RSC Advances Science Communications – Hydrogels: The Smart Solution for Energy-Efficient Windows in Sustainable Buildings

Harnessing solar energy through chemical bonds, as nature achieves via photosynthesis, represents a pivotal strategy for addressing global energy challenges. Efficiently splitting water to produce hydrogen—a clean fuel whose only byproduct is water—could revolutionize energy production. Achieving this requires the development of a cost-effective water-splitting cell, comprising stable semiconductors designed to directly catalyze water splitting at the semiconductor surface. The quest for effective solar-to-hydrogen production has driven significant research into developing stable and efficient semiconductors that are active under visible light.

On this occasion, we have, for the first time, explored the potential of a tetragonal dendritic nanostructured TiVO₄ photoelectrochemical (PEC) catalyst, synthesized through spray pyrolysis [1]. The resulting photoanode demonstrated an optical band gap of approximately 2.18 eV and exhibited a stable photocurrent density of 0.080 mA cm⁻² at 1.23 V, which remained consistent for up to 110 minutes. The optimization process revealed that a substrate temperature of 250 °C, coupled with an annealing temperature of 600 °C, was critical to achieving a single-phase TiVO₄ photoanode. Moreover, the sprayed TiVO₄ photoanode maintained excellent stability for up to 6000 seconds. Notably, the photocurrent density showed a significant increase from 73 to 400 mA cm⁻² at 1.8 V vs. RHE as the annealing temperature was elevated from 500 to 600 °C. These findings suggest that TiVO₄, as an underlying photo-absorbing semiconductor, addresses the challenge of inefficient photoanodes for water-splitting reactions, offering enhanced material performance and achieving long-term passivation without compromising stability.

Check out the article, published in RSC Advances:

Fabrication of TiVO4 photoelectrode for photoelectrochemical application

Manal Alruwaili, Anurag Roy, Srijita Nundy and Asif Ali Tahir
RSC Adv., 2022,12, 34640-34651

About the Web Writer:

Dr. Anurag Roy is a Doctor in Chemical Sciences and is currently an early career researcher in Renewable Energy at the University of Exeter, Cornwall Campus, UK. His research expertise lies in material design, synthesis, and characterization, with a focus on advancing solar energy technologies. With a strong background in both materials chemistry and materials engineering, he specializes in creating custom-designed nanoscale materials. Dr. Roy is also passionate about organizing and participating in science outreach and dissemination activities. You can connect with him on LinkedIn under his name or on X (formerly Twitter) at @Anuroyrag.

Submit to RSC Advances today! Check out our author guidelines for information on our article types or find out more about the advantages of publishing in a Royal Society of Chemistry journal.

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3rd Asian Conference on Molecular Magnetism- RSC Poster Prize Winner

The 3rd Asian Conference on Molecular Magnetism took place in Busan, Republic of Korea on 1st- 4th September 2024. The conference brought together researchers working in molecular magnetism, an interdisciplinary field connecting chemistry, physics and materials science. A range of early career researchers and students presented their cutting-edge molecular magnetism research. In addition to a plenary speaker the conference included both short talks and poster presentations.

We are delighted that the conference was a success and RSC Advances was pleased to have sponsored a poster prize. We would like to wish a huge congratulations to the poster prize winners, Dabeen Hong and Mikhail S. Batov.

Submit to RSC Advances today! Check out our author guidelines for information on our article types or find out more about the advantages of publishing in a Royal Society of Chemistry journal.

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August 2024 RSC Advances Review Articles

Welcome to August’s Review round up!

Every month we update our 2024 Reviews in RSC Advances collection to showcase all of the review articles published in RSC Advances in 2024. Don’t forget to come back next month to check out our latest reviews.

We hope you enjoy reading and as always, all of our articles are open access so you can easily share your favourites online and with your colleagues.

Explore the full collection!

 

Browse a selection of our August reviews below:

NIR-induced photothermal-responsive shape memory polyurethane for versatile smart material applications
Ki Yan Lam, Choy Sin Lee and Rachel Yie Hang Tan
RSC Adv., 2024, 14, 24265-24286

Metal-based non-enzymatic systems for cholesterol detection: mechanisms, features, and performance
M. Ameen Sha, P. C. Meenu, H. Haspel and Z. Kónya
RSC Adv., 2024, 14, 24561-24573

Recent progress in high-voltage P2-NaxTMO2 materials and their future perspectives
Manni Li, Weiqi Lin, Yurong Ji, Lianyu Guan, Linyuan Qiu, Yuhong Chen, Qiaoyu Lu and Xiang Ding
RSC Adv., 2024, 14, 24797-24814

