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Nominations open for the Cram Lehn Pedersen Prize in Supramolecular Chemistry 2015

Nominations are now open for the Cram Lehn Pedersen Prize in Supramolecular Chemistry. The prize, sponsored by ChemComm, is organised by the committee of the International Symposium on Macrocyclic and Supramolecular Chemistry and is awarded each year to a young supramolecular chemist.

The Cram Lehn Pedersen Prize is named in honour of the winners of the 1987 Nobel Prize in Chemistry and recognizes significant original and independent work in supramolecular chemistry. Previous winners include Oren Schermann, Tomoki Ogoshi, and Jonathan Nitschke.

The Prize
The winner will receive:

  • £2000
  • free registration for the ISMSC meeting in Strasbourg, France
  • the opportunity to give a lecture at the ISMSC as well as undertake a short lecture tour after the meeting, in consultation with the Editor of ChemComm

Eligibility
To be eligible for the award you must be within 10 years of receiving your PhD on 31st December 2014

Nomination Instructions
You may nominate yourself or someone else. Please send CV, list of publications (divided into publications from PhD and postdoc and publications from independent work), and, if desired, a letter of support to Prof. Roger Harrison (ISMSC Secretary) at rgharris@chem.byu.edu by 31st December 2014

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Ionic liquid-gas interfaces: more than a surface glance

Research by scientists in the UK suggests that small changes in the nature of binary ionic liquid systems can significantly alter their surface composition. The findings may aid the design of ionic liquid films for applications such as gas capture and supported catalysis, where surface adsorption is essential.

Studies on simple one-cation–one-anion mixtures have previously revealed that the outer layers contain a greater concentration of alkyl chains than in the bulk…


Read the full article in Chemistry World»

Read the original journal article in ChemComm – it’s free to access until 20 November:
Fine tuning the ionic liquid–vacuum outer atomic surface using ion mixtures
Ignacio J. Villar-Garcia, Sarah Fearn, Nur L. Ismail, Alastair J. S. McIntosh and Kevin R. J. Lovelock  
DOI: 10.1039/C4CC06307D

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FBNCO: all the 2p-block elements in one molecule

Scientists in Italy have made a molecule with one of each of the 2p-block elements. Well, almost. There’s no neon in FBNCO but it would be a bit unfair to expect them to include an element with no known chemistry.

Read the full article in Chemistry World»

You can read the original journal article in ChemComm – it’s free to access until 17th November 2014:
All the 2p-block elements in a molecule: experimental and theoretical studies of FBNCO and FBNCO+
Anna Troiani, Stefania Garzoli, Federico Pepi, Andreina Ricci, Marzio Rosi, Chiara Salvitti and Giulia de Petris  
DOI: 10.1039/C4CC05217J

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Hot ChemComm articles for October

All of the referee-recommended articles below are free to access until 9th November 2014

Relay cooperation of K2S2O8 and O2 in oxytrifluoromethylation of alkenes using CF3SO2Na
Qingquan Lu, Chao Liu, Zhiyuan Huang, Yiyang Ma, Jian Zhang and Aiwen Lei  
Chem. Commun., 2014, Advance Article
DOI: 10.1039/C4CC06328G, Communication

C4CC06328G GA


All the 2p-block elements in a molecule: experimental and theoretical studies of FBNCO and FBNCO+
Anna Troiani, Stefania Garzoli, Federico Pepi, Andreina Ricci, Marzio Rosi, Chiara Salvitti and Giulia de Petris  
Chem. Commun., 2014, Advance Article
DOI: 10.1039/C4CC05217J, Communication

C4CC05217J GA


Hierarchical porous metal–organic framework monoliths
Adham Ahmed, Mark Forster, Rob Clowes, Peter Myers and Haifei Zhang  
Chem. Commun., 2014, Advance Article
DOI: 10.1039/C4CC06967F, Communication

C4CC06967F GA


Live cell off-target identification of lapatinib using ligand-directed tosyl chemistry
Kei Yamaura, Keiko Kuwata, Tomonori Tamura, Yoshiyuki Kioi, Yousuke Takaoka, Shigeki Kiyonaka and Itaru Hamachi  
Chem. Commun., 2014, Advance Article
DOI: 10.1039/C4CC05885B, Communication

C4CC05885B GA


Organic nanoparticles with aggregation-induced emission for tracking bone marrow stromal cells in the rat ischemic stroke model
Kai Li, Mie Yamamoto, Su Jing Chan, Mun Yee Chiam, Wei Qin, Peter Tsun Hon Wong, Evelyn King Fai Yim, Ben Zhong Tang and Bin Liu  
Chem. Commun., 2014, Advance Article
DOI: 10.1039/C4CC06921H, Communication

