Archive for the ‘RSC Advances’ Category

Research Infographic: Excess chemical potential of thiophene in [C4MIM] [BF4, Cl, Br, CH3COO] ionic liquids, determined by molecular simulations

Ionic liquids are considered green solvents and can be used to extract sulfur based compounds in the desulfurization of fuels.

Gallo et al. have published an interesting research article investigating the excess chemical potential of a of imidazolium-based ionic liquids (ILs) using classical molecular dynamic simulations.

Find out more in the open access article:

Excess chemical potential of thiophene in [C4MIM] [BF4, Cl, Br, CH3COO] ionic liquids, determined by molecular simulations

Marco Gallo et al. RSC Adv., 2021,11, 29394-29406

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RSC Advances Popular Advances – an Interview with Ponnadurai Ramasami

We are very pleased to introduce Professor Ponnadurai Ramasami, who is joint corresponding author on the paper, Theoretical study of a derivative of chlorophosphine with aliphatic and aromatic Grignard reagents: SN2@P or the novel SN2@Cl followed by SN2@C?. The manuscript was well received by reviewers and was handpicked by our reviewers and handling editors to be part of our Popular Advances collection.  Ponnadurai told us more about the work that went into this article and what he hopes to achieve in the future. You can find out more about the authors and their article below. To view our other Popular Advances, please explore our collection here.

 

Professor Ponnadurai Ramasami, CSci, CChem, FRSC, FICCE, MMast, received his PhD in Physical Chemistry and became full Professor in 2013. He leads the Computational Chemistry Group, Department of Chemistry, Faculty of Science at the University of Mauritius. The research group focuses on the use of computational methods to solve chemistry and interdisciplinary problems. The group is particularly interested in collaborating with experimentalists, and they use computational methods to complement experimental research. He has already published 260 research papers in peer-reviewed journals and he has edited several books. He is the chairman of the annual Virtual Conference on Chemistry and its Applications.

 

 

 

 

 

Could you briefly explain the focus of your article to the non-specialist (in one or two sentences only) and why it is of current interest?

The focus of the article is the computational investigation of SN2 reactions in organic molecules which contain both phosphorus and chlorine atoms.

The SN2 reaction mechanism was discovered in the 1930’s by scientists Hughes and Ingold, and since then has been used in a number of syntheses; however, it is still of current interest as new aspects of this mechanism, at the molecular level, are still being discovered. These aspects include new sites of nucleophilic attack which are not immediately chemically intuitive.

How big an impact could your results potentially have?

In textbooks, SN2 reactions are defined in a firm way, often taking the example of SN2 at the carbon atom, detailing hill-shaped potential energy surfaces and nucleophilic attack at one specific atom centre. However, our research indicates that these well-established facts may change. Potential energy surfaces may take the shape of single, double or triple wells or a combination of hill and well shapes. The most preferred site of nucleophilic attack may change according to what neighbouring groups are present in the molecule of interest. It is important to include and try to explain these differences in chemistry textbooks.

Could you explain the motivation behind this study?

The Computational Chemistry Group of the University of Mauritius (CCUoM) was set up in 2003 in the Department of Chemistry. Our interest has always been on the investigation of different aspects of reaction mechanisms. We have a programme to study SN2 reaction mechanisms, which resulted in two PhD graduates and several publications. We started by studying the effect of different nucleophiles. Another part of the programme involved studying SN2 reactions at different atoms within one molecule. This started in 2017, when we came across one experimental study which involved SN2 at the phosphorus atom. We tried to explain the results of this experimental study using computational methods, which led us to discover SN2 at the chlorine atom.

In your opinion, what are the key design considerations for your study?

For SN2 reactions, the key design considerations involve the reactive atom centres, neighbouring groups, the solvent and the nucleophiles. These may be used to tune reactions to design molecules of interest.

Which part of the work towards this paper proved to be most challenging?

Working with bulky molecules was the most challenging part. Computations involving bulky molecules are demanding in terms of computational cost. It is often challenging to strike the right balance between computational cost and accuracy of results.

What aspect of your work are you most excited about at the moment?

