Green Chemistry Blog

Continuous-flow alkene metathesis

12 Sep 2012

The self-metathesis of 1-octene was used as a model reaction to demonstrate the performance of a continuous-flow alkene metathesis process using supercritical CO₂ as the carrier.

Over the last decade or so, olefin metathesis has become widely recognised as a good, general method to generate new C–C bonds, with an excellent synthetic scope. Here, an international collaboration of scientists from University Ca’Foscari (Italy), the University of Nottingham (UK) and the University of Sydney (Australia) led by Maurizio Selva have developed a continuous-flow process for heterogeneously-catalysed olefin metathesis.

Their process used a Re₂O₇ supported catalyst on γ-Al₂O₃, which although deactivated after the first 100-150 mins of the reaction, could be recycled for at least five subsequent reactions without any loss of performance. Improving this aspect further will be the focus of future research in this area. The authors propose that this methodology will be applicable to the metathesis of other terminal olefins in the C₆-C₁₂range of liquid compounds.

Read this article for free until the 11th October!

Continuous-flow alkene metathesis: the model reaction of 1-octene catalyzed by Re₂O₇/γ-Al₂O₃with supercritical CO₂ as a carrier, Maurizio Selva, Sandro Guidi, Alvise Perosa, Michela Signoretto, Pete Licence and Thomas Maschmeyer, Green Chem., 2012, DOI: 10.1039/C2GC35983A (Advanced Article)

You may also be interested in these articles – free to access for 2 weeks:

Electrostatic immobilization of an olefin metathesis pre-catalyst on iron oxide magnetic particles, Matthew J. Byrnes, Andrew M. Hilton, Clint P. Woodward, William R. Jackson and Andrea J. Robinson, Green Chem., 2012, 14, 81-84

Cross-metathesis transformations of terpenoids in dialkyl carbonate solvents, Hallouma Bilel, Naceur Hamdi, Fethy Zagrouba, Cédric Fischmeister and Christian Bruneau, Green Chem., 2011, 13, 1448-1452

Continuous flow homogeneous alkene metathesis with built-in catalyst separation, Rubén Duque, Eva Öchsner, Hervé Clavier, Fréderic Caijo, Steven P. Nolan, Marc Mauduit and David J. Cole-Hamilton, Green Chem., 2011, 13, 1187-1195

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4th International IUPAC Conference on Green Chemistry

09 Sep 2012

By Mary Badcock, Deputy Editor.

The 4th International IUPAC Conference on Green Chemistry (4th ICGC) was held in Foz do Iguaçu, Brazil between the 25-29th August 2012. The conference focused on broad topics including benign synthesis/processes, green chemistry for energy production, chemicals from renewable resources, green engineering, education in green chemistry and engineering and policy.

The conference was attended by the Editor, Sarah Ruthven and several members of the Journal’s Editorial and Advisory Boards spoke at the event, including Professor Buxing Han, Professor Paul Anastas, Professor James Clark, Professor Philip Jessop, Professor Robin Rogers and Professor Roger Sheldon.

The Green Chemistry poster prize which was presented by Professor Buxing Han was awarded to Tiago Artur da Silva from the University of Sao Paulo (pictured right).

The full title of the poster was: AuPd nanoparticles: reusable magnetic responsive catalyst for green oxidation of alcohols; by Tiago Artur da Silva, Érico Teixeira-Neto, Liane Marcia Rossi.

Congratulations to Tiago on winning this prize.

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How synthetic organic chemistry can help to feed the world

06 Sep 2012

By Anna Simpson, Executive Editor.

Chemistry for Tomorrow’s World 2012: Using Chemistry to Improve Agricultural Productivity – a policy event

Azoxystrobin is the world’s leading agricultural fungicide. It is a fully synthetic compound, whose invention was inspired by the structure and activity of the naturally-occurring fungicide strobilurin A. Today it is used worldwide to control fungi growing on over 120 types of crop, improving plant health, raising quality and increasing yield. The success of the project highlights the crucial importance of chemistry in meeting grand challenges such as global food security and the broader applicability of skills such as natural product synthesis. Keynote speaker Dr John Clough led the team of chemists at Syngenta that invented azoxystrobin. He will discuss the key role that synthetic organic chemistry played in creating an effective and safe fungicide. This policy event is organised by the Royal Society of Chemistry as part of a series of lectures designed to bring together active researchers and policy makers to highlight the role of the chemical sciences in tackling societal issues.

This event will be held in the Chemistry Centre on 26 September at the RSC’s recently refurbished building in Burlington House, London. Doors will open at 17:30 for refreshments. The event will begin at 18:00 and will finish with a wine reception. Please follow the link here for information and to register for the event.

If you cannot make it why not watch the video of the event which will be uploaded on the website after the event.

