International Symposium on Macro- and Supramolecular Architectures and Materials (MAM-14)

MAM-14 7th International Symposium on Macro- and Supramolecular Architectures and MaterialsThe 7th International Symposium on Macro- and Supramolecular Architectures and Materials (MAM-14) Conference will take place from 23–27th November in Johannesburg, South Africa. The conference will cover topics such as nanotechnology; materials chemistry and analysis; material functionalization; and macro- and supramolecular architectures.

Three Nobel laureates (Prof. Dan Shectman – Nobel Prize for the discovery of quasicrystals; Prof. Robert Huber –  Nobel Prize for the determination of the three-dimensional structure of a photosynthetic reaction centre; and Prof. Dr. Klaus von Klitzing – Nobel Prize for the discovery of the quantized Hall effect) will be speaking at the event. They will be joined by a host of other Plenary and invited speakers. To view the full speaker list, please click here.

To find out more about the conference and to register, please visit the website.

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Does size matter? Rational design of potent ice recrystallization inhibitors

Ice recrystallization inhibition (IRI) activity is a highly desirable property for an effective cryoprotectant. Cryopreservation is a very important process for regenerative medicine therapies, but ice recrystallization causes reduced post thaw cell viability. Although antifreeze proteins (AFPs) and antifreeze glycoproteins (AFGPs) were first investigated as cryoprotectants, their ability to bind and alter the ice crystals behaviour has encouraged researchers to look for further improvement in this field. This has led to the development of AFGP to AFGP analogues and further to the discovery of small carbohydrate-based IRIs with similar IRI activity to that of native AFGP-8.

In this review, Robert Ben and co-workers from the University of Ottawa, Canada, present recent developments of IRIs mainly focusing on novel small molecules that have emerged as potential cryoprotectants.

Designing ice recrystallization inhibitors: from antifreeze (glyco)proteins to small molecules

They begin with the molecular mechanism of the ice recrystallization phenomenon and it’s relation with IRI activities of biological antifreezes. The recent strategies for improving antifreeze compounds have been thoroughly discussed including large protein or peptide analogues, easily accessible synthetic polymers, simple mono- and disaccharide derivatives, truncated C-linked glycopeptides and carbohydrate or lysine-based surfactants/gelators. This review nicely highlights the importance of hydration index, relative orientation of hydrophilic groups and size of the linker of synthetic antifreeze compounds on their overall IRI activity.

In future these kinds of highly IRI active small molecules may replace the most widely used cytotoxic cryoprotectant DMSO and improve upon currently limited cryopreservation protocols.

Read the full review in RSC Advancesfree to access for 4 weeks:

Designing ice recrystallization inhibitors: from antifreeze (glyco)proteins to small molecules

Anna K. Balcerzak, Chantelle J. Capicciotti, Jennie G. Briard and Robert N. Ben,  RSC Adv., 2014, 4, 42682-42696

You may also be interested in these related articles:

The importance of hydrophobic moieties in ice recrystallization inhibitors

Anna K. Balcerzak, Michela Febbraro and Robert N. Ben,  RSC Adv., 2013, 3, 3232-3236

Developing highly active small molecule ice recrystallization inhibitors based upon C-linked antifreeze glycoprotein analogues

John F. Trant, Robyn A. Biggs, Chantelle J. Capicciotti and Robert N. Ben,  RSC Adv., 2013, 3, 26005-26009

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Supramolecular Chemistry Themed Collection now online

The latest RSC Advances web-collection on the topic of Supramolecular Chemistry is now available to view online!

The anion complexation properties of a fluorinated alcohol that is isosteric with a simple isophthalamide revealed that the alcohol can complex weakly basic anions with stability constants greater than those of the isophthalamide.The title of the collection is ‘Supramolecular chemistry: self-assembly and molecular recognition’ and is Guest Edited by Professor Mike Ward (University of Sheffield, UK). The articles presented here cover many aspects of the formation of, and molecular recognition with, non-covalent self-assembled systems. Systems studied span the range of supramolecular assemblies from MOFs to gels, and potential applications or functional behaviour that are on display here include host/guest chemistry, spin crossover, molecular sensors, and extraction/separation.  This collection of articles powerfully illustrates the diversity and increasing importance of supramolecular chemistry, and we hope you enjoy reading it.

Click here to view the full collection.