When this research project started, it was about SN2 reactions at the phosphorus atom but along the research journey, we stumbled on the SN2 at the chlorine atom, which offers a new world of possibilities to investigate. The possibilities are what we are most excited about.

What is the next step? What work is planned?

Our next projects will involve changing key factors in the SN2 reaction mechanism involving the chlorine atom and determining the effect. We are considering changing the nucleophiles which we investigated, modifying the solvent system, and changing neighbouring groups. We are also considering investigating SN2 reactions at other reactive atoms, such as bromine and iodine.

 

Theoretical study of a derivative of chlorophosphine with aliphatic and aromatic Grignard reagents: SN2@P or the novel SN2@Cl followed by SN2@C?

Nandini Savoo,a   Lydia Rhyman*ab  and  Ponnadurai Ramasami*ab

 

 

 

 

Submit to RSC Advances today! Check out our author guidelines for information on our article types or find out more about the advantages of publishing in a Royal Society of Chemistry journal.

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Research infographic: SWIR emissive RosIndolizine dyes with nanoencapsulation in water soluble dendrimers

The use of small molecule fluorescent probes for high resolution in vivo biological imaging has profoundly impacted clinical diagnostics.

Jared H. Delcamp et al. from the University of Mississippi and University of Southern Mississippi have synthesised two new xanthene-based rosindolizine dyes that demonstrate great potential to be applied as fluorescent imaging probes in the shortwave infrared region.

Find out more about RozIndz dyes in the open access article:

SWIR emissive RosIndolizine dyes with nanoencapsulation in water soluble dendrimers

Jared H. Delcamp et al. , RSC Adv., 2021,11, 27832-27836

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RSC Advances Science Communications: Detection and quantification of dioxins and furans in foods

Persistent organic pollutants (POPs) are harmful compounds resistant to biological, chemical and photolytic degradation. They are persistent in the environment especially in soils, sediments and air for several decades. Due to their toxicity, they pose a significant threat to animal, human and environmental health, as they accumulate in the fatty tissues of humans and animals. In humans, POPs have been linked to adverse health effects, such as alterations in the development of reproductive, endocrine, neurological, and immune behavior. In animals, they have caused disease and abnormalities, including certain types of birds, fish and mammals.

Dioxin-like compounds have been classified as POPs by the World Health Organization (WHO) and the US Environmental Protection Agency (USEPA) due to their hazardous properties including long shelf life, global distribution, accumulation and bioamplification in food chains; and its toxicological effects in humans, such as teratogenesis, tumor promotion, and modulation of the immune system. The POPs present in the environment have generated great interest within the scientific community due to their toxic effect, both for animal and human health.

Polychlorodibenzo-p-dioxins (PCDDs) and polychlorodibenzofurans (PCDFs) are compounds with similar chemical properties: they are organic solids, with high melting points and low vapor pressure, have extremely low solubility in water and are adsorbed strongly on particulate matter surfaces. Polychlorinated biphenyls (PCBs) are a group of organic chemical compounds that can cause a number of different adverse effects, and there are no known natural sources of PCBs in the environment. Although biphenyls are oily liquids or solids with an appearance that varies from colorless to light yellow, some PCBs are volatile and can exist as vapor in the air. PCBs have no known odor or taste, they enter the environment as mixtures containing a variety of individual components of polychlorinated biphenyls. They do not degrade easily and therefore remain for a long time, and can be easily detected in air, water and soil. Among the harmful effects they cause on human health, such as immune and neurological dysfunctions, they are also classified as possible human carcinogens and toxic in reproduction.

Currently, there are numerous gaps with respect to knowledge about these substances, in particular about methodologies for their detection and quantification, as well as about the levels that are potentially dangerous for humans. For this reason, the development, fine-tuning and validation of new methodologies that allow innovation and improvement of novel traceability systems for these compounds is of great interest. With the advent of sophisticated chromatography techniques, the development of innovative and alternative highly sensitive analytical methods for trace analysis of these compounds is a challenge.

Finally, it is of great importance to note that there are no laboratories in Argentina with analytical methodologies that detect and quantify these analytes, which is why they become so important and of great interest to study. In this way, it would allow to have the first bases for the quality control of products of agri-food origin for export and/or of the domestic market, and the great economic impact that it generates on their traceability.

