Hot Communication: Iodine doping in solid precursor-based CVD growth graphene film

In this Hot Communication, the team from Chubu University, Japan, demonstrate a simple synthesis of an iodine-doped graphene film using a mixture of camphor and iodine. Experiments confirm the presence of atomic iodine in the form of triiodide (I3) and pentaiodide (I5) through charge transfer reactions. The sp2 hybridized carbon in graphene is not disturbed by the presence of atomic iodine. The team say that the atomic iodine could be situated on the surface or as an intercalation in the form of polyiodides without disturbing the hexagonal lattice structure of the few-layers graphene film. Interested to know more? Read the full article for free until 12th October (free registration required): 

Graphical abstract: Iodine doping in solid precursor-based CVD growth graphene film

Golap Kalita, Koichi Wakita, Makoto Takahashi and Masayoshi Umeno, J. Mater. Chem., 2011, DOI:10.1039/C1JM13268G (Advance Article)

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Hot Highlights: phonon engineering and assembling nanostructures using polar surfaces

Formation of complex nanostructures driven by polar surfaces: In this Hot Highlight Huatao Wang and Tom Wu discuss the recent advances in synthesizing novel nanostructures whose formation is driven by the electrostatic forces between polar surfaces. (J. Mater. Chem., 2011, DOI: 10.1039/C1JM12417J, Advance Article)

Graphical abstract: Formation of complex nanostructures driven by polar surfaces

Phonon engineering through crystal chemistry: Low thermal conductivity is critical in a broad range of energy conversion technologies. In the second Hot Highlight Eric S. Toberer, Alex Zevalkink and G. Jeffrey Snyder review the structural and chemical parameters of materials which determine phonon velocity, and therefore lattice thermal conductivity, in complex materials. (J. Mater. Chem., 2011, DOI: 10.1039/C1JM11754H, Advance Article)

Graphical abstract: Phonon engineering through crystal chemistry

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Materials Chemistry of Nanofabrication themed issue is now online!

The Materials Chemistry of Nanofabrication themed issue is now online. The guest editor for this issue was Kenneth R. Carter University of Massachusetts, Amherst, USA. Here is Professor Carter’s editorial “Nanofabrication: past, present and future” introducing the topic. 

 front and inside front cover images for Journal of Materials Chemistry, Issue 37, 2011

The outside front cover showcases “DNA nanofabrication by scanning near-field photolithography of oligo(ethylene glycol) terminated SAMs: Controlled scan-rate dependent switching between head group oxidation and tail group degradation” by Shuqing Sun and co-workers. Fabrication of wafer-scale polystyrene photonic crystal multilayers via the layer-by-layer scooping transfer technique” is the paper featured on the inside front cover.

The full issue contains 4 hot articles.

 

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Top Ten most-read Journal of Materials Chemistry articles in July

This month sees the following articles in that are in the top ten most accessed in July:

A review of advanced and practical lithium battery materials 
Rotem Marom, S. Francis Amalraj, Nicole Leifer, David Jacob and Doron Aurbach
J. Mater. Chem., 2011, 21, 9938-9954
DOI:10.1039/c0jm04225k 

Editorial – Themed issue: Chemical transformations of nanoparticles 
Dmitri V. Talapin and Yadong Yin
J. Mater. Chem., 2011, 21, 11454-11456 
DOI:10.1039/c1jm90095a 

Formation and morphology control of nanoparticles via solution routes in an autoclave 
Yongchun Zhu, Tao Mei, Yan Wang and Yitai Qian
J. Mater. Chem., 2011, 21, 11457-11463 
DOI:10.1039/c1jm11079a 

Emerging functional nanomaterials for therapeutics
 Xuejia Xue, Feng Wang and Xiaogang Liu 
J. Mater. Chem., 2011, 21, 13107-13127 
DOI:10.1039/c1jm11401h 

Nanostructured cathode materials: a key for better performance in Li-ion batteries 
Ragupathy Pitchai, Velmurugan Thavasi, Subodh G. Mhaisalkar and Seeram Ramakrishna 
J. Mater. Chem., 2011, 21, 11040-11051 
DOI:10.1039/c1jm10857c 

Conversion of carbon dioxide to few-layer graphene 
Amartya Chakrabarti, Jun Lu, Jennifer C. Skrabutenas, Tao Xu, Zhili Xiao, John A. Maguire and Narayan S. Hosmane 
J. Mater. Chem., 2011, 21, 9491-9493 
DOI:10.1039/c1jm11227a 

Controllable synthesis of mesoporous F–TiO2 spheres for effective photocatalysis 
Jia Hong Pan, Zhongyu Cai, Yong Yu and X. S. Zhao 
J. Mater. Chem., 2011, 21, 11430-11438 
DOI:10.1039/c1jm11326g 

Editorial – Advanced materials for lithium batteries 
M. Saiful Islam and Linda F. Nazar
J. Mater. Chem., 2011, 21, 9810-9810 
DOI:10.1039/c1jm90082j 

Dandelion-like Fe3O4@CuTNPc hierarchical nanostructures as a magnetically separable visible-light photocatalyst 
Zengcai Guo, Changlu Shao, Mingyi Zhang, Jingbo Mu, Zhenyi Zhang, Peng Zhang, Bin Chen and Yichun Liu
J. Mater. Chem., 2011, 21, 12083-12088 
DOI:10.1039/c1jm11098e 

Carboxylic group functionalized ordered mesoporous silicas 
Lu Han, Osamu Terasaki and Shunai Che 
J. Mater. Chem., 2011, 21, 11033-11039
DOI:10.1039/c1jm10561b 

Why not take a look at the articles today and blog your thoughts and comments below.

