Smartphones develop a taste for red wine

Written by Sarah Brown, web writer for RSC Advances

Colormetric sensor array that can distinguish red wines by grape and oxidation state using principal component analysisYou can find me with great infrequency (ahem) pacing the wine, beers and spirit aisles of the supermarket trying to select the best wine for the occasion that I may be attending, be it dinner at friends or watching season four of Game of Thrones, alone, with a pizza. It may amaze you to know that, despite this penchant for the finer things in life, my wine tasting ability is a work in constant progress. Currently, my selection criterion for a bottle comprises two factors; 1) how pretty is the bottle and 2) how special is the special offer on it?

Finally, to save me from my ignorance, Tu San Park and co-workers have developed a paper microfluidic chip for red wine tasting. Their recent publication in RSC Advances details the development of a colormetric sensor array that can distinguish red wines by grape and oxidation state using principal component analysis. This isn’t just good news for me; This could be employed in the wine industry as a simple  and low cost quality control check, helping to minimise the variation inherent by employing taste panellists.

What is exciting about this assay is the room for development. The authors have been investigating the alignment of the assay with a smartphone application that would be able to image the areas of interest and measure the red, green and blue pixel intensities. This data would then be reduced for principal component analysis.

The benefits of this low cost, portable check are obvious, especially for small wineries and also, small wine drinkers, like myself.

To find out more, click below to read the full article in RSC Advances. It’s free to access for the next 4 weeks:

Paper microfluidics for red wine tasting, Tu San Park, Cayla Baynes, Seong-In Cho and Jeong-Yeol Yoon, RSC Adv., 2014, 4, 24356–24362 (DOI: 10.1039/C4RA01471E)


Sarah Brown Sarah Brown is a guest web-writer for RSC Advances. Sarah hung up her lab coat after finishing her PhD and post-doctorate in nanotechnology for diagnostics and therapeutics and now works in academic publishing. When not trying to explain science through ridiculous analogies, you can often find her crocheting, baking or climbing, but not all at once.

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Mirror mirror on the ocean

Written by Dannielle Whittaker

A methyl cellulose–carrageenan foam

Long-life foams that can act as oceanic mirrors are being explored by scientists in the UK. These reflective foams could one day ease global warming by managing incoming solar radiation. 

Planetary albedo is the proportion of sunlight reflected by Earth’s surface; two main areas contribute – land and ocean. Oceanic albedo is primarily caused by naturally occurring bubbles or foams produced by surface waves called whitecaps. They create an oceanic mirror but without them, ocean reflectance is only around 5%. Whitecaps, however, are short-lived, urging research into persistent foams that boost albedo.  

To read the full article visit Chemistry World.

Long-term stabilization of reflective foams in sea water
Alex Aziz, Helen C. Hailes, John M. Ward and Julian R. G. Evans  
RSC Adv., 2014,4, 53028-53036
DOI: 10.1039/C4RA08714C

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Self-cleaning surfaces from scrap silicone

Written by Emma Cooper

Water droplets form spherical shapes on the composite’s surface

Water droplets form spherical shapes on the composite’s surface

Scientists in China have made a mechanically stable superhydrophobic material from waste silicone.

There is currently no widespread recycling option for silicone products. ‘It is hard to reuse waste silicone owing to its cross-linked network. At present, the green method to reuse waste silicone is to collect discarded silicone products and smash them for further processing for low value applications, but this method is not widespread because of its relatively high cost and complicated processing,’ explains Lie Shen who led the work at Zhejiang University.
To read the full article please visit Chemistry World.

Stable superhydrophobic surface based on silicone combustion product
Lie Shen, Wenlian Qiu, Bin Liu and Qipeng Guo  
RSC Adv., 2014, Accepted Manuscript
DOI: 10.1039/C4RA10838H, Communication

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International Conference on Clean Energy and Advanced Materials (ICCEAM)

The International Conference on Clean Energy and Advanced Materials (ICCEAM) will be taking place from the 14–17th November in Chongqing, China. The ICCEAM will consist of plenary lectures, invited talks, short talks and posters.

Clean energy and advanced materials have become a worldwide focus, due to energy demands and environmental pollution. The ICCEAM is a multidisciplinary international conference exploring new green energy and novel materials for energy conversion/storage, biosensors, biomedicine etc. It will provide an academic exchange platform to discuss the challenges, solutions and perspectives of green energy and advanced materials for global needs, as well as the new opportunities for green energy/advanced materials commercialization.