Water-soluble Schiff base ligands and metal complexes: an overview considering green solvent
Md. Tariqul Islam, Nur Amin Bitu, Bijan Mohon Chaki, Md. Jakir Hossain, Md. Ali Asraf, Md. Faruk Hossen, Md. Kudrat-E-Zahan and Md. Abdul Latif
RSC Adv., 2024, 14, 25256-25272

A comprehensive review on sustainable surfactants from CNSL: chemistry, key applications and research perspectives
Ashokkumar Veeramanoharan and Seok-Chan Kim
RSC Adv., 2024, 14, 25429-25471

Unveiling the photocatalytic potential of graphitic carbon nitride (g-C3N4): a state-of-the-art review
Mahmoud A. Ahmed, Safwat A. Mahmoud and Ashraf A. Mohamed
RSC Adv., 2024, 14, 25629-25662

Interaction of anionic Fe3O4 nanoparticles with lipid vesicles: a review on deformation and poration under various conditions
Mohammad Abu Sayem Karal, Md. Masum Billah, Tawfika Nasrin and Md. Moniruzzaman
RSC Adv., 2024, 14, 25986-26001
 

Submit to RSC Advances today! Check out our author guidelines for information on our article types or find out more about the advantages of publishing in a Royal Society of Chemistry journal.

Keep up to date with our latest Popular Advances, Reviews, Collections & more by following us on Twitter. You can also keep informed by signing up to our E-Alerts.

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RSC Advances Outstanding Student Paper Awards 2023

We are delighted to announce the winners for the RSC Advances Outstanding Student Paper Awards 2023. RSC Advances presents an annual award series to recognise the hard work of students within the chemistry community.

All research articles published in RSC Advances in 2023 were considered. In order to be eligible for this award, the first author or co-first author must have been a student at the time of carrying out the research. From the support of corresponding authors, we received over 700 nominations highlighting the incredible talent and potential within the next generation of chemists. It is particularly inspiring to learn about the exceptional work from a diverse range of research fields and countries, a testament to the quality of research and curiosity throughout the community.

The nominations were shortlisted based on a number of criteria, and the winning papers were then selected by our Editorial Board and Associate Editors.

Below, we highlight the winner of each subject category, and the research paper that won them the award. Please join us in congratulating all of our winners for their exceptional achievement. We look forward to witnessing their continued growth and impact as they embark on a promising career in the field of chemistry.

Analytical chemistry

Kumar Shwetabh, Indian Institute of Technology (Indian School of Mines), India

 

Kumar is recognised for his outstanding contribution to the research presented in:

Synthesis and upconversion emission studies of CaYF5:Ho3+/Yb3+ phosphor and its applications in optical thermometry, fingerprint detection, and security ink 

Kumar Shwetabh, from Bihar, India, completed his B.Sc. and M.Sc. in Physics in the years 2015 and 2018 respectively, from Lalit Narayan Mithila University, India. He joined the Indian Institute of Technology (Indian School of Mines) for a PhD, and completed his PhD in July 2024 under the supervision of Prof. Kaushal Kumar at the Department of Physics, IIT(ISM) Dhanbad, India. During his PhD, he explored various rare earth-doped nanomaterials for upconversion-based multifunctional applications via, biomedical, optical thermometry, forensics, and security applications. His work is mainly focussed on rare earth-doped fluoride-based materials viz, NaYF4, NaGdF4, LiYF4, CaYF5, and KYF4 nanoparticles. Apart from academics, he likes to read books and play cricket.

Biological and Medicinal Chemistry

Mateusz Kozarski, University of Warsaw, Poland

 

Mateusz is recognised for his outstanding contribution to the research presented in:

Towards superior mRNA caps accessible by click chemistry: synthesis and translational properties of triazole-bearing oligonucleotide cap analogs 