C4CC06921H GA


The coaction of tonic and phasic dopamine dynamics
Christopher W. Atcherley, Kevin M. Wood, Kate L. Parent, Parastoo Hashemi and Michael L. Heien  
Chem. Commun., 2014, Advance Article
DOI: 10.1039/C4CC06165A, Communication

C4CC06165A GA

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Assessing covalency in the hydrogen bond zoo

Covalency, a term describing bonding by sharing electrons, divides opinion when mentioned alongside hydrogen bonding. Worried that the concept of hydrogen bonding has been getting fuzzier over time, scientists in Germany have sought a fresh look at the very nature of these bonds, and how much covalency they involve.

Richard Dronskowski and colleagues at RWTH Aachen University collected evidence from hydrogen-bonded molecular crystals to elucidate how these crystals are held together and compare the covalency of long and short hydrogen bonds.


Read the full article in Chemistry World»

Read the original journal article in ChemComm – it’s free to access until 13th November:
Covalency of hydrogen bonds in solids revisited
Volker L. Deringer, Ulli Englert and Richard Dronskowski  
Chem. Commun., 2014,50, 11547-11549, DOI: 10.1039/C4CC04716H

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Top 25 ChemComm articles April–June 2014

We are delighted to share with you the top 25 most downloaded articles in ChemComm from April–June 2014. 

Top 25 most downloaded ChemComm articles for Q2 2014

Nanoparticles act as protein carriers during cellular internalization
Gerard W. Doorley and Christine K. Payne
DOI: 10.1039/C2CC16937A

Alzheimer’s disease amyloid beta converting left-handed Z-DNA back to right-handed B-form
Jie Geng, Chuanqi Zhao, Jinsong Ren and Xiaogang Qu
DOI: 10.1039/C0CC02049D

Polyfunctional benzylic zinc chlorides by the direct insertion of magnesium into benzylic chlorides in the presence of LiCl and ZnCl2
Albrecht Metzger, Fabian M. Piller and Paul Knochel
DOI: 10.1039/B812396A

Proton-regulated rectified ionic transport through solid-state conical nanopores modified with phosphate-bearing polymer brushes
Basit Yameen, Mubarak Ali, Reinhard Neumann, Wolfgang Ensinger, Wolfgang Knoll and Omar Azzaroni
DOI: 10.1039/B920870D

Wet chemical synthesis of silver nanorods and nanowires of controllable aspect ratio
Nikhil R. Jana, Latha Gearheart and Catherine J. Murphy
DOI: 10.1039/B100521I

Self-assembly of functional columnar liquid crystals
Takashi Kato, Takuma Yasuda, Yuko Kamikawa and Masafumi Yoshio
DOI: 10.1039/B816624B

Multifunctional catalysis by Pd-polyoxometalate: one-step conversion of acetone to methyl isobutyl ketone
Robert D. Hetterley, Elena F. Kozhevnikova and Ivan V. Kozhevnikov
DOI: 10.1039/B515325E

A robust, catalytic metal–organic framework with open 2,2′-bipyridine sites

Honghan Fei and Seth M. Cohen
DOI: 10.1039/C4CC01607F

Examination of native chemical ligation using peptidyl prolyl thioesters
Takahiro Nakamura, Akira Shigenaga, Kohei Sato, Yusuke Tsuda, Ken Sakamoto and Akira Otaka
DOI: 10.1039/C3CC47228K

Photo- and electro-chromism of diarylethene modified ITO electrodes—towards molecular based read–write–erase information storage
Jetsuda Areephong, Wesley R. Browne, Nathalie Katsonis and Ben L. Feringa
DOI: 10.1039/B608502D

Aggregation-induced emission: phenomenon, mechanism and applications
Yuning Hong, Jacky W. Y. Lam and Ben Zhong Tang
DOI: 10.1039/B904665H

Direct arylation of pyridines without the use of a transition metal catalyst
Yahui Li, Wei Liu and Chunxiang Kuang
DOI: 10.1039/C4CC02546F

One-pot synthesis of magnetic particle-embedded porous carbon composites from metal–organic frameworks and their sorption properties
Hee Jung Lee, Won Cho, Eunji Lim and Moonhyun Oh
DOI: 10.1039/C4CC01914H

Interaction of modified liposomes with Bacillus spores
Sergey Kazakov, Marian Kaholek, Tao Ji, Charles L. Turnbough, Jr and Kalle Levon
DOI: 10.1039/B312389H

