Archive for the ‘Hot Article’ Category

Hot Article: Controlling the micellar morphology of binary PEO–PCL block copolymers in water–THF through controlled blending

Scientist have studied the self-assembly of a binary mixture of polycaprolactone-polyethylene oxide block copolymers in solution. The different polymers form vesicles and spherical micelles in water and self-assembly is triggered by changing the solvent from THF to water. The team led by Peter Schuetz, Unilever, UK, also used Self-Consistent Field Theory based modelling to give further insights into the forces driving self assembly.

Graphical abstract: Controlling the micellar morphology of binary PEO–PCL block copolymers in water–THF through controlled blending

The team say that both experiment and theory demonstrate that controlled blending of block copolymers is an effective design parameter for controlling the morphology of the self-assembled structures in block copolymer solutions. This allows a much richer range of nano-morphologies than is possible with single, monomodal block copolymer solutions, they claim.

Peter Schuetz, Martin J. Greenall, Julian Bent, Steve Furzeland, Derek Atkins, Michael F. Butler, Tom C. B. McLeish and D. Martin A. Buzza, Soft Matter, 2011, DOI: 10.1039/C0SM00938E

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Hot Article: Strain stiffening induced by molecular motors in active crosslinked biopolymer networks

The elastic response of active biopolymer networks is determined not only by molecular motors but also by the density and stiffness of crosslinking proteins say US Scientists.

Graphical abstract: Strain stiffening induced by molecular motors in active crosslinked biopolymer networks

Peng Chen and Vivek B. Shenoy from Brown University, USA, studied the elastic response of actin networks with both compliant and rigid crosslinks by modeling molecular motors as force dipoles.

Fancy knowing more? Read the full article for free here: Peng Chen and Vivek B. Shenoy, Soft Matter, 2011, DOI:10.1039/C0SM00908C

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Hot Article: Constructing robust 3-dimensionally conformal micropatterns: vulcanization of honeycomb structured polymeric films

A robust micro-porous 3D polymeric film has been constructed using a sacrificial template by Chinese scientists. This simple and cheap method has a variety of promising applications including biosensors, liquid chromatography and micro-reactors the team say.

 Graphical abstract: Constructing robust 3-dimensionally conformal micropatterns: vulcanization of honeycomb structured polymeric films

The team led by Lei Li at Xiamen University and Zhi Ma at Shanghai Institute of Organic Chemistry demonstrated that commercially available triblock polymers can perfectly contour nonplanar substrates with hierarchical micro-structures, despite the sharp corners and shapes. This robust strategy is ascribed to the fluid-like property of the rubber matrix of the polymers. In the sequent vulcanization, the resultant 3D structures are effectively cross-linked and become self-supported with improved thermal stability and solvent resistance.

Why not read the full article for free here:

Lei Li, Yawen Zhong, Jianliang Gong, Jian Li, Caikang Chen, Birong Zeng and Zhi Ma, Soft Matter, 2011, DOI: 10.1039/C0SM00809E

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Soft Matter Hot Article: Nematic order in suspensions of colloidal rods by application of a centrifugal field

Nematic order in suspensions of colloidal rods has been induced by a centrifugal field. The research was published in Soft Matter by Deshpremy Mukhija and Michael J. Solomon from University of Michigan, Ann Arbor, USA. These results could have implications for optical materials that require assemblies with high quality ordering in a three dimensions.

Graphical abstract: Nematic order in suspensions of colloidal rods by application of a centrifugal field

The team from University of Michigan say that comparison to previous theory and simulation of the isotropic–nematic transition of rod particles indicates that the field strengths required to generate nematic order were larger than would have been predicted under the assumption of local equilibrium in the sediments.

Read the full article for free here: Deshpremy Mukhija and Michael J. Solomon, Soft Matter, 2011, DOI:10.1039/C0SM00493F

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Hot Article: Very small bubbles at surfaces—the nanobubble puzzle

Nanobubbles: what do we know and how can we understand their surprising stability and morphology?

Graphical abstract: Very small bubbles at surfaces—the nanobubble puzzleIn this Tutorial Review Vincent Craig discusses the nanobubble puzzle. Nanobubbles are thought to play a role in the rupture of thin films during froth flotation, hydrodynamic slip over surfaces, interaction forces between hydrophobic surfaces and influence the electroplating and electrolysis processes. Craig covers what is known of nanobubbles and discuss the challenges in understanding nanobubble morphology and stability.

Read the full the full article for free here: Vincent Stuart James Craig, Soft Matter, 2011, DOI:10.1039/C0SM00558D

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Hot Article: Interaction of double-stranded DNA with a nanosphere: a coarse-grained molecular dynamics simulation study

In the tightly packed molecular world of the cell DNA is protected and wrapped up into small packages called chromatins. The complex plays a crucial role in living organisms because its dynamic organization is a key factor for controlling the regulation of gene expression.

