Tales of Granada: Day 3

Report from the 5th EuCheMS Conference on Nitrogen Ligands in Granada.

Wednesday, as a half day, had a lighter schedule of “only” 10 talks. Some highlights included the following presentations.

  • Enzo Alessio (University of Trieste), in his plenary lecture, reviewed his group’s work on porphyrins in supramolecular chemistry (a variety of geometries can be obtained, including some very large constructs) and in medicinal chemistry (ruthenium anticancer complexes).
  • Multimetallic systems were a recurring theme this morning, as Marius Andruh (University of Bucarest), James Wilton-Ely (Imperial College London) and Enrique Colacio (University of Granada) all presented their results in this area.
  • In a good complement to a previous day’s lecture, Joan Aguiló Carreras (Autonomous University of Barcelona) addressed the production of hydrogen as the energy of the future, using Ru catalysts (electropolymerized or covalently anchored for the water splitting reaction).

After the morning’s session, a delicious buffet lunch awaited the delegates. And wait we did, if we were slow to get in line…providing a good occasion for further discussions with fellow delegates.

The 2nd poster session followed lunch—with the poster prizes in play—check back here soon to find out who the winners are!

In the afternoon came the eagerly awaited visit to the Alhambra. Busloads of chemists invaded the grounds, surely looking for inspiration in the intricate structures to be found everywhere one looked!

  • The Nasrid Palace itself was not as impressive as in my memories of my previous visit 35 years ago, in 1976. Perhaps because back then we were free to wander around more of the palace (or so I recall) and the famous Court of the Lions had its 12-lion fountain in place. (It is currently being restored and so we can only hope to see it in place once again in the near future.)
  • For me, the highlight of the Alhambra complex is its gardens—vast formal ones and small intimate ones—with water and fountains filling the air with their music. These gardens are a real oasis in the desert and a treat for the senses.

Don’t forget to visit us soon for the last day’s update and close of the 5th EuCheMS Conference on Nitrogen Ligands!

Digg This
Reddit This
Stumble Now!
Share on Facebook
Bookmark this on Delicious
Share on LinkedIn
Bookmark this on Technorati
Post on Twitter
Google Buzz (aka. Google Reader)

Tales of Granada: Day 2

Report from the 5th EuCheMS Conference on Nitrogen Ligands in Granada.

Tuesday was a marathon—20 talks—starting at 8:30 in the morning and ending 11 hours later at 19:30 that evening.

Amongst these many lectures, I particularly liked the following talks.

  • Ramon Vilar (Imperial College London) gave a very clear presentation on metallic terpyridine complexes that bind quadruplex DNA for potential medical applications.
  • Jeff Long (University of California, Berkeley) related his work on promising metal-organic frameworks (MOFs) to capture the CO2 produced in power plants.
  • Mike Scott (University of Florida) also addressed a real problem, that of the destruction of highly radioactive nuclear waste, with the design of actinide selective ligands.
  • Cameron Kepert (University of Sydney) looked at selective guest binding in metal-organic host materials.
  • Guillem Aromí (University of Barcelona) presented his work on cluster nanomagnets, containing up to 14 paramagnetic metal ions, which are of interest for applications that include qubit carriers.
  • V. Chandrasekhar (IIT Kanpur) also talked about multinuclear magnetic clusters, based on phosphorus-nitrogen ligands.

After this long day, dinner and sleep! See you tomorrow!

Digg This
Reddit This
Stumble Now!
Share on Facebook
Bookmark this on Delicious
Share on LinkedIn
Bookmark this on Technorati
Post on Twitter
Google Buzz (aka. Google Reader)

Tales of Granada*: Day 1

Report from the 5th EuCheMS Conference on Nitrogen Ligands in Granada.

Greetings from sunny Granada! Having arrived a day early, I walked around (and up and down) the downtown and old quarters of the Albayzin Arab neighborhood. Surprises and treasures abounded, to be discovered around each bend in my path.

Sunday evening the conference kicked off with a cocktail mixer held on the rooftop terrace of the Palacio des Congresos. Sipping a dry sherry and sampling Spanish “tortilla”, Iberico ham and manchego cheese, I and the other guests enjoyed compelling views of the surrounding city and magnificent Alhambra, lit up in the clear evening sky.

We got an early start (at the very un-Spanish hour of 8:30 am) on Monday with a plenary lecture by Makoto Fujita (of Tokyo University). Makoto reviewed about 10 years of his work on cage compounds. A recent interest is “starting and stopping” reactions in these cages, which allows them to view the reaction intermediates.