Fancy submitting an article to Journal of Materials Chemistry ? Then why not submit to us today!

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Three Hot Articles on hierarchical silica nanochannels, seeded nanowire growth and the electrochemical behavior of graphene

Graphical abstract: Formation of hierarchical silica nanochannels through nanoimprint lithographyFormation of hierarchical silica nanochannels through nanoimprint lithography: Scientists at the University of Massachusetts Amherst have fabricate hierarchical silica nanochannels, with device and domain level patterns using nanoimprint lithography and scCO2 infusion process. (J. Mater. Chem., 2011, 21, 14213-14218)

Graphical abstract: Seeded silicon nanowire growth catalyzed by commercially available bulk metals: broad selection of metal catalysts, superior field emission performance, and versatile nanowire/metal architecturesSeeded silicon nanowire growth catalyzed by commercially available bulk metals: broad selection of metal catalysts, superior field emission performance, and versatile nanowire/metal architectures: In this hot article an alternative metal-seeded synthetic protocol provides a facile route to prepare versatile Si nanowires/metal architectures for advanced applications. (J. Mater. Chem., 2011, 21, 13793-13800)

Graphical abstract: Electrochemical behavior of graphene nanosheets in alkylimidazolium tetrafluoroborate ionic liquid electrolytes: influences of organic solvents and the alkyl chainsElectrochemical behavior of graphene nanosheets in alkylimidazolium tetrafluoroborate ionic liquid electrolytes: influences of organic solvents and the alkyl chains. To understand the influence of the structure of ionic liquids on the GNS electrode, researchers at Lanzhou Institute of Chemical Physics created a simple model of the GNS electrode/ionic liquid interface. (J. Mater. Chem., 2011, 21, 13205-13212)

Read all the articles for free until 4th October (free registration required)

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Hot Article: Photo-switchable polyelectrolyte brush for dual protein patterning

A photo-switchable polyelectrolyte brush that can prepare dual-component protein patterns by electrostatic attraction has been developed by scientists at Cornell University, USA. Varying the UV exposure of the cationic brush can lead to either a fully charge-reversed brush or patterned cationic/anionic binary brush. The team say this is the first time that a polyelectrolyte brush’s charge has been easily switched from cationic to anionic by UV radiation.

Graphical abstract: Photo-switchable polyelectrolyte brush for dual protein patterning

Youyong Xu, Yosuke Hoshi and Christopher K. Ober, J. Mater. Chem., 2011, 21, 13789-13792

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Journal of Materials Chemistry Article Highlighted in Chemistry World

Self-cleaning fabrics now even cleaner: US scientists have made a self-cleaning fabric that lasts longer, shows better antibacterial action and is more comfortable to wear than current materials.

Fabrics treated with certain compounds such as N-halamines can produce oxidative species, which kill pathogens and degrade toxic chemicals. However, the compounds either degrade rapidly under sunlight or are only used to coat the fabric’s surface so are easily washed off…

 Magnified images of cotton fibres, without and with 2-anthraquinone carboxylic acid

Interested to know more? You can read the rest of the Chemistry World news story here or the original research article here.

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Conference: Materials that don’t cost the Earth

3rd October 2011
The Chemistry Centre, London, UK
www.rsc.org/costearth

This free workshop has been devised to explore technological advancements which could see the UK reduce reliance on imported scarce naturally sourced metals and help it become a leader in substitution.

Deadlines – Speed presentation abstract: 9 September 2011 & Final registration deadline: 18 September 2011

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A selection of Hot Feature Articles

Graphical abstract: Light-trapping nano-structures in organic photovoltaic cells

Light-trapping nano-structures in organic photovoltaic cells: Iridescent photonic crystal nano-patterns in a bulk heterojunction polymer blend are reminiscent of the metallic sheen reflected from butterfly wings. (J. Mater. Chem., 2011, DOI: 10.1039/C1JM12300A, Advance Article)

Graphical abstract: Structure–property relationships of iron arsenide superconductorsStructure–property relationships of iron arsenide superconductors: Unique structure–property relationships of iron-arsenide superconductors prove to be a good recipe for future discoveries in the lively field of superconducting materials. (J. Mater. Chem., 2011, 21, 13726-13736)

Graphical abstract: Nucleic acid-functionalized nanomaterials for bioimaging applicationsNucleic acid-functionalized nanomaterials for bioimaging applications: This review covers recent advances in nucleic acid-functionalized nanomaterials as sensing platforms for bioimaging applications. (J. Mater. Chem., 2011, DOI: 10.1039/C1JM12588E, Advance Article)

Read all the Feature Articles for free until 29th September (free registration required)

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Poster Prize winners at MC10

Congratulations to Benjamin de Laune from the University of Birmingham, UK, for winning a Journal of Materials Chemistry poster prize and to Prapatsorn Techawanitchai from Tsukuba University, Japan, for winning a Soft Matter poster prize at the 10th International Conference on Materials Chemistry (MC10).

Benjamin de Laune’s winning poster was on ‘The Structural Characterisation of LiSbO2.’ Techawanitchai‘s winning poster was titled ‘Spatial shrinking of pH-responsive hydrogels utilizing photo-triggered acid generation reaction.‘

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