Archive for December, 2013

Happy holidays from Polymer Chemistry!

All of us in the Polymer Chemistry Editorial team would like to wish you all a merry Christmas and a happy new year! The Editorial office will be closed from 24th December 2013 and will reopen on 2nd January 2014.

We’re really looking forward to 2014, which will see more high quality articles from top international polymer chemists, some great themed issues and much more.

Don’t miss out on all the journal news – follow us on twitter @PolymChem and like us on Facebook!

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Poster prize winners at the 2013 International Symposium on Stimuli-Responsive Materials

Many congratulations to the winners at the 2013 International Symposium on Stimuli-Responsive Materials! 

Chosen by an independent panel, the winners were: Akira Matsumoto (Institute of Biomaterials and Bioengineering at Tokyo Medical and Dental University) for the Journal of Materials Chemistry A, B & C poster prize, Justin Poelma for Polymer Chemistry and Saemi Oh for Soft Matter (University of California, Santa Barbara). 

The symposium which focuses on the field of stimuli-responsive materials from academia, industry, and government took place in October (20 – 22) this year at the Hilton Sonoma Wine Country in Santa Rosa, CA and was co-sponsored by the Royal Society of Chemistry. 

Akira Matsumoto

Akira Matsumoto receiving his poster prize for Journal of Materials Chemistry A, B, C

Justin Poelma

Justin Poelma receiving his prize for Polmer Chemistry

Saemi Oh winning the Soft Matter poster prize

Follow the latest journal news on Twitter @PolymChem or go to our Facebook page.

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Paper of the week: All-carbon composite paper and its application in supercapacitors

Flexible papers, which utilize graphene (G) sheets as building blocks in vacuum-assisted self-assembly, have already been developed as binder-free flexible electrodes for supercapacitors due to their excellent mechanical flexibilities and electrical conductivities. Nevertheless, in most cases, the large specific surface area of the closely-packed and oriented G sheets throughout the G papers is inevitably lost which significantly reduces their potential application as supercapacitor electrodes. Thus, it is still a great challenge to develop a feasible and effective way to fabricate G-based hybrid papers as flexible electrodes with relatively high capacitances and without the sacrifice of their good cyclic stabilities.

Graphical abstract: All-carbon composite paper as a flexible conducting substrate for the direct growth of polyaniline particles and its applications in supercapacitors

In this study, Liu and co-workers reported a new strategy for the synthesis of polyaniline (PANI) nanostructures on a flexible G–carbon nanotube (G-CNT) composite paper substrate, which can be directly used as flexible electrodes possessing both electric double layer (EDL) capacitance and pseudocapacitance. The ternary hybrid paper exhibited a reversible capacity of up to 432 F g-1 at a discharge rate of 0.5 A g-1, which was much larger than that of bare G–CNT composite paper (172.4 F g-1); and its cyclic performance was dramatically enhanced, sustaining greater than 96% of its original capacitance after 600 charge–discharge cycles. Besides, the good electrical conductivity of the G–CNT composite paper provided improved conductive pathways for charge transfer at the electrodes thus resulting in superior capacitance during charge–discharge processes. Therefore, the method reported here provides a simple and efficient approach to fabricating G–CNT–PANI ternary hybrid papers with designed hierarchical nanostructures, and may be easily extended to the design of next generation high performance flexible supercapacitors.

All-carbon composite paper as a flexible conducting substrate for the direct growth of polyaniline particles and its applications in supercapacitors by Chao Zhang, Weng Weei Tjiu and Tianxi Liu Polym. Chem. 2013, 4, 5785-5792.

Julien Nicolas is a web-writer and advisory board member for Polymer Chemistry. He currently works at Univ. Paris-Sud (FR) as a CNRS researcher.

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PPC 2013:Polymer Chemistry poster prize winners!

Polymer Chemistry was delighted to award three Poster Prizes at the 13th Pacific Polymer Conference, held in Kaoshiung, Taiwan between 17-22nd November 2013. The winners were:

Daisuke Aoki
‘Synthesis and Characterization of Rotaxane-Linked Graft Polymers’

Hua Deng
‘The Electrical Property-Strain Sensing Behavior of CPCs Based on Polyurethane’

Chieh-Cheng Huang
‘Hypoxia-Induced Therapeutic Neovascularization in A Mouse Model of An Ischemic Limb Using Cell Aggregates Composed of HUVECs and cbMSCs’

Congratulations to all three winners!

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Paper of the week: A CeO2/PVDC hybrid latex mediated by a phosphonated macro-RAFT agent

Combining organic matter with divided inorganic matter (nanoparticles, clays, nanofibers, etc.) is one of the main current trends to bring about new properties to polymer films. More specifically, emulsion polymerization allows the elaboration of waterborne hybrid films by incorporating mineral fillers into polymer particles to create hybrid latexes. Hence, when such latexes are directly applied as a coating, mineral entities are well distributed within the polymer matrix. Cerium oxide nanoparticles possess valuable properties, such as catalytic oxidation activity, relatively high ionic conductivity, and great potential as UV stabilizers. However, to benefit from the specific properties provided by nanoceria, a preliminary step is required in order to compatibilize the mineral phase with the polymer phase.

Graphical abstract: A CeO<sub>2</sub>/PVDC hybrid latex mediated by a phosphonated macro-RAFT agent

In their paper, Lacroix-Desmazes and co-workers reported the synthesis of a CeO2/poly(vinylidene chloride) (PVDC) hybrid latex carried out via the functionalization of CeO2 nanoparticles by reversible addition-fragmentation chain transfer (RAFT) polymerization from a phosphonated macro-RAFT agent, with very efficient formation of hybrid structures (neither free ceria nanoparticles nor free latex particles). This hybrid latex, obtained by emulsion polymerization with a reasonably high solid content (25%), represents a good candidate for the elaboration of high performance coatings. Furthermore, the authors also considered the use of such hybrid latexes as templates for the preparation of functional organic or inorganic porous materials with CeO2 nanoparticles (or other nanoparticles) evenly distributed in the porous matrix.

A CeO2/PVDC hybrid latex mediated by a phosphonated macro-RAFT agent by Jérôme Warnant, Jérôme Garnier, Alex van Herk, Pierre-Emmanuel Dufils, Jérôme Vinas and Patrick Lacroix-Desmazes Polym. Chem. 2013, 4, 5656-5663.

Julien Nicolas is a web-writer and advisory board member for Polymer Chemistry. He currently works at Univ. Paris-Sud (FR) as a CNRS researcher.

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