Toilet purification system doubles as hydrogen fuel cell

An electrolysis cell that couples energy storage with water purification and reuse has been developed as part of a wider project to make a self-sustaining toilet.

The electrochemical system reduces the yellow colour of wastewater at the same time as producing hydrogen

The electrochemical system reduces the yellow colour of wastewater at the same time as producing hydrogen

Electrochemical approaches to water purification are not unknown but often focus on wastewater in industrially developed areas. Michael Hoffmann, and colleagues at the California Institute of Technology in the US, hope their electrochemical water splitting method for purifying human waste, at the same time as generating hydrogen gas, will eventually be introduced into areas with underdeveloped infrastructure.

Read the full article at Chemistry World.

Electrochemical treatment of human waste coupled with molecular hydrogen production
Kangwoo Cho, Daejung Kwon and Michael R. Hoffmann  
RSC Adv., 2014, 4, 4596-4608
DOI: 10.1039/C3RA46699J

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Reclaiming spilt oil

The ability to recover oil from land-based spills should reduce the cost of decontamination

© Shutterstock

Scientists in Canada have shown they can recover oil from contaminated sand using surfactants whose emulsion stabilising ability is deactivated by carbon dioxide.

Land-based oil spills can be remedied by taking the sand (or soil away) for washing. The sand is heated and mixed with a surfactant solution, before the oil containing emulsion is removed to leave clean sand. However, the entire emulsion must be disposed of as hazardous waste.

Switchable surfactants could offer a less wasteful solution. Unlike normal surfactants, switchable surfactants can be switched off by an external trigger, allowing the oil and water phases to separate, by destabilising the emulsion.

The negative surface charges on sand particles mean that surfactants for cleaning oil contaminated sand need to be anionic. Cationic switchable surfactants were pioneered by Philip Jessop and his colleagues at Queens University, Kingston, Ontario, in 2006, and now the team have created an anionic version.

To release oil captured by Jessop’s carboxylate and phenolate anionic surfactants carbon dioxide is bubbled through the emulsion, acidifying the aqueous phase. This switches the surfactant structure from anionic to neutral, disrupting the emulsion by removing its ability to stabilise the oil/water interface. The oil separates and can be decanted for reuse and sale. Decarbonising the solution will switch the surfactants back on.

Read the rest of the story by Emily Skinner in Chemistry World!

Read the original research paper in RSC Advances:

Switchable anionic surfactants for the remediation of oil-contaminated sand by soil washing
Elize Ceschia, Jitendra R. Harjani, Chen Liang, Zahra Ghoshouni, Tamer Andrea, R. Stephen Brown and Philip G. Jessop
RSC Adv., 2014, 4, 4638-4645
DOI: 10.1039/C3RA47158F, Paper

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HOT papers in RSC Advances

Here are the latest HOT papers published in RSC Advances:

Size-adjustable annular ring-functionalized mesoporous silica as effective and selective adsorbents for heavy metal ions
Fa-Kuen Shieh, Chia-Teng Hsiao, Hsien-Ming Kao, Yu-Chein Sue, Kuan-Wei Lin, Chang-Cheng Wu, Xi-Hong Chen, Lei Wan, Ming-Hua Hsu, Jih Ru Hwu, Chia-Kuang Tsung and Kevin C.-W. Wu  
RSC Adv., 2013, 3, 25686-25689
DOI: 10.1039/C3RA45016C

GA

A quantitative assessment of the production of ˙OH and additional oxidants in the dark Fenton reaction: Fenton degradation of aromatic amines
Claudio Minero, Mirco Lucchiari, Valter Maurino and Davide Vione  
RSC Adv., 2013, 3, 26443-26450
DOI: 10.1039/C3RA44585B

GA 

Synthesis of dibenzyl carbonate: towards a sustainable catalytic approach
Giulia Fiorani and Maurizio Selva  
RSC Adv., 2014, 4, 1929-1937
DOI: 10.1039/C3RA42904K

GA

All the papers listed above are free to access for the next 4 weeks!

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RSC Advances breaks new ground

For a new journal, RSC Advances has already seen significant successes:

  • The first articles were published just 16 weeks after the journal was announced in April 2011
  • It was the first chemistry journal to use topic modelling technology to automatically classify articles into one or more of 12 subject categories.
  • 2000 articles were published by November 2012, with the journal moving to weekly issues

 And now this journal is pushing the boundaries again.

RSC Advances Issue in Progress image

The RSC Advances Issue in Progress image

From Issue 1 of 2014, RSC Advances is moving to article-based publishing, with articles assigned page numbers and published in an Issue in Progress as soon as they are in their final (fully edited and formatted) form.

As an author, this means you will receive your RSC Advances page numbers much faster. 

And as a reader, you can now decide how you’d like to view articles, with the options of ordering the issue by article type, pagination, subject, or date published.

But that’s not all – the next level of topic modelling technology has just been introduced, so  you can easily drill down to the topics most relevant to your research. For example, the energy category is now subdivided into eight sections, covering: biofuels & biomass; biotechnology; fossil fuels; electrochemical energy; hydrogen; materials & nanotechnology; nuclear power; and solar energy. Other subject categories have between seven and sixteen sub-categories – you can view them here.

