Author Archive

Titanate cigarette filter

Cigarette in a handChinese researchers have shown for the first time that nanomaterials made from titanium dioxide (TiO2) can be used in cigarette filters to significantly reduce the amount of harmful chemicals inhaled by smokers. They say it offers a cheaper and safer alternative than using carbon-based nanomaterials and show potential for use in other filtering devices including gas masks and air purification systems. 

Current cigarette filters are made from cellulose acetate, which absorbs some of the toxic and carcinogenic compounds present in tobacco smoke, including tar, nicotine, polycyclic aromatic hydrocarbons and tobacco-specific nitrosamines. In recent years, scientists have attempted to improve standard filters by adding nanomaterials, including carbon nanotubes or mesoporous silica, to capture more of these chemicals. But these experimental methods remain expensive and could pose unknown health risks. 

Now, Mingdeng Wei’s lab at Fuzhou University in Fujian province, together with colleagues at the Fujian Tobacco Industrial Corporation, Xiamen, have found that titanate nanosheets and nanotubes can filter tobacco smoke. ‘A great range of harmful compounds including tar, nicotine, ammonia, hydrogen cyanide, selected carbonyls and phenolic compounds can be reduced efficiently,’ says Wei. 
Intrigued? Read the full news story in Chemistry World and download the ChemComm communication.
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ChemComm Emerging Investigator Lectureship – winner announced

On behalf of the ChemComm Editorial Board, I am delighted to announce that Dr Scott Dalgarno (Heriot Watt University, Edinburgh, UK) has won the inaugural ChemComm Emerging Investigator Lectureship.

This annual award recognises an emerging scientist in the early stages of their independent academic career. The Editorial Board commended Dr Dalgarno’s contributions to the field of supramolecular chemistry, in particular the assembly and properties of calixarenes.  

Dr Dalgarno will present his award lecture, entitled ‘Metal-Organic Calixarene Assemblies’, at the following locations:

For more details about these lectures, please contact ChemComm Editor, Robert Eagling.

To find out more about Dr Dalgarno’s research, read these recent ChemComm articles:
Calix[4]arene supported clusters: a dimer of [MnIIIMnII] dimers
Stephanie M. Taylor, Ruaraidh D. McIntosh, Christine M. Beavers, Simon J. Teat, Stergios Piligkos, Scott J. Dalgarno and Euan K. Brechin, Chem. Commun., 2011, 47, 1440-1442

Calixarene supported enneanuclear Cu(II) clusters
Georgios Karotsis, Stuart Kennedy, Scott J. Dalgarno and Euan K. Brechin, Chem. Commun., 2010, 46, 3884-3886

Magnetism in metal–organic capsules
Jerry L. Atwood, Euan K. Brechin, Scott J. Dalgarno, Ross Inglis, Leigh F. Jones, Andrew Mossine, Martin J. Paterson, Nicholas P. Power and Simon J. Teat, Chem. Commun., 2010, 46, 3484-3486

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Antonio Echavarren joins the ChemComm Editorial Board

Antonio EchavarrenOn behalf of the ChemComm Editorial Board, I am delighted to welcome Professor Antonio Echavarren as the new ChemComm Associate Editor for organic chemistry and catalysis.

Professor Echavarren is Group Leader at the Institute of Chemical Research of Catalonia (ICIQ) in Tarragona, Spain. His research focuses on developing new catalytic methods based on the organometallic chemistry of transition metals as well as synthesing natural products and polyarenes.

Professor Echavarren’s editorial office is now open for submissions, welcoming urgent communications highlighting the latest advances in organic chemistry and catalysis.

Find out more about Professor Echavarren’s research on gold catalysis by reading these exciting articles:

A multipurpose gold(I) precatalyst
Mihai Raducan, Carles Rodríguez-Escrich, Xacobe C. Cambeiro, Eduardo C. Escudero-Adán, Miquel A. Pericàs and Antonio M. Echavarren, Chem. Commun., 2011, 47, 4893-4895

Mechanism of the gold-catalyzed cyclopropanation of alkenes with 1,6-enynes
Patricia Pérez-Galán, Elena Herrero-Gómez, Daniel T. Hog, Nolwenn J. A. Martin, Feliu Maseras and Antonio M. Echavarren, Chem. Sci., 2011, 2, 141-149

Are you an organic chemist based in North America? Submit your research to Michael Krische, ChemComm North American Associate Editor for organic chemistry.

