Archive for the ‘News’ Category

Introducing Journal of Materials Chemistry A Associate Editor Stephen Skinner

Stephen Skinner is a Reader in Materials Chemistry in the Department of Materials at Imperial College London with research interests in new materials for energy generation/storage technologies. He is primarily interested in the development of materials for solid oxide fuel cells and in understanding their transport properties, utilising a combination of diffraction and spectroscopic techniques. In-situ structural and electrical characterisation of oxides and the determination of the oxygen transport kinetics are key areas of interest. He is a member of the ISIS neutron source facility access panel, Diamond I20 working group and the Materials Chemistry Division Council of the RSC.

His recent papers include:

In situ compatibility studies of lanthanum nickelate with a ceria-based electrolyte for SOFC composite cathodes
R. Sayers, J. E. Parker, C. C. Tang and S. J. Skinner
J. Mater. Chem., 2012, 22, 3536-3543

Evidence for the catalytic oxidation of La2NiO4+δ
R. Sayers and S. J. Skinner
J. Mater. Chem., 2011, 21, 414-419

Structural properties of Ce-doped strontium titanate for fuel cell applications
Denis J. Cumming, John A. Kilner and Stephen Skinner
J. Mater. Chem., 2011, 21, 5021-5026

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Introducing Journal of Materials Chemistry B Associate Editor Jeroen Cornelissen

Jeroen Cornelissen is Professor in Biomolecular Nanotechnology at the University of Twente, Enschede, the Netherlands. He studied chemistry in The Netherlands with a minor in polymer chemistry carried out at the Eindhoven University of Technology with Prof. E.W. Meijer and a major in Supramolecular Chemistry and Catalysis at the University of Nijmegen with Prof. R.J.M. Nolte. He received his PhD (cum laude) from the latter university in 2001 for research carried out under the supervision of Prof. R.J.M. Nolte. After post-doctoral work at the IBM Almaden Research Center in San Jose, U.S.A. he returned to Nijmegen, where he was appointed as an Assistant Professor until 2009. His current research interests are in well-defined polymer architectures, hybrid systems of synthetic macromolecules and biopolymers and the use of viruses as building blocks in functional materials.

His recent papers include:

Time-programmed helix inversion in phototunable liquid crystals
Sarah J. Aßhoff, Supitchaya Iamsaard, Alessandro Bosco, Jeroen J. L. M. Cornelissen, Ben L. Feringa and Nathalie Katsonis
Chem. Commun., 2013, Advance Article

Relative size selection of a conjugated polyelectrolyte in virus-like protein structures
Melanie Brasch and Jeroen J. L. M. Cornelissen
Chem. Commun., 2012,48, 1446-1448

Solution scattering studies on a virus capsid protein as a building block for nanoscale assemblies
Marta Comellas-Aragonès, Friso D. Sikkema, Guillaume Delaittre, Ann E. Terry, Stephen M. King, Dirk Visser, Richard K. Heenan, Roeland J. M. Nolte, Jeroen J. L. M. Cornelissen and Martin C. Feiters
Soft Matter, 2011,7, 11380-11391

Hydrogen bonding and chemical shift assignments in carbazole functionalized isocyanides from solid-state NMR and first-principles calculations
Chandrakala M. Gowda, Filipe Vasconcelos, Erik Schwartz, Ernst R. H. van Eck, Martijn Marsman, Jeroen J. L. M. Cornelissen, Alan E. Rowan, Gilles A. de Wijs and Arno P. M. Kentgens
Phys. Chem. Chem. Phys., 2011,13, 13082-13095

Electrostatic self-assembly of virus–polymer complexes
Mauri A. Kostiainen, Panu Hiekkataipale, Jose Á. de la Torre, Roeland J. M. Nolte and Jeroen J. L. M. Cornelissen
J. Mater. Chem., 2011,21, 2112-2117

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Introducing Journal of Materials Chemistry C Associate Editor Natalie Stingelin

Natalie Stingelin is a Reader at the Department of Materials, Imperial College London, UK, where she conducts research in the broad area of organic functional materials, including organic electronics, multifunctional inorganic/organic hybrids and smart, advanced optical systems based on organic matter. She has more than 70 papers, is an Associate Editor of Journal of Materials Chemistry C, and in 2011 she received an ERC Young Investigator Award.