Mateusz Kozarski completed his B.Sc. in Molecular Biophysics at the University of Warsaw in 2016, focussing on the application of copper(I)-catalysed alkyne-azide cycloaddition to synthesise novel 7-methylguanosine nucleotide analogs modified at the 5’ position. Continuing at the University of Warsaw, he completed his MSc. in Molecular Biophysics in 2018, exploring new molecular tools to investigate the biological role of the enzyme cNIIIB through the design, synthesis, and evaluation of novel 7-methylguanosine 5’-monophosphate analogs.
His pursuit of knowledge led him to a PhD programme at the Faculty of Physics, University of Warsaw, and the Centre of New Technologies, University of Warsaw in Chemical Biology and Biophysical Chemistry Laboratory. His doctoral research, supervised by Joanna Kowalska, PhD, DSc, and Prof. Jacek Jemielity, focussed on the synthesis and evaluation of nucleoside-based molecular tools for monitoring mRNA-related biological processes, where he co-authored three scientific publications on 5’-end mRNA metabolism.
From 2022 to 2023, he worked in industry as a scientist at Celon Pharma (Poland), where he was involved in research and development in the mRNA bioengineering group, working on RNA synthesis and purification. Mateusz is currently a Senior Scientist at etherna (Belgium), biotechnological company which focusses on customizable Lipid Nano Particles (cLNPs), supported by RNA chemistry and process technologies, here, Mateusz is responsible for optimising processes of RNA production and purification.

Catalysis

Respati K. Pramadewandaru, University of Ulsan, Republic of Korea

 

Respati is recognised for his outstanding contribution to the research presented in:

Synergistic effect of bimetallic Pd–Pt nanocrystals for highly efficient methanol oxidation electrocatalysts 

Respati Kevin Pramadewandaru is an Assistant Professor in the Department of Materials and Metallurgical Engineering at Sepuluh Nopember Institute of Technology (ITS), Indonesia. He earned his Ph.D. in Nano-Energy Chemistry from the University of Ulsan, South Korea (2024), where he also completed his master’s degree. His research focuses on material synthesis, characterisation, and applications, particularly in electrochemical systems and nanotechnology.

Respati has published several papers in reputable journals and has received awards such as the Best Paper Presentation at the International Joint Symposium of Ulsan University and Fukuoka University Conferences in 2022. He is actively involved in professional organizations, including the Indonesian Engineers Association (PII), collaborates with Nanyang Technological University (NTU) on hydrogen energy projects (REIDI ITS) and fuel cell team with NTU-Univeristas Indonesia (UI).

Computational & Theoretical Chemistry

Songyuan Yao, University of Oklahoma, USA

 

Songyuan is recognised for his outstanding contribution to the research presented in:

Machine learning based implicit solvent model for aqueous-solution alanine dipeptide molecular dynamics simulations 

Sonyuan Yao graduated with a Ph.D. from Dr. Yihan Shan’s group at the University of Oklahoma. His primary research focus during his studies was on utilising machine learning to assist in molecular dynamics simulations. In addition to his work in simulation and dry lab research, he also engaged in wet lab activities, which enhanced my understanding of drug discovery and molecular modelling.

Energy Chemistry

Naufal Hanif Hawari, A*STAR (Agency for Science, Technology and Research), Singapore

 

Naufal is recognised for his outstanding contribution to the research presented in:

Understanding SEI evolution during the cycling test of anode-free lithium-metal batteries with LiDFOB salt 

Naufal Hanif Hawari earned his BSc in 2020 and MSc in 2023, both in Materials Science and Engineering from Institut Teknologi Bandung, Indonesia. His research focusses on developing high-energy density batteries, including silicon anodes and lithium metal batteries under the supervision of Dr. Afriyanti Sumboja. During the final year of his master’s program, he received the Singapore Pre-Graduate Award (SIPGA), allowing him to spend five months at the Institute of Materials Research and Engineering (IMRE) at the Agency for Science, Technology, and Research (A*STAR) in Singapore. Additionally, he was awarded the Singapore International Graduate Award (SINGA) from A*STAR to pursue a 4-year PhD program at Nanyang Technological University (NTU) under the supervision of Dr. Ning Ding and Prof. Yan Qingyu.

Environmental Chemistry

       

 Valtteri Suorsa, Miho Otaki and Topi Suominen, University of Helsinki, Finland

Valtteri, Miho and Topi are recognised for their outstanding contribution to the research presented in:

Anion exchange on hydrous zirconium oxide materials: application for selective iodate removal 

Valtteri Suorsa obtained his PhD in CHEMS doctoral school of University of Helsinki, Finland in 2023. Within his PhD studies he and his co-authoring colleagues in associate professor Risto Koivula’s Ion exchange for nuclear waste treatment and for recycling research group focused on different ion exchange materials suitable for purification of radioactive waste. His doctoral thesis, Selective iodate removal using zirconium oxides, summarises his research regarding the utilization of zirconium oxides for the selective purification of solutions containing radioactive iodine. Currently, he works as a senior inspector at Finnish Radiation Safety Authority (STUK) and his work focuses on the radiochemical and ICP-MS analytics of radionuclides.

