From ink wells to solar cells

Dye sensitised solar cells (DSSCs) have long been recognised as a possible answer to the energy crisis we are facing. Unfortunately, many current solar cells rely on expensive platinum or inflexible carbon based materials in their manufacture. Now, scientists in China have found a cheaper and more efficient alternative in commercial fountain pen ink.

Until now, none of the materials investigated has managed to achieve the light weight, low-cost and biodegradable properties that are attractive in manufacturing flexible electronics. However, Dechun Zou and co-workers at Peking University have found a material that has all these attributes in fountain pen ink.

Device structures of ink-based dye sensitised solar cells

The idea to use ink in DSSCs came from the concept of ‘paper electronics’, says Zou. Compared to traditional, rigid electronic devices, paper electronics may be the future in achieving the flexibility needed in many commercial applications. An example for the eco-friendly fashion conscious being the application of DSSCs on backpacks and bags for powering portable electronic devices.

Commercial pen ink consists of well-dispersed carbon nanoparticles. Here, the researchers took advantage of the good catalytic activity, high stability and well-established industrial production of the material and directly introduced the ink as a counter electrode material for DSSCs. The ink film was prepared via a spin-coating technique and the layer was shown to be only 3m thick.

Andrew Hamnett, an expert in solar energy and  president of the Scottish Marine Institute, UK, comments how the authors have ‘cleverly exploited’ the effort that has gone into optimising carbon suspensions in fountain pen inks and congratulates them on ‘a nice bit of lateral thinking’.

The energy efficiency of the cells is currently at 6.2%, which is comparable to a standard Pt electrochemical device that would be around 1000 times more expensive. Future strategies to increase the catalytic activity may include utilising other film preparation processes or further investigation into the catalytic mechanism of the ink nanoparticles, which Zou says may be ‘challenging but also promising’.

Direct application of commercial fountain pen ink to efficient dye-sensitized solar cells
Xin Cai, Zhibin Lv, Hongwei Wu, Shaocong Hou and Dechun Zou
DOI: 10.1039/C2JM16265B

Read the original Chemistry World article here

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Hot Article: Phosphorescent co-crystal assembled using halogen bonding

Halogen bonding has emerged as a powerful tool for self-assembly due to its highly directional and hydrophobic nature. In spite of the number of one dimensional or infinite linear networks assembled by 1,4-DITFB with different acceptors, no example describing C–I π halogen bonding phosphorescence crystal has been reported. In this hot article Wei Jun Jin and colleagues at Beijing Normal University, China, describe a new organic phosphorescent co-crystal material based on 1,4-DITFB and carbazole. The team says that The halogen bonding of 1,4-DITFB with carbazole is selective, and the co-crystal microparticle suspension displays strong phosphorescence. Wei Jun Jin and the team say this is the first report of a phosphorescent co-crystal assembled by weak C–I π interaction. Read the article for free until 30th April.

Phosphorescent co-crystal assembled by 1,4-diiodotetrafluorobenzene with carbazole based on C–I π halogen bonding: Hai Yue Gao, Qian Jin Shen, Xiao Ran Zhao, Xiao Qing Yan, Xue Pang and Wei Jun Jin, J. Mater. Chem., 2012, 22, 5336-5343.

 Graphical abstract: Phosphorescent co-crystal assembled by 1,4-diiodotetrafluorobenzene with carbazole based on C–Iπ halogen bonding

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Drug release polymer triggered by ultrasound

Scientists from China and Canada have found that a drug-loaded shape memory polymer can be manipulated by ultrasound and that they can control when and how the drugs are released.

Shape memory polymers (SMPs) can be deformed and fixed into a temporary shape and then recover their original permanent shape under external stimuli such as heat, explains lead researcher Hesheng Xia from Sichuan University, Chengdu. ‘When a piece of polymer is placed in the body, it is subjected to heating at 37°C everywhere and the whole piece undergoes shape recovery,’ he says. Xia and co-workers directed an ultrasound beam on a selected area of a polymer, causing a local rise in temperature and triggering shape recovery only in that area. Xia adds that ultrasound has the advantage of easily penetrating body tissue.

Schematic of the polymer changing shape and drug release

Using high intensity focused ultrasound (HIFU), the polymer was changed from its permanent M shape to a temporary I shape, then a V then an N and back to the M, releasing drugs with each change

Xia’s group loaded their SMP sample with a drug and folded it into a temporary ‘I’ shape. By directing the ultrasound onto different positions on the polymer, they could control its shape on demand, changing it from ‘I’ to ‘V’ to ‘N’ and back to the original ‘M’, releasing drugs with each shape change. They stopped the drug release by switching off the ultrasound. This caused a quick temperature drop, which allowed the polymer to adopt a stable intermediate shape.

