red fluorescent protein “Killer Red”
Russell B. Vegh, Kyril M. Solntsev, Marina K. Kuimova, Soohee Cho, Yue Liang, Bernard L. W. Loo, Laren M. Tolbert and Andreas S. Bommarius
Chem. Commun., 2011,47, 4887-4889, DOI: 10.1039/C0CC05713D

Also of interest: You can now browse the 2013 Emerging Investigators Issue – which features research from outstanding up-and-coming scientists

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Viewpoints on groundbreaking ChemComms– celebrating our first baker’s dozen!

Since last year, our thought-provoking Viewpoints have highlighted some of the seminal research published in ChemComm and its predecessors over the last 100 years. Here are the first thirteen Viewpoints we have published so far– read them all for FREE till the 13th of May!

N2 coordination
Michael D. Fryzuk
Chem. Commun., 2013, Advance Article
DOI: 10.1039/C3CC42001A

C3CC42001A


The supramolecular approach for the syntheses of porphyrin complex species
Alessandro D’Urso, Maria Elena Fragalà and Roberto Purrello
Chem. Commun., 2013, Advance Article
DOI: 10.1039/C3CC41777H

C3CC41777H


The making of iLiquids – the chemist’s equivalent of the iPhone
Zhaofu Fei and Paul J. Dyson
Chem. Commun., 2013, 49, 2594-2596
DOI: 10.1039/C3CC38671F

C3CC38671F

Click here to read more Viewpoints for free!

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Cram Lehn Pedersen Prize winner Tomoki Ogoshi: US lectures 2013

Our 2013 Cram Lehn Pedersen Prize winner, Professor Tomoki Ogoshi (Kanazawa University, Japan), is set to visit the US this year to deliver his award lectures.

Tomoki Ogoshi will first present his lecture, entitled “Pillararenes: Easy-to-make and versatile receptors for supramolecular chemistry,” at the 8th International Symposium on Macrocyclic and Supramolecular Chemistry (8-ISMSC) in Crystal City, Virginia, USA from 7-11 July 2013.

Later in the year, Tomoki Ogoshi will speak at the University of Texas at Austin (20 Sept) where he will be hosted by ChemComm Associate Editor Professor Jonathan Sessler.  He will then travel to San Diego, CA, to present his talk at the Scripps Research Institute (23 Sept), hosted by Professor Julius Rebek, Jr.

Register online for the 8-ISMSC between now and 1 July to catch Professor Ogoshi’s first award lecture this summer– reduced fees for students and post-docs are available!

2013 ISMSC-8

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ChemComm-RSC Prizes and Awards Symposium: Supramolecular Chemistry

We invite you to join us for the ChemComm-RSC Prizes and Awards Symposium which will be taking place on 24 May 2013 in Dublin, Ireland.

This free one-day event will comprise of stimulating lectures reflecting the academic and industrial breadth of supramolecular chemistry, delivered by RSC Prize and Award winners and leaders in the field.

Confirmed Speakers:

  • Jerry Atwood, University of Missouri-Columbia – Winner of the 2012 RSC Supramolecular Award
  • John Callan, University of Ulster
  • Chris Chang, University of California, Berkeley – Winner of the 2012 RSC Chemistry of Transition Metals Award
  • Sylvia Draper, Trinity College Dublin
  • Phil Gale, University of Southampton – ChemComm sponsored lecture
  • David Leigh, University of Manchester – ChemComm sponsored lecture
  • Donal O’Shea, University College Dublin
  • Susan Quinn, University College Dublin
  • Eoin Scanlon, Trinity College Dublin
  • Jonathan Steed, Durham University – ChemComm sponsored lecture

We hope you and your colleagues will be able to attend the ChemComm-RSC Prizes and Awards Symposium. For further information about this event and to register, please visit the dedicated webpage.

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‘The next generation of SEC/GPC Analysis’ free webinar on 30 April 2013– register now!

‘The Next Generation of SEC/GPC Analysis’ free webinar – 30 April 2013, 4pm BST (11am EST)

Waters_Webinar_RSC_online_April_2013.jpg

Join Chemistry World and Waters for this free webinar on ‘The Next Generation of SEC/GPC Analysis’ in order to…

  • Identify the requirements for an advanced chromatographic system to meet the needs for determination of molecular weight distributions
  • Understand the benefits of a complete system approach to molecular weight characterization
  • See how the new paradigm in molecular size characterization will reduce test cycle time and consumption of operating chemicals while providing improved test precision with statistically enhanced data sets
  • See where the innovative separation approach can allow for a deeper understanding of polymeric properties and their variation

Register today at http://rsc.li/waters-acquity

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Metal organic frameworks for moisture-triggered fragrance release

Our web-writer Cally Haynes blogs about a HOT ChemComm article on MOFs for controlled fragrance release

The controlled release of fragrance molecules is of great interest in the development of fragranced products such as deodorants, as the volatility of the fragrance molecules can reduce the action of the product over time.  In this HOT ChemComm article, Jing Li and her group at Rutgers University, New Jersey have joined forces with researchers from Colgate-Palmolive Company to investigate using metal organic frameworks (MOFs) to take up and release fragrances in response to external stimuli.

frangrance release by MOFs

MOFs are a class of porous materials that are receiving a significant amount of research interest.  In particular, their ability to take up and store small molecules makes them an exciting prospect for storing gases, such as hydrogen, for catalysis and for drug delivery.

In this study, researchers examined the ability of some zinc based MOFs containing hydrophobic channels to take up and release the fragrances ethyl butyrate and D-limonene.  They found that the release of these fragrances could be triggered by moisture.

Importantly, both the hydrophilic ethyl butyrate and the hydrophobic D-limonene could be stored and released in this way, whereas leading encapsulation technologies based on modified starch are generally only useful for storing hydrophobic fragrances.  MOFs could therefore well find commercial applications for storing a wide range of fragrances.

Read this ‘HOT’ ChemComm article today!

Encapsulated recyclable porous materials: an effective moisture-triggered fragrance release system
John Vaughn, Haohan Wu, Bisera Efremovska, David H. Olson, Jairajh Mattai, Claudio Oritz, Allen Puchalski, Jing Li and Long Pan
Chem. Commun., 2013, Advance Article
DOI: 10.1039/C3CC41236A

Cally Haynes is a guest web-writer for ChemComm.  She is currently a post doctoral researcher  at the University of Southampton, and her research interests include the supramolecular chemistry of anions.  When not in the laboratory, she likes travelling and watching football.

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