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Green Chemistry Issue 1, 2012 now online!

Issue 1 2012 of Green Chemistry is now online!

The front cover of the issue highlights work by Graham Hutchings and colleagues from Cardiff University, UK, who prepared several Au-Pd exchanged supported Cs-heteropolyacid catalysts and applied them to the direct synthesis of hydrogen peroxide from H2 and O2 in water under ambient conditions

The inside front cover features work by George Huber and co-workers from the University of Massachusetts-Amherst, USA and Southeast University, China, who report the catalytic fast pyrolysis of wood and alcohol mistures in a fluidized bed reactor.  By looking at the various reaction parameters, the authors demonstrate that catalytic fast pyrolysis can selectively produce a mixture of compounds and that the overall yield is a function of the hydrigen to carbon effective ratio. 

All articles in this issue are free to access.

Don’t forget to keep up-to-date with our latest hot articles and reviews!

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Top ten most accessed articles in November

This month sees the following articles in Green Chemistry that are in the top ten most accessed:-

Recent advances in ionic liquid catalysis
Qinghua Zhang, Shiguo Zhang and Youquan Deng
Green Chem., 2011, Advance Article, DOI: 10.1039/C1GC15334J

Continuous flow reactors: a perspective
Qinghua Zhang, Shiguo Zhang and Youquan Deng
Green Chem., 2011, 13, 2619-2637, DOI: 10.1039/C1GC15334J

Industrial biotechnology – the future of green chemistry?
Stefanie Wenda, Sabine Illner, Annett Mell and Udo Kragl
Green Chem., 2011, 13, 3007-3047, DOI: 10.1039/C1GC15579B

l-Proline catalysed multicomponent synthesis of 3-amino alkylated indoles via a Mannich-type reaction under solvent-free conditions
Atul Kumar, Maneesh Kumar Gupta and Mukesh Kumar
Green Chem., 2012, Advance Article, DOI: 10.1039/C1GC16297G

Environmentally benign synthesis of heterocyclic compounds by combined microwave-assisted heterogeneous catalytic approaches?
Arif Daştan, Aditya Kulkarni and Béla Török
Green Chem., 2012, Advance Article, DOI: 10.1039/C1GC15837F

A critical review on recent methods used for economically viable and eco-friendly development of microalgae as a potential feedstock for synthesis of biodiesel
Yogesh C. Sharma, Bhaskar Singh and John Korstad
Green Chem., 2011, 13, 2993-3006, DOI: 10.1039/C1GC15535K

Synthesis and properties of trialkyl(2,3-dihydroxypropyl)phosphonium salts, a new class of hydrophilic and hydrophobic glyceryl-functionalized ILs
Fabio Bellina, Cinzia Chiappe and Marco Lessi
Green Chem., 2012, Advance Article, DOI: 10.1039/C1GC16035D

A magnetic nanoparticle supported dual acidic ionic liquid: a ‘quasi-homogeneous’ catalyst for the one-pot synthesis of benzoxanthenes
Qiang Zhang, Hong Su, Jun Luo and Yunyang Wei
Green Chem., 2012, Advance Article, DOI: 10.1039/C1GC16031A

Aqueous and biphasic nitrile hydration catalyzed by a recyclable Ru(ii) complex under atmospheric conditions
Wei-Chih Lee and Brian J. Frost
Green Chem., 2012, Advance Article, DOI: 10.1039/C1GC15950J

Syntheses of cyclic carbonates with amidinium halide catalysts in reusable, reversible, room-temperature ionic liquids or acetonitrile
Tao Yu and Richard G. Weiss
Green Chem., 2012, Advance Article, DOI: 10.1039/C1GC16027C

Why not take a look at the articles today and blog your thoughts and comments below.

Fancy submitting an article to Green Chemistry? Then why not submit to us today or alternatively email us your suggestions.

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Top cited Green Chemistry articles from 2011

As we near the end of 2011, here are some of the top cited Green Chemistry articles published this year.  These articles are all free to access until the 27th January 2012!