Miho Otaki earned her bachelor’s degree in Chemistry from the University of Tokyo and pursued her master’s degree in Radiochemistry at the University of Helsinki. Her master’s research involved the synthesis and characterization of ion-exchange sorbents for the removal of radioactive substances. Currently, she is a doctoral researcher at the University of Helsinki, working with Dr. Risto Koivula. Her ongoing project is focused on developing highly selective methods for the separation of Group 3 and f-block elements, utilising inorganic-organic hybrid sorbents and selective precipitation techniques.

Topi Suominen is a PhD researcher at the University of Helsinki, working in the ion exchange group of the radiochemistry laboratory. He earned his master’s degree in chemistry and molecular sciences from the University of Helsinki in 2019. Originally focusing on environmental chemistry during his master’s, he moved into materials research in the ion exchange group under the supervision of Risto Koivula in 2020 when he started his PhD. Currently, his research interests include separation of lanthanides and synthesis of mesoporous metal oxides.

Inorganic Chemistry

Anderson Moledo Vicente Guedes, Federal University of Rio de Janeiro, Brazil

 

Anderson is recognised for his outstanding contribution to the research presented in:

Valence tautomerism in a cobalt–dioxolene complex containing an imidazolic ancillary ligand 

Anderson Moledo Vicente Guedes attended chemical engineering college and obtained a bachelor’s degree in 2016. Still in 2016, he entered the master’s course in Chemistry at the Federal University of Rio de Janeiro, Brazil, under the supervision of professors Giordano Poneti and Rafael Alves Allão Cassaro. Here, he worked on the synthesis and the magnetic properties of transition metal complexes seeking to obtain the phenomenon of valence tautomerism. After completing his master’s degree in 2018, he joined the doctorate course in 2019 in the same University. During his doctorate, Anderson worked to increase the complexity of systems that exhibited the phenomenon of valence tautomerism and used various techniques to study the complexes he developed, having contact with techniques such as synchrotron x-ray absorption spectroscopy, x-ray photoelectron spectroscopy, magnetometry and others. Anderson is currently in the process of completing his doctorate and, concomitantly, using part of the knowledge acquired during postgraduate studies in a profession as a forensic expert.

Materials Chemistry

Kun-Lin Wu, University of Washington (UW), USA

 

Kun-Lin is recognised for his outstanding contribution to the research presented in:

Pharmacological regulation of protein-polymer hydrogel stiffness 

Kun-Lin Wu is a PhD candidate in chemical engineering at the University of California, Davis, under the direction of Prof. Ambarish Kulkarni. His current research interest is using computational modelling to investigate CO2 adsorption in microporous materials for carbon reduction application. Before his PhD studies, he was a master’s student at the University of Washington under the guidance of Prof. Cole DeForest. He employed protein engineering and molecular biology techniques to design and synthesise biomaterials for drug delivery application. His research interest is developing and designing materials from an atomistic scale with applications in diverse domains, including carbon capture, nanoscience and biomaterials.

Nanoscience

Ashima Makhija, Maharshi Dayanand University, India

 

Ashima is recognised for her outstanding contribution to the research presented in:

Green emission from trivalent cerium doped LaAlO3/MgO nano-composite for photonic and latent finger printing applications 

Ashima Makhija is a Research Scholar in the Department of Physics at Maharishi Dayanand University, India. Currently, she is pursuing a Ph.D. on the topic “Synthesis and Characterization of Rare-earth metal doped nanomaterials.” Ashima’s research interest lies in enhancing luminescence and the photocatalytic properties of nanomaterials, contributing to advancements in Materials Science and Nanotechnology. Under the expert guidance of Prof. Rajesh Punia, she embarked on a journey to explore the suitability of luminescent materials for LEDs and latent fingerprint identification applications. Her research work has led to the publication of seven research papers in peer-reviewed international journals and one in conference proceedings. Ashima has actively participated in numerous international and national conferences, workshops, seminars, and webinars that have enriched my research experience. She has received the Best Poster Presentation Awards at 2 National Conferences, i.e. RAMAN-2023 and FMS-2024. Her academic achievements include securing the University 3rd rank in graduation and qualifying GATE 2018. She has also been awarded the POSE fellowship at graduation and post-graduation levels.

Organic Chemistry

Margarita Damai, London Metropolitan University, UK

 

Margarita is recognised for her outstanding contribution to the research presented in:

Crafting mono- and novel bis-methylated pyrroloquinoxaline derivatives from a shared precursor and its application in the total synthesis of marinoquinoline A

Margarita Damai is a second-year student at London Metropolitan University pursuing a BSc Biomedical Sciences degree. Her research work primarily revolves around synthesising complex molecular structures and their applications in medicinal chemistry.
She is an active individual and has participated in several research conferences to represent her work. Apart from research, Margarita is heavily involved in democracy, particularly within the LondonMet Students Union, where she served one year as a sabbatical officer.