Read the article:

https://pubs.rsc.org/en/content/articlelanding/2021/ra/d1ra00599e

Ying Li, Yanan Han, Zhuochao Teng, Xianwei Zhao, Yanhui Sun, Fei Xu, Qingzhu Zhang and Wenxing Wang. RSC Adv., 2021, 11, 12626-12640.

 

About the Web Writer:

 

BIOGRAPHY

Cristian M. O. Lépori is Doctor in Chemical Sciences and is currently a researcher at JLA Argentina S.A., General Cabrera – Argentina. He researched and developed analytical methods for the detection of contaminants in food, water, and soil. He likes to plan, organize and carry out science dissemination activities. You can find him on Twitter at @cristianlepo.

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Welcome to our new Associate Editor: Hideko Nagasawa

We are delighted to welcome Professor Hideko Nagasawa to the RSC Advances team this month!

Hideko Nagasawa

 

Dr Hideko Nagasawa is a Professor in the Department of Medicinal Chemistry at Gifu Pharmaceutical University, where she heads the Laboratory of Pharmaceutical and Medicinal Chemistry. She completed her PhD at Graduate School of Pharmaceutical Sciences, Kyoto University. Her research mainly focuses on drug discovery and chemical biology targeting the tumor microenvironment (TME). Projects pursued in her laboratory include the development of selective cancer therapies in TMEs of hypoxia and nutrient deprivation, and the creation of unique functional molecules such as fluorescent probes and caged compounds for the study of diverse cellular stresses.

Nagasawa says, “I am excited to join RSC Advances as an Associate Editor and look forward to contributing to the field of Chemical Biology and Medicinal”.

Browse a selection of Hideko’s RSC publications:

Asymmetric bismuth-rhodamines as an activatable fluorogenic photosensitizer
Akari Mukaimine, Tasuku Hirayama and Hideko Nagasawa
Org. Biomol. Chem., 2021, 19, 3611-3619
DOI: 10.1039/D0OB02456B

A 19F-MRI probe for the detection of Fe(ii) ions in an aqueous system
Ryo Kakiuchi, Tasuku Hirayama, Daijiro Yanagisawa, Ikuo Tooyama and Hideko Nagasawa
Org. Biomol. Chem., 2020, 18, 5843-5849
DOI: 10.1039/D0OB00903B

A Golgi-targeting fluorescent probe for labile Fe(ii) to reveal an abnormal cellular iron distribution induced by dysfunction of VPS35
Tasuku Hirayama, Masatoshi Inden, Hitomi Tsuboi, Masato Niwa, Yasuhiro Uchida, Yuki Naka, Isao Hozumi and Hideko Nagasawa
Chem. Sci., 2019, 10, 1514-1521
DOI: 10.1039/C8SC04386H

Organelle-specific analysis of labile Fe(ii) during ferroptosis by using a cocktail of various colour organelle-targeted fluorescent probes
Tasuku Hirayama, Ayaji Miki and Hideko Nagasawa
Metallomics, 2019, 11, 111-117
DOI: 10.1039/C8MT00212F

 

RSC Advances Royal Society of ChemistrySubmit to RSC Advances today! Check out our author guidelines for information on our article types or find out more about the advantages of publishing in a Royal Society of Chemistry journal.

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Welcoming our new Associate Editors: Carmen L Gomes, Patrícia Valentão & Yu Wang

We are delighted to welcome Professors Carmen Gomes, Patrícia Valentão & Yu Wang to the RSC Advances team this week!

Carmen Gomes RSC Advances Associate EditorDr. Carmen Gomes is currently an Associate Professor in the Mechanical Engineering Department at Iowa State University where she is leading a successful research program on the design of novel nanoscale materials using carbon-based nanomaterials and polymers for food safety and agricultural applications. Projects pursued in her laboratory range from fabrication of polymeric nanomaterials and nanostructured devices for biosensors to bioactive delivery systems. Dr. Gomes has over 14 years of experience working in the research area of nanotechnology applied to food processing, food safety and food quality to develop effective solutions in food and agriculture production.

Gomes says, “I am excited for the opportunity to join RSC Advances as an associate editor and look forward to working with the food science and engineering community”.

