Hot Article: Transparent, stretchable, carbon-nanotube-inlaid conductors enabled by standard replication technology for capacitive pressure, strain and touch sensors

Although the constant miniaturisation of consumer electronics has made it perfectly normal for somebody to leave their home in the morning carrying more screens than they leave behind, modern devices are still limited to being as physically rigid as spinning wheels and seed drills. The usefulness of flexible displays, wearable electronics and tactile sensors would all be improved dramatically by the development of reliable non-rigid conductors.

Wang et al. have recently devised a methodology for the manufacture of a stretchable material composed of highly conductive single-walled carbon nanotubes (SWCNTs) and a polydimethylsiloxane (PDMS) elastomer. The procedure starts with the preparation of a “non-stick” substrate obtained by perfluorinating glass. A suspension of SWCNTs in chloroform is then airbrushed over the substrate followed by the application of uncured PDMS. Following curing, an elastomer film with embedded nanotubes is obtained. An experiment examining the change in resistance with respect to tensile strain revealed that although resistance increased with strain when first stretched (as is generally observed), when the strain was removed and for the next ninety-nine strain-release cycles the resistance consistently decreased with increasing strain. This suggests that the first strain serves to orient the nanotubes in a particular way leading to this unexpected behaviour. In addition, the researchers found that specific patterns could be obtained by using patterned substrates or by simply spraying the SWCNT suspension through a patterned mask. The latter allowed the fabrication of a proof-of-concept strain sensor, touch pad and pressure sensor. All three devices were effective and demonstrate the utility of the fabrication technique.

Transparent, stretchable, carbon-nanotube-inlaid conductors enabled by standard replication technology for capacitive pressure, strain and touch sensors
Xiaolong Wang, Tingjie Le, Jillian Adams and Jun Yang
J. Mater. Chem. A, 2013, 1, 3580.  DOI:10.1039/C3TA00079f

James Serginson is a guest web writer for the Journal of Materials Chemistry blog. He currently works at Imperial College London carrying out research into nanocomposites.

To keep up-to-date with all the latest research, sign-up to our RSS feed or Table of contents alert.

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Sustainable materials sound good

Cellulose fibres covered with magnetic nanoparticles have been used to make ultrathin loudspeakers by researchers in Sweden. The material could provide a cheaper and more sustainable alternative to the polymers traditionally used in speakers.

The speaker membrane is only 50 μm thick

The speaker membrane is only 50 μm thick

Conventional loudspeakers contain a bulky magnet that is becoming harder to incorporate into our ever-shrinking gadgets. A coil attached to the speaker membrane is essential for moving the membrane and creating sound waves but the force of this coil can also reduce sound quality. The biocomposite membrane developed by Richard Olsson, Lars Berglund and their teams at the Royal Institute of Technology in Stockholm removes the need for a bulky magnet and enhances sound quality because there is no coil in contact with the membrane.

Read the full story at Chemistry World.

Cellulose Nanofibers Decorated with Magnetic Nanoparticles – Synthesis, Structure and Use in Magnetized High Toughness Membranes for a Prototype Loudspeaker
Richard T Olsson et al, J. Mater. Chem. C, 2013, Accepted Manuscript, DOI: 10.1039/C3TC31748J

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Top 10 most-read Journal of Materials Chemistry C articles – Q3 2013

This month sees the following Journal of Materials Chemistry C articles that are in the top ten most accessed from July – September:

Oxadiazole- and triazole-based highly-efficient thermally activated delayed fluorescence emitters for organic light-emitting diodes
Jiyoung Lee, Katsuyuki Shizu, Hiroyuki Tanaka, Hiroko Nomura, Takuma Yasuda and Chihaya Adachi
J. Mater. Chem. C, 2013,1, 4599-4604
DOI: 10.1039/C3TC30699B

Solution processed metal-oxides for organic electronic devices
Kirill Zilberberg, Jens Meyer and Thomas Riedl
J. Mater. Chem. C, 2013,1, 4796-4815
DOI: 10.1039/C3TC30930D

Ternary and quaternary metal chalcogenide nanocrystals: synthesis, properties and applications
Dmitry Aldakov, Aurélie Lefrançois and Peter Reiss
J. Mater. Chem. C, 2013,1, 3756-3776
DOI: 10.1039/C3TC30273C