Physical Chemistry

Maria Dekermenjian, INRS-EMT, Canada

 

Maria is recognised for her outstanding contribution to the research presented in:

Raman spectroscopy investigation of magnesium oxide nanoparticles 

Since high school, Maria Dekermenjian has found an interest and passion in science, especially in mathematics and physics.  She completed a bachelor’s degree in physics at University of Montreal (2005-2008).  Her real contact with research was during the three summer internships (financed by NSERC and RQMP scholarships) with her Physics professors during her bachelor’s degree. She wanted to learn more about research, so she pursued with a master’s in physics in the group of Prof Richard Martel at the same university from 2008 to 2011. Her thesis focussed on far infrared properties of carbon nanotube films. After finishing her master’s thesis, she worked as a private teacher alongside immersing herself in entrepreneurship. She wanted to learn more about nanotechnology and more importantly perfecting her research skills. Therefore, in 2017, she started a PhD at EMT-INRS (Varennes, Canada) in the group of Prof Andreas Ruediger co-supervised by Prof Alexandre Merlen. Maria graduated in 2024, her thesis being entitled “Raman spectroscopy study of magnesium oxide nanoparticles”. She co-supervises research activities in the same field. Thus far, she has 10 publications in highly impacted journals.

 

Please join us in congratulating all of our winners for their exceptional achievement. We extend our sincere gratitude to all the authors for their contributions, as well as to the editors and referees for their collaboration, which has resulted in this high-quality series.

We will continue to recognise outstanding student contributions and plan to give out these awards each year. If you published a research article in 2024, or go on to publish with the journal in the future, and would like to recognise a significant contribution made by a student, we invite them to join us in future editions of this series. Please email advances-rsc@rsc.org for more information.

 

Submit to RSC Advances today! Check out our author guidelines for information on our article types or find out more about the advantages of publishing in a Royal Society of Chemistry journal.

Keep up to date with our latest Popular Advances, Reviews, Collections & more by following us on Twitter. You can also keep informed by signing up to our E-Alerts.

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6th International Symposium on Silsesquioxanes-based Materials – Poster prize winners

The 6th International Symposium on Silsesquioxanes-based Materials was held in Poznań, Poland, between 8-11th July 2024. RSC Advances, New Journal of Chemistry and Dalton Transactions were delighted to award poster prizes to three outstanding researchers in the field.

Congratulations to Kamila Majewska-Smolarek, Dawid Frackowiak and Manisa Kongkaew!

For best poster presentation, sponsored by RSC Advances – Kamila Majewska-Smolarek

Kamila Majewska-Smolarek, Centre of Molecular and Macromolecular Studies Polish Academy of Sciences, Poland

Thiolactone derivatives of polyhedral silsesqiuioxanes synthesis, structure and thermal properties

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

For best short lecture presentation, sponsored by Dalton Transactions – Dawid Frąckowiak

Dawid Frąckowiak, Adam Mickiewicz University, Poland

Grinding the Cubes ─ Multigram Solid State Synthesis of Silsesquioxane Amic Acids

 

 

 

 

 

 

 

 

 

 

 

 

 

 

For best short lecture presentation, sponsored by New Journal of Chemistry – Manisa Kongkaew

Manisa Kongkaew, ICGM, University of Montpellier, CNRS, ENSCM, Montpellier, France

Synthesis of Fine tuned Hollow Periodic Mesoporous Organosilica Nanoparticles (HPMO Nps) for Drug Delivery

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Congratulations to all our winners!

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Open call for papers – Greening the Exposome

RSC Advances is delighted to announce a new themed collection entitled Greening the Exposome: Eco-Friendly Analytical Methods for Monitoring Chemical Exposures.

This collection is Guest Edited by Prof. Attilio Naccarato (University of Calabria, Italy) and Prof. Dr. Milena Horvat (Jožef Stefan Institute, Slovenia).

We welcome your submission to the series!

The exposome, encompassing all environmental exposures throughout life, plays a crucial role in human health and disease. Monitoring chemical exposures from various sources, including the environment and food, is essential for understanding their impact on health outcomes. However, traditional analytical methods often rely on harsh chemicals, generate hazardous waste, and contribute to environmental burdens.