Converting carbohydrates to bulk chemicals and fine chemicals over heterogeneous catalysts, Maria J. Climent, Avelino Corma and Sara Iborra, Green Chem., 2011, 13, 520-540

Enzyme-mediated oxidations for the chemist, Frank Hollmann, Isabel W. C. E. Arends, Katja Buehler, Anett Schallmey and Bruno Bühler, Green Chem., 2011, 13, 226-265

Searching for green solvents, Philip G. Jessop, Green Chem., 2011, 13, 1391-1398

A critical assessment of the greenness and energy efficiency of microwave-assisted organic synthesis, Jonathan D. Moseley and C. Oliver Kappe, Green Chem., 2011, 13, 794-806

5-Hydroxymethylfurfural (HMF) as a building block platform: Biological properties, synthesis and synthetic applications, Andreia A. Rosatella, Svilen P. Simeonov, Raquel F. M. Frade and Carlos A. M. Afonso, Green Chem., 2011, 13, 754-793

Glycerol eutectics as sustainable solvent systems, Andrew P. Abbott, Robert C. Harris, Karl S. Ryder, Carmine D’Agostino, Lynn F. Gladden and Mick D. Mantle, Green Chem., 2011, 13, 82-90

Use of carbon dioxide in chemical syntheses via a lactone intermediate, A. Behr and G. Henze, Green Chem., 2011, 13, 25-39

Greener solvents for ruthenium and palladium-catalysed aromatic C–H bond functionalisation, Cedric Fischmeister and Henri Doucet, Green Chem., 2011, 13, 741-753

The irruption of polymers from renewable resources on the scene of macromolecular science and technology, Alessandro Gandini, Green Chem., 2011, 13, 1061-1083

Synthesis of sugar alcohols by hydrolytic hydrogenation of cellulose over supported metal catalysts, Hirokazu Kobayashi, Yukiko Ito, Tasuku Komanoya, Yuto Hosaka, Paresh L. Dhepe, Koji Kasai, Kenji Hara and Atsushi Fukuoka, Green Chem., 2011, 13, 326-333

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Green Chemistry issue 12 now online

Green Chemistry issue 12 is now online! 

The front cover of this issue features work by Sibudjing Kawi and W. Thitsartarn from the National University of Singapore.  They report a stable and active CaO-CeO2 catalyst, prepared by simple gel formation viaa co-precipitation method, which was applied to the transesterification of oil to biodiesel.  The catalyst could be reused up to 18 times without significant loss of activity and showed only low amounts of leaching.  Find out more by reading the full article ‘An active and stable CaO–CeO2catalyst for transesterification of oil to biodiesel.’

The inside front cover highlights work from Jérôme Husson and co-workers from the Université de Franche-Comté.  They report a new synthesis route to 4,4′,4′′-tricarboxy-2,2′:6′,2′′-terpyridine, a ligand that is a component of the “Black-dye” sensitizer for dye-sensitized solar cells.  The route developed by Husson has a lower ecological impact with respect to atom economy, yield, solvent and chemicals used and wastes generated, compared to the previously reported method.  Find out more by reading the full article ‘A more efficient synthesis of 4,4′,4′′-tricarboxy-2,2′:6′,2′′-terpyridine.’

These articles are free to access until 16th January 2012!

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Top ten most accessed articles in October

This month sees the following articles in Green Chemistry that are in the top ten most accessed:-

Industrial biotechnology-the future of green chemistry?
Stefanie Wenda, Sabine Illner, Annett Mell and Udo Kragl
Green Chem., 2011, 13, 3007-3047, DOI: 10.1039/C1GC15579B

Recent advances in ionic liquid catalysis
Qinghua Zhang, Shiguo Zhang and Youquan Deng
Green Chem., 2011, Advance Article, DOI: 10.1039/C1GC15334J

Extracting wood lignin without dissolving or degrading cellulose: investigations on the use of food additive-derived ionic liquids
André Pinkert, Dagmar F. Goeke, Kenneth N. Marsh and Shusheng Pang
Green Chem., 2011, 13, 3124-3136, DOI: 10.1039/C1GC15671C

Green synthesis of metal nanoparticles using plants
Siavash Iravani
Green Chem., 2011, Advance Article, DOI: 10.1039/C1GC15386B

A facile method for the recovery of ionic liquid and lignin from biomass pretreatment
Dean C. Dibble, Chenlin Li, Lan Sun, Anthe George, Aurelia Cheng, Özgül Persil Çetinkol, Peter Benke, Bradley M. Holmes, Seema Singh and Blake A. Simmons
Green Chem., 2011, 13, 3255-3264, DOI: 10.1039/C1GC15111H

