Archive for September, 2014

Supramolecular Chemistry Themed Collection now online

The latest RSC Advances web-collection on the topic of Supramolecular Chemistry is now available to view online!

The anion complexation properties of a fluorinated alcohol that is isosteric with a simple isophthalamide revealed that the alcohol can complex weakly basic anions with stability constants greater than those of the isophthalamide.The title of the collection is ‘Supramolecular chemistry: self-assembly and molecular recognition’ and is Guest Edited by Professor Mike Ward (University of Sheffield, UK). The articles presented here cover many aspects of the formation of, and molecular recognition with, non-covalent self-assembled systems. Systems studied span the range of supramolecular assemblies from MOFs to gels, and potential applications or functional behaviour that are on display here include host/guest chemistry, spin crossover, molecular sensors, and extraction/separation.  This collection of articles powerfully illustrates the diversity and increasing importance of supramolecular chemistry, and we hope you enjoy reading it.

Click here to view the full collection.

Some highlights from the collection include:

A ligand possessing two orthogonal metal binding sites is designed to bind three-fold and four-fold symmetric metal ions in such a way as to form a cage.An octahedral aluminium(III) complex as a three-fold node for supramolecular heterometallic self-assemblies: solution and solid state chemistry
Damien Simond, Sarah E. Clifford, Andreia F. Vieira, Céline Besnard and Alan F. Williams 
RSC Adv., 2014, 4, 16686-16693
DOI: 10.1039/C4RA00575A

Subtle backbone modifications control the interpenetration of dibenzosuberone-based coordination cages
Thorben R. Schulte, Marcel Krick, Carmen I. Asche, Sabrina Freye and Guido H. Clever 
RSC Adv., 2014, 4, 29724-29728
DOI: 10.1039/C4RA04679J

The versatility of “click” reactions: molecular recognition at interfaces
Thomas Heinrich, Christoph H.-H. Traulsen, Erik Darlatt, Sebastian Richter, Johannes Poppenberg, Nora L. Traulsen, Igor Linder, Andreas Lippitz, Paul M. Dietrich, Baha Dib, Wolfgang E. S. Unger and Christoph A. Schalley 
RSC Adv., 2014, 4, 17694-17702
DOI: 10.1039/C4RA01730G

Melting temperatures deduced from molar volumes: a consequence of the combination of enthalpy/entropy compensation with linear cohesive free-energy densities
Thibault Dutronc, Emmanuel Terazzi and Claude Piguet 
RSC Adv., 2014, 4, 15740-15748
DOI: 10.1039/C4RA00348A

Bis-triazolium containing macrocycles, pseudorotaxanes and interlocked structures for anion recognition
Nicholas G. White, Henry G. Lovett and Paul D. Beer 
RSC Adv., 2014, 4, 12133-12147
DOI: 10.1039/C4RA00615A

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Winning by an E-nose

By Sarah Brown, web writer for RSC Advances

Superhuman olfaction isn’t right up there on my list of desired super powers for a number of reasons that I won’t share here; however, an enhanced appreciation for the detection of various gases is underrated.

For example, the ability to detect toxic gases is of huge benefit, particularly at levels before they pose danger to humans. Electronic noses (E-noses) have been created from nanowire arrays as devices for sensing technology; however, most E-noses require operating temperatures of over 200 °C, which may be a limiting factor in their practical application.

Writing in RSC Advances, Chatchawal Wongchoosuk and co-workers describe the fabrication of a ZnO-based E-nose that operates at room temperature and can detect down to the ppb level. The ZnO nanowires were surface modified to include ZnO-ZnAl2O3 and ZnO-Zn2TiO4 core-shell nanowires, which formed electrical connections by self-assembly. Ultraviolet light, positioned above the sensors, was used to generate electron hole pairs and oxygen species, which, on reaction with a gas or gases could change the layer width of the nanowires and ultimately lead to the detection and characterisation of the substance.

The ability for the E-nose to operate sensitively at room temperature makes a lot of scents and these developments are not something to be sniffed at (groan!)