Plus you can now select subject-specific table of content alerts – taking you straight to the most relevant articles.

Visit the RSC Advances homepage to explore these new developments – and if you have any comments, please contact us.

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HOT papers in RSC Advances

Here are the latest HOT papers published in RSC Advances:

Synthesis of [18F]4-(4-fluorophenyl)-1,2,4-triazole-3,5-dione: an agent for specific radiolabelling of tyrosine
Flagothier Jessica, Warnier Corentin, Dammicco Sylvestre, Lemaire Christian and Luxen André
RSC Adv., 2013, 3, 24936-24940
DOI: 10.1039/C3RA44666B

GA

Novel environmentally friendly (Bi, Ca, Zn, La)VO4 inorganic yellow pigments
Wendusu, Taihei Honda, Toshiyuki Masui and Nobuhito Imanaka  
RSC Adv., 2013, 3, 24941-24945
DOI: 10.1039/C3RA43978J

GA

Iron-catalysed alkene hydrogenation and reductive cross-coupling using a bench-stable iron(II) pre-catalyst
Dominik J. Frank, Léa Guiet, Alexander Käslin, Elliot Murphy and Stephen P. Thomas  
RSC Adv., 2013, 3, 25698-25701
DOI: 10.1039/C3RA44519D

GA

All the papers listed above are free to access for the next 4 weeks!

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Top 10 most-accessed articles July–September 2013

The 10 most-accessed RSC Advances articles between April and June were as follows:

SBR–PVDF based binder for the application of SLMP in graphite anodes
Lei Wang, Yanbao Fu, Vincent S. Battaglia and Gao Liu
RSC Adv., 2013,3, 15022-15027
DOI: 10.1039/C3RA42773K, Paper

Iron-containing nanomaterials: synthesis, properties, and environmental applications
Boris I. Kharisov, H. V. Rasika Dias, Oxana V. Kharissova, Victor Manuel Jiménez-Pérez, Betsabee Olvera Pérez and Blanca Muñoz Flores
RSC Adv., 2012, 2, 9325-9358
DOI: 10.1039/C2RA20812A, Review Article

Graphene–inorganic nanocomposites
Song Bai and Xiaoping Shen
RSC Adv., 2012,2, 64-98
DOI: 10.1039/C1RA00260K, Review Article

Bioinspired self-cleaning surfaces with superhydrophobicity, superoleophobicity, and superhydrophilicity
Shunsuke Nishimoto and Bharat Bhushan
RSC Adv., 2013, 3, 671-690
DOI: 10.1039/C2RA21260A, Review Article

Using a two-step deposition technique to prepare perovskite (CH3NH3PbI3) for thin film solar cells based on ZrO2 and TiO2 mesostructures
Dongqin Bi, Soo-Jin Moon, Leif Häggman, Gerrit Boschloo, Lei Yang, Erik M. J. Johansson, Mohammad K. Nazeeruddin, Michael Grätzel and Anders Hagfeldt
RSC Adv., 2013,3, 18762-18766
DOI: 10.1039/C3RA43228A, Communication

Synthesis of graphene-based nanomaterials and their application in energy-related and environmental-related areas
Guixia Zhao, Tao Wen, Changlun Chen and Xiangke Wang
RSC Adv., 2012, 2, 9286-9303
DOI: 10.1039/C2RA20990J, Review Article

Visible-light plasmonic photocatalyst anchored on titanate nanotubes: a novel nanohybrid with synergistic effects of adsorption and degradation
Yuxin Tang, Zhelong Jiang, Qiuling Tay, Jiyang Deng, Yuekun Lai, Dangguo Gong, Zhili Dong and Zhong Chen
RSC Adv., 2012,2, 9406-9414
DOI: 10.1039/C2RA21300A, Paper

Electrode materials for aqueous asymmetric supercapacitors
Faxing Wang, Shiying Xiao, Yuyang Hou, Chenglin Hu, Lili Liu and Yuping Wu
RSC Adv., 2013,3, 13059-13084
DOI: 10.1039/C3RA23466E, Review Article

Graphene-based photocatalytic composites
Xiaoqiang An and Jimmy C. Yu
RSC Adv., 2011, 1, 1426-1434
DOI: 10.1039/C1RA00382H, Review Article

Biobased chitosan hybrid aerogels with superior adsorption: Role of graphene oxide in CO2 capture
Almahdi A. Alhwaige, Tarek Agag, Hatsuo Ishida and Syed Qutubuddin
RSC Adv., 2013,3, 16011-16020
DOI: 10.1039/C3RA42022A, Paper

Take a look at the articles, and then let us know your thoughts and comments below.

Fancy submitting your own work to RSC Advances? You can submit online today, or email us with your ideas and suggestions.