In another plenary lecture, Ged Parkin of Columbia University showed how tripodal nitrogen ligands can be used as models for zinc enzymes and in relation to organometallic toxicity. Ged finished his presentation with a card trick and the help of two volunteers from the audience, which impressed us until he revealed part of the secret. (Only a part though, or else I would conclude that human behavior is 100% predictable.)

This was just two of the talks amongst a very full program. I can’t possibly discuss all of them but my editor’s choice for the day would include the lectures by:

  • Joost Reek on using supramolecular chemistry to develop encapsulated catalysts;
  • Sandeep Verma on metal-adenine complexes, of use for catalysis when attached to carbon nanotubes;
  • Roland Sigel who looks at metal ion binding to DNA;
  • Hideki Masuda presenting ways to activate oxygen species by di-iron compounds on electrodes.

The first poster session ended a long day of science, which continued in a typical Moroccan restaurant. With NJC Associate Editor Mike Scott and our four guests we were transported to Marrakech, to experience another facet of the local culture. In enjoyable company, we compared research funding, football (soccer) and housing prices in our 5 countries.

Two of my guests at dinner have recent papers in NJC:

Check back on the NJC blog for my reports on the rest of this conference, including a visit to the Alhambra.

* With apologies to Washington Irving. His Tales of the Alhambra is, at 6 euros, the best bargain in Granada. It is a wonderful companion for a visit to this beautiful city.

Digg This
Reddit This
Stumble Now!
Share on Facebook
Bookmark this on Delicious
Share on LinkedIn
Bookmark this on Technorati
Post on Twitter
Google Buzz (aka. Google Reader)

New faces in the Montpellier editorial office

A new deputy editor, a publishing assistant and a 3rd assistant editor join the ranks of NJC.

This summer has seen the arrival of three new members on the NJC editorial team:
• Eva Balentova (Deputy Editor)
• Cynthia Challencin (Publishing Assistant)
• Ling Peng (Assistant Editor)
Read short profiles of each below, and more details on the NJC CNRS website.


Dr Eva Balentova was recently recruited as the Deputy Editor of NJC, replacing Dr Marie Cote (now with RSC Publishing in Cambridge).

Eva carried out her Ph.D. research in organic chemistry at the University of Pavol Jozef Šafárik in Košice, a city in eastern Slovakia. These studies involved long-term stays at both Turku University (Finland) and Universidad del País Vasco (EHU) in Spain. Postdoctoral positions at EHU and in France (Nancy and Montpellier) followed.

Eva’s research background in organic and natural product synthesis, as well as medicinal, peptide and carbohydrate chemistry, will beautifully complement the scientific expertise already covered by the other NJC editors.


Read more »

Digg This
Reddit This
Stumble Now!
Share on Facebook
Bookmark this on Delicious
Share on LinkedIn
Bookmark this on Technorati
Post on Twitter
Google Buzz (aka. Google Reader)

NJC Issue 9 now online!

NJC Issue 9, now published online, covers trends and progress in the areas of supramolecular chemistry, organometallic chemistry, catalysis, nanostructures, material sciences, and much more. This issue also includes a preview of RSC events in 2011/2012.

The outside front cover highlights the article by Lirong Lin (Xiamen University) and Hui Zhang (Zhejiang University) who present a characterization study of stereochemically labile atropisomers by solid-state circular dichroism and UV-Vis spectra.

Concentration effects in solid-state CD spectra of chiral atropisomeric compounds by Lei Ding, Lirong Lin, Chengyong Liu, Hongkun Li, Anjun Qin, Yan Liu, Ling Song, Hui Zhang, Ben Zhong Tang and Yufen Zhao, New J. Chem., 2011, 35, 1781-1786; DOI:10.1039/C1NJ20185A

The inside front cover features work by Mireille Blanchard-Desce and Olivier Mongin from the University of Rennes on design and synthesis of dual-role biphotonic chromophores. The ability to preserve their fluorescence property makes novel banana-shaped fluorophores very attractive molecules for photodynamic therapy (TPA). Furthermore, possible encapsulating of these biphonic fluorophores within nanoparticles is now of high interest.

Banana-shaped biphotonic quadrupolar chromophores: from fluorophores to biphotonic photosensitizers by Cédric Rouxel, Marina Charlot, Youssef Mir, Céline Frochot, Olivier Mongin and Mireille Blanchard-Desce, New J. Chem., 2011, 35, 1771-1780, DOI: 10.1039/C1NJ20073A

To be alerted to each new issue of the NJC journal, sign-up for the FREE Contents list email alert.