Some highlights from the collection include:

A ligand possessing two orthogonal metal binding sites is designed to bind three-fold and four-fold symmetric metal ions in such a way as to form a cage.An octahedral aluminium(III) complex as a three-fold node for supramolecular heterometallic self-assemblies: solution and solid state chemistry
Damien Simond, Sarah E. Clifford, Andreia F. Vieira, Céline Besnard and Alan F. Williams 
RSC Adv., 2014, 4, 16686-16693
DOI: 10.1039/C4RA00575A

Subtle backbone modifications control the interpenetration of dibenzosuberone-based coordination cages
Thorben R. Schulte, Marcel Krick, Carmen I. Asche, Sabrina Freye and Guido H. Clever 
RSC Adv., 2014, 4, 29724-29728
DOI: 10.1039/C4RA04679J

The versatility of “click” reactions: molecular recognition at interfaces
Thomas Heinrich, Christoph H.-H. Traulsen, Erik Darlatt, Sebastian Richter, Johannes Poppenberg, Nora L. Traulsen, Igor Linder, Andreas Lippitz, Paul M. Dietrich, Baha Dib, Wolfgang E. S. Unger and Christoph A. Schalley 
RSC Adv., 2014, 4, 17694-17702
DOI: 10.1039/C4RA01730G

Melting temperatures deduced from molar volumes: a consequence of the combination of enthalpy/entropy compensation with linear cohesive free-energy densities
Thibault Dutronc, Emmanuel Terazzi and Claude Piguet 
RSC Adv., 2014, 4, 15740-15748
DOI: 10.1039/C4RA00348A

Bis-triazolium containing macrocycles, pseudorotaxanes and interlocked structures for anion recognition
Nicholas G. White, Henry G. Lovett and Paul D. Beer 
RSC Adv., 2014, 4, 12133-12147
DOI: 10.1039/C4RA00615A

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Winning by an E-nose

By Sarah Brown, web writer for RSC Advances

Superhuman olfaction isn’t right up there on my list of desired super powers for a number of reasons that I won’t share here; however, an enhanced appreciation for the detection of various gases is underrated.

For example, the ability to detect toxic gases is of huge benefit, particularly at levels before they pose danger to humans. Electronic noses (E-noses) have been created from nanowire arrays as devices for sensing technology; however, most E-noses require operating temperatures of over 200 °C, which may be a limiting factor in their practical application.

Writing in RSC Advances, Chatchawal Wongchoosuk and co-workers describe the fabrication of a ZnO-based E-nose that operates at room temperature and can detect down to the ppb level. The ZnO nanowires were surface modified to include ZnO-ZnAl2O3 and ZnO-Zn2TiO4 core-shell nanowires, which formed electrical connections by self-assembly. Ultraviolet light, positioned above the sensors, was used to generate electron hole pairs and oxygen species, which, on reaction with a gas or gases could change the layer width of the nanowires and ultimately lead to the detection and characterisation of the substance.

The ability for the E-nose to operate sensitively at room temperature makes a lot of scents and these developments are not something to be sniffed at (groan!)

Read the full article by clicking the link below – free to access until 16th October:

Electronic nose for toxic gas detection based on photostimulated core–shell nanowires
Chatchawal Wongchoosuk, Kittitat Subannajui, Chunyu Wang, Yang Yang, Firat Güder, Teerakiat Kerdcharoen, Volker Cimalla and Margit Zacharias, RSC Adv., 2014, 4, 35084–35088, DOI: 10.1039/C4RA06143H


Sarah Brown Sarah Brown is a guest web-writer for RSC Advances. Sarah hung up her lab coat after finishing her PhD and post-doctorate in nanotechnology for diagnostics and therapeutics and now works in academic publishing. When not trying to explain science through ridiculous analogies, you can often find her crocheting, baking or climbing, but not all at once.

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Top 10 most-downloaded articles: April–June 2014

Take a look at the most-downloaded RSC Advances articles from the months of April, May and June 2014 and let us know what you think!