Read the full article by clicking the link below – free to access until 16th October:

Electronic nose for toxic gas detection based on photostimulated core–shell nanowires
Chatchawal Wongchoosuk, Kittitat Subannajui, Chunyu Wang, Yang Yang, Firat Güder, Teerakiat Kerdcharoen, Volker Cimalla and Margit Zacharias, RSC Adv., 2014, 4, 35084–35088, DOI: 10.1039/C4RA06143H


Sarah Brown Sarah Brown is a guest web-writer for RSC Advances. Sarah hung up her lab coat after finishing her PhD and post-doctorate in nanotechnology for diagnostics and therapeutics and now works in academic publishing. When not trying to explain science through ridiculous analogies, you can often find her crocheting, baking or climbing, but not all at once.

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Top 10 most-downloaded articles: April–June 2014

Take a look at the most-downloaded RSC Advances articles from the months of April, May and June 2014 and let us know what you think!

Size-controlled silver nanoparticles synthesized over the range 5–100 nm using the same protocol and their antibacterial efficacy
Shekhar Agnihotri, Soumyo Mukherji and Suparna Mukherji
RSC Adv., 2014,4, 3974-3983
DOI: 10.1039/C3RA44507K

Using a two-step deposition technique to prepare perovskite (CH3NH3PbI3) for thin film solar cells based on ZrO2 and TiO2 mesostructures
Dongqin Bi, Soo-Jin Moon, Leif Häggman, Gerrit Boschloo, Lei Yang, Erik M. J. Johansson, Mohammad K. Nazeeruddin, Michael Grätzel and Anders Hagfeldt
RSC Adv., 2013,3, 18762-18766
DOI: 10.1039/C3RA43228A

Graphene-based photocatalytic composites
Xiaoqiang An and Jimmy C. Yu
RSC Adv., 2011,1, 1426-1434
DOI: 10.1039/C1RA00382H

Synthesis of multicomponent sulfide Ag2ZnSnS4 as an efficient photocatalyst for H2 production under visible light irradiation
Kan Li, Bo Chai, Tianyou Peng, Jin Mao and Ling Zan
RSC Adv., 2013,3, 253-258
DOI: 10.1039/C2RA21481D

Engineered fluorescence tags for in vivo protein labelling
Zhipeng Wang, Xiaozhe Ding, Sijian Li, Jing Shi and Yiming Li
RSC Adv., 2014,4, 7235-7245
DOI: 10.1039/C3RA46991C

Copper-catalyzed aerobic alcohol oxidation under air in neat water by using a water-soluble ligand
Guofu Zhang, Xingwang Han, Yuxin Luan, Yong Wang, Xin Wen, Li Xu, Chengrong Ding and Jianrong Gao
RSC Adv., 2013,3, 19255-19258
DOI: 10.1039/C3RA43366H

Biosynthesis of natural products by microbial iterative hybrid PKS–NRPS
Katja Maria Fisch
RSC Adv., 2013,3, 18228-18247
DOI: 10.1039/C3RA42661K

Bioinspired self-cleaning surfaces with superhydrophobicity, superoleophobicity, and superhydrophilicity
Shunsuke Nishimoto and Bharat Bhushan
RSC Adv., 2013,3, 671-690
DOI: 10.1039/C2RA21260A

Nanoscale conductive niobium oxides made through low temperature phase transformation for electrocatalyst support
Kan Huang, Yunfeng Li, Litao Yan and Yangchuan Xing
RSC Adv., 2014,4, 9701-9708
DOI: 10.1039/C3RA47091A

Role of graphene/metal oxide composites as photocatalysts, adsorbents and disinfectants in water treatment: a review
Ravi Kant Upadhyay, Navneet Soin and Susanta Sinha Roy
RSC Adv., 2014,4, 3823-3851
DOI: 10.1039/C3RA45013A

Interesting in submitting to RSC Advances? You can submit online today, or email us with your ideas and suggestions.

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