Hot Article: Polymerization kinetics under confinement

Researchers from Technion–Israel Institute of Technology have studied the kinetics of polymerization under confinement.

Experimental results show that the polymerisation kinetics are different inside a core–shell electrospun nanofibre compared to the bulk. The reaction rate decreases when the mean size of the clusters approaches the size of the internal fibre diameter. This causes the polymerisation reaction to become polychromatic, where the rate of reaction decreases with time.

Interested to know more? Why not read the full article for free: C. S. Reddy, A. Arinstein and E. Zussman, Polym. Chem., 2011, DOI: 10.1039/C0PY00285B (Advance Article)

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Polymer Chemistry Author of the Week-Levent Toppare

Levent Toppare is a professor of chemistry at the Department of Chemistry, Department of Polymer Science and Technology and Department of Biotechnology in Middle East Technical University with an expertise in electrochemistry. He is also a member of Center for Solar Energy Research and Applications (GÜNAM). His research interests include conducting polymers and his group has recently been involved in electrochromism, electrochromic devices and photovoltaic cells. Toppare obtained his PhD (1982) degree from METU. He has published over 300 scientific papers and he is the recipient of British Council, Fulbright and Alexander von Humboldt Scholarships. Please follow the links for further information on the Toppare group and his recent paper in Polymer Chemistry.

 

 

 

What was your inspiration in becoming a chemist?
My High School Chemistry teacher, rest in peace, had an important impact on me in deciding to become a Faculty member in Chemistry. I consulted the Chairman of the Department of Chemistry and Chemical Engineering at METU when I was an 11th grade student, and finally decided on studying Chemistry at the Department of Chemistry, METU.

What was the motivation behind the research in your recent Polymer Chemistry paper?
Actually, we were invited by the editor to submit a paper. He very much liked our paper and its content on the electrochromism of polymers published in Chemical Communications.

Why did you choose Polymer Chemistry to publish your work?
We believe it will turn out to be a very high impact factor journal soon. Besides returning Prof. Haddleton’s offer would not be polite.

In which upcoming conferences may our readers meet you?
We recently developed a new laboratory on organic Solar Cells; we anticipate revealing our studies in future meetings.

How do you spend your spare time?
Spare time? I have my dinner with my wife before retiring for bed. Just joking, I play bridge twice a week.

Which profession would you choose if you were not a scientist?
I never thought about that. I decided on this when I was only 16.

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Hot Article: New micellar morphologies from amphiphilic block copolymers: disks, toroids and bicontinuous micelles

Simon Holder and Nico Sommerdijk summarise recent approaches to controlling the self-assembly of amphiphilic block copolymers.

The review particularly focuses on methods to obtain novel micellar morphologies from amphiphilic block copolymers. Of special interest is the control of the overall shape of micelles, which increase the variety of available shapes from simple, such as cylinders and spheres etc., to more complex morphologies, such as disks, toroids and bicontinuous micelles.

Interested to know more? Why not read the full article for free: S. J. Holder and N. A. J. M. Sommerdijk, Polym. Chem., 2011, DOI: 10.1039/C0PY00379D (Advance Article)

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Polymer Chemistry Author of the Week- Helmut Schlaad


Helmut Schlaad received his chemistry diploma from the University of Mainz, Germany, in 1993. He continued his studies in Mainz and completed his Ph.D. in 1997 on anionic polymerization of (meth)acrylates under the supervision of Prof. Dr. Axel H. E. Müller. In 1998, he went to the University of Massachusetts at Lowell, USA, to work with Prof. Dr. Rudolf Faust in the field of cationic polymerization of vinyl monomers. In 1999, he joined the Max Planck Institute of Colloids and Interfaces, shortly before the institute moved from Teltow to its new location in Golm, Germany, to lead the project “Amphiphilic Block Copolymers” (workedfor habilitation, finished in 2004) in the group of Prof. Dr. Dr. Markus Antonietti. His research is devoted to (i) the development of new controlled polymerization techniques, modular synthetic pathways, and “thio-click” chemistry (ii) advanced characterization of functional polymers, and (iii) study of complex structure formation of bioinspired (co-)polymers through specific non-covalent interactions. Please follow the link for further information on Helmut’s research group and his recent publication in Polymer Chemistry. 