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Antibody acts as rudder to steer DNA into a pore

Scientists from China and Canada have studied the effect of a DNA-binding antigen-binding fragment (Fab) of an antibody on the translocation of a DNA polymer. Both poly(dT)45:Fab HED10 and poly(dT)45 produce unique double step current traces, which were analysed in detail to get information about the translocation events.

Representation of an α-HL pore and the mechanism for the poly(dT)45 specific binding with Fab HED10. A biological α-HL nanopore is embedded in a lipid bilayer. The narrowest section of α-HL is 1.4 nm. The potential across the bilayer membrane is applied through Ag/AgCl electrodes. In 10 mM Tris-HCl (pH = 7.8) buffer, the antibody recognizes four consecutive thymine residues of poly(dT)45.

The results have important implications for understanding the translocation behaviour of polymers, which could help to develop nanopore biosensors with high sensitivity and specificity, says Yitao Long, from East China University of Science and Technology. In particular, the addition of polymer-binding antibodies may facilitate the use of nanopores in sequencing technologies.

The presence of the FAB HED10 decreases the time of the first level of the step but not the second. The Fab appears to behave as a rudder, which significantly decreases the energy barrier for poly(dT)45 translocation. A more rigid or extended conformation of poly(dT)45 would decrease the time required to find the entrance to the narrow constriction in the pore. The entropic barrier required to linearise the DNA strand may be the dominant contribution to the entire energy barrier.

Find out more by downloading the communication, recently published in ChemComm.

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Call for communications: catalytic C–C bond formation via late transition metals

Michael KrischeChemComm Associate Editor Michael Krische is delighted to announce a forthcoming web themed issue:

New advances in catalytic C–C bond formation via late transition metals

Guest editor: Michael Krische (University of Texas at Austin)

Submission deadline: 30th September 2011

We are now welcoming submissions for this web theme, which will be a celebration of current achievements and future perspectives in this exciting field of research.

All manuscripts will undergo strict peer review and should be very important and conceptually significant in accord with the ChemComm mandate.

Publication of the peer-reviewed articles will occur without delay to ensure the timely dissemination of the work. The articles will then be assembled on the ChemComm website as a web-based thematic issue, to permit readers to consult and download individual contributions from the entire series.

Communications for this web theme can be submitted anytime from now until 30th September using our web submission system. Please add the phrase ‘catalytic C–C bond formation’ in the comments to the editor field.

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Nanoparticles help reveal hidden fingerprints

Criminal investigations may benefit from new forensic methods based on nanoparticles. A technique using gold nanoparticles in combination with antibodies has shown promising results for enhancing fingerprints that are over a week old.

Fingerprinting, first reported in the 19th century, is still the primary source of evidence used in crime scene investigation and new methods for improving fingerprint visualisation remain in demand. Unseen (latent) fingerprints can be revealed using chemical treatments that target molecules likely to be deposited in fingerprints, such as those in hair follicle secretions.

Xanthe Spindler at the University of Technology Sydney in Australia and colleagues now report a technique that targets amino acids – present ubiquitously in sweat and thus in most fingerprints. They linked amino acid-binding antibodies to gold nanoparticles and applied them to fingerprints. To develop and image the prints, they used red fluorescent secondary antibodies that would stick to the nanoparticle-bound antibodies.

Antibody structures
Antibodies bound to nanoparticles can bind to amino acids in fingerprints that are over 12 months old

 Read the full news story in Chemistry World and Spindler’s ChemComm communication to find out more.

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A Sustainable Global Society: How Can Materials Chemistry Help?

A high profile white paper A Sustainable Global Society: How Can Materials Chemistry Help? was launched internationally on 27 March.

