A functional interface between PbS and CdSe NCs and a new fullerene ligand is demonstrated. The dramatic PL quenching upon increasing amount of attached fullerenes indicates photoinduced charge transfer from the NCs to the fullerene derivatives.
This molecule is an excellent candidate to serve as electroactive ligand for NCs and form novel complexes, which could be very promising building blocks for optoelectronic devices.
Alexis Laforgue creates electrically controlled colour-changing textiles suitable for clothing, active visual camouflage or interactive textiles.
A simple way of fabricating electrochromic textiles was developed by coating thermochromic inks on top of conductive electrospun nanofiber non-woven mats; the colour change is then triggered by the heat generated when applying a current through the mat.
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Hot Article: ‘Thermoreversible ionogels with tunable properties via aqueous gelation of an amphiphilic quaternary ammonium oligoether-based ionic liquid’ by Josep Casamada Ribot, Carlos Guerrero-Sanchez, Richard Hoogenboom and Ulrich S. Schubert.
The aqueous gelation of a quaternary ammonium oligoether-based ionic liquid yields thermoreversible ionogels with tunable and enhanced physical properties. Read the full article here:
Ivo B. Rietveld’s latest paper ‘Electrospray induced ferroelectricity in poly(vinylidene fluoride) thin films’ was selected as a hot article in Journal of Materials Chemistry.
Electrospray deposition of poly(vinylidene fluoride) (PVDF) allows control over the level of ferroelectricity in thin film. It is a single-step procedure involving deposition, β-phase formation and poling. The extent of β-phase formation and poling depends on the ratio of ion current and PVDF concentration and on spray time. Read the full article here:
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Scientists from China have shown that cationic conjugated polymers can take on a number of different roles when it comes to anticancer activity in cells.
Conjugated polymers have been studied for a range of applications from optoelectronic devices to sensors for various molecules, but their therapeutic properties for cancer treatment have yet to be exploited. Now, Libing Liu, Shu Wang and colleagues at Beijing National Laboratory for Molecular Science have investigated cellular uptake of a cationic polythiophene polymer, PMNT, in cancer cells and shown that it has potential for simultaneous therapeutic and imaging applications.
Although the polymer is highly charged, the team found that it readily enters cells, independent of temperature and molecular weight of the polymer. PMNT shows selective toxicity for the renal cell carcinoma lines and irradiating with a mercury lamp enhances the toxicity demonstrating potential for these conjugated polymers in photodynamic therapy, explains Wang. Additionally, the polymers were used to distinguish live and dead, or apoptotic cells under fluorescence microscopy.
Wang is especially excited about dual role of the PMNT saying it makes it ‘an attractive candidate as a multifunctional therapeutic agent’.
‘This work is a really nice study of the interaction of these highly charged systems with cells, comments Vincent Rotello, professor of chemistry at the University of Massachusetts in Amherst, US. ‘It opens the doors for imaging and potential therapeutic applications with fine-tuning of polymer functionality.’
The multifunctional nature of PMNT is a promising start to the study of conjugated polymers in disease therapeutics; further study and fine-turning of the properties of conjugated polymers is the next step in what could be an intriguing area of anti-cancer research.
Patricia Pantos
Read this article in Journal of Materials Chemistry
