Poster Prizes at the The Brazilian Humboldt Kolleg 2016

The Brazilian Humboldt Kolleg 2016 titled “Environments: technoscience and its relation to sustainability, ethics, aesthetics, health and the human future” took place on 3rd-5th November at the Center of Advanced Materials and Energy Research (CPqMAE) in São Carlos, SP, Brazil. The event was also sponsored by Green Chemistry and a number of poster prizes were awarded by a committee coordinated by the Green Chemistry Advisory Board member Professor Vânia Zuin of Federal University of São Carlos, Brazil.

The first prize was awarded to Livia Loiola of the University of Campinas, Brazil for her poster ‘Amphiphilic block copolymers: what are they and what are they worth for?‘. Kassio Zanoni, of São Paulo University, Brazil, received the second prize for his poster ‘Chemical concepts for energy conversion and sustainability ‘, and `Lísias Novo, of São Paulo University, Brazil, was awarded the third prize for his poster ‘Production of nanocellulose through hydrolysis without mineral acids using sub-critical water ‘.

Congratulations!

More information about the event can be seen on http://www.avh.kollegbr.ufscar.br/

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New Green Chemistry Editorial Board Members: Michael Meier and Rajender S. Varma

We are delighted to welcome Dr Rajender S. Varma and Professor Michael Meier to the Green Chemistry Editorial Board.

Michael Meier, Karlsruhe Institute of Technology, Germany
Michael Meier is full professor at the Karlsruhe Institute of Technology (KIT, Germany) since 2010. He received his diploma degree (M.Sc.) in chemistry in 2002 from the University of Regensburg (Germany) and his PhD under the supervision of Prof. Ulrich S. Schubert from the Eindhoven University of Technology (the Netherlands) in 2006. His research interests include the sustainable use and derivatization of renewable resources for polymer chemistry as well as the design of novel highly defined macromolecular architectures.

Rajender S. Varma, U.S. Environmental Protection Agency, USA
Rajender S. Varma was born in India and received his Ph.D. from Delhi University, 1976. After postdoctoral research at Robert Robinson Laboratories, Liverpool, U.K., he was faculty member at Baylor College of Medicine and Sam Houston State University prior to joining the Sustainable Technology Division at the U.S. Environmental Protection Agency in 1999 with an adjunct appointment at Palacky University, Olomouc, Czech Republic. He has over 40 years of research experience in management of multidisciplinary technical programs and is extensively involved in sustainable aspects of chemistry that include photocatalysis, synthesis, environmental sciences, and development of environmentally benign synthetic methods using alternate energy input using microwaves, ultrasound, mechanochemistry, etc.; efficient technologies for greener remediation of contaminants; and environmental sciences. Lately, he has focused on greener approaches to assemble nanophotocatalysts and sustainable applications of magnetically retrievable nanophotocatalysts in benign media.

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Themed Collection online Molecular Design for Reduced Toxicity

Click through to read the Themed Collection online Molecular Design for Reduced Toxicity guest edited by Paul Anastas, Julie Zimmerman and Adelina Voutchkova-Kostal.

Molecular design for reduced toxicity is an area of green chemistry which seeks to increase our understanding and enable the design of molecules across structural classes and applications that can provide the required functions, without the undesirable toxicity.

Safer by Design
Paul T. Anastas and Julie B. Zimmerman
Green Chem., 2016,18, 4324-4324
DOI: 10.1039/C6GC90074G
Probabilistic diagram for designing chemicals with reduced potency to incur cytotoxicity
Longzhu Q. Shen, Richard S. Judson, Fjodor Melnikov, John Roethle, Aditya Gudibanda, Julie B. Zimmerman and Paul T. Anastas
Green Chem., 2016,18, 4461-4467
DOI: 10.1039/C6GC01058J

A chemical–biological similarity-based grouping of complex substances as a prototype approach for evaluating chemical alternatives
Fabian A. Grimm, Yasuhiro Iwata, Oksana Sirenko, Grace A. Chappell, Fred A. Wright, David M. Reif, John Braisted, David L. Gerhold, Joanne M. Yeakley, Peter Shepard, Bruce Seligmann, Tim Roy, Peter J. Boogaard, Hans B. Ketelslegers, Arlean M. Rohde and Ivan Rusyn
Green Chem., 2016,18, 4407-4419
DOI: 10.1039/C6GC01147K

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2016 AIChE Annual Meeting, San Francisco, November 13-18, 2016

The AIChE Annual Meeting is the premier educational forum for chemical engineers interested in innovation and professional growth. Academic and industry experts will cover wide range of topics relevant to cutting-edge research, new technologies, and emerging growth areas in chemical engineering.