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HOT papers in RSC Advances

Here are the latest HOT papers published in RSC Advances:

Biobutanol: An outlook of an academist and industrialist
 Sandip B. Bankar, Shrikant A. Survase, Heikki Ojamo and Tom Granström, 
RSC Adv., 2013, 3, 24734-24757, DOI: 10.1039/C3RA43011A

GA

A cationic water-soluble pillar[6]arene: synthesis, host–guest properties, and self-assembly with amphiphilic guests in water
Yingjie Ma, Jie Yang, Jinying Li, Xiaodong Chi and Min Xue,
RSC Adv., 2013, 3, 23953-23956, DOI: 10.1039/C3RA44727H

GA

Multifunctional graphene quantum dots-conjugated titanate nanoflowers for fluorescence-trackable targeted drug delivery
Xin Ting Zheng, Hui Ling He and Chang Ming Li,
RSC Adv., 2013, 3, 24853-24857, DOI: 10.1039/C3RA44125C

GA

All the papers listed above are free to access for the next 4 weeks!

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Iridium complexes for solid state lighting

Sara Coles is a guest web-writer for RSC Advances. She currently works for Johnson Matthey in Royston, UK.


 

Interesting research is being done on solid state lighting, organic light emitting diodes (OLEDs), light emitting electrochemical cells (LEECs) and dye sensitised solar cells (DSSCs). Eli Zysman-Colman’s group, which recently moved from Université de Sherbrooke in Canada to University of St Andrews in the UK, works on precious metals complexes for light-emitting applications.

The group has a wealth of publications in the field, among the latest are this paper in RSC Advances which correlates the structures of heteroleptic cationic iridium complexes with their electrochemiluminescence behaviour to gain insight into tuning their emission wavelength and intensity. The aim, of course, is to generate efficient complexes that could one day find use in various lighting applications, display screens and devices.

Find out about the Zysman-Colman group’s fundamental research in RSC Advances. Free to access for 4 weeks.

Correlating electronic structures to electrochemiluminescence of cationic Ir complexes
Kalen N. Swanick, Sébastien Ladouceur, Eli Zysman-Colman and Zhifeng Ding 
RSC Adv., 2013, 3, 19961–19964, DOI: 10.1039/C3RA43134G

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The private lives of plants

Scientists in Japan have designed a microdevice to monitor the effect that chemicals have on the growth of pollen tubes.

  

In higher plants, the male and female gametes are located in separate tissues within the plant. The male gamete is produced inside a pollen grain and for pollination to occur it must be carried to the female part of the plant by a growing pollen tube. Chemical signals from the female part of the plant attract the pollen tube towards it and only compatible pollen tubes make it all the way.

While these events are happening around us every day, they happen on the microscale, making them very difficult to study. Previous research into plant reproduction has suggested that the direction of pollen tube growth is controlled by a gradient of attractant molecules. However, most assays spot chemoattractant onto a medium then allow it to spread, which makes it difficult to determine the exact concentration of attractant molecule at the head of the pollen tube.

Now, Noritada Kaji and colleagues at Nagoya University have created a microfluidic assay that can more accurately investigate pollen tube growth. ‘Lab-on-a-chip technologies have found a new partner in plant physiology research,’ says Kaji. ‘Our simple microfluidic platform provides precisely defined concentration gradients of chemoattractants over an extended time period to enable the digital discrimination of chemoattractant effects on directional pollen tube growth.’

Read the rest of the story in Chemistry World!

Read the original research paper in RSC Advances:

M Horade et al, RSC Adv., 2013, DOI: 10.1039/c3ra42804d

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Nanoparticles stop mosquitoes breeding

William Bergius writes on a HOT RSC Advances paper in Chemistry World…

A simple synthesis for environmentally benign carbon nanoparticles that could be used to control mosquito populations has been demonstrated by scientists in India.

Mosquitoes are found across the globe, with the exception of Antarctica and Iceland. A holiday nuisance, they are also a well-known vector for many diseases, including malaria, dengue fever, yellow fever and viral encephalitis. The transmission of diseases by mosquitoes is estimated to be responsible for 2 million deaths every year.

Control or eradication of the mosquito population could significantly restrict the spread of disease. Screens and nets can be used to exclude the pests, while traps or insecticides can be used to eliminate them. More permanent solutions include draining pools of stagnant water where mosquitoes like to breed, or the introduction of natural mosquito predators such as dragonflies.

Sabyasachi Sarkar and his team of inorganic chemists at the Bengal Engineering and Science University have now come across a new answer to the mosquito problem. When trying to take pictures of zebrafish, that had been fed on mosquitos treated with water-soluble carbon nanoparticles (wsCNPs) to help with the imaging, they noticed that the presence of the wsCNPs appeared to be retarding the development of the mosquito larvae.

After further investigation, Sarkar and his team were able to show that a concentration of these wsCNPs as low as 3mg/l prevents the larvae from ever reaching maturity, resulting in their death. At this concentration, the wsCNPs are otherwise harmless to the surrounding environment and can persist in stagnant pools of water for periods of several months.

Read what Sabyasachi Sarkar and Pilar Mateo had to say about the research in the Chemistry World story.

Read the original research paper in RSC Advances:

Water soluble nano carbons arrest the growth of mosquito, Manav Saxena, Sumit Kumar Sonkar and Sabyasachi Sarkar, RSC Advances, DOI: 10.1039/C3RA44100H

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