Digg This
Reddit This
Stumble Now!
Share on Facebook
Bookmark this on Delicious
Share on LinkedIn
Bookmark this on Technorati
Post on Twitter
Google Buzz (aka. Google Reader)

Late news

NJC Assistant Editor Laurent Vial is unable to attend the 4ECCLS conference.

Due to an unfortunate accident, Dr Laurent Vial (NJC Assistant Editor) will not be able to attend the 4th European Conference on Chemistry for Life Sciences (August 31 – September 3, 2011 in Budapest, Hungary) as announced.

The NJC Poster Prizes will be awarded, as planned.

Digg This
Reddit This
Stumble Now!
Share on Facebook
Bookmark this on Delicious
Share on LinkedIn
Bookmark this on Technorati
Post on Twitter
Google Buzz (aka. Google Reader)

NJC at end-of-summer conferences

NJC will be a sponsor of 3 conferences being held in the coming weeks.

Chemistry in the life sciences, nitrogen ligands everywhere, and catalysis are the themes of three conferences where NJC staff and board members will be representing the journal:

4th European Conference on Chemistry for Life Sciences (August 31 – September 3, 2011 in Budapest, Hungary)
5th EuCheMS Conference on Nitrogen Ligands in Coordination Chemistry, Metal-organic Chemistry, Bioinorganic Chemistry, Materials & Catalysis (September 4 – 8, 2011 in Granada, Spain)
21st Century Catalysis Science and Applications (September 29 – 30, 2011 in Ottawa, Ontario, Canada)


Kicking off this final round of summer conferences, Assistant Editor Dr Laurent Vial will be in Budapest for the 4th European Conference on Chemistry for Life Sciences. As part of the sponsorship of this conference by NJC, he will present poster prizes to two young chemists*. (Contact Laurent if you would like to meet him in Budapest.)

The conference covers both bioorganic and bioinorganic chemistry with an interdisciplinary flavor. The scientific sessions will cover a wide range of topics, including biomolecules in 3D, metals in medicine, synthetic biology, bioinspired catalysis, glycochemistry and many more.

This 4th edition in the series of meetings is co-chaired by Tamás Kiss and András Perczel and will be held in the ELTE Convention Center located at Eötvös Loránd University.

Following close behind is the 5th EuCheMS Conference on Nitrogen Ligands, at which NJC is sponsoring a poster prize*. Associate Editor Prof. Mike Scott and NJC Managing Editor Dr Denise Parent will be attending and look forward to meeting you there. Drop us a line if you will also be in Granada.

Ten eminent scientists from throughout the world will present plenary lectures on nitrogen-containing ligands used in a variety of areas, including biology, medicine, energy and the environment, materials….and almost 50 other speakers will expand on the subject.

This European Association for Chemical and Molecular Sciences conference will take place in the Granada Congress Centre and is organized by Jorge A. R. Navarro with colleagues from Spain, Italy and Germany.


At the end of September the 21st Century Catalysis Science and Applications colloquium of the Entretiens Jacques Cartier will take place in Ottawa. NJC Board member Dr Odile Eisenstein, one of the speakers, will present an NJC poster prize*. (Contact Odile.)

Conference topics range from a fundamental understanding of catalysis, biocatalysis and biomass conversion, to applications in nanoscience and energy.

This two-day conference is organized by researchers in Canada and France, and in particular Professors Tom Baker, Nicolas Abatzoglou and Davit Zargarian locally.
Read more »

Digg This
Reddit This
Stumble Now!
Share on Facebook
Bookmark this on Delicious
Share on LinkedIn
Bookmark this on Technorati
Post on Twitter
Google Buzz (aka. Google Reader)

NJC article featured in ACS Noteworthy Chemistry

We are delighted to announce the highlight of an NJC article by ACS Noteworthy Chemistry.

ACS Noteworthy Chemistry, in its August 15th edition, has highlighted an NJC article in a post entitled “Use cobalt(II) thiocyanate with TLC to identify cocaine” among the weekly selected publications presenting the most innovative ideas.

In this NJC article, O. Siri and co-workers from the University of Marseille (France) have designed a novel method for cocaine detection using cobalt thiocyanate reagent impregnated directly on TLC plates. This new strategy is rapid, low cost and offers perspectives for future use as a new field test kit for the identification of illicit substances.