 

Patrícia Valentão RSC Advances Associate Editor

Patrícia Valentão is Associate Professor with Habilitation at the Faculty of Pharmacy of University of Porto. She completed her PhD in Pharmaceutical Sciences at the University of Porto for work on Pharmacognosy in 2003. She is an Integrated Member of the Associated Laboratory for Green Chemistry (LAQV) of the Network of Chemistry and Technology (REQUIMTE), the Portuguese Research Centre for Sustainable Chemistry, within the “Natural Products – Chemistry and Bioactivity” group. Her research has been focused on the development and application of analytical methods for the study of terrestrial and non-terrestrial natural matrices, and on the chemical and biological characterization of natural and hemi-synthetic compounds in a context of drug discovery, to modulate diabetes, inflammatory and neurodegenerative diseases, and cancer. Her expertise is evidenced in more than 30 book chapters and more than 300 articles published in international peer-reviewed journals (h-index = 56).

 

Yu Wang RSC Advances Associate EditorDr. Yu Wang is an Assistant Professor of Food Chemistry at the Food Science and Human Nutrition Department and Citrus Research and Education Center, University of Florida. Dr. Wang’s research mainly focuses on flavor chemistry and natural product chemistry, emphasizing the flavor (aroma and taste) of fruits, herbs and other agricultural commodities, and use of citrus by-product for health benefits. She got her PhD in Food Chemistry, at Rutgers, the State University of New Jersey. Dr. Wang had her postdoc. training at Massachusetts Institute of Technology focusing on “Omics” techniques for early diagnosing inflammation bowel disease (IBD). Dr. Wang received the Alexander von Humboldt Fellowship to work in the Chair of Food Chemistry and Molecular Sensory Science at the Technical University of Munich. Her research experience includes flavor chemistry, sensory science and food/plant metabolomics. Before joining University of Florida, Dr. Wang was a Flavor Chemist at Mars Chocolate Inc, working in global R&D directing flavor application, developing novel flavor profiles, analyzing cocoa and chocolate flavor, setting up flavor training program, and providing technical guidance.

 

Browse a selection of Yu, Patrícia & Carmen’s RSC publications:

All-graphene-based open fluidics for pumpless, small-scale fluid transport via laser-controlled wettability patterning
Lucas S. Hall, Dohgyu Hwang, Bolin Chen, Bryan Van Belle, Zachary T. Johnson, John A. Hondred, Carmen L. Gomes, Michael D. Bartlett and Jonathan C. Claussen
Nanoscale Horiz., 2021, 6, 24-32
DOI: 10.1039/D0NH00376J, Communication

Novel styrylpyrazole-glucosides and their dioxolo-bridged doppelgangers: synthesis and cytotoxicity
Ana R. F. Carreira, David M. Pereira, Paula B. Andrade, Patrícia Valentão, Artur M. S. Silva, Susana Santos Braga and Vera L. M. Silva
New J. Chem., 2019, 43, 8299-8310
DOI: 10.1039/C9NJ01021A, Paper

Preventive mechanism of bioactive dietary foods on obesity-related inflammation and diseases
Jeehye Sung, Chi-Tang Ho and Yu Wang
Food Funct., 2018, 9, 6081-6095
DOI: 10.1039/C8FO01561A, Review Article

Actuation of chitosan-aptamer nanobrush borders for pathogen sensing
Katherine D. Hills, Daniela A. Oliveira, Nicholas D. Cavallaro, Carmen L. Gomes and Eric S. McLamore
Analyst, 2018, 143, 1650-1661
DOI: 10.1039/C7AN02039B, Paper

Tuning protein folding in lysosomal storage diseases: the chemistry behind pharmacological chaperones
David M. Pereira, Patrícia Valentão and Paula B. Andrade
Chem. Sci., 2018, 9, 1740-1752
DOI: 10.1039/C7SC04712F, Perspective

Protective effects of theasinensin A against carbon tetrachloride-induced liver injury in mice
Wei-Lun Hung, Guliang Yang, Yu-Chuan Wang, Yi-Shiou Chiou, Yen-Chen Tung, Meei-Ju Yang, Bi-Ni Wang, Chi-Tang Ho, Yu Wang and Min-Hsiung Pan
Food Funct., 2017, 8, 3276-3287
DOI: 10.1039/C7FO00700K, Paper

RSC Advances Royal Society of ChemistrySubmit to RSC Advances today! Check out our author guidelines for information on our article types or find out more about the advantages of publishing in a Royal Society of Chemistry journal.

