Hot Article: Synthesis and self-assembly of amphiphilic semi-brush and dual brush block copolymers in solution and on surfaces

Scientists have made giant surfactants that form globular micelles in water and can spread to worm-like structures on surfaces. The surfactants are formed from amphiphilic block copolymers and synthesised by combining RAFT and ATRP techniques.

 Graphical abstract: Synthesis and self-assembly of amphiphilic semi-brush and dual brush block copolymers in solution and on surfaces

In aqueous solution, the polymers aggregate into globular micellar aggregates, their size being determined by the length of the stretched polymer molecules. For the dual brush copolymer, a rather compact structure is formed, which is dominated by the large hydrophobic poly(n-butyl acrylate) block. On mica surfaces the triblock copolymers adsorb with worm-like backbones and stretched out side chains.

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Daniel Zehm, André Laschewsky, Peggy Heunemann, Michael Gradzielski, Sylvain Prévost, Hua Liang, Jürgen P. Rabe and Jean-François Lutz, Polym. Chem., 2011, DOI:10.1039/C0PY00200C

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