ICCEAM Conference Chongqing ChinaTopics to be covered during the conference include:

Energy Materials & Clean Energy
     – Organic and inorganic photovoltaics
     – Batteries and supercapacitors
     – Fuel cells
     – Hydrogen generation and storage
     – Water splitting and photocatalysis
     – Solar fuels and thermosolar power
 Biosensors
     – DNA chips, nucleic acid sensors and aptasensors
     – Enzyme-based biosensors
     – Immunosensors
     – Lab-on-a-chip
     – Microfluidics and immobilisation technology
     – Printed biosensors and microfabrication
     – Proteomics, single-cell analysis and cancer-cell detection
 New materials for biomedicine
     – Controlled-release systems
     – Microcapsules
     – Targeted drug delivery
     – Vesicles and macromolecular conjugates
 Industrialization of clean energy and advanced materials

The Chair of the conference is Professor Changming Li (Southwest University, China, and RSC Advances Editorial Board member). For more details about the conference and to register, please visit the website: http://www.2014icceam.com

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International Symposium on Macro- and Supramolecular Architectures and Materials (MAM-14)

MAM-14 7th International Symposium on Macro- and Supramolecular Architectures and MaterialsThe 7th International Symposium on Macro- and Supramolecular Architectures and Materials (MAM-14) Conference will take place from 23–27th November in Johannesburg, South Africa. The conference will cover topics such as nanotechnology; materials chemistry and analysis; material functionalization; and macro- and supramolecular architectures.

Three Nobel laureates (Prof. Dan Shectman – Nobel Prize for the discovery of quasicrystals; Prof. Robert Huber –  Nobel Prize for the determination of the three-dimensional structure of a photosynthetic reaction centre; and Prof. Dr. Klaus von Klitzing – Nobel Prize for the discovery of the quantized Hall effect) will be speaking at the event. They will be joined by a host of other Plenary and invited speakers. To view the full speaker list, please click here.

To find out more about the conference and to register, please visit the website.

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Does size matter? Rational design of potent ice recrystallization inhibitors

Ice recrystallization inhibition (IRI) activity is a highly desirable property for an effective cryoprotectant. Cryopreservation is a very important process for regenerative medicine therapies, but ice recrystallization causes reduced post thaw cell viability. Although antifreeze proteins (AFPs) and antifreeze glycoproteins (AFGPs) were first investigated as cryoprotectants, their ability to bind and alter the ice crystals behaviour has encouraged researchers to look for further improvement in this field. This has led to the development of AFGP to AFGP analogues and further to the discovery of small carbohydrate-based IRIs with similar IRI activity to that of native AFGP-8.

In this review, Robert Ben and co-workers from the University of Ottawa, Canada, present recent developments of IRIs mainly focusing on novel small molecules that have emerged as potential cryoprotectants.

Designing ice recrystallization inhibitors: from antifreeze (glyco)proteins to small molecules

They begin with the molecular mechanism of the ice recrystallization phenomenon and it’s relation with IRI activities of biological antifreezes. The recent strategies for improving antifreeze compounds have been thoroughly discussed including large protein or peptide analogues, easily accessible synthetic polymers, simple mono- and disaccharide derivatives, truncated C-linked glycopeptides and carbohydrate or lysine-based surfactants/gelators. This review nicely highlights the importance of hydration index, relative orientation of hydrophilic groups and size of the linker of synthetic antifreeze compounds on their overall IRI activity.

In future these kinds of highly IRI active small molecules may replace the most widely used cytotoxic cryoprotectant DMSO and improve upon currently limited cryopreservation protocols.

Read the full review in RSC Advancesfree to access for 4 weeks:

Designing ice recrystallization inhibitors: from antifreeze (glyco)proteins to small molecules

Anna K. Balcerzak, Chantelle J. Capicciotti, Jennie G. Briard and Robert N. Ben,  RSC Adv., 2014, 4, 42682-42696

You may also be interested in these related articles:

The importance of hydrophobic moieties in ice recrystallization inhibitors

Anna K. Balcerzak, Michela Febbraro and Robert N. Ben,  RSC Adv., 2013, 3, 3232-3236

Developing highly active small molecule ice recrystallization inhibitors based upon C-linked antifreeze glycoprotein analogues

John F. Trant, Robyn A. Biggs, Chantelle J. Capicciotti and Robert N. Ben,  RSC Adv., 2013, 3, 26005-26009

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Supramolecular Chemistry Themed Collection now online

The latest RSC Advances web-collection on the topic of Supramolecular Chemistry is now available to view online!