Her recent papers include:

Synthesis and charge transport studies of stable, soluble hexacenes
Balaji Purushothaman, Sean R. Parkin, Mark J. Kendrick, Daniel David, Jeremy W. Ward, Liyang Yu, Natalie Stingelin, Oana D. Jurchescu, Oksana Ostroverkhova and John E. Anthony
Chem. Commun., 2012, 48, 8261-8263

Solution-processed small molecule transistors with low operating voltages and high grain-boundary anisotropy
Liyang Yu, Xiaoran Li, Jeremy Smith, Steven Tierney, Richard Sweeney, B. K. Charlotte Kjellander, Gerwin H. Gelinck, Thomas D. Anthopoulos and Natalie Stingelin
J. Mater. Chem., 2012, 22, 9458-9461

A flexible n-type organic semiconductor for optoelectronics
Ke Gui, Karyn Mutkins, Paul E. Schwenn, Karsten B. Krueger, Almantas Pivrikas, Pascal Wolfer, Natalie Stingelin Stutzmann, Paul L. Burn and Paul Meredith
J. Mater. Chem., 2012, 22, 1800-1806

Fullerene crystallisation as a key driver of charge separation in polymer/fullerene bulk heterojunction solar cells
Fiona C. Jamieson, Ester Buchaca Domingo, Thomas McCarthy-Ward, Martin Heeney, Natalie Stingelin and James R. Durrant
Chem. Sci., 2012, 3, 485-492

A low band gap co-polymer of dithienogermole and 2,1,3-benzothiadiazole by Suzuki polycondensation and its application in transistor and photovoltaic cells
Zhuping Fei, Jong Soo Kim, Jeremy Smith, Ester Buchaca Domingo, Thomas D. Anthopoulos, Natalie Stingelin, Scott E. Watkins, Ji-Seon Kim and Martin Heeney
J. Mater. Chem., 2011, 21, 16257-16263

Low band gap selenophene–diketopyrrolopyrrole polymers exhibiting high and balanced ambipolar performance in bottom-gate transistors
Munazza Shahid, Thomas McCarthy-Ward, John Labram, Stephan Rossbauer, Ester Buchaca Domingo, Scott E. Watkins, Natalie Stingelin, Thomas D. Anthopoulos and Martin Heeney
Chem. Sci., 2012, 3, 181-185

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Advancing the Chemistry of the Actinides – Dalton Discussion 14

Advancing the Chemistry of the Actinides – Dalton Discussion 14

The oral abstract deadline is 15 February 2013 – so submit yours now!

The chemistry of the actinides has the potential to impact upon many of the 21st century chemical challenges requisite for a secure and sustainable future.

This conference will highlight the burgeoning role and exciting prospects for actinides in modern, metal-based chemistry.

Why take part in this discussion?

It’s a great way to get your own research better known.

The excellent keynote and invited speakers will focus on the following themes:

•    Probing structure and bonding in actinide compounds
•    Actinide properties and materials applications
•    Advances in actinide reactivity and catalysis
•    Actinides in the environment

So don’t miss this opportunity to hear from and network with the best in the field!

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2013 Journal of Materials Chemistry Lectureship – Nominations now open!

Now in its 4th year, we are looking for nominations from you for the next Journal of Materials Chemistry Lectureship recipient.

We are pleased to announce that the 2013 Lectureship is now open for nominations. This annual lectureship honours a younger scientist who has made a significant contribution to the field of materials chemistry.

Xiangfeng Duan, the winner of the 2012 lectureship, was chosen as last year’s recipient, and will be giving his Journal of Materials Chemistry lecture during the next few months.

Qualification
To be eligible for the Journal of Materials Chemistry Lectureship, the candidate should be in the earlier stages of their scientific career, typically within 10 years of attaining their doctorate or equivalent degree, and will have made a significant contribution to the field.

Description
The recipient of the award will be asked to present one Journal of Materials Chemistry lecture, at a conference decided upon by the recipient and the Editorial Office. The Journal of Materials Chemistry Editorial Office will provide the sum of £1000 to the recipient for travel and accommodation costs. The award recipient will be presented with the award at this lecture. They will also be asked to contribute a lead article to the journal and will have their work showcased on the back cover of the issue in which their article is published.