Cobalt thiocyanate reagent revisited for cocaine identification on TLC
Rose Haddoub, Daniel Ferry, Philippe Marsal and Olivier Siri,
New J. Chem., 2011, 35, 1351-1354.; to read the original paper (if a subscriber)

Digg This
Reddit This
Stumble Now!
Share on Facebook
Bookmark this on Delicious
Share on LinkedIn
Bookmark this on Technorati
Post on Twitter
Google Buzz (aka. Google Reader)

Meet Our Authors – August 2011

Here is a selection of author profiles from the August issue of NJC. The editorial team would like to warmly thank them for accepting the invitation, giving us the opportunity to know some of our fellow chemists a little better.

Our first author is Stefan Bräse, who is Full Professor for Organic Chemistry and has been the Dean of the Faculty of Chemistry and Biochemistry for four consecutive years at the Karlsruhe Institute of Technology (KIT) in Karlsruhe, Germany. His research interests cover a wide range of organic chemistry reaching from total synthesis over solid phase chemistry to molecular transporters and carbohydrate chemistry. For some time now, Stefan Bräse has also been interested in nanosciences with a special focus on material chemistry. He is an active member of the Center for Functional Nanostructures (CFN) and, very recently, the Karlsruhe School of Optics and Photonic (KSOP) within the KIT. His latest contribution to NJC is a joint research project with colleagues from the KIT and Italy and deals with the generation and characterization of a Hyper-Cross-linked Polymer via Click chemistry. An adamantane based HCP exhibits efficient CO2 capture at low pressure

Besides the lab Stefan enjoys gardening around his recently finished house and spending time with his wife and their 10 months old son. Stefan is also keen on taking part in his group’s famous summer barbecue evenings.

“Click chemistry produces hyper-cross-linked polymers with tetrahedral cores”, Oliver Plietzsch, Christine I. Schilling, Tobias Grab, Stephan L. Grage, Anne S. Ulrich, Angiolina Comotti, Piero Sozzani, Thierry Muller and Stefan Bräse, New J. Chem., 201135, 1577-1581. DOI: 10.1039/C1NJ20370C.




Scott McIndoe is Associate Professor at the University of Victoria, Canada. He is currently working in the field organometallic catalyst discovery using ESI-MS . In this NJC paper, Scott and coworkers were interested in ensuring that their ESI-MS results are representative of solution speciation, and they discovered some interesting phenomena when exploring the degree to which they could leave ions partially solvated. They found that some fundamental solution properties of ions, notably their acidity, are reflected in their gas-phase behavior.

On choosing NJC to publish this work, Scott comments that “It touches on a broad range of topics, from the lanthanide contraction to ion acidity to the details of the electrospray ionisation mechanism, so we thought it deserved a broad audience”.

Outside of the lab, getting his hands dirty designing, making, and growing things is Scott’s favorite activity. If he could not be a scientist, he would be a professional cricketer.

“Blurring the line between solution and the gas phase: collision-induced dissociation of hypersolvated lanthanide trications provides insights into solution acidity”, Jennifer Pape, Keri McQuinn, Fraser Hof and J. Scott McIndoe, New J. Chem., 201135, 1582-1587. DOI: 10.1039/C1NJ20105K.

The next author is Plinio Innocenzi, Full Professor of Materials Science and Head of the Materials Science and Nanotechnology Laboratory at the University of Sassari, Italy. His research group is currently working on self-assembled nanomaterials, hybrid sol-gel materials for photonics, and X-ray lithography for soft matter. In their paper, Plinio and his team explore the possibility of using self-assembly to fabricate hierarchical porous materials as a very challenging road to master complexity. They believe that controlling the porosity in a material in terms of size and shape through a one-pot synthesis is a little step forward to get more complex materials.

The wide diffusion of NJC, with a particular attention to innovative nanochemistry synthesis, was Plinio’s motivation behind his submission to the journal.

Outside the lab, Plinio appreciates spending time with my family. Beside this he really like swimming : “I swim a couple of km almost every day, this is a very nice way of relaxing and thinking about science. I like also reading and sailing (sometimes at the same time…).” Because Plinio is so much happy to be a scientist, he cannot imagine to do anything else.

“Controlling shape and dimensions of pores in organic–inorganic films: nanocubes and nanospheres”, Plinio Innocenzi, Luca Malfatti, Daniela Marongiu and Maria F. Casula, New J. Chem., 201135, 1624-1629. DOI: 10.1039/C1NJ20186G.

