NJC Themed Issue 10 online – in honor of Prof. Didier Astruc

We invite you to read the October issue of NJC.

NJC is delighted to introduce this issue in honor of Didier Astruc, on the occasion of his 65th birthday. The outside front cover highlights molecules from 5 of the articles in this issue, placed on a background of grape leaves and vineyards (in honor of Didier’s Bordeaux location).

We’ve invited his colleagues, Jean-René Hamon, Jean-Yves Saillard and Jaime Ruiz, to introduce this special issue and highlight Didier’s many outstanding scientific achievements in a wide range of research areas, including organometallic chemistry, catalysis, molecular chemistry, dendrimers and nanostructures.

Introduction to the themed issue in honour of Prof. Didier Astruc. A success story from electron reservoir complexes to dendritic molecular nanostructures, New J. Chem., 2011, 35, 1931-1932; DOI: 10.1039/C1NJ90032C

The articles presented in this themed issue of NJC address recent developments in material science, cancer research, organometallic complexes, metallodendrimers and preparation of nanostructures, amongst other themes. New ideas are presented, some long-held views are strengthened and others are questioned.

In all, there are 56 articles including 2 Focuses, 4 Perspectives, 6 Letters and 44 Full papers. The high quality of research presented exemplifies what scientists are able to achieve, and Didier Astruc certainly occupies a leading position among them.

Some of the articles in this themed issue:

A new series of ferrocifen derivatives, bearing two aminoalkyl chains, with strong antiproliferative effects on breast cancer cells; Pascal Pigeon, Siden Top, Anne Vessières, Michel Huché, Meral Görmen, Mehdi El Arbi, Marie-Aude Plamont, Michael J. McGlinchey and Gérard Jaouen; New J. Chem., 2011, 35, 2212-2218; DOI: 10.1039/C1NJ20192A

Synthesis of spin crossover nano-objects with different morphologies and properties; Alexey Tokarev, Lionel Salmon, Yannick Guari, Gábor Molnár and Azzedine Bousseksou; New J. Chem., 2011, 35, 2081-2088 DOI:10.1039/C1NJ20218A

A meta-xylenediamide macrocycle containing rotaxane anion host system constructed by a new synthetic clipping methodology; Nicholas H. Evans, Christopher J. Serpell and Paul D. Beer; New J. Chem., 2011, 35, 2047-2053; DOI: 10.1039/C1NJ20109C

The inside front cover by Hiroshi Nishihara and co-workers (University of Tokyo) represents their work on 3-ferrocenylazobenzene (3-FcAB) containing polymer particles, envisioning their potential application to act as nano-sized photo-memories or switches.

Synthesis of photo-switchable 3-FcAB-modified polymer particles by Kosuke Namiki, Masaki Murata, Shoko Kume and Hiroshi Nishihara; New J. Chem., 2011, 35, 2146-2152; DOI: 10.1039/C1NJ20189A

A symposium in honor of Didier Astruc will be held in Bordeaux (December 1–2, 2011) at which Yves Chauvin (2005 Nobel Laureate) will present this themed issue to Didier. The two-day symposium program will include plenary lectures by Henri Kagan and Jean-Pierre Sauvage, 25 other lectures, as well as a Grand Public discussion with Yves Chauvin.

Don’t miss the October themed Issue 10, available online!

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Rapid synthetic access to ferrocenyl benzodiazepines, novel antimalarial drug candidates.

Malaria, caused by single cell protozoon parasites of the Plasmodium species, is a tropical disease causing almost three million deaths every year. The alarming spread of drug resistance and limited number of effective drugs now available underline how important it is to discover new antiplasmodial compounds.

Combining both organometallic and bioorganic characters of molecules into one bio-structure is currently an attractive approach to cancer and malarial therapeutics.

The idea of Pelinsky et al. (University of Lille, France) of “metallo”-derivatising benzodiazepines in a search for new antiplasmodial drugs have led to development of the original synthetic method to prepare new ferrocenyl derivatives of benzodiazepines.

This one-pot procedure using microwave-assisted irradiation allowed preparation of novel ferrocenyl 1,4-benzodiazepin-2-ones in significantly short reaction time and in higher yields compared to the conventional synthetic methods. In collaboration with other French researchers, their antiplasmodial and antiproliferative activities were also investigated.