Selection
The recipient of the lectureship will be selected and endorsed by the Journal of Materials Chemistry Executive Editorial Board.

Nominations
Those wishing to make a nomination should send details of the nominee including a brief C.V. (no longer than 2 pages) together with a letter supporting the nomination (no longer than 2 pages), to the Journal of Materials Chemistry Editorial Office by 28 February 2013. Please note that self-nomination is permitted.

Send a nomination here today: materials-rsc@rsc.org

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Meet the materials chemistry team in 2013

Liz Dunn and the team will be attending a host of exciting conferences this year. Please do let us know if you’ll be there too – we’d love to meet you!

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Journal of Materials Chemistry A, B and C Issue 3’s online now!

The Issue 3’s of Journal of Material Chemistry A, B and C have been published online. Each journal showcases high impact research you expect from Journal of Materials Chemistry, now in three separate journals. For more information, please go to http://rsc.li/jmc-abc.

Journal of Materials Chemistry C features articles on the following:

Self assembled monolayers (SAMs) on metallic surfaces (gold and graphene) for electronic applications, Aravind Vijayaraghavan et al.: We review advances in the last decade in self-assembled monolayers (SAMs) for electronic applications, focusing on gold and graphene surfaces.

A D–A–D swivel-cruciform oligothiophene based on 5,5′-bibenzothiadiazole, Xiaowei Zhan et al.: A multi-dimensional D–A–D oligothiophene, 4,4′,7,7′-tetrakis(hexylbithiophene)–5,5′-bibenzo[c][1,2,5]thiadiazole swivel cruciform (BBT-SC), was synthesized. BBT-SC thin films exhibited a high intrinsic charge carrier mobility of 0.1 cm2 V−1 s−1, measured by a time-resolved microwave conductivity technique.

Low operation voltage macromolecular composite memory assisted by graphene nanoflakes, Yang-Fang Chen et al.: Bistable nonvolatile memory devices using an insulating polymer doped with solution phase of graphene nanoflakes are fabricated through a simple one-step solution-process.

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Journal of Materials Chemistry A features articles on the following:

Ca-based synthetic materials with enhanced CO2 capture efficiency, Jose Manuel Valverde, This manuscript reviews the development of novel sorbents to improve the CO2 capture performance of natural limestone at Ca-looping conditions.

Microporous metal–organic frameworks with open metal sites as sorbents for selective gas adsorption and fluorescence sensors for metal ions
, Xian-He Bu et al.: Two cluster-based microporous MOFs exhibit highly selective uptake for CO2 over CH4 and N2 under ambient conditions. 1 also provides an ideal luminescence sensor for selectively probing Ba2+ and Cu2+ ions based on its significant fluorescence enhancement or quenching.

Derivatives of 5-nitro-1,2,3-2H-triazole – high performance energetic materials, Jean’ne M. Shreeve et al.: The derivatives of 5-nitro-1,2,3-2H-triazole are energetic materials, in particular 2-amino-4,5-dinitro-1,2,3-2H-triazole which exhibits good properties (Td,onset, 190 °C; P, 36.2 GPa; vD, 8843 m s−1; IS, 24 J).
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Journal of Materials Chemistry B features articles on the following:

Biologically responsive, sustainable release from metallo-drug coordinated 1D nanostructures, Naohiro Kameta, Toshimi Shimizu et al.: A multistep self-assembly process produced nanotubes and nanotapes with a ligand that coordinated an anticancer Pt complex. Nanotubes were superior to nanotapes with respect to sustainable release of the drug.

A water-soluble phosphorescent polymer for time-resolved assay and bioimaging of cysteine/homocysteine, Qiang Zhao, Fuyou Li, Wei Huang et al.: A water-soluble phosphorescent bioprobe was successfully developed by introducing an iridium(III) complex as a phosphorescent signaling unit with poly(N-isopropylacrylamide) (PNIPAM) as the stimuli-responsive backbone.

A graphene oxide platform for the assay of DNA 3′-phosphatases and their inhibitors based on hairpin primer and polymerase elongation, Jianhui Jiang, Ruqin Yu et al.: A label-free sensitive GO sensing platform for DNA 3′-phosphatases and their inhibitors, based on a hairpin primer and polymerase elongation.