The anion complexation properties of a fluorinated alcohol that is isosteric with a simple isophthalamide revealed that the alcohol can complex weakly basic anions with stability constants greater than those of the isophthalamide.The title of the collection is ‘Supramolecular chemistry: self-assembly and molecular recognition’ and is Guest Edited by Professor Mike Ward (University of Sheffield, UK). The articles presented here cover many aspects of the formation of, and molecular recognition with, non-covalent self-assembled systems. Systems studied span the range of supramolecular assemblies from MOFs to gels, and potential applications or functional behaviour that are on display here include host/guest chemistry, spin crossover, molecular sensors, and extraction/separation.  This collection of articles powerfully illustrates the diversity and increasing importance of supramolecular chemistry, and we hope you enjoy reading it.

Click here to view the full collection.

Some highlights from the collection include:

A ligand possessing two orthogonal metal binding sites is designed to bind three-fold and four-fold symmetric metal ions in such a way as to form a cage.An octahedral aluminium(III) complex as a three-fold node for supramolecular heterometallic self-assemblies: solution and solid state chemistry
Damien Simond, Sarah E. Clifford, Andreia F. Vieira, Céline Besnard and Alan F. Williams 
RSC Adv., 2014, 4, 16686-16693
DOI: 10.1039/C4RA00575A

Subtle backbone modifications control the interpenetration of dibenzosuberone-based coordination cages
Thorben R. Schulte, Marcel Krick, Carmen I. Asche, Sabrina Freye and Guido H. Clever 
RSC Adv., 2014, 4, 29724-29728
DOI: 10.1039/C4RA04679J

The versatility of “click” reactions: molecular recognition at interfaces
Thomas Heinrich, Christoph H.-H. Traulsen, Erik Darlatt, Sebastian Richter, Johannes Poppenberg, Nora L. Traulsen, Igor Linder, Andreas Lippitz, Paul M. Dietrich, Baha Dib, Wolfgang E. S. Unger and Christoph A. Schalley 
RSC Adv., 2014, 4, 17694-17702
DOI: 10.1039/C4RA01730G

Melting temperatures deduced from molar volumes: a consequence of the combination of enthalpy/entropy compensation with linear cohesive free-energy densities
Thibault Dutronc, Emmanuel Terazzi and Claude Piguet 
RSC Adv., 2014, 4, 15740-15748
DOI: 10.1039/C4RA00348A

Bis-triazolium containing macrocycles, pseudorotaxanes and interlocked structures for anion recognition
Nicholas G. White, Henry G. Lovett and Paul D. Beer 
RSC Adv., 2014, 4, 12133-12147
DOI: 10.1039/C4RA00615A

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Winning by an E-nose

By Sarah Brown, web writer for RSC Advances

Superhuman olfaction isn’t right up there on my list of desired super powers for a number of reasons that I won’t share here; however, an enhanced appreciation for the detection of various gases is underrated.

For example, the ability to detect toxic gases is of huge benefit, particularly at levels before they pose danger to humans. Electronic noses (E-noses) have been created from nanowire arrays as devices for sensing technology; however, most E-noses require operating temperatures of over 200 °C, which may be a limiting factor in their practical application.

Writing in RSC Advances, Chatchawal Wongchoosuk and co-workers describe the fabrication of a ZnO-based E-nose that operates at room temperature and can detect down to the ppb level. The ZnO nanowires were surface modified to include ZnO-ZnAl2O3 and ZnO-Zn2TiO4 core-shell nanowires, which formed electrical connections by self-assembly. Ultraviolet light, positioned above the sensors, was used to generate electron hole pairs and oxygen species, which, on reaction with a gas or gases could change the layer width of the nanowires and ultimately lead to the detection and characterisation of the substance.

The ability for the E-nose to operate sensitively at room temperature makes a lot of scents and these developments are not something to be sniffed at (groan!)

Read the full article by clicking the link below – free to access until 16th October:

Electronic nose for toxic gas detection based on photostimulated core–shell nanowires
Chatchawal Wongchoosuk, Kittitat Subannajui, Chunyu Wang, Yang Yang, Firat Güder, Teerakiat Kerdcharoen, Volker Cimalla and Margit Zacharias, RSC Adv., 2014, 4, 35084–35088, DOI: 10.1039/C4RA06143H


Sarah Brown Sarah Brown is a guest web-writer for RSC Advances. Sarah hung up her lab coat after finishing her PhD and post-doctorate in nanotechnology for diagnostics and therapeutics and now works in academic publishing. When not trying to explain science through ridiculous analogies, you can often find her crocheting, baking or climbing, but not all at once.