Stimuli-responsive molecularly imprinted polymers: versatile functional materials
Shoufang Xu, Hongzhi Lu, Xiuwen Zheng and Lingxin Chen
J. Mater. Chem. C, 2013,1, 4406-4422
DOI: 10.1039/C3TC30496E

Structure–processing–property correlations in solution-processed, small-molecule, organic solar cells
Benjamin H. Wunsch, Mariacristina Rumi, Naga Rajesh Tummala, Chad Risko, Dun-Yen Kang, K. Xerxes Steirer, Jeremy Gantz, Marcel Said, Neal R. Armstrong, Jean-Luc Brédas, David Bucknall and Seth R. Marder
J. Mater. Chem. C, 2013,1, 5250-5260
DOI: 10.1039/C3TC30774C

Fluorinated 9,9′-spirobifluorene derivatives as host materials for highly efficient blue organic light-emitting devices
Zhanfeng Li, Bo Jiao, Zhaoxin Wu, Peng Liu, Lin Ma, Xiaoli Lei, Dongdong Wang, Guijiang Zhou, Huaiming Hu and Xun Hou
J. Mater. Chem. C, 2013,1, 2183-2192
DOI: 10.1039/C3TC00466J

Plant leaf-derived fluorescent carbon dots for sensing, patterning and coding
Liangliang Zhu, Yongjin Yin, Cai-Feng Wang and Su Chen
J. Mater. Chem. C, 2013,1, 4925-4932
DOI: 10.1039/C3TC30701H

Two-dimensional semiconductors: recent progress and future perspectives
Xiufeng Song, Jinlian Hu and Haibo Zeng
J. Mater. Chem. C, 2013,1, 2952-2969
DOI: 10.1039/C3TC00710C

Photochemical stability of electrochromic polymers and devices
Jacob Jensen, Morten V. Madsen and Frederik C. Krebs
J. Mater. Chem. C, 2013,1, 4826-4835
DOI: 10.1039/C3TC30751D

Reduction of graphene oxide to highly conductive graphene by Lawesson’s reagent and its electrical applications
Hongtao Liu, Lei Zhang, Yunlong Guo, Cheng Cheng, Lianjiang Yang, Lang Jiang, Gui Yu, Wenping Hu, Yunqi Liu and Daoben Zhu
J. Mater. Chem. C, 2013,1, 3104-3109
DOI: 10.1039/C3TC00067B

Why not take a look at the articles today and blog your thoughts and comments below.

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Top 10 most-read Journal of Materials Chemistry B articles – Q3 2013

This month sees the following Journal of Materials Chemistry B articles that are in the top ten most accessed from July – September:

Carbon “quantum” dots for optical bioimaging
Pengju G. Luo, Sushant Sahu, Sheng-Tao Yang, Sumit K. Sonkar, Jinping Wang, Haifang Wang, Gregory E. LeCroy, Li Cao and Ya-Ping Sun
J. Mater. Chem. B, 2013,1, 2116-2127
DOI: 10.1039/C3TB00018D

Bioinspired prospects of graphene: from biosensing to energy
Ying Wang, Haixin Chang, Hongkai Wu and Honglai Liu
J. Mater. Chem. B, 2013,1, 3521-3534
DOI: 10.1039/C3TB20524J

Hydrogen-bonds in molecular solids – from biological systems to organic electronics
Eric Daniel Głowacki, Mihai Irimia-Vladu, Siegfried Bauer and Niyazi Serdar Sariciftci
J. Mater. Chem. B, 2013,1, 3742-3753
DOI: 10.1039/C3TB20193G

Synthesis of nanoparticles, their biocompatibility, and toxicity behavior for biomedical applications
Anurag Gautam and Frank C. J. M. van Veggel
J. Mater. Chem. B, 2013,1, 5186-5200
DOI: 10.1039/C3TB20738B

One-step preparation of nitrogen-doped graphene quantum dots from oxidized debris of graphene oxide
Chaofan Hu, Yingliang Liu, Yunhua Yang, Jianghu Cui, Zirong Huang, Yaling Wang, Lufeng Yang, Haibo Wang, Yong Xiao and Jianhua Rong
J. Mater. Chem. B, 2013,1, 39-42
DOI: 10.1039/C2TB00189F

