Archive for August, 2011

Active and passive liquid crystals

Example of nematic texture and defect structures observed in LC confined in micro-channels.

Example of nematic texture and defect structures observed in liquid crystals confined in micro-channels.

Can the flow of active and passive liquid crystals be accurately described using the same theoretical model? This was the question posed by Miha Ravnik, from the University of Oxford in a recent seminar. The motivation for this work is to improve the understanding of liquid crystal (LC) flow in micro-channels. The coupling of material flow with orientation in LC, via internal material stress, is very interesting both technologically, as a driving mechanism for controlling material flow, and for understanding the behaviour of artificial and biological swimmers. Flow is also important for understanding topological defects in LC (Soft Matter doi: 10.1039/B810933H).

The model of Ravnik is based on the phenomenological Beris-Edwards model, solved using a hybrid lattice-Boltzmann method. The equations couple the orientation, described by an order parameter, with the flow velocity field, which is modelled using a generalised Navier-Stokes description. The orientation describes the LC alignment in the flow, the molecular field and the internal motility of the LC (this is zero for passive LC). The results show that for both passive and active LC the behaviour is dependent on the magnitude of the driving flow and the dimensions of the channel. This includes the LC orientation and flow profiles and the position of defect lines.

Similar behaviour was recently observed experimentally by Sengupta et al. (Soft Matter doi: 10.1039/C1SM05052D), who studied the flow of nematic LC through micro-channels. Different textures and defect structures were observed to develop depending on the channel dimensions and the flow rate applied. Some very nice movies, showing the formation of these structures, can be found as supplementary information with the article.

Miha Ravnik is also interested in understanding the behaviour of topological defect loops seen when colloidal particles are added to liquid crystals (Soft Matter doi: 10.1039/B913065A). The controlled manipulation of these defect loops was discussed in a previous post.

A talk given by Ravnik on liquid crystal colloids can be found here. The talk presents routes for the functionalisation of colloidal particles and continuum liquid crystals.

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Hot Articles: Liquid crystals, anti-pathogenic and stimuli-responsive hydrogels

Read free until 23 September>>>

Antimicrobial and antiviral hydrogels: This brief review provides some illustrative examples of different types of antimicrobial (antibacterial/antifungal) and antiviral hydrogels. The triggered response of the  hydrogels is discussed and a focus is placed on formulation principles, and on how the physicochemical properties of such hydrogels influence their antimicrobial/antiviral action. Martin Malmsten, Soft Matter, 2011, DOI: 10.1039/C1SM05809F

Thermal liquid crystal phases: An interaction assisted approach for realization of biaxiality in smectic A phases is demonstrated in addition to the effectiveness of perfluoroarene-arene and C-H/F interactions as the intermolecular interactions. The slow rotation of the molecules showed unique phenomena such as no clear odd–even effect in their clearing and melting points. Keiki Kishikawa, Takahiro Inoue, Yoshiyuki Sasaki, Sumihiro Aikyo, Masahiro Takahashi and Shigeo Kohmoto, Soft Matter, 2011, 7, 7532-7538, DOI: 10.1039/C1SM05887H

Stimuli-responsive hydrogels: Researchers have functionalised poly(N-isopropylacrylamide) gel with spirobenzopyrans and evaluated the effects of spontaneous ring-opening rates of the photo-chromic molecules on the light-responsive volume change of the subsequent gels. Rates of reswelling from the light-induced shrunken state of the spirobenzopyran-functionalized gels increased with increasing ring-opening rates of spirobenzopyrans in the gels. Taku Satoh, Kimio Sumaru, Toshiyuki Takagi and Toshiyuki Kanamori, Soft Matter, 2011, DOI: 10.1039/C1SM05797A

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Editorial Board Member wins Soft Matter prize

Professor Alejandro Rey (McGill University), who is on the Editorial Board for Soft Matter has won the Stanley George Mason Award. The Canadian Society of Rheology presents the award every three years to a Canandian scientist who has distinguished themselves in the field of Rheology. Read more here.

