Archive for the ‘news’ Category

I love carbon quantum dots. Full stop.

Posted on behalf of Sarah Brown, web writer for RSC Advances

I love dots. The dot is one of the protagonists in the Morse code. Dot Branning in Eastenders is one resilient lady. The addition of a dot changes the length of a musical note and turns cougars into leopards. But some of the best dots have to be quantum dots, and more specifically carbon quantum dots. 

In a review recently published in RSC Advances, Pengju Luo and co-authors give an insight into the rise of carbon-based quantum dots and the growing competition they represent to semiconductor quantum dots. 

Synthesised from ingredients you could get down at the local supermarket (eg, fruit juice, caramel and BBQ’d meat), carbon-based quantum dots are a non-toxic alternative to cadmium-based quantum dots – important for application in biomedical imaging and therapies. 

Quantum Dots 

It’s the defects of the carbon nanostructures that give rise to emissions that can be detected in the near infrared and red fluorescence regions, reducing interference from background signals which is promising for tissue analysis applications. The aqueous solubility, photochemical stability and non-blinking performance further underline the advantages of this class of quantum dot. The authors illustrate this with examples of their usage in vitro, ex vivo and in vivo studies.  

Although there is still work to be done, after reading this review, you can no longer claim to be naive, or should I say naïve, about the importance of carbon-based quantum dots.

Find out more by reading the full review:

Carbon-based quantum dots for fluorescence imaging of cells and tissues
P. G. Luo, F. Yang, S. -T. Yang, S. K. Sonkar, L. Yang, J. J. Broglie, Y. Liu and Y. – P. Sun
RSC Adv., 2014, 4, 10791-10807 DOI: 10.1039/C3RA47683A 


Sarah Brown Sarah Brown is a guest web-writer for RSC Advances. Sarah hung up her lab coat after finishing her PhD and post-doctorate in nanotechnology for diagnostics and therapeutics and now works in academic publishing. When not trying to explain science through ridiculous analogies, you can often find her crocheting, baking or climbing, but not all at once.

 

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Nanofair 2014 – 10th International Nanotechnology Symposium

The 10th International Nanotechnology Symposium Nanofair 2014 – will be held at the International Congress Center Dresden, Germany between the 1st-3rd July 2014.

The theme for Nanofair 2014 is “New ideas for industry” and will provide a forum for presenting current research and exchanging ideas and information between scientists and engineers for industry, research laboratories and academia.  Contributions presented at the conference will cover fundamental scientific aspects as well as application orientated research and development.  Specific topics include:

  • Functional nanocomposites
  • Nanostructured surfaces
  • Nanomaterials for life sciences
  • Nanomaterials for energy applications
  • Nanoelectronics & photonics
  • Processing aspects of nanomaterials
  • Nanoanalytical methods
  • Carbon nanotubes & graphene

In addition, the 2nd Dresden Nanoanalysis Symposium of the Dresden Centre for Nanoanalysis will be held as part of nanofair 2014 on the 2nd July.  This international symposium will provide highlights in the field of nanoanalysis and its applictions in materials science and engineering, advanced electronics, energy research and other branches.

Registration deadline is the 6th June 2014 – click here to register today.

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Blurred bonds rationalised by heavy atom tunnelling

Written by Jennifer Newton for Chemistry World

A new theoretical study of anti-aromatic systems has attributed the unusual way that their π-bonds shift to quantum tunnelling. These intriguing findings suggest that even though heavy atom tunnelling is rare, its effect is far from negligible.

antiaromatic compounds

Quantum-mechanical tunnelling is a process by which a particle can cross a potential barrier without having enough energy to go over it. It is a completely quantum effect based on the wave nature of the particle and is connected to the de Broglie wavelength, which gets shorter as the mass of the particle gets higher. Therefore, only the lightest particles can tunnel, and in chemistry it means that it is almost impossible for anything but hydrogen. Or that is what we were taught at university . . . .

Interested in learning more? Read the full story at Chemistry World

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Molecules mimic mesmerising mathematics

Written by Stephen McCarthy for Chemistry World

 Computer models that show how organic molecules could assemble into molecular quasicrystals may open the door to new materials with exotic properties.

Imitating the famous mathematical patterns known as Penrose tilings, Dimitri Laikov of Moscow State University in Russia, designed two complementary molecular ‘tiles’ and modelled their supramolecular interactions. The resulting assembly shows the aperiodicity and five-fold rotational symmetry characteristic of quasicrystals – the first time that a complex with this property has been predicted

 

Interested? If so, read the full article at Chemistry World here!

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Pumping gone soft

Written by Harriet Brewerton for Chemistry World

Scientists are a step closer to producing soft machines that are efficient and long-lasting enough for practical applications.

 Soft pump

Engines and other machinery are currently composed of rigid parts that bear considerable forces and degrade over time. They are also limited to moving in a certain direction or around a certain axis. In nature many mechanical processes are carried out using soft materials that are nevertheless highly durable, efficient and capable of deforming and returning to their original shape in complex ways, for example the heart.

Interested? If so, read the full article at Chemistry World here.

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RSC Advances is now on Twitter

Want to keep up with all the latest news from RSC Advances?

You can now follow us on Twitter @RSC_Adv.

The feed features news on the latest HOT articles, themed issues, review articles and journal announcements. It is also a great place to follow news from the Royal Society of Chemistry, with updates on the latest conferences and bursaries as well as featuring news from our other journal publications.