The technical program of the 2016 AIChE Annual Meeting includes:

  • Programming from 22 of AIChE’s Divisions and Forums
  • 10 topical conferences
  • 100+ invited sessions
  • 44 poster sessions

Register now or click through for more information on this meeting.

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ISGC, the International Symposium on Green Chemistry, La Rochelle, May 16th-19th 2017

ISGC, the International Symposium on Green Chemistry, will be held in La Rochelle – France, May 16th-19th 2017.
There will be 10 topics / 24 plenary lectures / 280 oral communications selected from a call for communications / a green chemistry challenge / 1000 participants (academic institutions and private industry).

The call for communications is in progress. Deadline for papers is October 31th 2016.

Green Chemistry will be publishing a selection of invited contributions following ISGC-2017 to showcase some of the research presented at the conference. Please note that all submissions will be subject to initial assessment and peer-review and as such we cannot guarantee publication of invited manuscripts.


Topics :
Renewable Carbon / Biomass conversion / Valorization of waste
Smart Use of Fossil
Polymers
Environmental Impact & Life Cycle Assessment
Mechanism
Catalytic Systems
Biotechnologies
Alternative Solvents
Non-thermal Activation Methods
Networking & Education

The main objective of ISGC 2017 is to gather the most eminent scientists involved in the field of green chemistry to debate on the future challenges of Chemistry keeping in mind the problems of access to a sustainable energy, the management of resources (carbon, water, metals, minerals), Human development, global warming, impact on the environment and competitiveness of our Industry.

For more information please see www.isgc-symposium.com

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Top 10 Reviewers for Green Chemistry

In celebration of Peer Review Week, with the theme of Recognition for Review – we would like to highlight the top 10 reviewers for Green Chemistry in 2016. They have been selected by the editor for their significant contribution to the journal.

Top 10 reviewers for Green Chemistry
Dr Feng Lu, University of Utah
Dr Yasuyuki Kita, Ritsumeikan University
Dr Jean Jacques Vanden Eynde, University of Mons-UMONS
Dr Nicholas E. Leadbeater, University of Connecticut
Dr Mark A. Harmer, SAC Tech Innovations
Dr Francois Jerome, Universite de Poitiers
Dr Zhijie Wu, China University of Petroleum
Professor Robin D. Rogers, McGill University
Dr Alistair King, University of Helsinki
Professor Luigi Vaccaro, Universita di Perugia

We would like to say a massive thank you to these reviewers as well as the Green Chemistry board and all of the community for their continued support of the journal, as authors, reviewers and readers.

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Methyl vinyl glycolate: a renewable platform compound with industrial potential

MVG reaction pathways

The metathesis and Claisen chemistry of methyl vinyl glycolate

Danish scientists have highlighted the diverse chemistry methyl vinyl glycolate (MVG) – a byproduct of the stannosilicate-catalysed formation of methyl lactate from monosaccharides and disaccharides – can offer as a powerful green platform molecule.

Robert Madsen and colleagues at the Technical University of Denmark used Grubbs-type catalysts to dimerise MVG by homo metathesis to yield (E)-2,5-dihydroxyhex-3-enedioate, a diastereomeric diester with potential for use as a monomer in the synthesis of functionalised polyesters. Cross metathesis of MVG with long chain terminal olefins gave unsaturated fatty acid methyl esters, which may be hydrogenated into customisable surfactants.

Performing Claisen-type rearrangements, the team also obtained industrially important unsaturated derivatives of adipic acid – a starting material for synthetic fibres. Palladium-catalysed transposition of MVG’s allylic alcohol derivative also resulted in a 1,4-dioxygenated motif which could be used as a precursor to 1,4-butanediol or γ-butyrolactone.