Soft Matter recently published a Themed Issue on the Dynamics and Rheology of Complex Fluid-Fluid Interfaces, see here…

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Polyelectrolytes and soft matter nanofabrication

Lipid bilayers, vesicles and lipid-polyelectrolyte phases forming on polyelectrolyte multilayers.

Sergio Moya is a soft matter scientist at the CIC biomaGUNE in San Sebastian, Spain. His research focuses on the nano-fabrication of soft matter for various applications including medical applications, to form membranes for water filtration and to study nano-toxicity. Moya is particularly interested in utilising polyelectrolytes as they are “easy to assemble, pattern and synthesise”.

Moya studies polyelectrolyte growth and behaviour using, amongst other things, a quartz crystal micro-balance in tandem with ellipsometry and atomic force microscopy. This allows the growth and assembly of polyelectrolyte multilayers to be monitored along with their mechanical properties and water content (doi: 10.1021/ma1015984).

Polyelectrolyte multilayers have a number of different uses including the non-covalent functionalisation of particles (doi: 10.1021/la803360n). Once coated with polyelectrolytes Moya has shown that the core particles can subsequently be removed without damaging the multilayer coating.  The multilayer can also be selectively removed or attached using the appropriate surfactants (doi:10.1021/jp908608u). Polyelectrolyte multilayers have also been used to support lipid bilayer membranes and study their formation (Soft Matter, doi: 10.1039/b805754k). Bilayers, absorbed vesicles and 3D lipid-polyelectrolyte phases have all been seen to form (see figure).

Finally, in a recent Soft Matter paper, not discussed in his talk, Moya has shown that the toxicity of carbon nanotubes can be reduced when coated with polyelectrolyte-lipid layers (Soft Matter, doi: 10.1039/C0SM01511C).

Sergio Moya recently gave a seminar at the Max-Planck Institute for Dynamics and Self-Organization as part of the Dynamics of Complex Fluids seminar series.

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Soft Matter poster prize winner

Congratulations to Rona Chandrawati from The University of Melbourne, Australia, for winning a Soft Matter poster prize at ESF-EMBO Symposium: Biological Surfaces and Interfaces held at Hotel Eden Roc, Sant Feliu de Guixols, Spain.

The title of Chandrawati’s winning poster was: Capsosomes: Enzyme-Loaded Liposomal Subcompartments within Polymer Carrier Capsules.

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Hot Articles on Biomimetic Soft Matter

These Hot Articles are from an upcoming Themed Issue on “Biomimetic Soft Matter” with Guest Editor Professor Ian Hamley (University of Reading and Diamond Light Source, UK). Keep an eye out for this and other Soft Matter Themed Issues here.

Proteins in biomimetic membranes: promises and facts. A Review on proteins immobilized on surfaces in different orientations to form protein-tethered bilayer lipid membranes, with the protein as the essential building block. Renate L. C. Naumann, Christoph Nowak and Wolfgang Knoll, Soft Matter, 2011, DOI: 10.1039/C1SM05626C

A reversible enzymatic trigger is reported by Samuel Stupp and co-workers, which controls the assembly and disassembly of peptide amphiphile nanostrucutres. This ability to control nanostructure through an enzymatic switch could allow for the preparation of highly sophisticated and biomimetic materials that incorporate a biological sensing capability to enable therapeutic specificity. Matthew J. Webber, Christina J. Newcomb, Ronit Bitton and Samuel I. Stupp, Soft Matter, 2011, DOI: 10.1039/C1SM05610G

These papers can be read for free until September 16.

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EPFDC-2011

Images of two nematodes (Panagrellus redivivus) merging.

Last week (8-12th August) saw the 5th European postgraduate fluid dynamics conference (EPFDC-2011) take place in Goettingen, Germany. The conference was jointly hosted by the Institute of Aerodynamics and Flow technology and the Max Planck Institute for Dynamics and Self-Organization. Organised by postgraduate students, the conference is an open-forum for PhD students allowing them to present their results in talks and posters to an audience of their peers.