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Top 10 most-downloaded articles: April–June 2014

Take a look at the most-downloaded RSC Advances articles from the months of April, May and June 2014 and let us know what you think!

Size-controlled silver nanoparticles synthesized over the range 5–100 nm using the same protocol and their antibacterial efficacy
Shekhar Agnihotri, Soumyo Mukherji and Suparna Mukherji
RSC Adv., 2014,4, 3974-3983
DOI: 10.1039/C3RA44507K

Using a two-step deposition technique to prepare perovskite (CH3NH3PbI3) for thin film solar cells based on ZrO2 and TiO2 mesostructures
Dongqin Bi, Soo-Jin Moon, Leif Häggman, Gerrit Boschloo, Lei Yang, Erik M. J. Johansson, Mohammad K. Nazeeruddin, Michael Grätzel and Anders Hagfeldt
RSC Adv., 2013,3, 18762-18766
DOI: 10.1039/C3RA43228A

Graphene-based photocatalytic composites
Xiaoqiang An and Jimmy C. Yu
RSC Adv., 2011,1, 1426-1434
DOI: 10.1039/C1RA00382H

Synthesis of multicomponent sulfide Ag2ZnSnS4 as an efficient photocatalyst for H2 production under visible light irradiation
Kan Li, Bo Chai, Tianyou Peng, Jin Mao and Ling Zan
RSC Adv., 2013,3, 253-258
DOI: 10.1039/C2RA21481D

Engineered fluorescence tags for in vivo protein labelling
Zhipeng Wang, Xiaozhe Ding, Sijian Li, Jing Shi and Yiming Li
RSC Adv., 2014,4, 7235-7245
DOI: 10.1039/C3RA46991C

Copper-catalyzed aerobic alcohol oxidation under air in neat water by using a water-soluble ligand
Guofu Zhang, Xingwang Han, Yuxin Luan, Yong Wang, Xin Wen, Li Xu, Chengrong Ding and Jianrong Gao
RSC Adv., 2013,3, 19255-19258
DOI: 10.1039/C3RA43366H

Biosynthesis of natural products by microbial iterative hybrid PKS–NRPS
Katja Maria Fisch
RSC Adv., 2013,3, 18228-18247
DOI: 10.1039/C3RA42661K

Bioinspired self-cleaning surfaces with superhydrophobicity, superoleophobicity, and superhydrophilicity
Shunsuke Nishimoto and Bharat Bhushan
RSC Adv., 2013,3, 671-690
DOI: 10.1039/C2RA21260A

Nanoscale conductive niobium oxides made through low temperature phase transformation for electrocatalyst support
Kan Huang, Yunfeng Li, Litao Yan and Yangchuan Xing
RSC Adv., 2014,4, 9701-9708
DOI: 10.1039/C3RA47091A

Role of graphene/metal oxide composites as photocatalysts, adsorbents and disinfectants in water treatment: a review
Ravi Kant Upadhyay, Navneet Soin and Susanta Sinha Roy
RSC Adv., 2014,4, 3823-3851
DOI: 10.1039/C3RA45013A

Interesting in submitting to RSC Advances? You can submit online today, or email us with your ideas and suggestions.

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Total Food 2014

The Total Food 2014 Conference will be taking place from the 11th–13th November in Norwich, UK.

Total Food 2014 is the fourth in a series of international conferences which focus on the sustainable exploitation of agri-food co-products and related biomass, thereby helping to minimise waste.

Total food 2014 Conference, Norwich, UK November 2014Under the auspices of the Royal Society of Chemistry (Food Group), this three day event will provide an open forum to highlight recent developments and to facilitate knowledge transfer between representatives of the agri-food industries, scientific research community, legal experts on food related legislation and waste management, and consumer organisations. The 2014 conference will be run by the Institute of Food Research in collaboration with the COST Action Network TD1203 Food waste valorisation for sustainable chemicals, materials and fuels (EUBis), and will comprise plenary lectures, short talks, poster sessions, and focussed workshops. The conference is currently open for registration and abstracts can be accepted for poster presentation.

For more details about the conference and to register, please visit the website: http://www.ifr.ac.uk/totalfood2014/

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