One-pot microwave-assisted synthesis and antimalarial activity of ferrocenyl benzodiazepines; Gabin Mwande-Maguene, Jouda Jakhlal, Jean-Bernard Lekana-Douki, Elisabeth Mouray, Till Bousquet, Sylvain Pellegrini, Philippe Grellier, Fousseyni Samba Toure Ndouo, Jacques Lebibi and Lydie Pelinski; New J. Chem., 2011, Advance Article; DOI: 10.1039/C1NJ20551J, Letter

Interested to know more? Why not read by accessing the full article now!  This “Hot article” will be FREE to access for a period of 4 weeks.

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NJC article on HCLPs selected as Noteworthy Chemistry

NJC article reporting the synthesis of new hyper-cross-linked polymers highlighted in ACS’s Noteworthy Chemistry

Once again, an article from the New Journal of Chemistry has been selected by the American Chemical Society as Noteworthy Chemistry (September 26, 2011). The groups of Thierry Muller and Stefan Bräse (Karlsruhe Institute of Technology, Germany) and of Piero Sozzani (University of Milan-Bicocca, Italy) developed new hyper-cross-linked polymers (HCLPs) using click chemistry via an unconventional route.

The adamantane-based compound shows remarkable efficiency for CO2 capture under the mild conditions of low pressure or at room temperature.

“Click chemistry produces hyper-cross-linked polymers with tetrahedral cores” by O. Plietzsch, C. I. Schilling, T. Grab, S. L. Grage, A. S. Ulrich, A. Comotti, P. Sozzani, T. Muller and S. Bräse in New J. Chem., 2011, 35, 1577–1581. If you are a subscriber, you can read the original article here:  DOI: 10.1039/C1NJ20370C.

To read more high quality chemistry, check out our other articles!

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Top ten most accessed articles in August

This month sees the following articles in New Journal of Chemistry that are in the top ten most accessed:-

Click chemistry produces hyper-cross-linked polymers with tetrahedral cores 
Oliver Plietzsch, Christine I. Schilling, Tobias Grab, Stephan L. Grage, Anne S. Ulrich, Angiolina Comotti, Piero Sozzani, Thierry Muller and Stefan Bräse 
New J. Chem., 2011, 35, 1577-1581 DOI: 10.1039/C1NJ20370C  

Preparation of graphene–TiO2 composites with enhanced photocatalytic activity 
Kangfu Zhou, Yihua Zhu, Xiaoling Yang, Xin Jiang and Chunzhong Li 
New J. Chem., 2011, 35, 353-359 DOI: 10.1039/C0NJ00623H

Dialkoxy functionalized quaternary ammonium ionic liquids as potential electrolytes and cellulose solvents 
Zhengjian Chen, Shimin Liu, Zuopeng Li, Qinghua Zhang and Youquan Deng 
New J. Chem., 2011, 35, 1596-1606 DOI: 10.1039/C1NJ20062C 

MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs) 
Christoph Janiak and Jana K. Vieth 
New J. Chem., 2010, 34, 2366-2388 DOI: 10.1039/C0NJ00275E 
 
A low band gap donor–acceptor copolymer containing fluorene and benzothiadiazole units: synthesis and photovoltaic properties 
Jianing Pei, Shanpeng Wen, Yinhua Zhou, Qingfeng Dong, Zhaoyang Liu, Jibo Zhang and Wenjing Tian 
New J. Chem., 2011, 35, 385-393 DOI: 10.1039/C0NJ00378F  

A noncovalently assembled porphyrinic catenane consisting of two interlocking [43]-membered rings 
Maryline Beyler, Valérie Heitz and Jean-Pierre Sauvage 
New J. Chem., 2011, 35, 1751-1757 DOI: 10.1039/C1NJ20294D 

Application of ferrocene and its derivatives in cancer research 
Cátia Ornelas 
New J. Chem., 2011, Advance Article DOI: 10.1039/C1NJ20172G  

Hydrogen bond descriptors and other properties of ion pairs 
Michael H. Abraham and William E. Acree 
New J. Chem., 2011, 35, 1740-1750 DOI: 10.1039/C1NJ20324J  

Rare earths: jewels for functional materials of the future 
Svetlana V. Eliseeva and Jean-Claude G. Bünzli 
New J. Chem., 2011, 35, 1165-1176 DOI: 10.1039/C0NJ00969E  

Synthesis and spectroscopic properties of meso-substituted quinoxalinoporphyrins 
Satyasheel Sharma and Mahendra Nath 
New J. Chem., 2011, 35, 1630-1639 DOI: 10.1039/C1NJ20248K  

Why not take a look at the articles today and blog your thoughts and comments below.