The sessions were wide ranging in their themes, which included turbulent flows, applied aerodynamics, hydrodynamic stability and geophysical flows. The conference also featured talks on the swimming of micro-organisms, biofluid dynamics and the patterning of polymer melt films.

The hydrodynamics of swimming micro-organisms

Douglas Brumley is a PhD student at DAMTP, University of Cambridge. His talk focused on his work on the low Reynolds number swimmer Volvox carteri. Volvox forms spherical colonies of up to 50,000 biflagelated cells. The cells on the surface of the colony beat their flagella in a coordinated fashion, resulting in a net fluid motion around the colony. Various pictures and videos of the flagella and fluid motion can be found on the DAMTP website. Brumley’s work focuses on modelling the flow fields around the Volvox colonies and characterising the metachronal wave propagating on its surface.

Recent publications in Soft Matter on similar low Reynolds number swimmers include: Hydrodynamic synchronization at low Reynolds number doi: 10.1039/C0SM01121E, The collective motion of nematodes in a thin liquid layer doi: 10.1039/C0SM01236J and Swimmer-tracer scattering at low Reynolds number doi: 10.1039/C0SM00164C.

Flow through shunts at low Reynolds number

Adriana Setchi is currently a PhD student at Imperial College London. In her talk Setchi discussed her work on the modelling of flow in shunts in the small intestine. Shunts are used by doctors in the small intestine to by-pass diseased areas, or to shorten the intestine for weight loss. While medical doctors are able to carry out the implantation of shunts effectively, the dynamics of flow in these by-passes are not well understood. To model the flow, Setchi finds solutions to the Papkovich-Fadle-eigenfunction and applies them to various flow scenarios.

Recent publications in Soft Matter on dynamics in the small intestine include: The adsorption and competitive adsorption of bile salts and whey protein at the oil-water interface doi: 10.1039/C1SM05840A, Transitions in the internal structure of lipid droplets during fat digestion doi:10.1039/C0SM00491J.

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Focus on: Ionic Liquid Phases & Interfaces

Soft Matter issue 15 front coverReview
Conditions for and characteristics of nonaqueous micellar solutions and microemulsions with ionic liquids
Oliver Zech and Werner Kunz,
Soft Matter, 2011, 7, 5507-5513

Communications
“Dry ionic liquid” as a newcomer to “dry matter”
Kazushi Shirato and Mitsuru Satoh,
Soft Matter, 2011, 7, 7191-7193

Microemulsions with novel hydrophobic ionic liquids
Jan H. Porada, Markus Mansueto, Sabine Laschat and Cosima Stubenrauch,
Soft Matter, 2011, 7, 6805-6810

Diffusion in ionic liquids: the interplay between molecular structure and dynamics
J. R. Sangoro, C. Iacob, S. Naumov, R. Valiullin, H. Rexhausen, J. Hunger, R. Buchner, V. Strehmel, J. Kärger and F. Kremer,
Soft Matter, 2011, 7, 1678-1681

Papers
Study of micelles and microemulsions formed in a hydrophobic ionic liquid by a dielectric spectroscopy method. I. Interaction and percolation
Yiwei Lian and Kongshuang Zhao,
Soft Matter, 2011, DOI: 10.1039/C1SM05491K, Advance Article

Reversible tuning of the hydrophobic–hydrophilic transition of hydrophobic ionic liquids by means of an electric field
Maolin Sha, Dongxiao Niu, Qiang Dou, Guozhong Wu, Haiping Fang and Jun Hu,
Soft Matter, 2011, 7, 4228-4233

Degree of chain branching-dependent assemblies and conducting behavior in ionic liquid crystalline Janus dendrimers
Jin-Woo Choi and Byoung-Ki Cho,
Soft Matter, 2011, 7, 4045-4049