Want to know more? Read this article online, which is free to access until 30 September 2016:

Methyl vinyl glycolate as a diverse platform molecule” by A. Sølvhøj et al., Green Chem., 2016, DOI: 10.1039/C6GC01556E

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Welcome Keiichi Tomishige, Burkhard Koenig and Karen Goldberg to the Green Chemistry Advisory Board

Keiichi Tomishige, Tohoku University, Japan, is focused on creating solid catalysts for converting biomass resources. For instance, environmentally friendly hydrocarbon resources such as rice straw and wood scrap are readily available and easily recycled, and could play a major role in the production of renewable chemicals and alternative fuels as oil reserves become exhausted. Likewise, natural gas harbors considerable potential as a liquid fuel if efficient conversion processes can be developed. However it is currently much easier to convert oil, so the aim therefore is to improve conversion efficiency. To this end, Keiichi Tomishige and his research group are continually designing, testing and analyzing new catalysts in a bid to find the optimum solution for each process. More information can be found on Keiichi Tomishige’s website.

Research activities of Burkhard Koenig, University of Regensburg, Germany, revolve around the use of intermolecular interactions in the molecular design of chemosensors, catalysts and pharmaceutically active compounds. Design, synthesis and determination of properties are the typical elements of all projects. More information can be found on Burkhard Koenig’s website.

Karen Goldberg, University of Washington, USA, has research interests including activation of strong bonds, anti-Markovnikov hydroamination of alkenes, harnessing and making molecular oxygen, a new generation of electrophilic oxidation catalysts and epoxidation with O2. More information can be found on Karen Goldberg’s website.

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4th International Conference of the Cluster of Excellence “Tailor-Made Fuels from Biomass”: Conference Report 2016

Dominik Limper M.Sc. / Dr. Kylie Luska
Institute of Technical and Macromolecular Chemistry (ITMC)

Marius Zubel M.Sc.
Institute for Combustion Engines (VKA)

Dipl.-Ing. Benedikt Heuser
COO Cluster of Excellence “Tailor-Made Fuels from Biomass”

Tailor-Made Fuels – From Production to Propulsion

The 4th International Conference on Tailor-Made Fuels from Biomass (TMFB) organized by the Cluster of Excellence was held from June 21st to 23rd in Aachen, Germany. Nearly 200 scientists took the opportunity to discuss the synthesis, production and combustion of modern biofuels and for the first time alternative fuels derived from carbon dioxide as well as from renewable electricity made up one additional focus of the lectures. Internationally renowned experts as well as TMFB members presented their findings and current research activities within the Cluster of Excellence. The program also contained a poster session, which included a poster award for the two most convincing posters. As in previous years, a framework program providing the chance of networking and thinking outside the box of the own discipline completed the conference.

Prof. Uwe Schröder from TU Braunschweig started off this year’s conference with a lecture on the opportunities and challenges of producing biofuels using electrochemical catalytic processes. He focused on new electrochemical reduction pathways for the transformation of biogenic platform molecules to possible fuel candidates including: (1) levulinic acid to valeric acid or octane; (2) 5-hydroxymethylfurfural to 2,5-dimethylfuran; and (3) fatty acids or triglycerides to Diesel‑like olefin/ether mixtures. Prof. Schröder’s work highlighted how the conversion of biomass using electrochemical routes can produce potential fuel candidates that cannot be readily obtained using chemocatalysis and provides a method to chemically store excess renewable electricity.

The second keynote lecture this morning was presented by Prof. Johannes G. de Vries from the Leibniz Institute for Catalysis (LIKAT) in Rostock, who outlined his quest towards the ‘holy grail’ of biomass conversion: the depolymerization of lignin. He pointed out a catalytic approach to convert β‑O‑4 lignin model compounds through a tandem reaction involving an acid catalyzed cleavage of the ether linkage followed by capture of the reactive intermediates through acetal formation, hydrogenation or decarbonylation. This chemocatalytic process can be applied directly to authentic lignin samples or even as a “lignin‑first” franctionation method of biomass feedstocks to provide moderate yields of monomeric products resulting mainly from cleavage of the β-O-4 linkages. Prof. de Vries emphasized how the development of advanced analytical tools is required in the field of lignin depolymerization to enable a detailed mechanistic understanding of which linkages are broken in novel catalytic transformations.