Fancy submitting an article to New Journal of Chemistry? Then why not submit to us today  or alternatively email us  your suggestions.

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Towards an artificial chlorosome

The approaches developed previously to mimic chlorosomal assembly and function (with potential applications that include, for instance, the creation of photosynthesis-inspired solar cells) rely on (i) modification of naturally occurring tetrapyrrole macrocycles and (ii) synthesis and derivatization of porphyrins. In this NJC paper, researchers from Raleigh (North Carolina State University), St. Louis (Washington University), and Riverside (University of California) propose a third approach with the design and preparation of hydroporphyrins. Altogether, 30 new macrocycles were successfully synthesized, characterized and studied. The authors claim that this de novo strategy allows a fine tuning of the steric and electronic characteristics of the synthetic bacteriochlorophyll mimics.


“De novo synthesis and properties of analogues of the self-assembling chlorosomal bacteriochlorophylls” Olga Mass, Dinesh R. Pandithavidana, Marcin Ptaszek, Koraliz Santiago, Joseph W. Springer, Jieying Jiao, Qun Tang, Christine Kirmaier, David F. Bocian, Dewey Holten and Jonathan S. Lindsey New J. Chem., 2011, Advance Article. DOI: 10.1039/C1NJ20611G

Interested to know more? Why not download and read the article today! It’s recently been published in NJC and will be FREE to access for a period of 4 weeks.

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Meet Our Authors, September 2011

We are pleased to present a selection of our authors of the September issue of NJC. We thank each of them for accepting our invitation and having kindly taken some of their time to answer a few questions for us.

Our first author is Frank Marken who is Professor at the University of Bath (UK). His current research interests are mainly focused on electrochemical processes and their applications. Frank and co-workers are interested in complex interfaces and they were looking for ways of bringing gases into close contact to electrode surfaces. In 2010, they started investigating salt-electrode contacts and based on the initial progress, they decided to explore different types of electrode processes including catalytic processes under these “salt conditions” which is the topic of their NJC paper. Frank declares to be lucky to have a very talented visitor, Fengjie Xia from Wuhan University of Technology, working on this topic and producing these results.

The fact that the work is fundamental and exploratory in character, that it could benefit from recognition by a wider community of chemist and that NJC provides a very good platform and ensures high levels of citations was Frank’s motivation behind his submission to the journal.

Outside of the lab, Frank enjoys swimming. If he could not be a scientific researcher, he would be an engineer.

Electrode processes at gas|salt|Pd nanoparticle|glassy carbon electrode contacts: salt effects on the oxidation of formic acid vapor and the oxidation of hydrogen by Fengjie Xia, Sara E. C. Dale, Richard A. Webster, Mu Pan, Shichun Mu, Shik Chi Tsang, John M. Mitchels and Frank Marken New J. Chem., 2011, 35, 1855-1860, DOI: 10.1039/C1NJ20421A.

Our next author is Lee Chia-Hung , Assistant Professor of Life Science at the National Dong Hwa University (Taiwan). He’s research interests focus on the biocatalytic reactions in the confined nanospaces of mesoporous silica materials and mesoporous silica nanoparticles for biomedical applications.

In this issue of NJC, he has authored the article Site-specific immobilization of cytochrome c on mesoporous silica through metal affinity adsorption to enhance activity and stability by Shih-Hsun Cheng, Kun-Che Kao, Wei-Neng Liao, Li-Ming Chen, Chung-Yuan Mou and Chia-Hung Lee New J. Chem., 2011, 35, 1809-1816, DOI: 10.1039/C1NJ20255C. “A rapid and highly efficient approach to immobilize a cysteine-containing enzyme through metal affinity interactions, which can both protect the protein folding and control the orientation to optimize the stability and catalytic activity. The immobilization of cyt c through this approach can provide a correct orientation of the catalytic center, where the active site can easily approach the substrate molecules”, explains Chia-Hung who chooses NJC for the publication of this article due to the journal’s high quality.

In his free time, Chia-Hung loves spending time traveling to visit new places because he can find many new things and try many new foods. In addition, his wife and he like to stroll in the department store or local bookstore with their child on weekends.

Chia-Hung usually cook chemical reactions in his lab. If he could not be a scientist, maybe he became a chief to create many delicious Chinese foods for foreigners.

Closing this month’s authors selection, David Farrusseng is Researcher at IRCELYON, University of Lyon (France).

His current research interests are focused on the design of materials for original catalytic & separation processes and on the development of high throughput approaches. More recently, he has explored the application of Metal-Organic Frameworks in catalysis.