A facile one-pot method to high-quality Ag-graphene composite nanosheets for efficient surface-enhanced Raman scattering
Zhe Zhang, Fugang Xu, Wenshu Yang, Mingyi Guo, Xiaodan Wang, Bailin Zhang and Jilin Tang
DOI: 10.1039/C1CC11125F

Graphene quantum dots: emergent nanolights for bioimaging, sensors, catalysis and photovoltaic devices

Jianhua Shen, Yihua Zhu, Xiaoling Yang and Chunzhong Li
DOI: 10.1039/C2CC00110A

Nitrogen-doped carbon nanotubes and graphene composite structures for energy and catalytic applications
Won Jun Lee, Uday Narayan Maiti, Ju Min Lee, Joonwon Lim, Tae Hee Han and Sang Ouk Kim
DOI: 10.1039/C4CC00146J

Novel hole transporting materials with a linear π-conjugated structure for highly efficient perovskite solar cells
Junjie Wang, Shirong Wang, Xianggao Li, Lifeng Zhu, Qingbo Meng, Yin Xiao and Dongmei Li
DOI: 10.1039/C4CC01637H

Metal-free oxidative synthesis of quinazolinones via dual amination of sp3 C–H bonds

Dan Zhao, Teng Wang and Jian-Xin Li
DOI: 10.1039/C4CC02648A

A dual functional additive for the HTM layer in perovskite solar cells
Hong Zhang, Yantao Shi, Feng Yan, Liang Wang, Kai Wang, Yujin Xing, Qingshun Dong and Tingli Ma
DOI: 10.1039/C3CC49458F

Copper-catalyzed olefinic C–H difluoroacetylation of enamides
Gilles Caillot, Jérémy Dufour, Marie-Charlotte Belhomme, Thomas Poisson, Laurence Grimaud, Xavier Pannecoucke and Isabelle Gillaizeau
DOI: 10.1039/C4CC01994F

Room-temperature Cu(II)-catalyzed aromatic C–H azidation for the synthesis of ortho-azido anilines with excellent regioselectivity

Yunpeng Fan, Wen Wan, Guobin Ma, Wei Gao, Haizhen Jiang, Shizheng Zhu and Jian Hao
DOI: 10.1039/C4CC01481B

Metal-mediated transformations of small molecules
Louise A. Berben and Jason B. Love
DOI: 10.1039/C4CC90123A
From themed collection Metal-Mediated Transformations of Small Molecules

A highly efficient mesoscopic solar cell based on CH3NH3PbI3−xClx fabricated via sequential solution deposition
Yingzhuang Ma, Lingling Zheng, Yao-Hsien Chung, Saisai Chu, Lixin Xiao, Zhijian Chen, Shufeng Wang, Bo Qu, Qihuang Gong, Zhaoxin Wu and Xun Hou
DOI: 10.1039/C4CC01962H

Reduction of graphene oxide viaL-ascorbic acid
Jiali Zhang, Haijun Yang, Guangxia Shen, Ping Cheng, Jingyan Zhang and Shouwu Guo
DOI: 10.1039/B917705A 


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Hot ChemComm articles for September

All of the referee-recommended articles below are free to access until 15th October 2014

A convergent rhodium-catalysed asymmetric synthesis of tetrahydroquinolines
Ho Yin Li, Joachim Horn, Amanda Campbell, David House, Adam Nelson and Stephen P. Marsden  
Chem. Commun., 2014,50, 10222-10224
DOI: 10.1039/C4CC04940C, Communication
From themed collection In Celebration of Richard Taylor’s 65th Birthday


On-surface aryl–aryl coupling via selective C–H activation
Qiang Sun, Chi Zhang, Huihui Kong, Qinggang Tan and Wei Xu  
Chem. Commun., 2014,50, 11825-11828
DOI: 10.1039/C4CC05482B, Communication


A single molecular probe for multi-analyte (Cr3+, Al3+ and Fe3+) detection in aqueous medium and its biological application
Junfeng Wang, Yingbo Li, Nikul G. Patel, Ge Zhang, Demin Zhou and Yi Pang  
Chem. Commun., 2014, Advance Article
DOI: 10.1039/C4CC04731A, Communication


Disentangling scalar coupling patterns by real-time SERF NMR
Nina Gubensäk, Walter M. F. Fabian and Klaus Zangger  
Chem. Commun., 2014, Advance Article
DOI: 10.1039/C4CC05892E, Communication


Isolation of stable non cyclic 1,2-disulfoxides. Revisiting the thermolysis of S-aryl sulfinimines
José A. Souto, Willian Lewis and Robert A. Stockman  
Chem. Commun., 2014, Advance Article
DOI: 10.1039/C4CC05751A, Communication


Chemical Reaction-Induced Multi-molecular Polarization (CRIMP)
Youngbok Lee, Niki M Zacharias, David Piwnica-Worms and Pratip K Bhattacharya  
Chem. Commun., 2014, Accepted Manuscript
DOI: 10.1039/C4CC06199C, Communication

 

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Antimalarial flow synthesis closer to commercialisation

Scientists in Germany have demonstrated the large scale and inexpensive production of a range of antimalarial drugs, using a continuous flow system.