Size-controlled silver nanoparticles synthesized over the range 5–100 nm using the same protocol and their antibacterial efficacy
Shekhar Agnihotri, Soumyo Mukherji and Suparna Mukherji
RSC Adv., 2014,4, 3974-3983
DOI: 10.1039/C3RA44507K

Using a two-step deposition technique to prepare perovskite (CH3NH3PbI3) for thin film solar cells based on ZrO2 and TiO2 mesostructures
Dongqin Bi, Soo-Jin Moon, Leif Häggman, Gerrit Boschloo, Lei Yang, Erik M. J. Johansson, Mohammad K. Nazeeruddin, Michael Grätzel and Anders Hagfeldt
RSC Adv., 2013,3, 18762-18766
DOI: 10.1039/C3RA43228A

Graphene-based photocatalytic composites
Xiaoqiang An and Jimmy C. Yu
RSC Adv., 2011,1, 1426-1434
DOI: 10.1039/C1RA00382H

Synthesis of multicomponent sulfide Ag2ZnSnS4 as an efficient photocatalyst for H2 production under visible light irradiation
Kan Li, Bo Chai, Tianyou Peng, Jin Mao and Ling Zan
RSC Adv., 2013,3, 253-258
DOI: 10.1039/C2RA21481D

Engineered fluorescence tags for in vivo protein labelling
Zhipeng Wang, Xiaozhe Ding, Sijian Li, Jing Shi and Yiming Li
RSC Adv., 2014,4, 7235-7245
DOI: 10.1039/C3RA46991C

Copper-catalyzed aerobic alcohol oxidation under air in neat water by using a water-soluble ligand
Guofu Zhang, Xingwang Han, Yuxin Luan, Yong Wang, Xin Wen, Li Xu, Chengrong Ding and Jianrong Gao
RSC Adv., 2013,3, 19255-19258
DOI: 10.1039/C3RA43366H

Biosynthesis of natural products by microbial iterative hybrid PKS–NRPS
Katja Maria Fisch
RSC Adv., 2013,3, 18228-18247
DOI: 10.1039/C3RA42661K

Bioinspired self-cleaning surfaces with superhydrophobicity, superoleophobicity, and superhydrophilicity
Shunsuke Nishimoto and Bharat Bhushan
RSC Adv., 2013,3, 671-690
DOI: 10.1039/C2RA21260A

Nanoscale conductive niobium oxides made through low temperature phase transformation for electrocatalyst support
Kan Huang, Yunfeng Li, Litao Yan and Yangchuan Xing
RSC Adv., 2014,4, 9701-9708
DOI: 10.1039/C3RA47091A

Role of graphene/metal oxide composites as photocatalysts, adsorbents and disinfectants in water treatment: a review
Ravi Kant Upadhyay, Navneet Soin and Susanta Sinha Roy
RSC Adv., 2014,4, 3823-3851
DOI: 10.1039/C3RA45013A

Interesting in submitting to RSC Advances? You can submit online today, or email us with your ideas and suggestions.

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Total Food 2014

The Total Food 2014 Conference will be taking place from the 11th–13th November in Norwich, UK.

Total Food 2014 is the fourth in a series of international conferences which focus on the sustainable exploitation of agri-food co-products and related biomass, thereby helping to minimise waste.

Total food 2014 Conference, Norwich, UK November 2014Under the auspices of the Royal Society of Chemistry (Food Group), this three day event will provide an open forum to highlight recent developments and to facilitate knowledge transfer between representatives of the agri-food industries, scientific research community, legal experts on food related legislation and waste management, and consumer organisations. The 2014 conference will be run by the Institute of Food Research in collaboration with the COST Action Network TD1203 Food waste valorisation for sustainable chemicals, materials and fuels (EUBis), and will comprise plenary lectures, short talks, poster sessions, and focussed workshops. The conference is currently open for registration and abstracts can be accepted for poster presentation.

For more details about the conference and to register, please visit the website: http://www.ifr.ac.uk/totalfood2014/

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21st century bumps in the night

Posted on behalf of Sarah Brown, web writer for RSC Advances

To state the obvious, Louis Braille was a bit of a legend. Taking an existing idea, developing and simplifying it, he enabled those with visual impairments another level of independence. What adds to his profile as genius is that he wasn’t even appreciated in his own time.