Biomineral-inspired growth of metal–organic frameworks in gelatin hydrogel matrices
Ashesh Garai, William Shepherd, Jia Huo and Darren Bradshaw
J. Mater. Chem. B, 2013,1, 3678-3684
DOI: 10.1039/C3TB20814A

Double network hydrogels from polyzwitterions: high mechanical strength and excellent anti-biofouling properties
Haiyan Yin, Taigo Akasaki, Tao Lin Sun, Tasuku Nakajima, Takayuki Kurokawa, Takayuki Nonoyama, Toshio Taira, Yoshiyuki Saruwatari and Jian Ping Gong
J. Mater. Chem. B, 2013,1, 3685-3693
DOI: 10.1039/C3TB20324G

Recent advancements of graphene in biomedicine
Huacheng Zhang, George Grüner and Yanli Zhao
J. Mater. Chem. B, 2013,1, 2542-2567
DOI: 10.1039/C3TB20405G

A bifunctional nanocarrier based on amphiphilic hyperbranched polyglycerol derivatives
Indah N. Kurniasih, Hua Liang, Sumit Kumar, Andreas Mohr, Sunil K. Sharma, Jürgen P. Rabe and Rainer Haag
J. Mater. Chem. B, 2013,1, 3569-3577
DOI: 10.1039/C3TB20366B

Polymeric theranostics: using polymer-based systems for simultaneous imaging and therapy
Theodora Krasia-Christoforou and Theoni K. Georgiou
J. Mater. Chem. B, 2013,1, 3002-3025
DOI: 10.1039/C3TB20191K

Why not take a look at the articles today and blog your thoughts and comments below.

Fancy submitting an article to Journal of Materials Chemistry B? Then why not submit to us today!

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Top 10 most-read Journal of Materials Chemistry A articles – Q3 2013

This month sees the following Journal of Materials Chemistry A articles that are in the top ten most accessed from July – September.

Promising defect thermoelectric semiconductors Cu1-x GaSb x Te2 (x = 0–0.1) with the chalcopyrite structure:
Jiaolin Cui, Yapeng Li, Zhengliang Du, Qingsen Meng and Hong Zhou
J. Mater. Chem. A, 2013,1, 677-683
DOI: 10.1039/C2TA00157H

Colloidal synthesis and thermoelectric properties of Cu2SnSe3 nanocrystals
Maria Ibáñez, Doris Cadavid, Umberto Anselmi-Tamburini, Reza Zamani, Stéphane Gorsse, Wenhua Li, Antonio M. López, Joan Ramon Morante, Jordi Arbiol and Andreu Cabot
J. Mater. Chem. A, 2013,1, 1421-1426
DOI: 10.1039/C2TA00419D

Synthesis and crystal chemistry of the hybrid perovskite (CH3NH3)PbI3 for solid-state sensitised solar cell applications
Tom Baikie, Yanan Fang, Jeannette M. Kadro, Martin Schreyer, Fengxia Wei, Subodh G. Mhaisalkar, Michael Graetzel and Tim J. White
J. Mater. Chem. A, 2013,1, 5628-5641
DOI: 10.1039/C3TA10518K

Photoelectrochemical properties of chemically exfoliated MoS2
Laurie A. King, Weijie Zhao, Manish Chhowalla, D. Jason Riley and Goki Eda
J. Mater. Chem. A, 2013,1, 8935-8941
DOI: 10.1039/C3TA11633F

Recent progress in organic–inorganic hybrid solar cells
Xia Fan, Mingliang Zhang, Xiaodong Wang, Fuhua Yang and Xiangmin Meng
J. Mater. Chem. A, 2013,1, 8694-8709
DOI: 10.1039/C3TA11200D

Nanophotocatalysts via microwave-assisted solution-phase synthesis for efficient photocatalysis
Likun Pan, Xinjuan Liu, Zhuo Sun and Chang Q. Sun
J. Mater. Chem. A, 2013,1, 8299-8326
DOI: 10.1039/C3TA10981J