This year’s poster session was followed by the keynote of Dr. Gautam Kalghatgi with “The Outlook for Transport Fuels”. He opened his talk by highlighting the importance of the transport sector for modern society but also its impact on global CO2 emissions and greenhouse gasses. Furthermore, he outlined the relevance of petroleum and liquid fuels, especially for heavy duty transportation, and mentioned the limited impact of alternative fuels within the next few decades. Afterwards, he explained the challenges of increasing the efficiency of spark ignition engines. With further downsizing and downspeeding engine knock becomes more likely and future fuels need higher resistance against knock. However, the Research Octane Number (RON) which is characterizing the knock resistance of gasoline fuels does not fully apply for modern engines, since phenomena like pre‑ignition and super‑knock can occur. Therefore, he mentioned the need for new characteristic fuel numbers. During the second part of his presentation, Dr. Kalghatgi focused on the challenges for modern Diesel engines where the trade‑off between soot and NOX emissions is the main focus of research. To avoid this trade‑off, he proposed using low Cetane fuels or gasoline compression ignition, since greater homogenization can be achieved and therefore soot formation can be avoided.

PhD student Rene Büttgen, from the Institute for Physico-Chemical Fundamentals of Combustion (PCFC) RWTH Aachen University.

He concluded his talk with an outlook on the fuel distribution for the next few decades where a strong tendency towards Diesel fuel was evident. Therefore, gasoline and low octane fuels will be available in abundance, making research on gasoline engines and GCI very important.

The second day of the conference was opened by Prof. Robert Dibble from King Abdullah University of Science and Technology, who was giving a talk about “Better Biofuel Blending – Strategies for Optimal Blending of Biofuels with Petroleum Fuels to Improve Engine Combustion Performance”. In the beginning of his talk, he highlighted the importance of knock resistant fuels for spark ignition engines due to further downsizing and downspeeding trends in modern engine development. To obtain these knock resistant fuels, he presented several octane boosters which could be obtained from biomass. In addition to that, he presented a method to detect pre‑ignitions which would make it possible to enable counter measures like advanced spark timing.

For compression ignition engines a similar approach as the one from the previous keynote by Dr. Kalghatgi was presented. Prof. Dibble as well proposed the use of low Cetane fuels in order to achieve better homogenization of the fuel‑air mixture to eliminate the soot/NOX trade‑off. In contrast to the previous keynote,  Prof. Dibble was using fuels, which usually do not ignite in a Diesel engine and mixed them with ignition enhancers like the biofuel di ethyl ether.

Prof. Dibble was followed by Prof. Roger F. Cracknell, who was giving a talk on the “Combustion Challenges in Designing Fuels for Modern Engines”. He started his talk by outlining the challenges for future mobility and a life cycle analysis of a series production car, where the tank-to-wheel emissions represent the biggest share of CO2. Furthermore, the importance of downsizing on efficiency was highlighted as in the previous talks. Moreover, he mentioned the importance of burning velocity, which has an impact on the knocking resistance as well as higher velocities are more beneficial. Another promising way to reduce emissions and to further increase efficiency are low temperature combustion (LTC) modes for compression engines. These combustion modes avoid areas where soot and NOX are formed and increase efficiency due to lower heat losses. During the second part of his presentation, Prof. Cracknell focused on deposits in the engine and on local emissions. Here the effects of injector fouling of gasoline and Diesel injectors on emissions and engine efficiency were presented. To conclude his talk, he highlighted the potential of knock resistant gasoline fuels with high burning velocities in order to increase efficiency. Additionally, he mentioned that novel combustion modes for compression ignition engines are very promising but also represent challenges regarding stability and noise. Finally he explained the potential of GTL fuels and biofuels to achieve locally lower emissions.

