Archive for the ‘Hot Article’ Category

Hot Article: Light and temperature bi-responsive emulsion foams

A team of French scientists have developed a method for controlling the amount of foam. The system uses light and temperature as stimuli for controlling foamability of an emulsion. The foamability could be decreased upon heating, completely stopped under UV irradiation and recovered upon cooling, leading to bi-stimulable emulsion foaming.

Graphical abstract: Light and temperature bi-responsive emulsion foams

 The applications of foams are widespread and they are found in many fields ranging from food industry to detergency and oil recovery. This system shows allows scientists to control the amount of foam without changing the composition of the emulsion.

Read the full article here: A. Salonen, D. Langevin and P. Perrin, Soft Matter, 2010, DOI: 10.1039/C0SM00705F

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Hot Article: Characterisation and performance of hydrogel tissue scaffolds

Characterisation of pores over a broad range of sizes poses a problem especially when analysing soft polymer hydrogels, as no one methodology can adequately cover the entire range.

Graphical abstract: Characterisation and performance of hydrogel tissue scaffolds 

This paper by Sergey V. Mikhalovsky and co-workers describes a combined technique used for evaluation of the porous structure of a collagen hydrogel on the basis of NMR-cryoporometry (sensitive to nanopores) and confocal laser scanning microscopy (CLSM) imaging (sensitive to macropores). Thermodesorption of water, diffusion of proteins through a collagen membrane, migration and growth of normal primary human skin fibroblasts, and the interaction kinetics of 3T3 mouse fibroblast cells (using a quartz crystal microbalance) with collagen were also analysed with respect to the porous structure of the material.

Read the full article here: Vladimir M. Gun’ko, Lyuba I. Mikhalovska, Irina N. Savina, Rostislav V. Shevchenko, Stuart L. James, Paul E. Tomlins and Sergey V. Mikhalovsky, Soft Matter, 2010, DOI: 10.1039/C0SM00617C

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Sticky materials from bent pillars

Materials resembling a gecko’s hairy feet could lead to smart adhesives or microrobots capable of climbing walls claim South Korean and US scientists.

Asymmetric adhesion is used by many insects and gecko lizards, allowing them to move on nearly any surface – horizontal, tilted or vertical. Many of these creatures have feet covered by intricate fibrillar structures that are responsible for their superb climbing ability. Among these creatures, gecko lizards have one of the most efficient and interesting adhesion devices consisting of finely angled arrays of branched fibres (setae).

Now a team led by Ho-Young Kim at Seoul National University, South Korea, and Ashkan Vaziri at Northeastern University, Massachusetts, US, has created an array of tilted polymer pillars to form a surface with asymmetric adhesion and friction properties similar to a gecko’s footpad. An arrangement of straight polymer micropillars is created using soft lithography and then exposed to an argon ion beam. The ion beam causes the surface of the micropillars to wrinkle which uniformly bends the pillars towards the ion beam – forming a tilted array.

Tilted micropillars have similar adhesion properties to a gecko's footpad
Tilted micropillars have similar adhesion properties to a gecko’s footpad

‘A key feature of natural fibrillar interfaces is that properties such as friction and adhesion depend quite strongly on the direction of testing,’ explains Anand Jagota an expert in the mechanics of soft materials at Lehigh University, Pennsylvania, US. ‘One important reason is that the underlying fibrils are bent,’ he adds. Shu Yang an expert in biomimetic materials at the University of Pennsylvania in the US welcomes the research saying, ’tilted pillars as observed in gecko foot pads have often eluded us because of the complexity in fabrication and our inability to control the tilting angles. This is a novel and simple approach to create titled polymer pillars in a controlled fashion.’ The polymer micropillars don’t yet have the hierarchical structure found on a gecko’s setae. This is something the team hope to replicate in the future although they also have grander plans. ‘We’d like to work with other collaborators to create microrobots that use the tilted micropillars to climb walls’ says Ashkan Vaziri, ‘as well as improving the surface properties of the material.’

Tilted Janus polymer pillars
Myoung-Woon Moon, Tae-Gon Cha, Kwang-Ryeol Lee, Ashkan Vaziri and Ho-Young Kim, Soft Matter, 2010
DOI: 10.1039/c0sm00126k

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