In this NJC issue paper, David and co-workers report the synthesis of a multi-dimensional combinatorial library of functionalized MOFs. The impact of the grafting rate between the porous volumes of 1D and 3D channeled structures is also compared. “Metal-Organic Frameworks are fascinating crystalline porous Materials. The development of functionalization methods for decorating their pore will lead to breakthroughs in Applied Chemistry” says David.

Combinatorial synthesis of metal–organic frameworks libraries by click-chemistry by Marie Savonnet, Emanuel Kockrick, Aurélie Camarata, Delphine Bazer-Bachi, Nicolas Bats, Vincent Lecocq, Catherine Pinel and David Farrusseng, New J. Chem., 2011, 35, 1892-1897, DOI: 10.1039/C1NJ20350A.

NJC publishes original multi-disciplinary articles on a fair basis and very rapidly. What can I ask for more?”

Out of the lab, David like to “escape” by bike in the hilly Beaujolais area and then to make some stops in beautiful wineries to enjoy the local production.

When asked if he could not be a scientist but could be anything else what he would be? David answers that being a young boy, at the time of the first computers; he did recreate the first video games, such as Tetris and Pacman. He was coding nights and days. Later at the university, he was told that there was nothing good to expect for a carrier in informatics. It was 2 years before the Internet first steps…

Thanks to all of you, and see you next month for more!

Fancy submitting an article to NJC? Then why not submit to us today.

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Hot article: A supramolecular complex with temperature-dependent antioxidative capacity.

Scientists in China have designed and synthesized copolymer as the host and adamantyl fullerene as the guest to construct a host-guest supramolecular complex

Their work shows that the morphology of assemblies formed by the supramolecular complex can alter reversibly from vesicles to nano-spheres by the change of temperature in aqueous solution.

Due to the C60 moiety, the supramolecular complex shows excellent ability to scavenge hydroxyl radicals of biological system.

Thus, the combination of these two effects leads to the possibility of modulating the antioxidative properties of the supramolecular complex via the temperature.

Interested in reading further? Why not download the full article now, FREE to access for a period of 4 weeks!

Self-assembled nanostructures from C60-containing supramolecular complex: its stimuli-responsive reversible transition and biological antioxidative capacity

Haoyu Wang, Liang Wang, Xiaoguang Wang, Jiayun Xu, Quan Luo and Junqiu Liu New J. Chem., 2011, Advance Article DOI: 10.1039/C1NJ20568D, Paper

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Top ten most accessed articles in July

This month sees the following articles in NJC that are in the top ten most accessed:-

Facile synthesis of monodispersed silver nanoparticles on graphene oxide sheets with enhanced antibacterial activity 
Lei Liu, Jincheng Liu, Yinjie Wang, Xiaoli Yan and Darren Delai Sun 
New J. Chem., 2011, 35, 1418-1423 DOI: 10.1039/C1NJ20076C  

Combinatorial synthesis of metal–organic frameworks libraries by click-chemistry 
Marie Savonnet, Emanuel Kockrick, Aurélie Camarata, Delphine Bazer-Bachi, Nicolas Bats, Vincent Lecocq, Catherine Pinel and David Farrusseng 
New J. Chem., 2011, 35, 1892-1897 DOI: 10.1039/C1NJ20350A   

Synthesis of nearly monodispersed metal oxide nanoparticles in water 
Sandip Kumar Pahari, Narottom Sutradhar, Apurba Sinhamahapatra, Provas Pal and Asit Baran Panda 
New J. Chem., 2011, 35, 1460-1465 DOI: 10.1039/C1NJ20221A  

A new ortho-phenylenediamine-based cleft for selective sensing of H2PO4 – and ATP 
Kumaresh Ghosh and Indrajit Saha 
New J. Chem., 2011, 35, 1397-1402 DOI: 10.1039/C1NJ20116F    

Rare earths: jewels for functional materials of the future 
Svetlana V. Eliseeva and Jean-Claude G. Bünzli 
New J. Chem., 2011, 35, 1165-1176 DOI: 10.1039/C0NJ00969E    

Preparation of graphene–TiO2 composites with enhanced photocatalytic activity 
Kangfu Zhou, Yihua Zhu, Xiaoling Yang, Xin Jiang and Chunzhong Li 
New J. Chem., 2011, 35, 353-359 DOI: 10.1039/C0NJ00623H  