Efficient catalytic conversion of fructose into hydroxymethylfurfural by a novel carbon-based solid acid
Jianjian Wang, Wenjie Xu, Jiawen Ren, Xiaohui Liu, Guanzhong Lu and Yanqin Wang
Green Chem., 2011, 13, 2678-2681, DOI: 10.1039/C1GC15306D

Ethyl lactate as a solvent: Properties, applications and production processes – a review
Carla S. M. Pereira, Viviana M. T. M. Silva and Alírio E. Rodrigues
Green Chem., 2011, 13, 2658-2671, DOI: 10.1039/C1GC15523G

Stabilization of Cu(0)-nanoparticles into the nanopores of modified montmorillonite: An implication on the catalytic approach for ‘Click’ reaction between azides and terminal alkynes
Bibek Jyoti Borah, Dipanka Dutta, Partha Pratim Saikia, Nabin Chandra Barua and Dipak Kumar Dutta
Green Chem., 2011, Advance Article, DOI: 10.1039/C1GC16021D

An active and stable CaO-CeO2 catalyst for transesterification of oil to biodiesel
W. Thitsartarn and S. Kawi
Green Chem., 2011, Advance Article, DOI: 10.1039/C1GC15596B

Reusable ammonium salt-tagged NHC-Cu(i) complexes: preparation and catalytic application in the three component click reaction
Wenlong Wang, Junliang Wu, Chungu Xia and Fuwei Li
Green Chem., 2011, Advance Article, DOI: 10.1039/C1GC15871F

Why not take a look at the articles today and blog your thoughts and comments below.

Fancy submitting an article to Green Chemistry? Then why not submit to us today or alternatively email us your suggestions.

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Green Chemistry Issue 11 Now Online

Issue 11 ofcGreen Chemistry Issue 11 is now online. The cover features work from Jairton Dupont and co-workers from the Universidade Federal do Rio Grande do Sul in Brazil. They show that a dicyclohexylguanidine group covalently attached on silica gel is an efficient basic heterogeneous catalyst for the production of biodiesel in a continuous flow reactor. Find out more by reading the full article ‘Silica-supported guanidine catalyst for continuous flow biodiesel production’. Issue 11 ifc

The inside front cover highlights a paper from Alexander Bismark and colleagues at Imperial College London in which frothing of acrylated epoxidised soybean oil (AESO) followed by microwave initiated polymerisation is used to make bacterial cellulose reinforced polyAESO nanocomposite foams. The introduction of Bacterial Cellulose significantly enhanced the stability of the gas-soybean oil foam templates and enhanced the mechanical properties of the polymer nanocomposite foams. Find out more by reading the full article ‘Bio-based macroporous polymer nanocomposites made by mechanical frothing of acrylated epoxidised soybean oil’.

These cover articles are free for all to access until December 15th.

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Top ten most accessed articles in September

This month sees the following articles in Green Chemistry that are in the top ten most accessed:-

Recent advances in ionic liquid catalysis
Qinghua Zhang, Shiguo Zhang and Youquan Deng
Green Chem., 2011, Advance Article, DOI: 10.1039/C1GC15334J

Green synthesis of metal nanoparticles using plants
Siavash Iravani
Green Chem., 2011, Advance Article, DOI: 10.1039/C1GC15386B

Functional ionic liquid mediated synthesis (FILMS) of dihydrothiophenes and tacrine derivatives
Atul Kumar, Garima Gupta and Suman Srivastava
Green Chem., 2011, 13, 2459-2463, DOI: 10.1039/C1GC15410A

Enzymatic reductions for the chemist
Frank Hollmann, Isabel W. C. E. Arends and Dirk Holtmann
Green Chem., 2011, 13, 2285-2314, DOI: 10.1039/C1GC15424A

Sustainable hydrogen production by the application of ambient temperature photocatalysis
Michael Bowker
Green Chem., 2011, 13, 2235-2246, DOI: 10.1039/C1GC00022E

Could the energy cost of using supercritical fluids be mitigated by using CO2 from carbon capture and storage (CCS)?
James G. Stevens, Pilar Gómez, Richard A. Bourne, Trevor C. Drage, Michael W. George and Martyn Poliakoff
Green Chem., 2011, 13, 2727-2733, DOI: 10.1039/C1GC15503B