RSC Advances is pleased to announce a themed collection dedicated to innovative and eco-friendly analytical methods for monitoring chemical exposures within the exposome framework. This special issue aims to showcase recent advancements in sustainable analytical strategies for assessing human exposure to environmental and foodborne contaminants, offering valuable insights that can benefit the fields of epidemiology, clinical chemistry, and environmental medicine.

Topics of interest include, but are not limited to:

1. Advancements in eco-friendly analytical techniques: Innovative analytical methods for exposome analysis designed to minimize environmental impact, including the use of green solvents, sustainable sample preparation techniques, and miniaturized analytical platforms.

2. Microfluidics and Lab-on-a-Chip technologies: Application of Microfluidics and Lab-on-a-Chip technologies for high-throughput analysis of environmental and biological samples to rapidly detect contaminants and biomarkers.

3. High-throughput screening for exposome-wide chemical analysis: Innovative approaches for conducting exposome-wide chemical analysis, including high-throughput screening methods and advanced data processing techniques for mapping exposure profiles and potential health risks.

4. Use of novel sensors: Implementation of biosensors, in-situ sensors, on-site, and personal sensing devices for monitoring exposures.

5. Analytical challenges and solutions: Addressing key analytical challenges with exposome investigations, such as sample complexity, matrix effects, and data integration, with a focus on novel analytical solutions and methodologies.

6. Quality assurance and quality control (QA/QC) procedures: Emphasizing the critical role of robust QA/QC procedures to ensure the reliability and validity of exposome data. Topics could include calibration strategies, method validation, proficiency testing, and inter-laboratory comparisons, metrological challenges, and analytical data interpretation in line with the FAIR (Findable, Accessible, Interoperable, and Reusable) data principles.

Authors are encouraged to submit original research articles and reviews that address the theme of greening the exposome through sustainable analytical methods.

Submission deadline: 31st January 2025

Submit your article to this collection

Both Papers and Review articles will be considered for this themed collection. All submissions will be subject to an initial assessment by Associate Editors and, if suitable for the journal, they will be subject to rigorous peer review to meet the usual high standards of RSC Advances.

RSC Advances’ article processing charge (APC) is among the lowest in chemistry and waivers are also available for authors who meet the eligibility criteria outlined here. We have a number of Read & Publish deals in place with institutions, please see Chronoshub for more information on specific institutions and funders.

If you would like to submit to this themed collection the manuscript should be prepared according to our article guidelines and submitted via our online system any time before the submission deadline of 31 01 2025. During submission, authors will be asked if they are submitting for a themed collection and should include the name of the themed collection. If you would like to submit but require additional time to prepare your article, please do let us know by contacting the journal.

Submit to RSC Advances today! Check out our author guidelines for information on our article types or find out more about the advantages of publishing in a Royal Society of Chemistry journal.

Keep up to date with our latest Popular Advances, Reviews, Collections & more by following us on X. You can also keep informed by signing up to our E-Alerts.

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Mid-Year 2024 Popular Advances Articles

Welcome to our mid-year Popular Advances article round up!

Every month we update our 2024 RSC Advances Popular Advances Article Collection to showcase all of the articles selected by our reviewers and handling editors as Popular Advances in 2024. Don’t forget to come back next month to check out our latest Popular articles.

We hope you enjoy reading and as always, all of our articles are open access so you can easily share your favourites online and with your colleagues.

Explore the full collection!

 

Browse a selection of our mid-year Popular Advances articles below:

An efficient alternative to DBU in the oxathiaphospholane (OTP) method for the solid phase synthesis of P-stereodefined phosphorothioate analogs
Katarzyna Jastrzębska
RSC Adv., 2024, 14, 21174-21179

Total synthesis of [β-HIle]2-nodupetide: effect of ester to amide substitution on its antimicrobial activity
Harra Ismi Farah, Unang Supratman, Ace Tatang Hidayat and Rani Maharani
RSC Adv., 2024, 14, 21778-21785

Swietemicrolides A–D, mexicanolide-type limonoids from the bark of Swietenia macrophylla with in vitro cytotoxic and α-glucosidase inhibitory activities
Tu-Quyen Thi Tran, Duong Hoang Trinh, Binh Thi Dieu Trinh, Dzung Ngoc Bui, Lien-Hoa Dieu Nguyen and Phuong Thu Tran
RSC Adv., 2024, 14, 18608-18616

An ethyl cellulose novel biodegradable flexible substrate material for sustainable screen-printing
Elena Palmieri, Rocco Cancelliere, Francesco Maita, Laura Micheli and Luca Maiolo
RSC Adv., 2024, 14, 18103-18108