The Braille system was based on a system known as ‘night writing’ invented by the fabulously titled Captain Charles Barbiere la Sierre for soldiers to communicate in the dark without having to turn on a light or talk. This comprised 12 dots in six rows, formed by indents into the back of a surface to create patterns of raised dots that could be scanned by touch. Louis Braille stripped this back to the system that we now recognise, of up to six dots in three rows. Apparently Barbiere took the hump at this and Braille’s peers at the school for the blind where he taught were reluctant to take it up until after his death. I detect a hint of jealousy.3D printing for better Braille - RSC Advances

As Wongjin Jo and co-workers, authors of a paper recently published in RSC Advances, point out, characters in Braille generally come in only one font size, with no distinctions for titles or paragraph text. Furthermore, the characters can become more difficult to detect if repeatedly depressed. The recent surge in the capabilities of 3D printing can help overcome these limitations and more by adding the ‘dots’ to surfaces, rather than indenting them. Using a thermoplastic polymer, layers of dots can be added to generate characters of varying sizes and thicknesses on various surfaces, with the potential to offer visually impaired people the ability to add braille characters as they require and for the circumstances they personally encounter.

To protect the characters and improve their durability, the authors used a thermal reflow process to improve the surface smoothness and adhesion to the platform it was built on.

The flexibility of 3D printers and their expected drop in costs as they become more ubiquitous furthers the work of Louis Braille and opens the world up a little wider for those with visual impairments.

Interested in finding out more? Read the full article using the link below:

3D printed tactile pattern formation on paper with thermal reflow method, Wonjin Jo, Hyun Kim, Jeong Sim Lee, Jeon Ju Lee and Myoung-Woon Moon, RSC Advances, 2014, 4, 31764


Sarah Brown Sarah Brown is a guest web-writer for RSC Advances. Sarah hung up her lab coat after finishing her PhD and post-doctorate in nanotechnology for diagnostics and therapeutics and now works in academic publishing. When not trying to explain science through ridiculous analogies, you can often find her crocheting, baking or climbing, but not all at once.

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Tracking complex reactions in space and time

Helen Bache writes about a hot RSC Advances article for Chemistry World

Scientists in Taiwan have put together a system that uses a computer screen and digital camera to obtain spatial, temporal and spectral information on reaction samples, with a set-up cost of just £400.

Pawel Urban who led the research at National Chiao Tung University, Taiwan, points out that ‘chemical processes occur in space and time, but few analytical methods provide both spatial and temporal information’. Most chemical reaction mixtures are also not homogeneous, but traditional spectral techniques for monitoring them assume homogeneity. Pawel believes it is important to look into the intrinsic non-uniformities which can affect the progress of chemical reactions


Read the full article in Chemistry World»

Read the original journal article in RSC Advances – it’s free to access until 10th September:
Spectral imaging of chemical reactions using a computer display and a digital camera
Kai-Ta Hsieh and Pawel L. Urban  
RSC Adv., 2014, 4, 31094-31100, DOI: 10.1039/C4RA04207G

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8th International Conference on Environmental Catalysis – ICEC 2014

The 8th International Conference on Environmental Catalysis (ICEC 2014) will be held in Asheville, North Carolina, USA between the 24-27 August 2014.

The conference aims to discuss technological challenges in environmental catalysis and the scientific programme will be based around the following main topics:

Sustainable and clean energy production
– Bio-fuel catalysis
– Fuel cells, electrolysis and solar fuels
– Fuel reforming
– Catalytic oxidation
– Photocatalysis
– Hydrotreatment of fuels
Emission control
– Mobile and stationary source emissions
– TWC, Lean de-NOx, and diesel emissions
Indoor air cleaning
– Catalytic processes to clean indoor air (VOCs, PAH)

Water treatment
– Non-biodegradable organic oxidation
– Nitrates reduction
– Sludge removal
Green Chemistry
– Biomass to chemicals
– Catalytic conversion of CO2
– Environmentally friendly catalytic processes
– Photocatalysis

The conference programme will also include three Plenary lectures by:

  • Professor Masakazu Anpo (Osaka Prefecture University)
  • Dr Klaus Harth (BASF)
  • Professor Enrique Iglesia (UC Berkeley)

Advanced registration ends the 31st July 2014 – click here to register today.

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A real red alert for explosives

Susannah May writes about a hot RSC Advances article for Chemistry World

Scientists in Spain have developed a new material that changes colour around air- or waterborne TNT. The chemical, which could be used to make intelligent clothing, alerts users to the presence of the explosive. It may prove lifesaving in former war zones, and invaluable in anti-terrorism investigations.


Read the full article in Chemistry World»

Read the original journal article in RSC Advances – it’s free to access until 1st August:
Involuntary graphene intake with food and medicine
Manav Saxena and Sabyasachi Sarkar  
RSC Adv., 2014, Accepted Manuscript, DOI: 10.1039/C4RA04022H, Paper

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