Chemical Communications Blog

Professor Philip P. Power (University of California, Davis) turned 65 in April 2018 and in honour of this anniversary and his immense influence on the field of organometallic chemistry we’re pleased to introduce a new cross-journal themed collection. 

Guest edited by Roland C. Fischer, Michael S. Hill, and David J. Liptrot the collection brings together 27 of Professor Power’s key RSC papers with specially commissioned work for Dalton Transactions and Chem. Commun. by over 45 by his coworkers and protégés.

Read the editorial, in which the guest editors give an overview of Professor Power’s career and highlight some of his contributions to the study of low coordinate systems, multiple bonding, small molecule activation, and London dispersion forces, or read on to check out some of the many hot articles inspired by his work.

1,3,2-Diazaborole-derived carbene complexes of boron

Hunter P. Hickox, Yuzhong Wang, Kaitlin M. Luedecke, Yaoming Xie, Pingrong Wei, Deidrah Carrillo, Nathaniel L. Dominique, Dongtao Cui, Henry F. Schaefer, III and Gregory H. Robinson

Dalton Trans., 2018,47, 41-44 10.1039/C7DT04079B   1,3,2-Diazaborole-derived carbene complexes of boron were synthesized via 1,2-hydrogen migration.

A snapshot of inorganic Janovsky complex analogues featuring a nucleophilic boron center

Di Wu, Yongxin Li, Rakesh Ganguly and Rei Kinjo 

Neutral two-dimensional organometallic–organic hybrid polymers based on pentaphosphaferrocene, bipyridyl linkers and CuCl

M. Elsayed Moussa, B. Attenberger, E. V. Peresypkina and  M. Scheer 

Dalton Trans., 2018,47, 1014-1017 10.1039/C7DT04286H   The reaction of the Pn ligand complex [Cp*Fe(η5-P5)] (1: Cp* = η5-C5Me5) with CuCl in the presence of 4,4′-bipyridine or 1,2-di(4-pyridyl)ethylene leads to the formation of three unprecedented neutral 2D organometallic–organic hybrid networks.

C–H and H–H activation at a di-titanium centre

Nikolaos Tsoureas, Jennifer C. Green and  F. Geoffrey N. Cloke 

Divergent reactivity of nucleophilic 1-bora-7a-azaindenide anions

Matthew M. Morgan, J. Mikko Rautiainen, Warren E. Piers, Heikki M. Tuononen and Chris Gendy 

Dalton Trans., 2018,47, 734-741 10.1039/C7DT04350C   The reactions of 1-bora-7a-azaindenide anions, prepared in moderate to excellent yields by reduction of the appropriate 1-bora-7a-azaindenyl chlorides with KC8 in THF, with alkyl halides and carbon dioxide were studied.

Carbodiimides as catalysts for the reduction of a cadmium hydride complex

D. J. Webb, C. M. Fitchett, M. Lein and J. R. Fulton

All articles in this collection will be free to access until the 19th of June.