The afternoon keynote was held by Dr. Hermann Pengg from Audi AG with a talk about “Emission Neutrality in the Transport Sector” in which he presented the opportunities of e-fuels. First, he outlined the need for liquid or gaseous energy carriers, since the transition to electric mobility will be too long and with e-fuels the current infrastructure can be used. Furthermore, with increasing amount of renewable energy like wind and solar power, huge amounts of excess energy will be available which have to be stored somewhere. For these reasons, a power to gas plant was presented which could fuel 1,500 passenger cars. This technology shows that it is possible to achieve a great reduction in greenhouse gas emissions for long range passenger transport and heavy duty. Finally, it was concluded that power to fuel in combination with electric cars is the only solution for a significant reduction of greenhouse gasses and that the power to fuel approach can also help with the big fluctuation in power supply of renewable energy.

The final day of the conference included a keynote presentation from Prof. Johan Sanders from Wageningen University on the economic and social aspects of the biorefinery concept. He emphasized the importance of small-scale biorefineries as they allow for reduced costs associated with decreased feedstock transportation, capital costs and process energy requirements. However, for small‑scale production to be economically viable, a biomass feedstock must be carefully chosen to allow for the formation of a variety of high-value products (e.g. sugar, amino acids, lipids). Furthermore, Prof. Sanders outlined how the transition to a bio-based economy can also led to job creation in the agricultural and chemical sectors and thus also provide significant socioeconomic benefits.

Not only the mentioned keynote sessions brought a lot of innovative input to the conference – many inspiring presentations were held during the various sessions. In total, 38 speeches were given in parallel sessions with 25 presentations being held by external speakers coming both from industry and universities from all over the world. Moreover, the previously mentioned poster session, consisting of more than 30 diverse posters, extended the scientific value of TMFB’s 4th International Conference. The presented posters covered a wide range of topics. Ronny Uhlig was awarded for his outstanding poster on “Microbial Electroreduction of Biomass Intermediates to Tailor-Made Fuels” as well as Karin Munch for her inspiring poster on “An Analysis of Butanol and Octanol/Diesel Blends from Both a Sustainable and an Engine Point of View”.

Besides the scientific input during the daily sessions, the conference offered the opportunity to establish and maintain contacts in a relaxed atmosphere in the evenings. The social program began on the first evening with a get‑together at the conference location, where food and drinks were served while the participants had the opportunity to watch the football match of the German Men’s National Team in the UEFA Euro 2016. The highlight of the second evening was the conference dinner, held at the Forum M in Aachen. All participants were invited to join the dinner and enjoy a picturesque view of the Aachen old town while musician Kathi Monta entertained the guests with her saxophone music.

Taking a look back, the 4th International Conference bore the comparison with the previous conferences, which set a high standard. The organizers thank everyone who was part of the event and we are already looking forward to our 5th International Conference, taking place from June 20th to 22nd in Aachen. Once again, researchers who are interested in an interdisciplinary perspective on the development of novel biofuels and other alternative fuels are invited to take part. Vital discussions, diverse networking opportunities and a lot of valuable input are the main characteristics of TMFB’s International Conference, and we will be happy to share all these benefits with you again next year.

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Register now and book a slot for Green Chemistry 2016 International Conference

Written by John Dixon, Program Director, Green Chemistry 2016

Conference Series LLC invites all the participants from all over the world to attend “3rd International Conference on Past and Present Research Systems of Green Chemistry” during September 19-21, 2016 in Las Vegas, USA. This includes prompt keynote presentations, Oral talks, Poster presentations and Exhibitions.

Green Chemistry Conference will be a multidisciplinary gathering and present major areas such as green synthesis, green energy, green catalysis, education and policies. The forum of scientists, students and researchers from all corners of the globe come together to discuss future developments. Each session of the meeting will include expert lectures, poster presentations and discussions, including sustainable development processes. We are glad to invite you to join us on behalf of the organizing committee.

Every year over 300 experts representing renewable energy companies, technology and service providers, governments, investors and consultants attend our Green Chemistry Conferences.

With so much to see and do, you can’t miss the excitement and energy of Green Chemistry Conference in Las Vegas, USA.

For more information, pleae contact:
John Dixon
Program Director
Green Chemistry 2016
greenchemistry@conferenceseries.net
731 Gull Ave., Foster City │CA 94404, USA │Tel: +1-702-508-5200 | Ext:8046

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