Archive for February, 2016

Magnetic leathers

Leather is a natural, durable and flexible material that has been prepared and used by humans for millennia. Now, scientists in India have developed magnetic leathers that can make this material evermore versatile.

Made from animal hide, leather is largely made of a chromium-collagen matrix and is paramagnetic. Despite this, it does not interact effectively with magnetic fields. Introducing ferromagnetic properties to leather could enable this material to be used in smart or intelligent garments, electromagnetic interference shielding, adhesive-free wall covering and even in energy harvesting from human motion. As such, a team lead by Dr Krishbaraj Kaliappa at the Central Leather Institute in Chennai, added iron oxide nanoparticles to leather that show significant magnetic behaviour.

The team prepared leather samples using conventional finishing techniques. During this process, they applied a coating of  iron oxide nanoparticles produced by co-precipitation, or a commercially available magnetic pigment. The presence of Fe3O2 in both samples was confirmed by X-ray diffraction analysis. When compared to the paramagnetic control leather, magnetic hysteresis revealed considerable ferromagnetic behavior in the two samples. In addition, the leathers show significant response to permanent magnets. Further tests revealed that particle incorporation leaves other physical properties of the leather, largely unchanged.

Investigations in to the applications of these magnetic leathers have already shown them to be promising adhesive-free wall tiles. The team also demonstrate that their properties may also enable application in electromagnetic energy generation from human motion.

Digital images of the control leather , that with iron oxide nanoparticles and that with the commercially available magnetic pigment added during finishing.

Read the full article:

Magnetic leathers
P. Thanikaivelan, R. Murali and K. Krishnaraj
RSC Adv., 2016,6, 6496-6503 DOI: 10.1039/C5RA21909D

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Canine tea time

Researchers in China have manufactured dog food containing tea polyphenols. They have shown that when dogs are fed tea polyphenol containg food, antioxidant and antimicrobial effects, similar to those observed in humans, are demonstrated.

Fang Zhong and colleagues also wanted to test the foods palpability to find out if the dogs would actually enjoy eating it. Following a five day trial, it emerged that dogs actually preferred eating food that contained 0.5% tea polyphenols. The dogs’ diet was then restricted to either tea polyphenol containing food or the control food. Subsequent tests revealed higher levels of antioxidant activity in the dogs on the tea polyphenol diet, along with lower levels of fecal bacteria in their stool.

To find out more, read the full Chemistry World article.

Quantitative optimization and assessments of supplemented tea polyphenols in dry dog food considering palatability, levels of serum oxidative stress biomarkers and fecal pathogenic bacteria,
Maoshen Chen, Xuemei Chen, Wenli Cheng, Yue Li, Jianguo Ma and Fang Zhong
RSC Adv., 2016,6, 16802-16807
DOI: 10.1039/C5RA22790A

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Introducing the organic chemistry collection

This organic chemisty collection has been collated by Editorial Board member Professor Russell Cox (Leibniz University Hannover, Germany). It brings together articles with the continued aim of inspiring new authors to submit their best work to the journal, and also to highlight great work by regular authors. These articles are already among the most highly cited works in the journal, illustrating their impact.

The subject areas of the articles include those traditionally regarded as organic, such as synthesis, catalysis, heterocyclic and organometallic chemistry, natural products chemistry and method development. In addition, the collection also includes articles from overlapping areas, such as green chemistry, fuel production, ionic solvents and materials chemistry, where there is a strong organic and biological component. Underpinning all are theoretical and computational studies. Finally, emerging areas, including photovoltaics and chemical biology, have strong organic chemistry foundations and also find a natural home in this RSC Advances collection.

This selection aims to illustrate the breadth, depth and impact of papers published in RSC Advances in the area of organic chemistry and stimulate new submissions in these and allied areas.

The collection contains reviews, communications and full papers, all of which can be found here.

Credit: Recent advances in 4(3H)-quinazolinone syntheses, 10.1039/C4RA00351A

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