Archive for the ‘Hot Article’ Category

A flexible future for robotics: Soft Matter article in Chemistry World

US researchers have created a series of smart materials that twist and coil in response to light. These soft materials could be used in the muscle systems of future robots.

The field of robotics is looking to move beyond the clanking, jerky monstrosities of bad Hollywood movies. Most robotic systems are still hard, composed of metal structures with joints based on conventional bearings. Wheels and treads are often used, unnatural elements that cannot reproduce natural motions. A further limitation is they require large on-board energy sources to power motion, which increases weight and limits portability.

Now, a team including Timothy White and Matthew Smith at the US Air Force Research Laboratory in Ohio, have fabricated a series of cantilevers made from azobenzene liquid crystal polymer networks that can twist and coil, powered only by a change in the polarity and intensity of an external light source. The direction of the resulting torsional movement is partly controlled by the order within the material.

Smith, now an assistant professor at Hope College in Michigan says that while stimuli-responsive materials have exhibited planar and twisting motions before, the aim of the study was to ‘expand the suite of motions available’. The out-of-plane motions developed in this work are essential to ‘drive the field forward’ and better copy the more dexterous movements of living creatures.

Gursel Alici, a robotics expert at the University of Wollongong in Australia says this work ‘makes a significant contribution towards the realisation of biologically inspired robotic systems’. However, he believes ‘there are some immediate questions, which should be addressed before seeing application of this and other similar smart materials in novel device concepts.’ These questions include how to scale up the cantilevered structures to provide mechanical outputs as good as those of skeletal muscles.

Smith agrees that application of these materials in practical robots is far off, but this is only one of many interesting applications for their work. He admits that the main ‘limitation of these materials, right now, is [that] they are confined to small scales’ and thin films.

Future work will aim to produce materials that are capable of more complex motions and that are more mechanically robust for larger scale applications.

Torsional mechanical responses in azobenzene functionalized liquid crystalline polymer networks
Jeong Jae Wie, Kyung Min Lee, Matthew L. Smith, Richard A. Vaia and Timothy J. White
Soft Matter, 2013, Advance Article DOI: 10.1039/C3SM51574E

This feature was written by Jason Woolford and was originally published online in Chemistry World.

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Hot papers for August!

Photo-sensitivity of dye-doped liquid crystal elastomers
Jean E. Marshall and Eugene M. Terentjev, Paper



Discovering crystals using shape matching and machine learning
Carolyn L. Phillips and Gregory A. Voth, Paper



Collective alignment of nanorods in thin Newtonian films
Yu Gu, Ruslan Burtovyy, James Townsend, Jeffery R. Owens, Igor Luzinov and Konstantin G. Kornev, Paper



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July’s hot papers

Phase behavior of rigid, amphiphilic star polymers
Christian Koch, Athanassios Z. Panagiotopoulos, Federica Lo Verso and Christos N. Likos

 



Topological defects, surface geometry and cohesive energy of twisted filament bundles
Isaac R. Bruss and Gregory M. Grason


Ultrastretchable, cyclable and recyclable 1- and 2-dimensional conductors based on physically cross-linked thermoplastic elastomer gels
Kenneth P. Mineart, Yiliang Lin, Sharvil C. Desai, Arjun S. Krishnan, Richard J. Spontak and Michael D. Dickey

These papers are free to read until 27th August!


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Flat-pack structures build themselves

Scientists in the US have developed flat pack structures that can autonomously assemble into three-dimensional shapes on application of an electrical current. Unlike traditional three-dimensional assembly techniques, which require sophisticated printers to reach the final product, this approach uses heat triggered shape memory polymers.

Three-dimensional structures normally come pre-assembled or equipment needs to be transported to create them in situ. Now, along with his colleagues, Samuel Felton, from Harvard University, has demonstrated that by printing shape memory polymers (SMP) onto laser-cut joints with conductive coatings, the assembly process can be separated entirely from the original printing.

Initiation of the SMP transformation is central to Felton’s technique. A SMP is printed in a deformed, flat state and aligned with a resistive circuit over a scored substrate, in this case, paper. An electric current is then run through the circuit and joule heating activates the phase transformation of the shape memory polymer back into its original shape and folds the paper. As this combination is electrically triggered, it allows both simultaneous and sequential folding of complicated shapes.