One step catalytic conversion of cellulose to sustainable chemicals utilizing cooperative ionic liquid pairs
Jinxing Long, Bin Guo, Xuehui Li, Yanbin Jiang, Furong Wang, Shik Chi Tsang, Lefu Wang and Kai Man K. Yu
Green Chem., 2011, 13, 2334-2338, DOI: 10.1039/C1GC15597K

Ionic liquid pretreatment of lignocellulosic biomass with ionic liquid–water mixtures
Agnieszka Brandt, Michael J. Ray, Trang Q. To, David J. Leak, Richard J. Murphy and Tom Welton
Green Chem., 2011, 13, 2489-2499, DOI: 10.1039/C1GC15374A

The solvent-free and catalyst-free conversion of an aziridine to an oxazolidinone using only carbon dioxide
Chau Phung, Rani M. Ulrich, Mostafa Ibrahim, Nathaniel T. G. Tighe, Deborah L. Lieberman and Allan R. Pinhas
Green Chem., 2011, Advance Article, DOI: 10.1039/C1GC15850C

Microwave assisted conversion of carbohydrates and biopolymers to 5-hydroxymethylfurfural with aluminium chloride catalyst in water
Sudipta De, Saikat Dutta and Basudeb Saha
Green Chem., 2011, 13, 2859-2868, DOI: 10.1039/C1GC15550D

Why not take a look at the articles today and blog your thoughts and comments below.

Fancy submitting an article to Green Chemistry? Then why not submit to us today or alternatively email us your suggestions.

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Green Chemistry Volume 13 Issue 10 online now!

Green Chemistry issue 10 is now online and features some exciting contributions to the field.  The outside front cover highlights the recent article form Martyn Poliakoff and co-workers on using carbon dioxide from carbon capture and storage as a solvent, and asks whether this could help mitigate the cost of using supercritical fluids.  This article was also featured in Chemistry World – click here to read more!

The inside front cover highlights work by George Kraus and co-workers and illustrates the synthesis of aromatic compounds from pyrones via Diels-Alder chemistry.  The main pyrone employed in the work is derived from the natural product malic acid, and the reaction provides para-substituted adducts in good yields.  Read the full article here.

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Top ten most accessed articles in August

This month sees the following articles in Green Chemistry that are in the top ten most accessed:-

Recent advances in ionic liquid catalysis

Qinghua Zhang, Shiguo Zhang and Youquan Deng
Green Chem., 2011, Advance Article, DOI: 10.1039/C1GC15334J

Examples of heterogeneous catalytic processes for fine chemistry
Carlo Lucarelli and Angelo Vaccari
Green Chem., 2011, 13, 1941-1949, DOI: 10.1039/C0GC00760A

Efficient catalytic conversion of fructose into hydroxymethylfurfural by a novel carbon-based solid acid
Jianjian Wang, Wenjie Xu, Jiawen Ren, Xiaohui Liu, Guanzhong Lu and Yanqin Wang
Green Chem., 2011, Advance Article, DOI: 10.1039/C1GC15306D

Ionic liquid pretreatment of lignocellulosic biomass with ionic liquid–water mixtures
Agnieszka Brandt, Michael J. Ray, Trang Q. To, David J. Leak, Richard J. Murphy and Tom Welton
Green Chem., 2011, 13, 2489-2499, DOI: 10.1039/C1GC15374A

Selective catalytic oxidation of glycerol: perspectives for high value chemicals
Benjamin Katryniok, Hiroshi Kimura, Elżbieta Skrzyńska, Jean-Sébastien Girardon, Pascal Fongarland, Mickaël Capron, Rémy Ducoulombier, Naoki Mimura, Sébastien Paul and Franck Dumeignil
Green Chem., 2011, 13, 1960-1979, DOI: 10.1039/C1GC15320J, Critical Review

Impact of ionic liquid pretreated plant biomass on Saccharomyces cerevisiae growth and biofuel production
Mario Ouellet, Supratim Datta, Dean C. Dibble, Pramila R. Tamrakar, Peter I. Benke, Chenlin Li, Seema Singh, Kenneth L. Sale, Paul D. Adams, Jay D. Keasling, Blake A. Simmons, Bradley M. Holmes and Aindrila Mukhopadhyay
Green Chem., 2011, Advance Article, DOI: 10.1039/C1GC15327G

Green synthesis of metal nanoparticles using plants
Siavash Iravani
Green Chem., 2011, Advance Article, DOI: 10.1039/C1GC15386B