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What’s new with carbon dioxide?

04 Sep 2012

By Mary Badcock, Deputy Editor.

In this tutorial review, Donald Darensbourg and Stephanie Wilson highlight the recent advances in the copolymerisation of carbon dioxide (CO₂) with epoxides (oxiranes) to produce polycarbonates.

The advances in this area are discussed with specific reference to catalysts that have been designed to afford high selectivity for the copolymer versus cyclic carbonate formation. The authors not only illustrate the advances in poly(propylene carbonate) (PPC) production by also investigate the underlying reasons for the differences in the reactivity of propylene oxide and cyclohexene oxide.

Darensbourg and Wilson conclude by highlighting the need for improved catalysts which can prevent the degradation of PPC in the presence of azide ions – specifically those catalysts with appended amines or ammonium salts.

Interested? Read the full article for free until the 2nd October 2012…

What’s new with CO₂? Recent advances in its copolymerization with oxiranes, Donald J. Darensbourg and Stephanie J. Wilson, Green Chem., 2012, DOI: 10.1039/C2GC35928F

You may also be interested in this critical review article – free to access for 2 weeks:

Synthesis of cyclic carbonates from epoxides and CO₂, Michael North, Riccardo Pasquale and Carl Young, Green Chem., 2010, 12, 1514-1539

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One-pot reduction of 5-hydroxymethylfurfural via hydrogen transfer from supercritical methanol

31 Aug 2012

By Mary Badcock, Deputy Editor.

Scientists from Denmark and the USA have achieved efficient conversion of 5-hydroxymethylfurfural (HMF) to valuable chemicals over a Cu-doped porous metal oxide catalyst in supercritical methanol.

HMF (readily obtained from hexose sugars) has been identified as a key platform compound to generate useful renewable chemicals for the fuel industry, such as 2,5-dimethylfuran (DMF) and 2,5-dimethyltetrahydrofuran (DMTHF). However, achieving selective transformation of HMF to a specific product and preventing the formation of undesired side-products remains a challenge.

In this work, a collaboration between scientists at the Technical University of Denmark, Yale University (USA) and the University of California Santa-Barbara (USA) led by Katalin Barta and Andreas Riisager have developed an one-pot procedure for the reduction of HMF. The catalyst was prepared in aqueous solution from inexpensive and earth-abundant starting materials before undergoing calcination. By tuning the reaction temperature, DMF or DMTHF and 2-hexanol could be obtained as the major products, and no formation of higher boiling side products or undesired char was detected.

This article is free to access until the 28th September 2012! Click on this link below to fine out more…

One-pot reduction of 5-hydroxymethylfurfural viahydrogen transfer from supercritical methanol, Thomas S. Hansen, Katalin Barta, Paul T. Anastas, Peter C. Ford and Anders Riisager, Green Chem., 2012, 14, 2457-2461

You may also be interested in reading this article – free to access for 2 weeks:

Synergy of boric acid and added salts in the catalytic dehydration of hexoses to 5-hydroxymethylfurfural in water, Thomas S. Hansen, Jerrik Mielby and Anders Riisager, Green Chem., 2011, 13, 109-114

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Meet our Editorial Board: Walter Leitner (Chair)

24 Aug 2012

By Mary Badcock, Deputy Editor.

Walter Leitner is a full Professor at Technische Chemie und Petrolchemie, Institut für Technische Chemie und Makromolekulare Chemie at the RWTH Aachen University and is the new Chair of the Green Chemistry Editorial Board. As Walter takes up his new position, we asked for his thoughts on how sees the Journal, and the area of green chemistry, developing in the future…

Who or what initially inspired you to become a chemist?

I cannot fix this to a single person or event. To be honest, a large number of coincidences and external factors led me to study chemistry at Regensburg University, and it was mostly during my time as PhD-student with Henri Brunner and PostDoc with John Brown that I developed a strong research interest into catalysis and organometallic chemistry – and started to become fascinated by the idea of academic freedom!

You’ve recently been appointed as the new Chair of the Green Chemistry Editorial Board – what most excites you about the Journal?

The ever increasing scientific quality of the contributions and the incredible enthusiasm of the community – just coming back from the Green Chemistry Gordon Conference near Lucca in Italy, I am still nurtured by the same experience there!

Where would you like to see the Journal develop during your time as Chair?

Click here to read more…

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Issue 9 of Green Chemistry now online!

22 Aug 2012

By Mary Badcock, Deputy Editor.

The latest issue of Green Chemistry is now available to read online.