Closing this month’s selection, we are pleased to present Michael H. Abraham, Honorary Professor at the University College London, UK. Michael research focuses on physical organic chemistry, especially as applied to environmental chemistry and medicinal/pharmaceutical chemistry. His paper contributes to the considerable discussion on the role of ion pairs in water-solvent partition and in membrane partition and permeation. It has been difficult to reach any conclusions so far, mainly because little is known about any properties of ion pairs that are relevant to partitioning and permeation processes. The aim in starting this work was to obtain physicochemical properties (or descriptors) of ion pairs that would allow quantitative assessment of the ability of ion pairs to undergo partition and permeation, especially by comparison to ionic species and neutral molecules.

NJC is a highly regarded journal that covers a wide range of  chemistry, including physical organic chemistry. The chosen reviewers for our manuscripts that we have previously submitted have always been knowledgeable and very perceptive, and an additional advantage is that time to publication is short.”, says Michael.

Michael is also a professional artist (painter) and so a great deal of his activity revolves around the practice of painting. This includes not only painting in the studio, but going out looking for sites for landscape painting, and a lot of time spent in setting up exhibitions. Michael also very keen on classical music concerts especially chamber music. When asked for an alternative career path if not a scientist, Michael naturally answered: “I suppose that my other profession, that as an artist, would have taken over as my sole profession.”

“Hydrogen bond descriptors and other properties of ion pairs”, Michael H. Abraham and William E. Acree, New J. Chem., 201135, 1740-1750. DOI: 10.1039/C1NJ20324J.

Thanks to all of you, and see you next month for more!

Fancy submitting an article to NJC? Then why not submit to us today or alternatively email us your suggestions.












Digg This
Reddit This
Stumble Now!
Share on Facebook
Bookmark this on Delicious
Share on LinkedIn
Bookmark this on Technorati
Post on Twitter
Google Buzz (aka. Google Reader)

June’s Top 10: the most popular NJC articles

NJC’s most downloaded articles in June 2011

June’s hit parade of downloaded articles from 2011 includes one Focus and three Perspective reviews.

Rare earths: jewels for functional materials of the future
Svetlana V. Eliseeva and Jean-Claude G. Bünzli
New J. Chem., 2011, 35, 1165-1176. DOI: 10.1039/C0NJ00969E, Perspective

An excellent BODIPY dye containing a benzo[2,1,3]thiadiazole bridge as a highly selective colorimetric and fluorescent probe for Hg2+ with naked-eye detection
Hui-Bin Sun, Shu-Juan Liu, Ting-Chun Ma, Nan-Nan Song, Qiang Zhao and Wei Huang
New J. Chem., 2011, 35, 1194-1197. DOI: 10.1039/C0NJ00850H, Letter

Application of ferrocene and its derivatives in cancer research
Cátia Ornelas
New J. Chem., 2011, Advance Article. DOI: 10.1039/C1NJ20172G, Perspective

Lanthanide-based luminescent molecular thermometers
Carlos D. S. Brites, Patricia P. Lima, Nuno J. O. Silva, Angel Millán, Vitor S. Amaral, Fernando Palacio and Luís D. Carlos
New J. Chem., 2011, Advance Article. DOI: 10.1039/C0NJ01010C, Perspective

A rigid metallohexameric macrocycle composed of endo- and exo-cyclic bisterpyridine-metal complexes
Sinan Li, Charles N. Moorefield, Carol D. Shreiner, Pingshan Wang, Rajarshi Sarkar and George R. Newkome
New J. Chem., 2011, Advance Article. DOI: 10.1039/C1NJ20195F, Paper

An efficient naphthalimide based fluorescent dyad (ANPI) for F and Hg2+ mimicking OR, XNOR and INHIBIT logic functions
Mohammad Shahid, Priyanka Srivastava and Arvind Misra
New J. Chem., 2011, Advance Article. DOI: 10.1039/C1NJ20058E, Paper

Preparation of graphene–TiO2 composites with enhanced photocatalytic activity
Kangfu Zhou, Yihua Zhu, Xiaoling Yang, Xin Jiang and Chunzhong Li
New J. Chem., 2011, 35, 353-359. DOI: 10.1039/C0NJ00623H, Paper

A noncovalently assembled porphyrinic catenane consisting of two interlocking [43]-membered rings
Maryline Beyler, Valérie Heitz and Jean-Pierre Sauvage
New J. Chem., 2011, Advance Article. DOI: 10.1039/C1NJ20294D, Paper Read more »

Digg This
Reddit This
Stumble Now!
Share on Facebook
Bookmark this on Delicious
Share on LinkedIn
Bookmark this on Technorati
Post on Twitter
Google Buzz (aka. Google Reader)