Hydride transfer from dihydronicotinamide adenine dinucleotide (NADH) analogues to manganese(V)–oxo
corroles has been shown for the first time by scientists in Korea and Japan. Wonwoo Nam and colleagues at Ewha Womans University collaborated with Shunichi Fukuzumi from Osaka University to show that the reaction proceeds via proton-coupled electron transfer, followed by rapid electron transfer.
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