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Journal of Materials Chemistry A, B and C Issue 2’s online now!

The Issue 2’s of Journal of Material Chemistry A, B and C have been published online this week. Each journal showcases high impact research you expect from Journal of Materials Chemistry, now in three separate journals. For more information, please go to http://rsc.li/jmc-abc.

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Journal of Materials Chemistry B features articles on the following:

Design strategies for fluorescent biodegradable polymeric biomaterials, Yi Zhang and Jian Yang: In this paper, we provide a critical review on the fluorescent biodegradable polymers with emphases on material fluorescence mechanism, design criteria for fluorescence, and their cutting-edge applications in biomedical engineering. We expect that this review will provide an insightful discussion on the fluorescent biomaterial design and lead to innovations for the next generation of fluorescent biomaterials and fluorescence-based biomedical technology.

Polyol induced interpenetrating networks: chitosan–methylmethacrylate based biocompatible and pH responsive hydrogels for drug delivery system, Sharif Ahmad et al.: The hydrophobically modified hydrogels of CH–MMA/Polyol were prepared by free radical polymerization reaction. This study has come up with novel characteristics associated with the formation of interpenetrating networks by the introduction of polyol in the CH–MMA matrix..

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Journal of Materials Chemistry C features articles on the following:

Soft X-ray characterisation of organic semiconductor films, Christopher R. McNeill and Harald Ade: This feature article highlights the versatility of soft X-ray based techniques for characterising the structure of organic semiconductor devices.

The visible photoluminescence mechanism of oxidized multi-walled carbon nanotubes: an experimental and theoretical investigation, Hui Feng et al.: Dominant components of oxidized products of MWCNTs were separated by column chromatography, the origin of highly visible fluorescence from carbon nanotubes was revealed, and the nature of weak near UV-Vis fluorescence of oxidized carbon nanotubes from isolated sp2 clusters was supported.

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Journal of Materials Chemistry A features articles on the following:

Engineering nanostructured anodes via electrostatic spray deposition for high performance lithium ion battery application, Xifei Li and Chunlei Wang: ESD-derived nanostructured anodes show significantly improved cycling performance and rate capability in high performance lithium ion battery application.

Controlled synthesis of concave Cu2O microcrystals enclosed by {hhl} high-index facets and enhanced catalytic activity, Zhaoxiong Xie, Lansun Zheng et al.: Truncated concave octahedral Cu2O mainly with {332} high-index facets exhibit enhanced catalytic activity.

Counter electrodes from double-layered polyaniline nanostructures for dye-sensitized solar cell applications, Qunwei Tang et al.: DSSCs from double-layered polyaniline counter electrodes were fabricated by an electrochemical method and can be potentially used as high photoelectric conversion devices.

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Introducing the Journal of Materials Chemistry A, B and C Editor-in-Chief and Deputy Editors-in-Chief

Editor-in-Chief, Journal of Materials Chemistry

Dongyuan Zhao was born in Shenyang, Liaoning Province in June 1963. He was a undergraduate student at Jilin University (1980-84), got his Master degree from Chemistry Department at Jilin University (1987), and a Ph.D.degree from Jilin University and Dalin Institute of Chemical Physics (1990). He began his academic career almost immediately as a lecturer in Chemical Engineering Department at the Shenyang Institute of Chemical Technology, and was promoted to an Associate Professor in 1992. In 1992-93, he was a visiting scholar in the Chemistry Department of University of Regina. After postdoctoral research at the Weizmann Institute of Science (with Prof. Daniella Goldfarb, 1993-94), University of Houston (with Prof. Larry Kevan, 1995-96), and University of California at Santa Barbara (with Prof. Galen D. Stucky, 1996-98), he joined the faculty of the Fudan University in Dec.1998, where he is now Professor in the Department of Chemistry. Dr. Zhao‘s research includes:

• Macro- and Microscopically Topological Construction of Highly Ordered Porous Materials

• Designed Synthesis, Assembly, Growth and Properties of Mesoporous Materials

• Structure and Synthesis Design of Novel Microporous Molecular Sieves

…………………………………………………• Rational Synthesis and Organization of Novel Patterned Nanoscale Materials.