What was your inspiration in becoming a chemist?
I think the chemistry teachers during school time inspired and motivated me most to later study chemistry at university. My second inspiration, and also confirmation that becoming a polymer chemist was absolutely the right choice, was my PhD supervisor Axel H. E. Müller.

What was the motivation behind the research in your recent Polymer Chemistry paper? (DOI: 10.1039/c1py00002k)
The initial motivation was to make some sophisticated graft copolymers by thiol-yne photo click chemistry – however this did not work out as planned: no clicking but cross-linking! So we changed the direction a bit and used the same chemistry to make functional star polymers by in situ functionalization/cross-linking of block copolymer micelles. And this worked out really nicely… 

Why did you choose Polymer Chemistry to publish your work?
I am convinced that Polymer Chemistry will be among the top journals for original papers in polymer science. It has a broad readership and promises fast review process and publication – which I can now confirm from my own experience.

In which upcoming conferences may our readers meet you?
I will attend the Hybrid Materials 2011 Conference in Strasbourg, France (March), the Ionic Polymerization (IP’11) in Akron, Ohio (July), and the Symposium on Polymeric Materials in Bayreuth, Germany (September).

How do you spend your spare time?
Spare time…? Well, there are the kids (6 and 8 years old), lots of house and garden work, music, and no sports.

Which profession would you choose if you were not a scientist?
Drummer in a Rock band!!!


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Hot Article: Propylenedioxythiophene (ProDOT)–phenylene copolymers allow a yellow-to-transmissive electrochrome

Researchers from University of Florida have developed the first cathodically colouring yellow-to-transmissive switching electrochromic polymer.

Electrochromic displays require the modulation of three subtractive primary colours (red, yellow and blue or cyan, magenta and yellow) in order to express all of the colours in the spectrum. This work reports the first polymer that is yellow in its neutral state and highly transmissive in its oxidised state. The polymer achieves a 70% transmittance contrast at its absorption maximum and is capable of a full switch in under one second, therefore showing promise as a component of a full multicolour electrochromic device.

Interested to know more? Why not read the full article for free: C. M. Amb, J. A. Kerszulis, E. J. Thompson, A. L. Dyer and J. R. Reynolds, Polym. Chem., 2011, DOI: 10.1039/C0PY00405G (Advance Article)

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Polymer Chemistry Author of the week- Julien Nicolas


Julien Nicolas graduated in 2001 from the “Ecole Supérieure de Chimie Organique et Minérale (ESCOM)” (Cergy-Pontoise, France). He completed his PhD in 2005 under the supervision of Prof. Bernadette Charleux at the University Pierre and Marie Curie (Paris), where he studied nitroxide-mediated polymerization in homogeneous and aqueous dispersed media. Then, he joined the group of Prof. David M. Haddleton at the University of Warwick (United-Kingdom), for a postdoctoral fellowship to design polymer-protein bioconjugates by controlled/living radical polymerization. In 2007, he was appointed permanent CNRS researcher in the group of Prof. Patrick Couvreur, University Paris-Sud (France), where his current research activities are focused on the controlled/living radical polymerization and on the synthesis of novel (bio)polymers and nanoparticles for drug delivery purposes. Please follow the links for more information about Julien Nicolas and his recent paper in Polymer Chemistry.

 

What was your inspiration in becoming a chemist?

I think it all started with my family as my father is a professor of Biochemistry at the University Pierre and Marie Curie, here in Paris. When I was a child, he often brought me to his laboratory; so almost from the beginning, I’ve been used to the lab environment and scientific research. Actually, this is the place where I did my first (polymer!) experiment: plunging a rubber band into liquid nitrogen… At that time, I had no clue about what was going on… Thus, quite rapidly at school, I decided I would work in chemistry. Perhaps also because during secondary school, caring teachers used to give me chemicals to do some experiments in my homemade chemistry lab at home (I think I never told my mother I distilled her perfume by the way…). Then, more seriously, I had the chance to meet great polymer chemists, such as J.-F Pierson, B. Boutevin, B. Charleux and D. M. Haddleton, who guided and inspired me in the field of polymer science.