Felton explains that the most challenging aspect of the work was creating the precisely aligned composite as the approach relies upon separately cut layers that are then joined using a mixture of pins and silicone tape. As alignment is performed when manufacturing the flat structure, the end product is, as was the aim, ‘accessible for everyone.’

Jinsong Leng, an expert in smart materials at Harbin Institute of Technology, China, agrees: ‘shape memory composites play an enormous role in self-folding structures formed by remote and automated assembly. The approach could significantly accelerate the advancement of promising applications in 3D structure fabrication techniques.’

Self-folding with shape memory composites
Samuel M. Felton, Michael T. Tolley, ByungHyun Shin, Cagdas D. Onal, Erik D. Demaine, Daniela Rus and Robert J. Wood
Soft Matter, 2013, Advance Article

This feature was written by Charlie Quigg and was originally published online in Chemistry World.

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June’s hot papers

Review Article: Topology of nematic liquid crystal colloids confined to two dimensions
Uroš Tkalec and Igor Muševič


Precise determination of the Poisson ratio in soft materials with 2D digital image correlation
Robyn H. Pritchard, Pascal Lava, Dimitri Debruyne and Eugene M. Terentjev


Elasticity of flexible polymers under cylindrical confinement: appreciating the blob scaling regime in computer simulations
Juin Kim, Chanil Jeon, Hawoong Jeong, Youngkyun Jung and Bae-Yeun Ha 

 

These hot papers are free to read until 23rd July!


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May’s hot papers

Cationic poly(2-oxazoline) hydrogels for reversible DNA binding
Matthias Hartlieb, David Pretzel Kristian Kempe, Carolin Fritzsche, Renzo M. Paulus, Michael Gottschaldt and Ulrich S. Schubert

  


Tuning colloidal association with specific peptide interactions
Alia P. Schoen, Bob Hommersom, Sarah C. Heilshorn and Mirjam E. Leunissen

  


How coatings with hydrophobic particles may change the drying of water droplets: incompressible surface versus porous media effects
Benoît Laborie, Florent Lachaussée, Elise Lorenceau and Florence Rouyer


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April’s hot papers

Knotting and metric scaling properties of DNA confined in nano-channels: a Monte Carlo study
Cristian Micheletti and Enzo Orlandini


Computer simulations of colloidal particles under flow in microfluidic channels
Arash Nikoubashman, Christos N. Likos and Gerhard Kahl


Stimuli-responsive surfactants
Paul Brown, Craig P. Butts and Julian Eastoe


(more…)

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March’s hot papers

Cylindrical crystalline-core micelles: pushing the limits of solution self-assembly
Joachim Schmelz, Felix H. Schacher and Holger Schmalz


Viscoelastic effects on electromechanical instabilities in dielectric elastomers
Harold S. Park and Thao D. Nguyen


Compositional interface dynamics within symmetric and asymmetric planar lipid bilayer membranes
Tao Han and Mikko Haataja

(more…)

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February’s hot papers

Kinetics of multicompartment micelle formation by self-assembly of ABC miktoarm star terpolymer in dilute solution
Long Wang, Rui Xu, Zilu Wang and Xuehao He


A novel particle tracking method with individual particle size measurement and its application to ordering in glassy hard sphere colloids
Mathieu Leocmach and Hajime Tanaka


The buckling and invagination process during consolidation of colloidal droplets
F. Boulogne, F. Giorgiutti-Dauphiné and L. Pauchard

(more…)

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Hot paper: In vitro digestion of emulsions

Understanding the health, safety and nutritive aspects of foods is becoming increasing important, as evidence builds to suggest that diet plays a part in some chronic illnesses. As a part of this, the effective nutritive intake may differ from the food content, for example a structure containing a micronutrient is not broken down during digestion. A popular model food system is an emulsion, a liquid-liquid dispersion.

In this hot paper, Marze and Choimet compare the in vitro digestion of emulsions with different formulations using various techniques. They use classical physicochemical methods to build on their previous study (DOI: 10.1039/c2sm26334c) on diffusion methods to check the roles of other factors other than the effect of the triglyceride on digestion. The authors describe mass transfer models that identify the mechanistic paramenters and help the data interpretation. All the techniques showed that the type of triglyceride is the dominant parameter in explaining the emulsion digestion.

In vitro digestion of emulsions: mechanistic and experimental models
Soft Matter, 2012, 8, 10982.  DOI: 10.1039/c2sm26336j.
(free to read for a short time)

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