His recent papers include:

Ligand exchange triggered controlled-release targeted drug delivery system based on core–shell superparamagnetic mesoporous microspheres capped with nanoparticles, J. Mater. Chem., 2012,22, 17677-17684
Self-assembly of monodispersed silica nano-spheres with a closed-pore mesostructure, J. Mater. Chem., 2012, 22, 11523-11528
Post-enrichment of nitrogen in soft-templated ordered mesoporous carbon materials for highly efficient phenol removal and CO2 capture, J. Mater. Chem., 2012, 22, 11379-11389
A hierarchical adsorption material by incorporating mesoporous carbon into macroporous chitosan membranes, J. Mater. Chem., 2012, 22, 11908-11911

Ordered mesoporous graphitized pyrolytic carbon materials: synthesis, graphitization, and electrochemical properties, J. Mater. Chem., 2012, 22, 8835-8845Dr. Zhao

Deputy Editor-in-Chief, Journal of Materials Chemistry A

Kazuhito Hashimoto is currently a professor of chemistry at the University of Tokyo. After he received his BS and MS degrees from the University of Tokyo, he obtained a research position at the Institute for Molecular Science (Okazaki, Japan) in 1980. In 1989, he was invited as a lecturer in the Department Applied Chemistry at the University of Tokyo, where he was promoted to an associate professor in 1991. When he became a full professor in 1997, he opened his own laboratory at the Research Centre of Advanced Science & Technology. He also succeeded the chair of the Department of Applied Chemistry in 2003 and opened the laboratory at this department, too. His current research interests are development of functionalized materials for energy conversion and environmental purifications such as photocatalysts, polymer photovoltaic materials, electrochemical catalysts and microbial catalysts.

His recent papers include:

Efficient oxygen reduction by a Fe/Co/C/N nano-porous catalyst in neutral media, J. Mater. Chem. A, 2013, Advance Article, DOI: 10.1039/C2TA00392A
Poly(bis-2,6-diaminopyridinesulfoxide) as an active and stable electrocatalyst for oxygen reduction reaction, J. Mater. Chem., 2012, 22, 12263
Synthesis and application of poly(fluorene-alt-naphthalene diimide) as an n-type polymer for all-polymer solar cells, Chem. Commun., 2012,48, 5283-5285

.Deputy Editor-in-Chief, Journal of Materials Chemistry B

Christine E. Schmidt is the B.F. Goodrich Endowed Professor of Materials Engineering in the Departments of Biomedical Engineering and Chemical Engineering at the University of Texas at Austin. Dr. Schmidt received her B.S. degree in Chemical Engineering from the University of Texas at Austin in 1988 and her Ph.D. in Chemical Engineering from The University of Illinois at Urbana-Champaign in 1995. She conducted postdoctoral research at MIT as an NIH Postdoctoral Fellow, joining the UT Austin faculty in 1996. Dr. Schmidt will be moving to the University of Florida to be the J. Crayton Pruitt Family Professor & Department Chair for the J. Crayton Pruitt Family Department of Biomedical Engineering, effective January 1, 2013. Dr. Schmidt’s research is focused on developing new biomaterials and biomaterial composites (e.g., electronic polymer composites, natural material scaffolds and processed tissues) for neural engineering applications.

Her recent papers include:

Neuronal growth promoting sesquiterpene–neolignans; syntheses and biological studies, Org. Biomol. Chem., 2012,10, 383-393

Deputy Editor-in-Chief, Journal of Materials Chemistry C

Peter Skabara was born in Edinburgh in 1968. He was educated at Bolton School and gained his first degree from QMW, University of London. After completing his doctoral studies under the supervision of Professor Martin Bryce at the University of Durham (1994), he went on to work in the group of Professor Klaus Müllen at the Max-Planck Institute for Polymer Research in Mainz. In 2005 he joined the University of Strathclyde as the first WestCHEM Professor and is currently the 1870 Young Chair of Chemistry. His research activities involve the synthesis of electroactive molecules and macromolecules and their application in organic semiconductor devices.