An efficient naphthalimide based fluorescent dyad (ANPI) for F- and Hg2+ mimicking OR, XNOR and INHIBIT logic functions 
Mohammad Shahid, Priyanka Srivastava and Arvind Misra 
New J. Chem., 2011, 35, 1690-1700 DOI: 10.1039/C1NJ20058E    

Structure-property relationships in conjugated donor–acceptor systems functionalized with tetrathiafulvalene 
Chunyang Jia, Jiaqiang Zhang, Ligong Zhang and Xiaojun Yao 
New J. Chem., 2011, 35, 1876-1882 DOI: 10.1039/C1NJ20384C    

Microfluidic devices as tools for mimicking the in vivo environment 
Karina Ziółkowska, Radosław Kwapiszewski and Zbigniew Brzózka 
New J. Chem., 2011, 35, 979-990 DOI: 10.1039/C0NJ00709A 
  
Click chemistry produces hyper-cross-linked polymers with tetrahedral cores 
Oliver Plietzsch, Christine I. Schilling, Tobias Grab, Stephan L. Grage, Anne S. Ulrich, Angiolina Comotti, Piero Sozzani, Thierry Muller and Stefan Bräse 
New J. Chem., 2011, 35, 1577-1581 DOI: 10.1039/C1NJ20370C   

Why not take a look at the articles today and blog your thoughts and comments below.

Fancy submitting an article to NJC? Then why not submit to us today  or alternatively email us  your suggestions.

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NJC Poster Prize winner at the Nitrogen Ligands conference

A young graduate student from the University of Parma has won the latest NJC Poster Prize in Granada.


A 2nd year graduate student in the group of Luciano Marchio at the University of Parma, Italy, was awarded the NJC Poster Prize at the 5th EuCheMS Conference on Nitrogen Ligands held in Granada, Spain, last week.

Irene Bassenetti‘s winning poster dealt with silver(I) complexes used as lubricants. Pure silver has long been known to be a good lubricant. The trick is to obtain these pure silver layers, without organic contaminants from the ligands. The new bimetallic complexes gave high purity layers that showed excellent results on stainless steel.

The synthesis and characterization of the compounds was carried out in Parma. The analysis of the silver layers formed upon decomposition of the complex and the tribological properties when the complex was added to an oil were studied at Northwestern University in a collaboration with the group of Tobin Marks and the US Army.

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Tales of Granada: Day 4

Report from the 5th EuCheMS Conference on Nitrogen Ligands in Granada.

Another long day on Thursday, but the end was in sight. Amongst the 19 talks of the day a few themes stood out.

  • Three talks dealt with the interaction of metal ions with DNA: Jens Müller (University of Münster) spoke about metal-mediated (artificial) base pairs; Andrew Houlton (University of Newcastle) uses DNA to make metal nanowires, while Miguel Galindo (also at the University of Newcastle) studies the binding of metal complexes in the minor groove.
  • A related topic is that of metal ions and nucleobases, discussed by Angel Terrón-Homar (University of the Balearic Islands) and Pablo Sanz Miguel (University of Zaragoza).
  • Materials also occupied a large place during the day: Juan Herrera (University of Granada) showed bifunctional silica nanoparticles; Françoise Quignard (ENSC Montpellier) demonstrated the potential of hybrid catalysts based on polysaccharides; Christoph Janiak (University of Düsseldorf) presented MOFs for “useful cold” (using a cycle of water adsorption and desorption).

At the end of the afternoon, conference chair Jorge Navarro closed the meeting with a brief history of this series of conferences.

  • This 5th edition follows ones in Alghero (1992), Como (1996), Camerino (2004) and Garmisch (2008). The 6th is tentatively scheduled for 2015 somewhere in France.
  • There were about 260 participants from all over the world in this 5th edition; 65 talks over three and a half days and well over 100 posters in 2 sessions.

Three poster prizes were awarded: I presented the NJC Poster Prize to Irene Bassanetti (University of Parma) while the organizers recognized the work of Núria Aliaga-Alcalde (University of Barcelona) and Fawzia M.S. Al-Sogair (College of Basic Education, Kuwait).

Santiago Alvarez, speaking as the last session chair, listed the 3 ingredients necessary for a successful conference—good science, active participants, efficient organization—and judged that all three had been present in Granada. (I might add a 4th ingredient: an attractive location and venue.)


Congratulations to organizers Elisa Barea and Jorge Navarro! They were rewarded during that evening’s banquet with gifts presented by the organizing committee.

What’s this picture doing here you might ask?
Hint: what is the name of this fruit in Spanish?

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