A trio of hot papers: Sequestering oil from emulsions, reducing graphene oxide & simulating Li ion batteries

Read all the articles for free until 25th June

Sequestration of edible oil from emulsions using new single and double layered microcapsules from plant spores Sequestration of edible oil from emulsions using new single and double layered microcapsules from plant spores

Microcapsules developed from modified plant spores can sequester efficiently edible oils from oil-in-water emulsions. The microcapsules contain either a single layered shell or double layered shell and are modified by converting their surface hydroxyl groups (alcohols, phenols carboxylic acids) into salts (Na+ and K+), acetates and methyl ethers. (J. Mater. Chem., 2012, 22, 9767-9773)

Chemical reduction of an aqueous suspension of graphene oxide by nascent hydrogenChemical reduction of an aqueous suspension of graphene oxide by nascent hydrogen

South Korean scientists have shown that nascent hydrogen can effectively reduce graphene oxide. Using a combination of X-ray photoelectron spectroscopy and thermogravimetric analysis they demonstrate that most of the labile oxygen functional groups were removed during nascent hydrogen reduction. Compared to other reducing agents the use of low cost, non-toxic metals for nascent hydrogen reduction is a promising method for bulk preparation of high quality reduced graphene oxide. (J. Mater. Chem., 2012, 22, 10530-10536)

Structural requirements for fast lithium ion migration in Li10GeP2S12 Structural requirements for fast lithium ion migration in Li10GeP2S12

Developing high performance electrolytes that combine fast lithium ion conductivity with electrochemical stability and safety is one of the challenges facing scientists creating the next generation of batteries. In this hot article atomistic molecular dynamics simulations shed new light on the dynamic lithium distribution, structural stability and ion transport mechanism in the ultrafast ion conductor Li10GeP2S12. (J. Mater. Chem., 2012, 22, 7687-7691)

Don’t forget to keep up-to-date with all the latest research you can sign-up for the Journal of Materials Chemistry RSS feed or Table of contents alert.

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Author Profile: Gengfeng Zheng

Gengfeng Zheng talks about his research on low-dimensional semiconducting nanomaterials and the joy of watching his students succeed.

Gengfeng ZhengGengfeng Zheng is currently a professor of Chemistry at Fudan University, China. He obtained his B.Sc. degree in Chemistry in 2000 from Fudan University, and obtained his Ph.D. degree in Chemistry in 2006 from Harvard University, under the guidance of Prof. Charles M. Lieber. During 2007-2010, he was a postdoctoral fellow in the laboratory of Prof. Chad Mirkin at Northwestern University, USA. Dr. Zheng has been the recipient of the Professorship of Special Appointment (Eastern Scholar) at Shanghai Institutions of Higher Learning (2012), the China Ministry of Education New Century Excellent Talents (2011), and the Materials Research Society Graduate Student Gold Award (2006). His research interests include the synthesis of low-dimensional semiconducting nanomaterials, fabrication of nanodevices for solar energy conversion and lithium ion battery, and studies of hybrid nanomaterial-biomaterial interfaces for disease diagnosis.

1.      Which research projects are you working on at the moment?
We are working the synthesis of new low-dimensional semiconducting nanomaterials for energy conversion and storage, including: 1) metal oxide and sulfide nanowires for photoelectrochemical water splitting, and 2) hybrid porous and nanostructured materials for lithium ion battery and supercapacitors.

2.      What motivated you to work on porous and nanostructured materials?
Porous and nanostructured semiconducting materials with rationally designed architectures provide tunable electronic bandgap structures, efficient charge transport, and large interfacial area for surface reactions. A lot of unconventional properties and high device performances can be expected from these material building blocks.

Read the full interview

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Fibres improve solar-driven water treatment

Hot Paper: Photocatalytic Cellulosic Electrospun Fibers for the Degradation of Potent Cyanobacteria Toxin Microcystin-LR

Journal of Materials Chemistry issue 1 front cover 2012Scientists in the US have immobilised photocatalytic titania nanoparticles onto cellulose fibres to improve their ability to remove harmful bacteria (in this case cyanobacteria toxin microcystin-LR) from drinking water.

The team found that the type of titania nanoparticle (visible light activated or UV light activated), the surface area of the fibre mat and loading solution pH all had an effect on the distribution of titania along the fibres. Read the article for free until 19th June.