His recent papers include:

BODIPY-based conjugated polymers for broadband light sensing and harvesting applications, J. Mater. Chem., 2012,22, 14119-14126
Electrochromic properties of a poly(dithienylfuran) derivative featuring a redox-active dithiin unit, Polym. Chem., 2012,3, 2277-2286
Incorporation of fused tetrathiafulvalene units in a DPP–terthiophene copolymer for air stable solution processable organic field effect transistors, J. Mater. Chem., 2012,22, 11310-11315

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Journal of Materials Chemistry A, B and C Issue 1’s now online

The first issues of the newly formed Journal of Materials Chemistry A, B and C have been published online! Each journal showcases high impact research you expect from Journal of Materials Chemistry, now in three separate journals. For more information, please go to http://rsc.li/jmc-abc.

Journal of Materials Chemistry A features articles on the following:

Multifunctionality in metal@microgel colloidal nanocomposites, Jorge Pérez-Juste and Luis M. Liz-Marzán et al.: This Highlight describes recent developments related to hybrid nanocomposites comprising a metal core and a smart microgel shell.

Naturally occurring iron oxide nanoparticles: morphology, surface chemistry and environmental stability, Haibo Guo and Amanda S. Barnard : There is much to be learned from the simple and effective materials chemistry of naturally occurring nanomaterials.

Aluminum-stabilized NASICON-structured Li3V2(PO4)3, John B. Goodenough et al.: The redox couple, V4+/V3+, exhibits a potential of 3.76 V in NASICON-structured Li3Al0.1V1.9(PO4)3, which is suitable for a cathode material of a lithium-ion battery.

Importance of small micropores in CO2 capture by phenolic resin-based activated carbon spheres, Nilantha P. Wickramaratne and Mietek Jaroniec: Phenolic resin-based carbon spheres obtained by a slightly modified Stöber method are shown to be superior CO2 adsorbents.

Journal of Materials Chemistry B features articles on the following:

Biomimetic intracellular matrix (ICM) materials, properties and functions. Full integration of actuators and sensors, Toribio F. Otero and Jose G. Martinez: The electrochemistry of conducting polymers, and other organic compounds, originates biomimetic (intracellular matrix, ICM, reactive gels) materials, properties and devices here reviewed.

Cellular uptake and gene delivery using layered double hydroxide nanoparticles, Jun Lu, David G. Evans and Dermot O’Hare: The cellular uptake of fluorescein labelled 20 nm LDH nanoparticles into NSC 34 cells as a function of LDH particle concentration and incubation time was studied. The 20 nm LDH nanoparticles can also act as a DNA delivery agent to NSC 34 cell nuclei.

Biocompatible reduction-responsive polypeptide micelles as nanocarriers for enhanced chemotherapy efficacy in vitro, Xuesi Chen et al.: Biocompatible reduction-responsive micelles of disulfide-linked methoxyl poly(ethylene glycol) and poly(ε-benzyloxycarbonyl-L-lysine) block copolymers were developed for efficient intracellular drug delivery.

Theoretical understanding of single-stranded DNA assisted dispersion of graphene, Swapan K. Pati et al.: Using atomistic molecular dynamics (MD) simulation, we investigate the structure and energetic of single-stranded DNA (ssDNA) assisted solubilisation of single-layer graphene in aqueous medium at room temperature.

Journal of Materials Chemistry C features articles on the following:

Pyroelectric and electrocaloric materials, Q. M. Zhang et al.: This review summarizes typical properties of electrocaloric and pyroelectric materials and discusses related phenomena, and examines the relationship between these effects.

Graphenylene, a unique two-dimensional carbon network with nondelocalized cyclohexatriene units, Klaus Müllen and Linjie Zhi et al.: The unique structure and properties of a new hypothetical two-dimensional sp2-carbon network which is called graphenylene, have been predicted.

A deep-blue emitting charged bis-cyclometallated iridium(III) complex for light-emitting electrochemical cells, Wiebke Sarfert, Enrique Ortí, Michael Grätzel and Etienne Baranoff et al.: A cationic iridium(III) complex based on 2′,6′-difluoro-2,3′-bipyridine shows deep-blue emission in a concentrated film and is used in light-emitting electrochemical cells.

The design and investigation of porphyrins with liquid crystal properties at room temperature, Ross W. Boyle and Georg H. Mehl et al.: Porphyrins linked via hydrocarbon and siloxane spacers to cyanobiphenyls exhibit semectic LC behaviour at room temperature, confirmed by OPM, DSC and XRD.

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