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Welcome to our new Associate Editor: Lubomír Rulíšek

We are delighted to welcome Dr Lubomír Rulíšek to the RSC Advances team this month!

Lubomir Rulisek RSC Advances Associate Editor RSC

Lubomír Rulíšek is a Senior Research Group Leader at the Institute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences, Prague (IOCB). He completed his master’s degrees at the Charles University, Prague and obtained his Ph.D. at IOCB in 2001 (supervised by Dr. Zdeněk Havlas). He was a postdoctoral research fellow at Lund University, Sweden, with Prof. Ulf Ryde who introduced him into theoretical bioinorganic chemistry which has been one of his favorite research themes since then. In addition, the research in the Rulíšek group encompasses various applications of quantum chemistry and quantum and molecular mechanical (QM/MM) modelling: physico-chemical principles of protein structures, protein–ligand interactions, computational electrochemistry, theoretical spectroscopy, organic reactivity, computational homogeneous catalysis, and biomolecular design. He is a true believer in indispensable and integral role of computations in contemporary chemical and biological research.

Rulíšek says, “I am grateful for the opportunity to join RSC Advances as an associate editor and look forward to serve to a large community of chemists and biologists”.

Browse a selection of Lubomír’s RSC publications:

Conformational Energies and Equilibria of Cyclic Dinucleotides In Vacuo and In Solution: Computational Chemistry vs. NMR Experiments
Gutten, O., Jurečka, P., Aliakbar Tehrani, Z., Budešínský, M., Řezáč, J., Rulíšek, L.
Phys. Chem. Chem. Phys. 2021, Accepted Manuscript
DOI: 10.1039/D0CP05993E

Solvatochromic fluorene-linked nucleoside and DNA as color-changing fluorescent probes for sensing interactions
Dmytro Dziuba, Petr Pospíšil, Ján Matyašovský, Jiří Brynda, Dana Nachtigallová, Lubomír Rulíšek, Radek Pohl, Martin Hof and Michal Hocek
Chem. Sci., 2016, 7, 5775-5785
DOI: 10.1039/C6SC02548J

The non-planarity of the benzene molecule in the X-ray structure of the chelated bismuth(iii) heteroboroxine complex is not supported by quantum mechanical calculations
Jindřich Fanfrlík, Robert Sedlak, Adam Pecina, Lubomír Rulíšek, Libor Dostál, Ján Moncóľ, Aleš Růžička and Pavel Hobza
Dalton Trans., 2016, 45, 462-465
DOI: 10.1039/C5DT04381F

How simple is too simple? Computational perspective on importance of second-shell environment for metal-ion selectivity
Ondrej Gutten and Lubomír Rulíšek
Phys. Chem. Chem. Phys., 2015, 17, 14393-14404
DOI: 10.1039/C4CP04876H

A new insight into the zinc-dependent DNA-cleavage by the colicin E7 nuclease: a crystallographic and computational study
Anikó Czene, Eszter Tóth, Eszter Németh, Harm Otten, Jens-Christian N. Poulsen, Hans E. M. Christensen, Lubomír Rulíšek, Kyosuke Nagata, Sine Larsen and Béla Gyurcsik
Metallomics, 2014, 6, 2090-2099
DOI: 10.1039/C4MT00195H

Theoretical calculations of physico-chemical and spectroscopic properties of bioinorganic systems: current limits and perspectives
Tibor András Rokob, Martin Srnec and Lubomír Rulíšek
Dalton Trans., 2012, 41, 5754-5768
DOI: 10.1039/C2DT12423H

 

RSC Advances Royal Society of ChemistrySubmit to RSC Advances today! Check out our author guidelines for information on our article types or find out more about the advantages of publishing in a Royal Society of Chemistry journal.

