Molecular box treats chemists to a strained surprise

Introducing pillar[4]pyridinium – the first of a new family of macrocycles

Pillar[4]pyridinium
Source: Grzegorz Sobczak Oksana Danylyuk and Volodymyr Sashuk

Scientists in Poland have made the most compact multiply charged macrocycle to date. Pillar[4]pyridinium is a cyclic tetramer consisting of four pyridyl units with methylene bridges between their nitrogens and para carbons. The quadruply charged molecule has a very symmetrical and incredibly strained structure. It represents a new class of cationic macrocycles, the pillar[n]pyridiniums.

Read the full story by Jennifer Newton on Chemistry World.

Digg This
Reddit This
Stumble Now!
Share on Facebook
Bookmark this on Delicious
Share on LinkedIn
Bookmark this on Technorati
Post on Twitter
Google Buzz (aka. Google Reader)