Photocatalytic Cellulosic Electrospun Fibers for the Degradation of Potent Cyanobacteria Toxin Microcystin-LR
Nicholas M Bedford, Miguel Pelaez, Changseok Han, Dion D Dionysiou and Andrew J. Steckl
J. Mater. Chem., 2012, DOI: 10.1039/C2JM31597A

Don’t forget to keep up-to-date with all the latest research you can sign-up for the Journal of Materials Chemistry RSS feed or Table of contents alert.

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Focus on: Superhydrophobic surfaces

Soft Matter & Journal of Materials ChemistrySuperhydrophobic surfaces can cause water to roll off leaving little or no liquid behind and even pick-up and remove small dirt particles resting on the surface; however, despite the  progress made, there is still an opportunity fabricate these surfaces using simpler and cheaper methods, to maximise roll-off, or to introduction additional functional properties. Here we’ve brought together a selection of articles covering the preparation of superhydrophobic surfaces and coatings, their chemical and physical properties, and the origin of the superhydrophobic effect.

Review
Hydrophilic and superhydrophilic surfaces and materials
Jaroslaw Drelich ,  Emil Chibowski ,  Dennis Desheng Meng and Konrad Terpilowski
Soft Matter, 2011,7, 9804-9828

Highlight
Immersed superhydrophobic surfaces: Gas exchange, slip and drag reduction properties
Glen McHale ,  Michael I. Newton and Neil J. Shirtcliffe
Soft Matter, 2010,6, 714-719

Opinion
Characterization of superhydrophobic behavior: effect of vibrational energy
W. Li ,  Y. P. Diao ,  H. L. Zhang ,  G. C. Wang ,  S. Q. Lu ,  X. J. Dong ,  H. B. Dong and Q. L. Sun
Soft Matter, 2009,5, 2833-2835

Click here to see all the articles

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Author Profile: Samuel Thomas

Sam ThomasSamuel Thomas is an Assistant Professor of Chemistry at Tufts University, a position he has held since 2009.  He earned a B.S. in Chemistry in 2000 from the University of Rochester.  After a year-long stint at the Eastman Kodak Company as a research chemist, he entered graduate school at MIT.  He received his Ph.D. in organic chemistry in 2006 under the guidance of Prof. Timothy Swager.  From 2006-2009, he was an American Cancer Society postdoctoral fellow in the laboratory of Prof. George Whitesides at Harvard University.  Since starting his independent career at Tufts, Sam has been the recipient of a 2009 DARPA Young Faculty Award, a 2010 Thieme Publishers Journal Award, and a 2012 NSF CAREER Award.  His research focuses on using physical organic chemistry to design new photoresponsive materials for applications in self-assembly, sensing, and patterning.

1. Which research projects are you working on at the moment?
We work on three main projects in the area of photo-responsive organic materials: 1) Photochemical tuning of properties of conjugated polymers, 2) new applications of singlet oxygen chemistry, and 3) photochemical control of electrostatics.

2. What motivated you to focus on photo-responsive organic materials?
Light is such a versatile reagent.  It gives you real-time control over stoichiometry, energy, and spatial distribution.  It’s thrilling to exert that type of control over organic reactions, and use that control for inventing materials that do new things.

3. What are the hot topics in materials chemistry at the moment?
The rational design of condensed phase behavior from chemical structure

4. What current problem would you like to see science provide a solution to?
Two things: 1) The energy problem; 2) Increasing the possibility of science as a career for more people.

5. What do you find to be the most rewarding aspect of your career?
In terms of experiments, I live vicariously through the students who work in my lab.  Sharing the excitement of discovery with them is a real joy.

6. What’s the secret to being a successful scientist?
Passion and dedication…when an experiment or idea doesn’t work, coming back even more determined to solve the problem!

7. Which scientist past or present do you most admire?
A tie between Pasteur and Faraday.  Pasteur for the meticulousness of separating tartaric acid enantiomers by hand, and Faraday for amazing versatility and experimental genius.