What was the motivation behind the research in your recent Polymer Chemistry paper? (DOI: 10.1039/c1py00028d)

When Dr. Benjamin Le Droumaguet and I were writing our review about bioconjugates (DOI: 10.1039/B9PY00363K), it was astonishing to see how poor the literature was for biomaterials deriving from nitroxide-mediated polymerization. Taking into account the inherent features and main strengths of NMP, there was in my opinion a gap to fill in, especially in the field of polymer-protein bioconjugates. Then, we basically took inspiration from pioneering works in the bioconjugate area and developed a suitable bioconjugation platform via NMP, by putting together various achievements from ourselves and our colleagues (e.g., functional alkoxyamines, copolymerization with methacrylates, cytotoxicity of NMP-deriving polymers etc). In the near future, I wish to continue to develop novel biomaterials deriving from controlled/living radical polymerization, and especially from NMP.

Why did you choose Polymer Chemistry to publish your work?

When I first heard about the launch of a polymer journal from RSC, I thought it was a brilliant idea and a kind of missing link between Chem. Commun., Soft Matter and J. Mater. Chem. I really feel confident that it will soon become one of the leading polymer journals.

In which upcoming conferences may our readers meet you?

This year will be really exciting as I will be attending the International Nanomedicine Conference in Sydney and the ACS Meeting in Denver. But this time, I’m not going to miss my flight back from Australia, as I did in 2009 after the PPC11 2009!

How do you spend your spare time?

I mostly spend my spare time travelling and doing exciting road trips with my wife. Among them: Portugal, Scotland, Japan and Canada. Enjoying the breathtaking Scottish highlands and fishing for salmon in the Canadian wilderness are among my best trip memories.

Which profession would you choose if you were not a scientist?

Tough question. Actually, I would have liked to be a veterinarian or a computer programmer (my nerd side I guess!), although it is not completely disconnected from science. Otherwise, I think that a job where you create things with your hands, such as a cabinet-maker, would have suited me.

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Hot Article: How does a star chain (nanooctopus) crawl through a nanopore?

Collaborative research from Hong Kong, Greece and China has investigated the flow of star polymers through nanopores.

Ultrafiltration of star chains with different lengths and numbers of arms shows that the minimum flow rate at which the chains begin to pass through a nanopore is independent of the arm length, but is strongly affected by the total number of arms and the number that initially enter the pore. These results are expected to influence the design of non-viral polymeric carriers for transporting genes into or through organs, such as the liver or kidneys.

Interested to know more? Why not read the full article for free:  H. Ge, S. Pispas and C. Wu, Polym. Chem., 2011, DOI: 10.1039/C0PY00361A (Advance Article)

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Top Ten most-read Polymer Chemistry articles in January

The latest top ten most downloaded Polymer Chemistry articles

See the most-read papers of January 2011 here:  

Andrew B. Lowe, Polym. Chem., 2010, 1, 17-36
DOI: 10.1039/B9PY00216B
 
Xiaowei Zhan and Daoben Zhu, Polym. Chem., 2010, 1, 409-419
DOI: 10.1039/B9PY00325H
 
Guang-Zhao Li, Rajan K. Randev, Alexander H. Soeriyadi, Gregory Rees, Cyrille Boyer, Zhen Tong, Thomas P. Davis, C. Remzi Becer and David M. Haddleton, Polym. Chem., 2010, Advance Article
DOI: 10.1039/C0PY00100G
 
Francesca Ercole, Thomas P. Davis and Richard A. Evans, Polym. Chem., 2010, 1, 37-54
DOI: 10.1039/B9PY00300B
 
Benjamin Le Droumaguet and Julien Nicolas, Polym. Chem., 2010, 1, 563-598
DOI: 10.1039/B9PY00363K
 