Mitigating diabetes associated with reactive oxygen species (ROS) and protein aggregation through pharmacological interventions
Giulia Bennici, Hanan Almahasheer, Mawadda Alghrably, Daniela Valensin, Arian Kola, Chrysoula Kokotidou, Joanna Lachowicz and Mariusz Jaremko
RSC Adv., 2024, 14, 17448-17460

A nonsolvolytic fluorine/LiNO3-containing electrolyte for stabilizing dynamic interfaces in Li||LiMn2O4 batteries
Tian Tang, Nyalaliska W. Utomo, J. X. Kent Zheng and Lynden A. Archer
RSC Adv., 2024, 14, 14964-14972

Gamma-irradiated stibnite thin films set a remarkable benchmark performance for photoelectrochemical water splitting
Adel Chihi
RSC Adv., 2024, 14, 12475-12495

 

 

Submit to RSC Advances today! Check out our author guidelines for information on our article types or find out more about the advantages of publishing in a Royal Society of Chemistry journal.

Keep up to date with our latest Popular Advances, Reviews, Collections & more by following us on Twitter. You can also keep informed by signing up to our E-Alerts.

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July 2024 RSC Advances Review Articles

Welcome to July’s Review round up!

Every month we update our 2024 Reviews in RSC Advances collection to showcase all of the review articles published in RSC Advances in 2024. Don’t forget to come back next month to check out our latest reviews.

We hope you enjoy reading and as always, all of our articles are open access so you can easily share your favourites online and with your colleagues.

Explore the full collection!

 

Browse a selection of our July reviews below:

Advances in gold catalyzed synthesis of quinoid heteroaryls
Adnan Majeed, Ayesha Zafar, Zanira Mushtaq and Muhammad Adnan Iqbal
RSC Adv., 2024, 14, 21047-21064

Recent progress on CO2 separation membranes
Yuheng Fan, Weichu Yu, Aibin Wu, Wenming Shu and Ying Zhang
RSC Adv., 2024, 14, 20714-20734

Cutting-edge developments in zinc oxide nanoparticles: synthesis and applications for enhanced antimicrobial and UV protection in healthcare solutions
Egwonor Loveth Irede, Raymond Femi Awoyemi, Babatunde Owolabi, Omowunmi Rebecca Aworinde, Rofiat Odunayo Kajola, Ajibola Hazeez, Ayuba Adawale Raji, Latifat Oluwatobi Ganiyu, Chimezie O. Onukwuli, Asishana Paul Onivefu and Ikhazuagbe Hilary Ifijen
RSC Adv., 2024, 14, 20992-21034

Environmental remediation approaches by nanoscale zero valent iron (nZVI) based on its reductivity: a review
Mingyue Liu, Gang Chen, Linli Xu, Zhicai He and Yuyuan Ye
RSC Adv., 2024, 14, 21118-21138

Recent developments in speciation and determination of arsenic in marine organisms using different analytical techniques. A review
Bashdar Abuzed Sadee, Yaseen Galali and Salih M. S. Zebari
RSC Adv., 2024, 14, 21563-21589

Recent developments in the synthesis and applications of terpyridine-based metal complexes: a systematic review
Syeda Fariha Kainat, Mohammed B. Hawsawi, Ehsan Ullah Mughal, Nafeesa Naeem, Abdulaziz M. Almohyawi, Hatem M. Altass, Essam M. Hussein, Amina Sadiq, Ziad Moussa, Alaa S. Abd-El-Aziz and Saleh A. Ahmed
RSC Adv., 2024, 14, 21464-21537

Bio-based resources: systemic & circular solutions for (agro)environmental services
Gabrijel Ondrasek, Cristian Meriño-Gergichevich, Carlos Manterola-Barroso, Alex Seguel Fuentealba, Sebastián Meier Romero, Radovan Savić, Sarvamangala S. Cholin and Jelena Horvatine
RSC Adv., 2024, 14, 23466-23482
 

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RSC Advances Science Communications – Lignin Carbon Dots

Carbon dots (CD) have gained significant attention amongst researchers, including Aldakhil and co-workers at King Saud University in Saudi Arabia. CDs are amorphous nanospheres < 10 nm in diameter that are prepared by carbonizing organic precursors. CDs can be doped with heteroatoms depending on the initial organic material, and they can be further modified with polymers to add functional groups to their surface. They have many properties that make them useful, such as being stable photophysically and photochemically, being soluble in water, having low toxicity, being biocompatible, and having a fluorescence (FL) emission and excitation that are highly tunable. Thus, CDs have been explored in photocatalysis, bioimaging, FL probing, and analysis.