The output of the Chemical Sciences and Society Summit (CS3) 2010, which took place in London, September 2010, outlines five key areas in which materials chemists, through collaboration with other scientists, industry and policy makers, can seize exciting opportunities to address global challenges. This project was driven by the RSC and is a collaboration between the chemical societies of China, Germany, Japan, the US, the UK and national funding bodies. Around 30 leading materials chemists from the participating nations participated in CS3 2010 and the white paper is a reflection of the outcome of the summit, in particular their view of the future direction for materials chemistry.

View the official website of the white paper.

Read the 27 March press release.

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RSC Publishing Recognises Outstanding ChemComm Achievements in China

This week Dr James Milne (RSC Publishing) presented a certificate of achievement to Professor Hongjie Zhang, at Changchun Institute of Applied Chemistry. 

Professor Zhang was recognised for his prolific published research over the last year. RSC has published 17 of Professor Zhang’s papers – making him the most successful author from China during the year and three of these papers were published in ChemComm

Read Professor Zhang’s excellent work published in ChemComm: 

High intensity focused ultrasound and redox dual responsive polymer micelles
Yongwen Li, Rui Tong, Hesheng Xia, Hongji Zhang and Juan Xuan, Chem. Commun., 2010, 46, 7739-7741 (DOI: 10.1039/C0CC02628J)

Selective synthesis of dibenzo[a,c]cyclooctatetraenes via palladium-catalyzed [4+4] cyclic homocoupling of borylvinyl iodobenzene derivatives
Hui-jun Zhang, Junnian Wei, Fei Zhao, Yun Liang, Zitao Wang and Zhenfeng Xi, Chem. Commun., 2010, 46, 7439-7441 (DOI: 10.1039/C0CC02380A)

Making a [Co24] metallamacrocycle from the shuttlecock-like tetranuclear cobalt-calixarene building blocks
Yanfeng Bi, Guancheng Xu, Wuping Liao, Shangchao Du, Xinwu Wang, Ruiping Deng, Hongjie Zhang and Song Gao, Chem. Commun., 2010, 46, 6362-6364 (DOI: 10.1039/C0CC01844A)

Dr Milne and Dr Daping Zhang (RSC Publisher, China) are on a tour of China where they will visit seven universities/institutes and four companies in Beijing, Changchun, Shanghai and Xiamen.

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New tool for speeding up porous materials discovery

A new tool (Infrasorb-12) for screening porosity has been developed by scientists in Germany. The tool identifies high surface area materials in a very short time with high accuracy.  The researchers say that Infrasorb-12 development will speed up the discovery of new porous materials significantly and broaden the wide range of materials suitable for gas storage, selective adsorption, catalysis, and life science applications.

Further information:
High-throughput screening: speeding up porous materials discovery
Philipp Wollmann, Matthias Leistner, Ulrich Stoeck, Ronny Grünker, Kristina Gedrich, Nicole Klein, Oliver Throl, Wulf Grählert, Irena Senkovska, Frieder Dreisbach and Stefan Kaskel, Chem. Commun., 2011, DOI: 10.1039/C1CC10674K

Also of interest:
Modifying MOFs: new chemistry, new materials
Seth M. Cohen, Chem. Sci., 2010, 1, 32-36 (DOI: 10.1039/C0SC00127A)

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Carbon dioxide adsorption in porous phosphine coordination material

US, UK and Korean scientists have made a new porous phosphine coordination material, PCM-11. The material is an unusual 8,4-connected coordination polymer with an open 3-D pore structure, say the researchers. 

The team formed the material by reacting Mg(II) with tris(para-carboxylato)triphenylphosphine oxide. The highly ionic nature of the metal–ligand bonding results in excellent thermal stability upon desolvation (>460 ºC), they say. PCM-11 is easily activated for small molecule sorption at low temperature without the requirement for solvent pre-exchange.  It adsorbs 47.5 wt% CO2 at 11.6 bar and 30ºC.

Find out more in the ChemComm communication:
High capacity CO2 adsorption in a Mg(II)-based phosphine oxide coordination material
Alisha M. Bohnsack, Ilich A. Ibarra, Peter W. Hatfield, Ji Woong Yoon, Young Kyu Hwang, Jong-San Chang and Simon M. Humphrey, Chem. Commun., 2011, DOI: 10.1039/C1CC10754B

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