The processes yields several artemisinin-derived APIs that are key components in Artemisinin Combination Therapies

An important starting material for various anti-malarial drugs is artemisinin, which until recently could only be obtained by extraction from the plant Artemisia annua. As Peter Seeberger, from the Max Planck Institute for Colloids and Interfaces in Potsdam, explains, ‘the problem is that the drug is too expensive, such that in Africa and south east Asia between 40 and 50% of the artemisinin combination therapies are fake.’


Read the full article in Chemistry World»

Read the original journal article in ChemComm:
Continuous synthesis of artemisinin-derived medicines
Kerry Gilmore, Daniel Kopetzki, Ju Weon Lee, Zoltán Horváth, D. Tyler McQuade, Andreas Seidel-Morgenstern and Peter H. Seeberger  
Chem. Commun., 2014, Advance Article, DOI: 10.1039/C4CC05098C

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Hot ChemComm articles for August

All of the referee-recommended articles below are free to access until 17th September 2014

Nanoscale insight into C–C coupling on cobalt nanoparticles
E. A. Lewis, C. J. Murphy, A. Pronschinske, M. L. Liriano and E. C. H. Sykes  
Chem. Commun., 2014,50, 10035-10037
DOI: 10.1039/C4CC03678F, Communication
From themed collection Scanning Probe Studies of Molecular Systems


A bifunctional curcumin analogue for two-photon imaging and inhibiting crosslinking of amyloid beta in Alzheimer’s disease
Xueli Zhang, Yanli Tian, Peng Yuan, Yuyan Li, Mohammad A. Yaseen, Jaime Grutzendler, Anna Moore and Chongzhao Ran  
Chem. Commun., 2014, Advance Article
DOI: 10.1039/C4CC03731F, Communication


Rapid engineering of versatile molecular logic gates using heterologous genetic transcriptional modules
Baojun Wang and Martin Buck  
Chem. Commun., 2014, Advance Article
DOI: 10.1039/C4CC05264A, Communication


Geometric and redox flexibility of pyridine as a redox-active ligand that can reversibly accept one or two electrons
Richard A. Lewis, K. Cory MacLeod, Brandon Q. Mercado and Patrick L. Holland  
Chem. Commun., 2014, Advance Article
DOI: 10.1039/C4CC05495D, Communication
From themed collection Non-Innocent Ligands


Targeted theranostic prodrugs based on an aggregation-induced emission (AIE) luminogen for real-time dual-drug tracking
Youyong Yuan, Ryan T. K. Kwok, Ruoyu Zhang, Ben Zhong Tang and Bin Liu  
Chem. Commun., 2014, Advance Article
DOI: 10.1039/C4CC05255B, Communication


Anion–π interactions and positive electrostatic potentials of N-heterocycles arise from the positions of the nuclei, not changes in the π-electron distribution
Steven E. Wheeler and Jacob W. G. Bloom  
Chem. Commun., 2014, Advance Article
DOI: 10.1039/C4CC05304D, Communication 

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Radiolabels help evaluate emerging cancer treatment

Researchers in Spain have come up with a way to track the biodistribution of a boron cluster complex used to prepare boron-carrier drugs for a prospective cancer treatment called boron neutron capture therapy (BNCT).

Drugs based on the boron cluster complex COSAN (cobaltabisdicarbollide) exploit the over-expression of membrane receptors in cancer cells to deliver therapeutic levels of 10B across the membrane. Although 10B is a stable isotope, when a beam of low-energy neutrons is applied to the cell, 10B captures a neutron and subsequently decays, releasing a high-energy α-particle and destroying the cell.


Read the full article in Chemistry World»

Read the original journal article in ChemComm – it’s free to access until 26th September:
COSAN as a molecular imaging platform: synthesis and “in vivo” imaging
Kiran B. Gona, Adnana Zaulet, Vanessa Gómez-Vallejo, Francesc Teixidor, Jordi Llop and Clara Viñas  
Chem. Commun., 2014, Advance Article, DOI: 10.1039/C4CC05058D, Communication

 
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