Aldakhil et al. created CDs using lignin from date seeds (DS) as a source of carbon. The seeds, abundant agricultural by-products, are made of cellulose, hemicellulose, and lignin. The lignin was obtained by sonicating the seeds with NaOH and precipitating the desired product with dilute sulfuric acid. To synthesize CDs from the isolated lignin, a hydrothermal method was chosen because it is straightforward without needing special equipment. Furthermore, simple modifiers (H3PO4 and HCl) were explored to yield CDs with a reasonable FL quantum yield (QY). This is necessary since pure carbon nanoparticles lack FL, but it is increased by the presence of functional groups.

The optimal process to synthesize CDs with the highest FL from DS-derived lignin involved sonicating 1.50 g lignin in 18 mL 2 M NaOH, 1 mM H3PO4, and 3 mM HCl for 30 min before autoclaving for 16 h at 220 °C. The resulting product (PClCD) was dialyzed and filtered to remove impurities prior to analysis. According to TEM, these PClCDs had an average diameter of 5.08 ± 1.60 nm and XRD results suggest that an amorphous graphene oxide-like structure with several oxygen-containing functional groups was formed. This was further proved by IR and EDX analyses that indicate the presence of carboxylic acid groups and successful phosphorus and chlorine doping. The bandgap of the PClCDs was calculated with UV-vis to be 4.51 eV which is similar to others reported in literature. The photoluminescence (PL) behavior was studied using FL spectroscopy and the highest emission intensity was observed at at λex of 350 nm and compared with that of quinine sulfate to determine that the QY of the synthesized PClCDs was 37.7%. Compared to previous studies using biomass to create CDs, the authors propose that this value is greater because of the electron-withdrawing properties of chlorine and phosphorus atoms.

CDs are often used as fluorescence sensors to detect metal ions, anions, and molecules. They have already been used to detect several drugs because once specific drugs interact with CDs, they quench their emission signal. The researchers developed a fluorimetric method to detect valsartan, an angiotensin II receptor blocker that prevents chronic high blood pressure by stopping the constriction of blood vessels. This detection could be used to evaluate patients seeking assessments and assign risk factors.

The spectrofluorimetric method relied on comparing the change in FL at λex/em of PClCDs by plotting the FL difference (F0 – F) as a function of valsartan concentration (4 – 100 μg mL-1). The results produced strong correlation coefficients and low standard deviations and the percent recovery reported was 100.55 ± 1.19%. The LOD and LOQ were calculated to be 1.23 and 3.71 μg mL-1, respectively. These results were comparable or better than previously reported analytical methods and uses nontoxic and mild conditions. Overall, this study has successfully developed a simple and inexpensive spectrofluorimetric method to detect valsartan in samples with satisfactory results. In future studies, it would be interesting if the concentrations of valsartan and/or other drugs are measured in solutions that mimic bodily fluids instead of water using this spectrofluorimetric method.

Check out the article, recently published in RSC Advances:

Hydrothermal synthesis of modified lignin-based carbon dots derived from biomass waste for fluorescence determination of valsartan
Fatehmah Aldakhil, Nawal A. Alarfaj, Salma A. Al-Tamimi and Maha F. El-Tohamy

RSC Adv., 2024,14, 19969-19982

About the Web Writer:

Sarah Boudreau is a 3rd year PhD candidate at Memorial University of Newfoundland (MUN) in St. John’s, NL, Canada, studying under the supervision of Dr. Francesca Kerton. In 2021, she completed her BSc (Honours) in Chemistry at Cape Breton University, NS, Canada while researching the extraction of birch bark-oil (Maskwiomin) with Dr. Matthias Bierenstiel using an Indigenous Two-eyed seeing approach. She is currently an Ocean Graduate Excellence Network (OGEN) scholar who works in collaboration with the National Research Council of Canada (NRC) to transform wasted by-products of the seafood processing industry to nanomaterials with applications in high-value sectors. Sarah is particularly interested in applying the principles of Green Chemistry to help achieve a circular economy and net zero goals.

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Curious – Future Insight™ 2024 Conference – Poster prize winners

RSC Advances was delighted to sponsor a number of poster prizes at the Curious – Future Insight™ 2024 Conference.

www.julianhuke.com

  1. Dr. Lisa Maus and Dr. Stefan Liebig, Evonik Operations GmbHRevolutionizing the world of cleaning with glycolipid biosurfactants
  2. Dr. Jan Blankenburg, Evonik Operations GmbHEnabling Additives for Polymer-Based Electrolytes in Solid-State Batteries

The journal is delighted to provide support for this terrific work in such important areas of chemistry.

 

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