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RSC Advances Science Communications: In the search of a tangible product for healthcare

Treatment for cancer and bacterial infections is challenging to approach due to various reasons such as the development of resistant and unwanted side effects. Development of new chemotherapeutic agents often ends up with a blunt end. Therefore, finding a new formulation and an effective delivery method for the currently available agents is a gold alternative.

Curcumin and zinc oxide nanoparticles (ZnO Nps) are such compounds that have enormous advantages. Of the potent bioactive metabolites that have been identified from plant sources, curcumin is one of the most-investigated safe chemical compounds. Research over the last two decades has shown it to be a potent anticancer and antimicrobial agent in cell- and animal studies. But inheritably, curcumin has low efficacy mainly due to the poor bioavailability, contributed to by its insolubility, instability, poor absorption, and rapid biotransformation. ZnO Np is a well-investigated biocompatible and apparently nontoxic nanomaterial that has shown promising anticancer and antimicrobial activity as well. In the article “Curcumin loaded zinc oxide nanoparticles for activity-enhanced antibacterial and anticancer applications”, different shapes of curcumin loaded ZnO Nps were investigated for their effectiveness and safety as an anticancer and antibacterial agent. The results indicate that curcumin loaded ZnO Nps are low toxic and a highly effective combination compared with their bare counterparts. Moreover, since nanoparticles show different absorption mechanisms through the gastrointestinal tract, it is a good alternative to mask compound which has low absorption capacity. In this study, other than the synergetic effect of curcumin loaded Nps, ZnO Nps act as a carrier system for curcumin, which has bioavailability issues.

Graphical abstract: Curcumin loaded zinc oxide nanoparticles for activity-enhanced antibacterial and anticancer applications

Of particular note is the potential of this platform to act as an antibiotic-free formulation for use against infections caused by a range of different bacterial pathogens. Given the anticancer activity of the platform, it may prove to be of great use as an oncotherapy supplement, helping manage both the disease condition and opportunistic bacterial infections. The findings of this research open doors for different angles of curcumin and ZnO Np research. Therefore, the responsibility of the scientists is to use this finding to develop appropriate dosage foam for curcumin loaded ZnO Np.

I thank Dr. Ranga K. Dissanayake for his cordial responses.

Read the article:

Curcumin loaded zinc oxide nanoparticles for activity-enhanced antibacterial and anticancer applications

W. P. T. D. Perera, Ranga K. Dissanayake, U. I. Ranatunga, N. M. Hettiarachchi, K. D. C. Perera, Janitha M. Unagolla, R. T. De Silva and L. R. Pahalagedara. RSC Adv., 2020, 10, 30785–30795.

 

About the Web Writer:

Cristian M. O. Lépori is Doctor in Chemical Sciences and currently has a postdoctoral position at the Instituto de Física Enrique Gaviola, CONICET – Universidad Nacional de Córdoba, Argentina. He works in the area of green chemistry. He likes to plan, organize and carry out science dissemination activities. You can find him on Twitter at @cristianlepo.

 

 

 

 

RSC Advances Royal Society of ChemistrySubmit to RSC Advances today! Check out our author guidelines for information on our article types or find out more about the advantages of publishing in a Royal Society of Chemistry journal.

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RSC Advances Science Communications: For a safer earth for us and for the next generation

Current increasing demands for the effective photocatalytic system for the treatment of industrial effluent with low cost and highly effective tools influenced the use of systems based on TMO (tri-metal oxide) that work in both acidic and basic pH systems, and that combat resistance to multiple drugs in bacterial infections and cancer. To solve the global environmental problems and save people from carcinogenic exposure, work has been done to establish highly effective, highly reliable and sensitive electrochemical methods involving the I–V approach for the detection of toxins present in environmental samples as well as in food/drinks or in their containers.