8. If you weren’t a scientist, what would you be?
A musician.  I played the piano constantly as a teenager.

If you’re interested to know more about the Thomas lab’s research you can check out the group website or alternatively you can see a few of their recent papers below:

Structure, photophysics, and photooxidation of crowded diethynyltetracenes
Jingjing Zhang,  Syena Sarrafpour ,  Terry E. Haas,  Peter Müller and Samuel W. Thomas,
J. Mater. Chem., 2012, 22, 6182-6189

UV-induced fluorescence recovery and solubility modulation of photocaged conjugated oligomers
Robert H. Pawle, Victoria Eastman and Samuel W. Thomas,
J. Mater. Chem., 2011, 21, 14041-14047

Acene-linked conjugated polymers with ratiometric fluorescent response to 1O2
Jingjing Zhang,  Syena Sarrafpour,  Robert H. Pawle and Samuel W. Thomas III
Chem. Commun., 2011,47, 3445-3447

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Report & lecture on solar fuels and artificial photosynthesis

This week our Science Team marks the launch of its new report on solar fuels and artificial photosynthesis with a special international event at the Chemistry Centre in London for scientists, policymakers and business-people.  A highlight will be a lecture by Nathan S Lewis, professor of chemistry at Caltech and Editor-in-Chief of our journal Energy and Environmental Science.  He will describe and evaluate the technical, political and economic challenges involved with widespread adoption of renewable energy technologies.  

For more information and to watch this streamed lecture at 1725 BST, 1225 EDT, 0925 PST Thursday 17 May click here: 
http://www.rsc.org/chemistryworld/Webinar/Global_Energy_Perspectives.asp

To read the report or download the infographics click here:
http://www.rsc.org/solar-fuels.

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Recent Appointees in Polymer Science Web-Theme

Recent Appointees in Polymer Science is an organization of, and for, people in the early stages of their independent career. They aim to provide a forum for recent appointees in all sectors of UK polymer science in academia as well as in industry. They are also open to interaction with recent appointees outside of the UK and would be delighted to interact with similar organizations abroad.

This RAPS Web Theme highlights work from members published in RSC journals and new articles will be added as they appear. To see the papers, click here.

Interested in knowing more about RAPS? Check out the website at www.raps.org.uk  for more information

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Zeal for zeolites: an article collection

A collection of high impact articles on the topic of zeolites from the RSC’s Journal of Materials Chemistry (JMC), Catalysis Science & Technology and Physical Chemistry Chemical Physics (PCCP).

ZeoliteZeolites are truly fascinating materials, first noted in the 18th century they were recognized for their interesting ability to release steam when heated. Today around 3 million tons of natural zeolite are mined for commercial use each year. Zeolites have found applications in agriculture, construction, heating, refrigeration, nuclear energy, in the petrochemical industry, as detergents and cat litter!

Unsurprisingly these materials have sparked the interest of scientists around the world since their discovery, resulting in the creation of a vast number of unique zeolitic frameworks and pushing the boundaries of chemical understanding.

The articles below have been made free to access until 8th June to give you a sample of the high impact, cutting edge research being carried out in the exciting world of zeolites!

Click here for the full list of free articles

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Hot Article: Improving the organic-metal interface in polymer solar cells

Effective interfacial layer to enhance efficiency of polymer solar cells via solution-processed fullerene-surfactants

Improving the electronic properties of the organic-metal interface is important for developing high-performance polymer solar cells. In this hot paper two methanol-soluble fullerene surfactants are reported. These form interfacial layers for cathodes in polymer solar cells and significantly enhance open-circuit voltage and photocurrent generation. Bulk heterojunction solar cells developed using these surfactant-modified cathodes offer high power conversion efficiencies of up to 6.63%. Read the article for free until 7th June.

Effective interfacial layer to enhance efficiency of polymer solar cells via solution-processed fullerene-surfactants

Effective interfacial layer to enhance efficiency of polymer solar cells via solution-processed fullerene-surfactants: Chang-Zhi Li, Chu-Chen Chueh, Hin-Lap Yip, Kevin M. O’Malley, Wen-Chang Chen and Alex K.-Y. Jen, J. Mater. Chem., 2012,22, 8574-8578

Don’t forget to keep up-to-date with all the latest research you can sign-up for the Journal of Materials Chemistry RSS feed or Table of contents alert.

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Themed Issue on Metal-Organic Frameworks now published

The 2012 Journal of Materials Chemistry themed issue on ‘Integrating functionality into metal-organic frameworks’ has now been published on-line. View the full issue here.

Guest Editors for the themed issue were Professors Stephen Kaskel and Roland Fischer, and their Editorial can be found here.  A number of reviews were also published:

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