To investigate the unwrapping process Qianqian Cao and coworkers at Jilin University, China, used coarse-grained molecular dynamics simulations to study the unwinding of a DNA-nanosphere complex when a force exerted on the DNA chain.

 Graphical abstract: Interaction of double-stranded DNA with a nanosphere: a coarse-grained molecular dynamics simulation study

The team found that the wrapping degree and the folding state of DNA around the sphere is significantly dependent on the surface charge density and the salt concentration. When an external force is applied to two ends of DNA chain, different stages are observed in the stretching process as the complex is unwrapped. The team say that this behaviour also has been observed in experiments and other simulations on the stretching of chromatin.

Read Cao’s full article for free in Soft Matter here:  Qianqian Cao, Chuncheng Zuo, Yanhong Ma, Lujuan Li and Zhou Zhang, Soft Matter, 2011, DOI:10.1039/C0SM00512F

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Hot Article: Gibbs elasticity effect in foam shear flows: a non quasi-static 2D numerical simulation

Have you ever wondered what’s going on in a foam when it flows? In her latest Soft Matter paper, Isabelle Cantat at the Université Rennes, France, simulates the dissipation of bubbles in foam. Cantat used 2D numerical simulations involving 500 bubbles under simple shear, in a non-quasi static regime to study the dissipation of bubbles.

Graphical abstract: Gibbs elasticity effect in foam shear flows: a non quasi-static 2D numerical simulation

Cantat shows that small tension dynamical inhomogeneities induce foam structure modifications responsible for the largest part of the stress increase. The stress increase with increasing shear rate is mainly due to increasing bubble elongation that can be interpreted as an increase of the plastic threshold.

Interested to know more? Read Cantat’s Soft Matter paper here:

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Hot Article: Driving bioenergetic processes with electrodes

UK Scientists have created a hybrid system that uses non-biological energy to drive biological processes. Harnessing non-biological energy to power biological processes offers a convenient method to rapidly turn on and off biochemical reactions and the technology could be useful in many bioengineering applications.Graphical abstract: Driving bioenergetic processes with electrodes

Led by Lars Jeuken researchers at University of Leeds, UK, used a gold electrode to drive the removal of protons from lipid vesicles adsorbed onto the electrode’s surface. The system uses the electrode to reduce ubiquinone in the vesicles. Protons are then pumped across the lipid bilayer and out of the vesicle by an enzyme (ubiquinol oxidase) which re-oxidises the ubiquinone. Actively pumping protons out of the vesicle creates a proton gradient between the vesicle’s interior and the surroundings which the team detected using a fluorescent probe.

The team says that this technology could open a way to use the pH gradient to drive other reactions such as active transport of organic substrates across the membrane or ATP synthesis.

Read the full article for free here:

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Hot Article: Vacuum soft lithography to direct neuronal polarization

A simple method for simultaneously patterning different biomolecules on a surface can create complex patterns in a single step. These patterns can direct the adhesion, polarization, and guide neurites in neurons. The technique called vacuum soft lithography was developed by a team led by Sarah Heilshorn, University of California, Berkeley, USA, and could be used in to prepared surfaces for use in tissue engineering or translational medicine the team say.

Graphical abstract: Vacuum soft lithography to direct neuronal polarization

To create the complex patterns, biomolecules are physically adsorbed onto glass slides using a removable polydimethylsiloxane microfluidic template. The method uses the gas permeability of PDMS to fill circuitous and dead-end microfluidic channels. Upon removal from vacuum, degassed PDMS templates store a negative pressure relative to atmosphere which can be used to pull solutions through closed microfluidic channels. The technique is capable of preparing designs with better than 2 µm resolution.

Interested to know more? Read the full article here: J. Tanner Nevill, Alexander Mo, Branden J. Cord, Theo D. Palmer, Mu-ming Poo, Luke P. Lee and Sarah C. Heilshorn, Soft Matter, 2011, DOI:10.1039/C0SM00869A

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Hot Article: Grabbing water

Inspired by floating flowers, a passive pipetting mechanism allows for water to be grabbed with a flexible solid.

Graphical abstract: Grabbing waterThe technique was developed by a team led by Pedro Reis at Massachusetts Institute of Technology, USA, and co-workers in USA and France. The passive pipetting mechanism relies purely on the coupling of the elasticity of thin plates and the hydrodynamic forces at the liquid interface. By developing a theoretical model the team were able to design petal-shaped objects with maximum grabbing capacity.

Interested to know more? Read the full paper here: Pedro M. Reis, Jérémy Hure, Sungwan Jung, John W. M. Bush and Christophe Clanet, Soft Matter, 2010, DOI:10.1039/C0SM00895H

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