Micellar dye shuttle between water and an ionic liquid
Carlos Guerrero-Sanchez, Daan Wouters, Stephanie Hoeppener, Richard Hoogenboom and Ulrich S. Schubert,
Soft Matter, 2011, 7, 3827-3831

Ionic liquid crystals derived from 4-hydroxypyridine
Jung-Tang Lu, Ching-Kuan Lee and Ivan J. B. Lin,
Soft Matter, 2011, 7, 3491-3501

Don’t miss Faraday Discussion 154 on Ionic Liquids. The meeting will be held on 22 – 24 August 2011, and the papers will be published online a few months after the meeting. More here… www.rsc.org/fd154

To keep up-to-date with all the latest research, sign up for the journal’s e-alerts or RSS feeds or follow Soft Matter on Twitter.

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Tissue patterning—Self-organisation of dendrimers—Electrorheology in space!

Follow the links to read these articles for free until 9 September >>>

Review article on ‘The physics of tissue patterning and extracellular matrix organisation: how cells join forces’.  The authors discuss how cells interact with other cells and with substrates to form complex tissues and organs. Important examples are the patterning of growth and differentiation within tissues and the long-range organisation of the extracellular matrix. P. Kollmannsberger, C. M. Bidan, J. W. C. Dunlop and P. Fratzl, Soft Matter, 2011, DOI: 10.1039/C1SM05588G

Self-organisation of dendrimers is extensively modeled through molecular dynamics simulations of a coarse grained dendron model to show how the thermodynamic conditions play a decisive role on its self-organization. A global phase diagram for dendrons which shows the relation between columnar and supramolecular sphere phases was also realised. Andrew J. Crane and Erich A. Müller, Soft Matter, 2011, 7, 7465-7476, DOI: 10.1039/C1SM05599B

An electrorheological (ER) effect in a single phase ER suspension in microgravity is reported for the first time. Potential applications of single-phase ER fluids may be found in outer-space stations with micro-gravity environment, serving as a tunable friction-generating material. Guoqing Zhao, Shuyu Chen, Weijia Wen, Fumiaki Miyamaru, Mitsuo W. Takeda, Jianding Yu and Ping Sheng, Soft Matter, 2011, 7, 7198-7200, DOI: 10.1039/C1SM05736G

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Liquid marbles–Partially fluorinated amphiphles–Elastic fluids

Read these Hot Articles for free until 8 Sept >>>

Liquid Marbles are stabilised on the surface of an acidic liquid due to hydrophobic components. However, once the pH reaches 5.5 the stabilising chains become to hydrophilic and the sphere collapses. The organic polymer particles were made-up of polyacid-stabilised polystyrene latex. Damien Dupin, Kate L. Thompson and Steven P. Armes, Soft Matter, 2011, 7, 6797-6800,DOI: 10.1039/C1SM05889D

‘Liquid marble’ deposited onto (a) a glass slide and (b) the surface of liquid water in a Petri dish.

Partially fluorinated amphiphiles and their interaction with biomembrane lipids in Langmuir monolayers is studied in this Hot Article. This provides fundamental insights into the molecular function of biomembrane components and support for the biomedical use of fluorinated materials. Shorter perfluoroalkyl chains may have more potential for clinical use than higher fluorinated chains. Hiromichi Nakahara, Marie Pierre Krafft, Akira Shibata and Osamu Shibata, Soft Matter, 2011, 7, 7325-7333, DOI: 10.1039/C1SM05647F

Cross-slot extensional flow oscillatory rheometry, an opto-microfluidic technique, is used to quantify the response of elastic fluids to extensional flows. This understanding is necessary for optimising fluid composition for technological applications such as ink-jet printing. Elastic fluids are complex fluids which respond to applied stress with a combination of solid-like elasticity and liquid-like ability to flow. Simon J. Haward, Vivek Sharma and Jeffrey A. Odell, Soft Matter, 2011, DOI: 10.1039/C1SM05493G

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