The front cover of issue 9 features work by Tomislav Frišĉić from the University of Cambridge (UK) and McGill University (Canada) and colleagues from Croatia, the UK and USA. The authors discuss the concept of a solvent-free research laboratory which would eliminate the use of solvents for both chemical synthesis and the structural characterization. The team used the mechanochemical click coupling of isothiocyanates and amines as the model reaction using an electrical, digitally controllable laboratory mill. 49 different thiourea derivatives were synthesized and all products were characterised by X-ray diffraction and solid-state NMR spectroscopy.

A model for a solvent-free synthetic organic research laboratory: click-mechanosynthesis and structural characterization of thioureas without bulk solvents, Vjekoslav Štrukil, Marina D. Igrc, László Fábián, Mirjana Eckert-Maksić, Scott L. Childs, David G. Reid, Melinda J. Duer, Ivan Halasz, Cristina Mottillo and Tomislav Friščić, Green Chem., 2012, 14, 2462-2473

The inside front cover of this issue highlights work by Chan Beum Park and co-workers from KAIST and Seoul National University, Korea, who report the synthesis of graphene-wrapped CuO hybrid materials by CO₂mineralization. These materials were created from CoCO3 microspheres mineralized on graphene oxide nanosheets and were shown to be promising materials for lithium ion batteries. The hybrid materials demonstrated greatly enhanced stability and recyclability of the CuO anode for the Li ion batteries.

Synthesis of graphene-wrapped CuO hybrid materials by CO₂ mineralization, Jong Wan Ko, Sung-Wook Kim, Jihyun Hong, Jungki Ryu Kisuk Kang and Chan Beum Park, Green Chem., 2012, 14, 2391-2394

These articles are both free to access for 6 weeks!

Keep up-to-date with the latest content in Green Chemistry by registering for our free table of contents alerts!

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Ghent Bio-Economy Summer School – 7th-10th August 2012

20 Aug 2012

By Mary Badcock, Deputy Editor.

The Ghent Bio-Economy Summer School 2012 was held at Ghent University, Belgium, between the 7th-10th August 2012. The event presented a comprehensive and integrated overview of the bio-based economy by world-leading experts, covering the complete process of biomass to bioproduct.

Green Chemistrysponsored a poster prize at the event which was awarded to Julien Cousin Saint Remi, a PhD student at the Vrije Universiteit Brussel (VUB) in Belgium, where he is developing new and innovative techniques for the downstream processing of biobased products. He was awarded the prize for his poster ‘Recovery of biobutanol from ABE-fermentations with zeolites’ and received a copy of the book ‘Thermochemical conversion of biomass to liquid fuels and chemicals’ (pictured right receiving his prize from Professor Tom Desmet, chair of the organising committee). Many congratulations to Julien on receiving this prize.

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An interview with Martyn Poliakoff

17 Aug 2012

By Mary Badcock, Deputy Editor.

Martyn Poliakoff is a Professor of Chemistry at the University of Nottingham, and the out-going Chair of the Green Chemistry Editorial Board. As he steps down after leading the Journal for the last six years, Martyn took a few moments to talk to us about how he was inspired to become a chemist and how he sees the field of green chemistry developing in the future…

Who or what initially inspired you to become a chemist?

My father and grandfather were physicists. From as young as I can remember, it was always assumed that I would become a scientist. I was lucky to have inspirational physics and chemistry teachers, David Hepburn-Scott and Tony Roberts. I was not good enough at maths to become a physicist but Tony Roberts really inspired me to focus on chemistry and I am still in contact with him nearly 50 years later. (Find out more here)

What have you enjoyed most during your time as Chair of the Editorial Board of Green Chemistry?

I have really enjoyed meeting a variety of green chemists and also it has been a pleasure to promote the Journal across the world.

What do you consider to be the most significant development on the Journal during your time as Chair?

I think there have been three important developments during my tenure. Firstly, the greatly increased Impact Factor; the friendly rivalry with ChemComm has been a great spur to us all. Secondly, the increased rejection rate (including at least one paper of mine!) indicates not only that the Journal has become a more attractive place to publish but also that the standard of Green Chemistry publications is increasing. Thirdly, the appearance of at least three new journals in this area clearly demonstrates that the foresight of the RSC in recognising the potential of green chemistry. I am determined that our Journal shall remain the market leader.

What do you see as the biggest challenge facing the field of green chemistry?

Click here to read more…

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Green Chemistry Blog

Continuous-flow alkene metathesis

4th International IUPAC Conference on Green Chemistry

How synthetic organic chemistry can help to feed the world

What’s new with carbon dioxide?

One-pot reduction of 5-hydroxymethylfurfural via hydrogen transfer from supercritical methanol

Top ten most accessed articles in July

Meet our Editorial Board: Walter Leitner (Chair)

Issue 9 of Green Chemistry now online!

Ghent Bio-Economy Summer School – 7th-10th August 2012

An interview with Martyn Poliakoff

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