Jiao-Tong Sun, Chun-Yan Hong and Cai-Yuan Pan, Polym. Chem., 2011, Advance Article
DOI: 10.1039/C0PY00356E
 
Neil Ayres, Polym. Chem., 2010, 1, 769-777
DOI: 10.1039/B9PY00246D
 
Jay A. Syrett, C. Remzi Becer and David M. Haddleton, Polym. Chem., 2010, 1, 978-987
DOI: 10.1039/C0PY00104J
 
Nicolas Sanson and Jutta Rieger, Polym. Chem., 2010, 1, 965-977
DOI: 10.1039/C0PY00010H
 
Kai Li and Bin Liu, Polym. Chem., 2010, 1, 252-259
DOI: 10.1039/B9PY00283A
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Polymer Chemistry Author of the week- Scott M. Grayson

Scott was born in St. Louis, MO, and graduated from Chaminade College Preparatory.  He came to Tulane for the first time to carry out Bachelors degrees in Chemistry, Mathematics, and History in 1996, and then moved to the University of Bradford where he completed a masters degree in Archaeological Chemistry under the direction of Professor Carl P. Heron in 1998.  He completed his doctoral studies in Chemistry in 2002 at the University of California, Berkeley, with Professor Jean Fréchet, developing new dendritic architectures for biological applications.  He continued his training as a post-doctoral researcher in the labs of C. Grant Willson, at the University of Texas at Austin, developing new polymer materials for photolithography and biosensing, and has been an Assistant Professor at Tulane University since 2005. Please follow the links for more information on the Grayson group and his recent paper in Polymer Chemistry.

What was your inspiration in becoming a chemist?

My first and most important scientific inspirations were my parents and older brothers.  My dad is a mass spectrometrist and my mom a Calculus teacher, so I was doomed from an early age.  In addition to some exceptionally inspiring chemistry teachers and mentors, I think my primary attraction to chemistry, rather than other sciences, is that I consider it the “mesoscience”.  Chemistry ties together the fundamental aspects of math and physics to the more complex and applied fields of the biological sciences as well as materials science and engineering.  I find exploring in this middle ground more intellectually appealing than elsewhere in the sciences.

What was the motivation behind the research in your recent Polymer Chemistry paper?

The field of cyclic polymers is one of the under-explored frontiers in polymer chemistry.  Although there are some tremendously valuable early studies in this field, recent synthetic advances are opening up the field to enable more in-depth explorations.  In addition to providing invaluable fundamental insight into polymer structure-property relationships, recent studies suggest that the unique physical and biological properties of cyclic polymers will lead to applications that justify these research efforts.  Jessica’s review highlights some of these issues as they relate specifically to cyclic polyesters.

Why did you choose Polymer Chemistry to publish your work?

I believe Polymer Chemistry fills a void which has existed in the journal geography for some time and therefore is poised from its onset to be a high impact and broadly relevant journal.

At which upcoming conferences may our readers meet you?

I will be helping to organize the International Dendrimer Conference (IDS7) in Washington, DC (26 June – 1 July 2011), and attending the American Society for Mass Spectrometry meeting in early June (Denver).

How do you spend your spare time?

Ha!  I am coming up for tenure at Tulane University next year, so this is a moot question.  But I do try to run regularly to keep myself healthy (mentally as much as physically) and spend every other spare moment with my fiancée.

Which profession would you choose if you were not a scientist?

I actually studied Archaeological Chemistry in the UK before pursuing my PhD in Chemistry with Jean Fréchet, so if I won the lottery I might become an archaeologist.  However, I would limit myself to studying a civilization in some place warm that also has fantastic food and culture, like the Romans/Italy or the Mayans/Yucatan.   (You now see why I live in New Orleans.)

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Video Interview: Bert Klumperman talks to Polymer Chemistry

Bert Klumperman talks to Polymer Chemistry about the inspiration behind his work.

Bert Klumperman talks to Polymer Chemistry

Watch the full interview on YouTube.

Interested to know more? Why not read Bert Klumperman’s review on Mechanistic considerations on styrene–maleic anhydride copolymerization reactions.

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