Archive for October, 2010

Organising nanoporous arrays

An intrinsically conducting polymer (ICP)-organised nanopore array can be formed by controlled
electropolymerisation of pyrrole from an ionic-surfactant-solution in a titanium dioxide nanotubular matrix. 

Damian Kowalski and Patrik Schmuki from the University of Erlangen–Nurnberg, in Germany, have shown that the polymerisation is initialised selectively in the space between nanotube walls, forming a mechanically stable polymer network where wall thicknesses can also be controlled. Such robust polymer nanostructures are very promising for application in electrochemical systems.

Would you like to know more on the methodology and reaction conditions used by the team? Then why not download the article today, which is free to access until the 22nd November. Why not blog some comments on this article below too?

 

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Iron nitrato complexes in a spin

Low-spin nitrato iron complexes were formed by sequential reactions of oxygen and ammonia with thin layers of an iron porphyrin complex at low temperatures (80–100 K). Tigran Kurtikyan from the National Academy of Sciences in Armenia and Peter Ford from the University of California in the US, believe that the kinetic barrier for such isomerisations must be quite low, regardless of the reaction mechanism used.

 

Fancy studying the IR and visible spectra obtained to support these conclusions? Why not download the article today, which is free to access until the 22nd of November and blog some comments below.

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Selective C-C bond forming reaction

Remarkably different selectivity can be obtained in the reaction of silicon enolates with α,β-unsaturated aldehydes by swapping the classically used Lewis acid catalysts for in situ-generated silicon Lewis acids, say Japanese scientists.

Read more about the conditions used by Takeo Taguchi and colleagues (Tokyo University of Pharmacy and Life Sciences) in their communication, free to access online until 22nd November.

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A silver bullet for DNA separation

A simple and greener way to separate DNA using branched silver microparticles is revealed by scientists in China.

Separation techniques are required for a multitude of applications from disease diagnosis to environmental monitoring. Many materials are used to separate complex chemical mixtures with more recent interest focussing on magnetic nanoparticles as they can be easily recovered.

However, preparation of magnetic nanoparticles requires a large amount of organic reagents and energy and it can be difficult to get the right dimensions. Now Erkang Wang and co-workers at the Changhun Institute of Applied Chemistry have developed crystalline silver particles, know as dendrites, as an alternative to magnetic nanoparticles for DNA separation. ‘The development of a facile, economical and simple strategy to synthesize a new monodisperse, easily-modified substitute for magnetic nanoparticles with controlled size is a great challenge’ explains Wang.

Nanoparticles can be used to detect DNA then be easily separated using gravity

Read the full story here

Link to journal article
Ultrasensitive nucleic acid detection using confocal laser scanning microscope with high crystalline silver dendrites
Xuan Yang, Xuping Sun, Zhaozi Lv, Weiwei Guo, Yan Du and Erkang Wang, Chem. Commun., 2010, DOI: 10.1039/c0cc03280h

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Are texaphyrins the next radiotherapeutic carriers?

US scientists have shown that texaphyrins can strongly bind lead and bismuth showing promise for future radiotherapeutic treatments of cancerous tumours.

ChemComm Associate Editor, Jonathan L. Sessler and colleagues from the University of Texas at Austin, have investigated the cytotoxicity of the stable texaphyrin complexes with ovarian cancer cells. Previous studies show that texaphyrin ligands accumulate in rapidly growing tissues, including cancerous lesions. So, to have now incorporated lead or bismuth – isotopes of which are commonly used in radiotherapy – into the texaphyrin structure makes a deadly combination for targeting and attacking cancerous cells.

 

Want to read more? Why not download the article today which is free to access until the 19th November.

Have you recently overcome a complex challenge? Why not submit your next set of exciting research results to ChemComm today.

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Filled carbon nanotubes used in batteries

A new anode material, consisting of carbon nanotubes (CNTs) filled with iron oxide nanoparticles, has been used in a lithium-ion battery, by scientists in China. The material showed highly desirable cycling performance and rate capability, which Chang Liu and co-workers at Chinese Academy of Sciences, in Shenyang attribute to the small size of the iron oxide nanoparticles, and also the confinement effect and good electrical conductivity of CNTs.