Dyes are extensively used in the textile industry, and considerable amounts are discharged into natural water reservoirs without any treatment. To treat wastewater, many catalysts have been investigated. However, it is tough to find an effective and efficient system for the waste- effluent treatment. The TMO system reported in the article “Photocatalysis, photoinduced enhanced antibacterial functions and development of a selective m-tolyl hydrazine sensor based on mixed Ag∙NiMn2O4 nanomaterials” was designed to meet the current need of industrial waste water treatment problem world-wide. For industrial effluent, especially from fabric and other industries where huge amounts of dyes are used, a proper treatment system is needed. This TMO system is very effective and highly efficient for the treatment of industrial waste water, it can degrade dyes present in waste water naturally in presence of sunlight. In particular, Ag·NiMn2O4 TMO can degrade dyes in both acidic and basic medium (in a wide pH range) in presence of sunlight. So, this TMO is useful for the treatment of varieties of industrial waste water. Further, its activity can be boosted by the use of a catalytic amount of H2O2 (as catalyst booster).

Graphical abstract: Photocatalysis, photoinduced enhanced anti-bacterial functions and development of a selective m-tolyl hydrazine sensor based on mixed Ag·NiMn2O4 nanomaterials

Ag·NiMn2O4 TMO is highly effective against both Gram positive and Gram negative MDR (multi drug resistant bacteria). This result is very promising because it is highly challenging to kill both Gram positive and Gram negative bacteria with a single drug (compound). It is expected that this compound can be a promising sterilizing agent for numerous industrial uses.

The authors also reports on a highly reliable and sensitive electrochemical method involving the I–V approach for the detection of hydrazine. Hydrazine is used as an industrial raw material to produce pesticides, herbicides, insecticides, corrosion inhibitors, pharmaceutical intermediates, dyestuffs, antioxidants, explosives, catalysts, fuel cells and rocket fuel, and it is a carcinogenic compound. In this study, the development of an electrochemical sensor using Ag·NiMn2O4 TMO nanomaterial on glassy carbon electrode (GCE) was developed. The m-tolyl hydrazine chemical sensor was fabricated with GCE coated with the Ag·NiMn2O4 TMO nanomaterial. The stability of the sensor probe was implemented by applying conductive Nafion (5% in ethanol) as a chemical glue under ambient conditions.

Finally, various real samples (collected from various environmental sources) were analyzed to check the applicability as well as the validity of the chemical sensor probe. As a potential sensor, it is reliable due to its good reproducibility, rapid response, high sensitivity, working stability for long duration and efficiency in the analysis of real environmental samples. Therefore, this method introduces a new route to develop selective chemical sensors using TMO nanomaterials for safety in the environmental and healthcare fields.

The authors strongly believe that the TMO research will have a tremendous effect on current as well as upcoming health and environmental global issues. Specifically, for a sustainable environment, medical and other health care issues.

I thank Dr. Md Abdus Subhan for his cordial responses.

Read the article:

“Photocatalysis, photoinduced enhanced antibacterial functions and development of a selective m-tolyl hydrazine sensor based on mixed Ag∙NiMn2O4 nanomaterials”. Md Abdus Subhan, Pallab Chandra Saha, Md Anwar Hossain, M. M. Alam, Abdullah M. Asiri, Mohammed M. Rahman, Mohammad Al-Mamun, Tanjila Parvin Rifat, Topu Raihan A. K. Azad. RSC Adv., 2020, 10, 30603–30619.

 

About the Web Writer:

Cristian M. O. Lépori is Doctor in Chemical Sciences and currently has a postdoctoral position at the Instituto de Física Enrique Gaviola, CONICET – Universidad Nacional de Córdoba, Argentina. He works in the area of green chemistry. He likes to plan, organize and carry out science dissemination activities. You can find him on Twitter at @cristianlepo.

 

 

 

RSC Advances Royal Society of ChemistrySubmit to RSC Advances today! Check out our author guidelines for information on our article types or find out more about the advantages of publishing in a Royal Society of Chemistry journal.

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RSC paper mill retractions

Below is a list of papers retracted in connection with what we believe is a paper mill. Please see http://rsc.li/paper-mill-response for more information.

1. https://doi.org/10.1039/D1RA90011K
2. https://doi.org/10.1039/D1RA90018H
3. https://doi.org/10.1039/D1RA90019F
4. https://doi.org/10.1039/D1RA90023D
5. https://doi.org/10.1039/D1RA90020J
6. https://doi.org/10.1039/D1RA90015C
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The associated Editorial published in RSC Advances can be found at the following url: https://doi.org/10.1039/D1RA90009A

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