NiMoO4 nanowires supported on Ni foam as novel advanced electrodes for supercapacitors
Di Guo, Ping Zhang, Haiming Zhang, Xinzhi Yu, Jian Zhu, Qiuhong Li and Taihong Wang
J. Mater. Chem. A, 2013,1, 9024-9027
DOI: 10.1039/C3TA11487B

Polymer-assisted synthesis of a 3D hierarchical porous network-like spinel NiCo2O4 framework towards high-performance electrochemical capacitors
Changzhou Yuan, Jiaoyang Li, Linrui Hou, Jingdong Lin, Xiaogang Zhang and Shenglin Xiong
J. Mater. Chem. A, 2013,1, 11145-11151
DOI: 10.1039/C3TA11949A

Nano-cellular carbon current collectors with stable cyclability for Li–S batteries
Sheng-Heng Chung and Arumugam Manthiram
J. Mater. Chem. A, 2013,1, 9590-9596
DOI: 10.1039/C3TA11819C

A sandwich N-doped graphene/Co3O4 hybrid: an efficient catalyst for selective oxidation of olefins and alcohols
Renfeng Nie, Juanjuan Shi, Weichen Du, Wensheng Ning, Zhaoyin Hou and Feng-Shou Xiao
J. Mater. Chem. A, 2013,1, 9037-9045
DOI: 10.1039/C3TA11672G

Why not take a look at the articles today and blog your thoughts and comments below.

Fancy submitting an article to Journal of Materials Chemistry A? Then why not submit to us today!

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Beetle feet inspire drug delivery patches

Researchers in Taiwan have developed a drug delivery plaster mimicking the wet adhesion of beetle feet.

The micropillar patch sticks to test surfaces and releases anti-inflammatory drugs in a controlled manner. Drug delivery patches are already is use for medical conditions such as Parkinson’s disease and helping people to quit smoking.

Read the full article by Sonja Hampelin Chemistry World
 
Chen-Yi Tsai and Cheng-Chung ChangJ. Mater. Chem. B, 2013, Accepted Manuscript
DOI: 10.1039/C3TB20735H
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BBC World Service Recording at ISACS12

Want to know what Daniel Nocera thinks about wirelessly beaming energy from space? Over the coming weekend, the BBC World Service will be broadcasting an episode of The Forum, which was recorded at the RSC’s ISACS12 conference last week entitled “Challenges in Chemical Renewable Energy”.

Quentin Cooper hosts the programme in which Daniel Nocera of Harvard University, Clare Grey of the University of Cambridge, Carlos Henrique de Brito Cruz of the State University of Campinas and Jim Watson of the UK Energy Research Council discuss the work in their areas of expertise and future challenges for renewable energy as a whole.

The programme will be broadcast at 23.06 GMT on Saturday 14th September, 10.06 GMT on Sunday 15th September and 2.06 GMT on Monday 16th September. Find out when this is in your local time at: http://www.bbc.co.uk/worldservice/programmeguide/.

It will also be available to listen on the iPlayer shortly after the broadcasts have finished and you will be able to hear it at http://www.bbc.co.uk/programmes/p01g94yj.

– Written by Yuandi Li, RSC Science Executive

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Hot Article: Construction of high strength hollow fibers by self-assembly of a stiff polysaccharide with short branches in water

Anybody who has spent time working in a chemistry laboratory would be forgiven for being jealous of nature’s ability to reliably prepare functional materials. One of its greatest tricks is the use of intermolecular forces to spontaneously create structures of incredible complexity out of many constituent parts. Recently, a great deal of research has focused on understanding these natural processes with a view to creating new materials unknown to nature.

As well as being inspired by naturally occurring self-assembly processes, Shuqin Xu et al. go one step further and also make use of a naturally occurring molecule – extracted from the commercially available fungus Auricularia auricula-judae. The molecule is a polysaccharide with a relatively hydrophobic backbone and hydrophilic side-chains. This combination of features means that – much like the self-assembly of lipids into bilayers – the chains self-assemble into hollow nanofibres with a hydrophilic surface and hydrophobic core. Fluorescence microscopy revealed these fibres to be several microns long with diameters of less than 100 nm. Furthermore, increasing the concentration of the nanofibres led to self-assembly into high aspect ratio thin films followed by rolling of the films into tubes. This fascinating hierarchical structure is believed to contribute to improved mechanical properties over comparable materials such as glucose.