Check out the feed at www.twitter.com/rsc_adv and start following RSC Advances today!

RSC Advances Twitter feed  

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Cystic fibrosis treatment clears the way

Stabilising a mucus attacking enzyme with cross-links could allow it to be delivered orally to fight infections in cystic fibrosis patients.

Pseudomonas aeruginosa is one of the commonest opportunistic pathogens in cystic fibrosis. The bacterium produces alginate, a polysaccharide which causes significant mucus build-up in the lungs and intestine. In addition to affecting patients’ quality of life, this also significantly obstructs the delivery of antibiotics, requiring increased dosages which can lead to antibiotic resistance and an increased chance of side-effects.

Guillermo Castro at the National University of La Plata in Argentina, and his team, investigate the delivery of drugs with significant administrative problems’…

Interested? If so, read the full article at Chemistry World here.

Cross-linking alginate lyase in the presence of BSA stabilises the enzyme but leaves the active site intact
Please click on the below title to access the original article which is free to access until 7th April 2014 :

Development of novel alginate lyase cross-linked aggregates for the oral treatment of cystic fibrosis
G. A. Islan, Y. N. Martinez, A. Illanes and G. R. Castro
RSC Adv., 2014, 4, 11758-11765
DOI: 10.1039/C3RA47850E

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Toilet purification system doubles as hydrogen fuel cell

An electrolysis cell that couples energy storage with water purification and reuse has been developed as part of a wider project to make a self-sustaining toilet.

The electrochemical system reduces the yellow colour of wastewater at the same time as producing hydrogen

The electrochemical system reduces the yellow colour of wastewater at the same time as producing hydrogen

Electrochemical approaches to water purification are not unknown but often focus on wastewater in industrially developed areas. Michael Hoffmann, and colleagues at the California Institute of Technology in the US, hope their electrochemical water splitting method for purifying human waste, at the same time as generating hydrogen gas, will eventually be introduced into areas with underdeveloped infrastructure.

Read the full article at Chemistry World.

Electrochemical treatment of human waste coupled with molecular hydrogen production
Kangwoo Cho, Daejung Kwon and Michael R. Hoffmann  
RSC Adv., 2014, 4, 4596-4608
DOI: 10.1039/C3RA46699J

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Reclaiming spilt oil

The ability to recover oil from land-based spills should reduce the cost of decontamination

© Shutterstock

Scientists in Canada have shown they can recover oil from contaminated sand using surfactants whose emulsion stabilising ability is deactivated by carbon dioxide.

Land-based oil spills can be remedied by taking the sand (or soil away) for washing. The sand is heated and mixed with a surfactant solution, before the oil containing emulsion is removed to leave clean sand. However, the entire emulsion must be disposed of as hazardous waste.

Switchable surfactants could offer a less wasteful solution. Unlike normal surfactants, switchable surfactants can be switched off by an external trigger, allowing the oil and water phases to separate, by destabilising the emulsion.

The negative surface charges on sand particles mean that surfactants for cleaning oil contaminated sand need to be anionic. Cationic switchable surfactants were pioneered by Philip Jessop and his colleagues at Queens University, Kingston, Ontario, in 2006, and now the team have created an anionic version.

To release oil captured by Jessop’s carboxylate and phenolate anionic surfactants carbon dioxide is bubbled through the emulsion, acidifying the aqueous phase. This switches the surfactant structure from anionic to neutral, disrupting the emulsion by removing its ability to stabilise the oil/water interface. The oil separates and can be decanted for reuse and sale. Decarbonising the solution will switch the surfactants back on.

Read the rest of the story by Emily Skinner in Chemistry World!

Read the original research paper in RSC Advances:

Switchable anionic surfactants for the remediation of oil-contaminated sand by soil washing
Elize Ceschia, Jitendra R. Harjani, Chen Liang, Zahra Ghoshouni, Tamer Andrea, R. Stephen Brown and Philip G. Jessop
RSC Adv., 2014, 4, 4638-4645
DOI: 10.1039/C3RA47158F, Paper

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HOT papers in RSC Advances

Here are the latest HOT papers published in RSC Advances:

Size-adjustable annular ring-functionalized mesoporous silica as effective and selective adsorbents for heavy metal ions
Fa-Kuen Shieh, Chia-Teng Hsiao, Hsien-Ming Kao, Yu-Chein Sue, Kuan-Wei Lin, Chang-Cheng Wu, Xi-Hong Chen, Lei Wan, Ming-Hua Hsu, Jih Ru Hwu, Chia-Kuang Tsung and Kevin C.-W. Wu  
RSC Adv., 2013, 3, 25686-25689
DOI: 10.1039/C3RA45016C

GA

A quantitative assessment of the production of ˙OH and additional oxidants in the dark Fenton reaction: Fenton degradation of aromatic amines
Claudio Minero, Mirco Lucchiari, Valter Maurino and Davide Vione  
RSC Adv., 2013, 3, 26443-26450
DOI: 10.1039/C3RA44585B

GA 

Synthesis of dibenzyl carbonate: towards a sustainable catalytic approach
Giulia Fiorani and Maurizio Selva  
RSC Adv., 2014, 4, 1929-1937
DOI: 10.1039/C3RA42904K

GA

All the papers listed above are free to access for the next 4 weeks!

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