Tao Xie, who works on shape memory polymers at the General Motors Research and Development Center, Michigan, US, was impressed that ultrasound controls the shape in a spatial and temporal manner, allowing selected regions of the polymer to be controlled on demand. He added that this would ‘significantly widen the application potential’.

Xia hopes that the switchable release of drugs from SMPs could be applied to polymer implants for minimally invasive surgery and that ultrasound may reduce infection risks. To minimise side effects, however, he says that the challenge will be to reduce the power and irradiation time of the ultrasound needed for the shape changes.

Spatial and temporal control of shape memory polymers and simultaneous drug release using high intensity focused ultrasound
Guo Li , Guoxia Fei , Hesheng Xia , Jianjun Han and Yue Zhao
DOI: 10.1039/C2JM30848G

Read the original Chemistry World article here

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Hot Article: Just add water

The giant dielectric permittivity of detonation-produced nanodiamond is caused by water, say scientists from Russia and the UK. Nanodiamonds can be produced cheaply from explosions. The team found that just by adding water to the nanodiamonds, the materials see a huge increase in electronic properties, which means that they could be used for many electronic applications, such as in high performance capacitors for microelectronics and developing large-scale capacitance-based energy storage devices that are in demand in the quest for green energy technology. Read the article for free until 26th April.

Paper: Giant dielectric permittivity of detonation-produced nanodiamond is caused by water
Stepan Segreevich Batsanov and A Batsanov,
J. Mater. Chem., 2012, DOI: 10.1039/C2JM30836C

Giant dielectric permittivity of detonation-produced nanodiamond is caused by water

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Hot Article: Changing polymer shapes with ultrasound

Scientists in China and Canada have used high intensity ultrasound to change the shape of polymers for use in surgical implants. Polymer shape recovery has been employed before using light and heat as external stimuli but not with ultrasound, which has much greater spatial and temporal control as well as being able to penetrate much deeper into body tissue.

In addition to being able to generate different shapes, the ultrasound can be used to simultaneously induce drug release from the polymer. This has a potential application in minimally invasive surgical techniques. Read this article for free until the 25th April.

Communication: Spatial and temporal control of shape memory polymers and simultaneous drug release using high intensity focused ultrasound
Guo Li, Guoxia Fei, Hesheng Xia, Jianjun Han and Yue Zhao
J. Mater. Chem., 2012, DOI: 10.1039/C2JM30848G (Advance Article)

 Spatial and temporal control of shape memory polymers and simultaneous drug release using high intensity focused ultrasound

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Top accessed Journal of Materials Chemistry Reviews of 2011

Journal of Materials Chemistry publishes highly relevant reviews by some of the leading researchers in their fields every year. We realise it can be difficult to keep on top of all the current research out there. Here’s a list of the most downloaded Feature and Highlight articles for 2011 for your convenience. We hope this helps you to keep in touch with what your peers are reading and what is hot in your field.

1. A review of advanced and practical lithium battery materials 
Rotem Marom, S. Francis Amalraj, Nicole Leifer, David Jacob and Doron Aurbach
J. Mater. Chem., 2011, 21, 9938-9954

2. Assembly of chemically modified graphene: methods and applications  
Yuxi Xu and Gaoquan Shi
J. Mater. Chem., 2011, 21, 3311-3323

3. Mesoporous silica nanoparticle based nano drug delivery systems: synthesis, controlled drug release and delivery, pharmacokinetics and biocompatibility      
Qianjun He and Jianlin Shi
J. Mater. Chem., 2011, 21, 5845-5855

4. Graphene: preparation and structural perfection
M. Inagaki, Y. A. Kim and M. Endo
J. Mater. Chem., 2011, 21, 3280-3294

5. Graphene filled polymer nanocomposites
Raquel Verdejo, M. Mar Bernal, Laura J. Romasanta and Miguel A. Lopez-Manchado
J. Mater. Chem., 2011, 21, 3301-3310

6. A review of chemical vapour deposition of graphene on copper
Cecilia Mattevi,  Hokwon Kim and Manish Chhowalla
J. Mater. Chem., 2011, 21, 3324-3334

7. SnO2 hollow structures and TiO2 nanosheets for lithium-ion batteries
Jun Song Chen, Lynden A. Archer and Xiong Wen (David) Lou
J. Mater. Chem., 2011, 21, 9912-9924

8. The oxidation of aniline to produce “polyaniline”: a process yielding many different nanoscale structures          
Henry D. Tran,  Julio M. D’Arcy,  Yue Wang,  Peter J. Beltramo,  Veronica A. Strong and Richard B. Kaner
J. Mater. Chem., 2011, 21, 3534-3550

9. Graphene: learning from carbon nanotubes
Liping Huang, Bin Wu, Gui Yu and Yunqi Liu
J. Mater. Chem., 2011, 21, 919-929

10. Mesoporous titania photocatalysts: preparation, characterization and reaction mechanisms
Adel A. Ismail and Detlef W. Bahnemann
J. Mater. Chem., 2011, 21, 11686-11707

 

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Oral abstract deadline for Challenges in Nanoscience (ISACS9): Friday 30th March

Challenges in Nanoscience (ISACS9)

The oral abstract submission deadline for Challenges in Nanoscience (ISACS9) is fast approaching. Please submit by Friday 30th March if you want to present your work alongside the sixteen outstanding plenary speakers.