 

Fancy reading more? Then why not download the article today, which is free to access until the 22nd November.

Is your research creating a buzz in the scientific community? Then why not submit your next high impact set of results to ChemComm today!

 

 

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Fullerenes put organic photovoltaics in order

Interactions that control the molecular ordering of fullerene are rare. This is a problem for scientists designing fullerene-based photovoltaic devices and field effect transistors, as the fullerenes must be ordered in the solid state to achieve high carrier mobility.

Now Eiichi Nakamura, at the University of Tokyo, Japan, and colleagues think they may have discovered an effective way to organise fullerene. They found that a perfluoro aromatic ring interacts face-to-face with fullerene resulting in close fullerene-fullerene contact. By attaching C6H5 groups to C60, they showed they could form an ordered crystalline arrangement of fullerenes in the solid state.

Graphical abstract: Face-to-face C6F5–[60]fullerene interaction for ordering fullerene molecules and application to thin-film organic photovoltaics

Nakamura tested the performance of the fullerenes in a thin film photovoltaic device and achieved a power conversion efficiency of 1.5 %. The group now plan to do detailed physical studies on the device performance.

Read more in Nakamura’s ChemComm communication, free to access until 22nd November.

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Where on Earth has our water come from?

Evidence that water came to Earth during its formation from cosmic dust, rather than following later in asteroids, has been shown by a group of international scientists.

The origin of the abundant levels of water on Earth has long been debated with the main differences in the theories being the nature of the material that carries the water, and whether the water came during or after planet formation.

Now, Nora de Leeuw at University College London, UK, and colleagues have used molecular-level calculations to prove that dissociative chemisorption of water onto the surface of olivine rich minerals, such as forsterite, is highly exothermic. And so when these mineral dust particles came together during Earth formation, gas-solid interactions could have resulted in water being adsorbed onto the surface of the dust particles. This means that water could have been part of the Earth from the very beginning.

Water could have been adsorbed onto minerals that created the Earth

‘Our calculations indicate that it is viable for water to become adsorbed at the surfaces of dust particles in the interstellar medium, where planets are formed. The water is thus trapped and becomes incorporated into the Earth,’ says de Leeuw.

De Leeuw’s work challenges the common assumption made by astronomers that the Earth’s water originated from bodies in the asteroid belt. ‘The work will be of tremendous interest to those modelling the geology and habitability of extrasolar terrestrial planets,’ comments Philip Armitage, an expert in astrophysical and planetary sciences at the University of Colorado, Boulder, US.

Rebecca Brodie

Find out more in de Leeuw’s communication. Are you sitting on results that are out of this world? Submit today to ChemComm and make an impact.

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Nucleases used to detect nucleic acids

Scientists in the US have used restriction endonucleases to detect nucleic acids that do not contain restriction endonuclease recognition sites. Herman Sintim and colleagues at the University of Maryland, College Park, show that the topology of DNA probes used in this detection strategy remarkably affects the efficiency of RNA/DNA detection.

Want to find out more? Why not download the article and let us know your thoughts by blogging some comments below. Published in ChemComm this article will be free to access until the 5th November. 

This article is also part of the ‘Emerging Investigators’ issue, due to be published later on this year.
This issue will highlight the very best work from scientists in the early stages of their independent career
from across the chemical sciences.

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Electron transfer for corroles

Hydride transfer from dihydronicotinamide adenine dinucleotide (NADH) analogues to manganese(V)–oxo
corroles has been shown for the first time by scientists in Korea and Japan. Wonwoo Nam and colleagues at Ewha Womans University collaborated with Shunichi Fukuzumi from Osaka University to show that the reaction proceeds via proton-coupled electron transfer, followed by rapid electron transfer.

Fancy reading more? Why not download the article today and blog some comments below. Published in ChemComm,
this article will be free to access until the 12th November.

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