Construction of high strength hollow fibers by self-assembly of a stiff polysaccharide with short branches in water

J. Mater. Chem. A, 2013, 1, 4198.  DOI:10.1039/C3TA00050H

James Serginson is a guest web writer for the Journal of Materials Chemistry blog. He currently works at Imperial College London carrying out research into nanocomposites.

To keep up-to-date with all the latest research, sign-up to our RSS feed or Table of contents alert.

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Hot Articles for September!

Theranostic magnetic nanoparticles for efficient capture and in situ chemotherapy of circulating tumor cells
Ya Wang, Hui-Zhen Jia, Kai Han, Ren-Xi Zhuoa and Xian-Zheng Zhang


Carbon-sulfur composites for Li-S batteries: status and prospects
Da-Wei Wang, Qingcong Zeng, Guangmin Zhou, Lichang Yin, Feng Li, Hui-Ming Cheng, Ian R. Gentle and Gao Qing Max Lu


Engineering highly efficient Eu(III)-based tri-ureasil hybrids toward luminescent solar concentrators
Mariela M. Nolasco, Patrícia M. Vaz, Vânia T. Freitas, Patrícia P. Lima, Paulo. S. André, Rute A. S. Ferreira, Pedro D. Vaz, Paulo Ribeiro-Claroa and Luís D. Carlos

These papers are free to access until 4th November

To keep up-to-date with all the latest  research, sign-up to our RSS feed or

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Introducing Journal of Materials Chemistry A Deputy Editor-in-Chief Hiroshi Imahori

We are delighted to introduce the new Deputy Editor-in-Chief of Journal of Materials Chemistry A, Professor Hiroshi Imahori.

Professor Imahori completed his doctorate in organic chemistry at Kyoto University. From 1990-1992, he was a post-doctoral fellow at the Salk Institute for Biological Studies, USA. In 1992, he became an Assistant Professor at ISIR, Osaka University. In 1999, he moved to the Graduate School of Engineering, Osaka University, as an Associate Professor. Since 2002, he has been a Professor of Chemistry at the Graduate School of Engineering, Kyoto University. Since 2007, he has also been a Principal Investigator at the Institute for Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University. He has been awarded the Japanese Photochemistry Association Prize (2004), JSPS Prize (2006), CSJ Award for Creative Work (2006), Tokyo Techno Forum 21 Gold Medal Prize (2007), Osaka Science Prize (2007), and NISTEP Researcher Award (2007).

Hiroshi Imahori’s current interests involve artificial photosynthesis, molecular photovoltaics, organic functional materials, and drug delivery systems. To date, he has written more than 250 original papers, including:

Conjugated donor–acceptor (D–A) copolymers in inverted organic solar cells – a combined experimental and modelling study
Venla Manninen, Mika Niskanen, Terttu I. Hukka, Felix Pasker, Simon Claus, Sigurd Höger, Jinseok Baek, Tomokazu Umeyama, Hiroshi Imahori and Helge Lemmetyinen
J. Mater. Chem. A, 2013, 1, 7451-7462

Synthesis of low bandgap polymers based on thienoquinodimethane units and their applications in bulk heterojunction solar cells
Tomokazu Umeyama, Yusuke Watanabe, Masaaki Oodoi, Douvogianni Evgenia, Tetsuya Shishido and Hiroshi Imahori
J. Mater. Chem., 2012, 22, 24394-24402

Tunable, strongly-donating perylene photosensitizers for dye-sensitized solar cells
Simon Mathew and Hiroshi Imahori
J. Mater. Chem., 2011, 21, 7166-7174

We would like to take this opportunity to thank the outgoing Deputy Editor-in-Chief, Professor Kazuhito Hashimoto, for his direction during the last year. Professor Hashimoto is stepping down as he has been appointed as an Executive Member of the Council for Science and Technology Policy for Japan. We would like to congratulate him on the role.

Follow the latest journal news on Twitter @JMaterChem or go to our Facebook page.

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