Ionic liquids and fragrances – direct isolation of orange essential oil
Katharina Bica, Peter Gaertner and Robin D. Rogers
Green Chem., 2011, 13, 1997-1999, DOI: 10.1039/C1GC15237H

Towards rational molecular design: derivation of property guidelines for reduced acute aquatic toxicity
Adelina M. Voutchkova, Jakub Kostal, Justin B. Steinfeld, John W. Emerson, Bryan W. Brooks, Paul Anastas and Julie B. Zimmerman
Green Chem., 2011, 13, 2373-2379, DOI: 10.1039/C1GC15651A

Sulfonic acid supported on hydroxyapatite-encapsulated-γ-Fe2O3 nanocrystallites as a magnetically separable catalyst for one-pot reductive amination of carbonyl compounds
Jia Deng, Li-Ping Mo, Fei-Yang Zhao, Lan-Lan Hou, Li Yang and Zhan-Hui Zhang
Green Chem., 2011, 13, 2576-2584, DOI: 10.1039/C1GC15470B

Why not take a look at the articles today and blog your thoughts and comments below.

Fancy submitting an article to Green Chemistry? Then why not submit to us today or alternatively email us your suggestions.

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Top ten most accessed articles in July

This month sees the following articles in Green Chemistry that are in the top ten most accessed:-

Selective oxidation of 5-hydroxymethyl-2-furfural using supported gold–copper nanoparticles
Thomas Pasini, Marco Piccinini, Magda Blosi, Rosa Bonelli, Stefania Albonetti, Nikolaos Dimitratos, Jose A. Lopez-Sanchez, Meenakshisundaram Sankar, Qian He, Christopher J. Kiely, Graham J. Hutchings and Fabrizio Cavani
Green Chem., 2011, 13, 2091-2099, DOI: 10.1039/C1GC15355B

Copper-catalyzed oxidative alkyne homocoupling without palladium, ligands and bases

Xueshun Jia, Kun Yin, Chunju Li, Jian Li and Haishan Bian
Green Chem., 2011, 13, 2175-2178, DOI: 10.1039/C1GC15318H

Ionic liquids and fragrances – direct isolation of orange essential oil
Katharina Bica, Peter Gaertner and Robin D. Rogers
Green Chem., 2011, 13, 1997-1999, DOI: 10.1039/C1GC15237H

Selective catalytic oxidation of glycerol: perspectives for high value chemicals
Benjamin Katryniok, Hiroshi Kimura, Elżbieta Skrzyńska, Jean-Sébastien Girardon, Pascal Fongarland, Mickaël Capron, Rémy Ducoulombier, Naoki Mimura, Sébastien Paul and Franck Dumeignil
Green Chem., 2011, 13, 1960-1979, DOI: 10.1039/C1GC15320J, Critical Review

Algae as a source of renewable chemicals: opportunities and challenges
Patrick M. Foley, Evan S. Beach and Julie B. Zimmerman
Green Chem., 2011, Advance Article, DOI: 10.1039/C1GC00015B

Production of liquid hydrocarbon fuels by catalytic conversion of biomass-derived levulinic acid
Drew J. Braden, Carlos A. Henao, Jacob Heltzel, Christos C. Maravelias and James A. Dumesic
Green Chem., 2011, 13, 1755-1765, DOI: 10.1039/C1GC15047B

A green approach to chemical building blocks. The case of 3-hydroxypropanoic acid
Cristina Della Pina, Ermelinda Falletta and Michele Rossi
Green Chem., 2011, 13, 1624-1632, DOI: 10.1039/C1GC15052A

Searching for green solvents
Philip G. Jessop
Green Chem., 2011, Advance Article, DOI: 10.1039/C0GC00797H, Perspective

Enzymatic reductions for the chemist
Frank Hollmann, Isabel W. C. E. Arends and Dirk Holtmann
Green Chem., 2011, 13, 2285-2314, DOI: 10.1039/C1GC15424A

Use of zeolites for greener and more para-selective electrophilic aromatic substitution reactions
Keith Smith and Gamal A. El-Hiti
Green Chem., 2011, 13, 1579-1608, DOI: 10.1039/C0GC00689K

Why not take a look at the articles today and blog your thoughts and comments below.

Fancy submitting an article to Green Chemistry? Then why not submit to us today or alternatively email us your suggestions.

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