For further details on Challenges in Nanoscience (ISACS9) or any of the conferences in the ISACS series, please sign up for the ISACS newsletter, follow ISACS on twitter or visit the dedicated webpage.

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Video Interview: Seth Marder discusses the importance of materials to society

Seth Marder discusses the importance of materials chemistry to society with Liz Davies.

Photograph of Seth Marder

Watch the video interview on YouTube here:

  

If you’re interested to know more about how new materials could improve people’s lives you can read reports on:

 

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2012 Journal of Materials Chemistry Lectureship- Nominations now open!

Do you know someone who deserves recognition for their contribution to the materials chemistry field?

Now is your chance to propose they receive the recognition they deserve.

We are pleased to announce that the 2012 Journal of Materials Chemistry Lectureship is now open for nominations. This annual lectureship honours a younger scientist who has made a significant contribution to the field of materials chemistry.

Liberato Manna, the winner of the 2011 lectureship, was chosen for his outstanding contribution to the field of inorganic nanotechnology.

Qualification
To be eligible for the Journal of Materials Chemistry Lectureship, the candidate should be in the earlier stages of their scientific career, typically within 10 years of attaining their doctorate or equivalent degree, and will have made a significant contribution to the field.

Description
The recipient of the award will be asked to present one Journal of Materials Chemistry lecture, at a conference decided upon by the recipient and the Editorial Office. The Journal of Materials Chemistry Editorial Office will provide the sum of £1000 to the recipient for travel and accommodation costs. The award recipient will be presented with the award at this lecture. They will also be asked to contribute a lead article to the journal and will have their work showcased on the back cover of the issue in which their article is published.

Selection
The recipient of the lectureshipwill be selected and endorsed by the Journal of Materials Chemistry Editorial Board.

Nominations
Those wishing to make a nomination should send details of the nominee including a brief C.V. (no longer than 2 pages) together with a letter supporting the nomination (no longer than 2 pages), to the Journal of Materials Chemistry Editorial Office by 11 May 2012. Please note that self-nomination is permitted.

Send a nomination here today: materials-rsc@rsc.org

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Conference: 2012 International Symposium on Stimuli-Responsive Materials, October 21-23

The 2012 International Symposium on Stimuli-Responsive Materials will be held 21st – 23rd October at the Hilton Sonoma Wine Country in Santa Rosa, CA. The symposium will cover the design, synthesis, characterization, and understanding of the physical, chemical, and applied principles of stimuli-responsive materials and devices.

Plenary Speakers include:

Cameron Alexander, University of Nottingham, UK; Takao Aoyagi, National Institute for Materials Science, JAPAN; Rachel Auzery, CNRS, FRANCE; Paul Braun, University of Illinois, USA; Barney Grubbs, SUNY at Stone Brook, USA; Kevin Healy, University of California, Berkley, USA; Henry Hess, Columbia University, USA; Christine Jerome, University of Liege, BELGIUM; Henry Kopeczek, University of Utah, USA; Dirk Kukling, University of Pederborn, GERMANY; Andreas Lendlein, Institute Polymer. Research HZG, GERMANY; Shiyong Liu, University of Science and Technology, CHINA; Julia Ljubimova, Cedar Sinai Research Center, Beverly Hills, USA; Tim Lodge, University of Minnesota, USA; C. Andrew Lyon, Georgia Tech, USA; Sergiy Minko, Clarkson University, USA; Kenichi Nakashima, Saga University, JAPAN; Derek Patton, University of Southern Mississippi, USA; Jerry H. Qi, University of Colorado, USA; Srinivasa R. Raghavan, University of Maryland, USA; Stuart Rowan, Case Western Reserve University, USA; Daniel Savin, University of Southern Mississippi, USA; Chris Weder, University of Friburg, SWITZERLAND; Kung-Hwa Wei, University of Taipei, TAIWAN; Robert Weiss, University of Akron, USA; Gary Wnek, Case Western Reserve University, USA; Timothy White, US Airforce, USA; Tao Xie, GM Global R&D, USA; Mingdi Yan, University of Massachusetts Lowell, USA; Shu Yang, University of Pennsylvania, USA.

More information and registration details are available on the conference website: http://www.stimuliresponsivematerials.org

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