On the importance of considering all reaction partners: a lesson from birnessite-induced BPA oxidation

Written by Rachele Ossola

Bisphenol A (BPA) is one of the most used industrial chemicals worldwide. Since its introduction in the market in 1959, BPA production has increased steadily and it is forecasted to reach 7.3 million tons by the end of 2023.1 BPA is used for a range of applications: from dental sealants to internal can coatings, electronic equipment and supermarket receipts.2 “In the past years, concerns have been raised over the use of this compound due to its estrogenic effects that can be observed also at low BPA concentration, such as the ones found in the natural environment.2,3 Thus, investigation of natural attenuation processes might help us developing strategies to reduce human exposure to this widespread chemical.

Several literature studies showed that manganese oxides (MnOx)-mediated oxidation represents the main PBA degradation pathway in anoxic conditions.2 This process produces a series of degradation products, including radicals that might couple to dissolved organic matter to form the so-called “bound residues”, unknown high molecular weight products whose long-term environmental risks are still debated.4 A detailed knowledge of the reaction mechanism will therefore allow to predict, and ideally prevent, the formation of degradation products that might be more hazardous than the parent compound.

In this context, Balgooyen et al. used stirred flow reactors to investigate the effect of influent concentrations on BPA degradation mechanism via birnessite (δ-MnO2) oxidation. This research question was motivated by the hypothesis that higher influent concentrations might lead to a higher formation of bound residues. The results of this work are directly relevant for engineered water treatment systems that use MnOx-coated sand,5 where contaminant inflow concentrations might change during time.

As a unique feature of this work, the authors used a combined approach based on the detection of both organic and inorganic reaction products. Specifically, they followed the formation of both hydroxycumil alcohol (HCA) and aqueous Mn(II). HCA is the main PBA oxidation product and is considered a proxy for bound residues formation, while Mn(II) is a reaction byproduct released in solution upon reduction of birnessite.

Unexpectedly, the two approaches gave opposite results: HCA yields were constant for the influent concentration range investigated, while Mn(II) yields decreased as the influent concentration increased. In order to explain their results, the authors hypothesized that Mn(II) was not an accurate proxy, as comproportionation and disproportionation reactions occurring at the mineral surface might alter aqueous Mn(II) concentrations. Using an elegant series of sorption and desorption experiments, Balgooyen et al. were able to confirm this hypothesis, leading to the conclusion that BPA oxidation mechanism in stirred-flow reactors is indeed independent from the influent concentration.

In addition to providing a valuable new piece of information for the complex puzzle of BPA cycling in anoxic conditions, the work of Balgooyen et al. teaches us something that has little to do with micropollutants or flow-through reactors: for a throughout study of a chemical mechanism, all reaction partners must be considered – no matter how many different analytical techniques you will have to use.

To download the full article for free*, click the link below:

Impact of bisphenol A influent concentration and reaction time on MnO2 transformation in a stirred flow reactor

Sarah Balgooyen, Gabrielle Campagnola, Christina K. Remucal and Matthew Ginder-Vogel

Environ. Sci.: Processes Impacts, 2019, 21, 19

DOI: 10.1039/c8em00451j


About the Webwriter:

Rachele Ossola is a PhD student in the Environmental Chemistry group at ETH Zurich. Her research focuses on photochemistry of dissolved organic matter in the natural environment.

 

 

 


Additional references

(1)        The Global Bisphenol A Market, https://www.researchandmarkets.com/reports/4665281/the-global-bisphenol-a-market (accessed May 26, 2019).

(2)        Im and Löffler, Environ. Sci. Technol. 2016, 50 (16), 8403–8416.

(3)        vom Saal and Hughes, Environ. Health Perspect. 2005, 113 (8), 926–933.

(4)        Barraclough et al. Environ. Pollut. 2005, 133 (1), 85–90.

(5)        Charbonnet et al., Environ. Sci. Technol. 2018, 52 (18), 10728–10736.

 

*Article free to access until the 30th June 2019

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Emerging Investigator Series: Sarah Jane White

Sarah Jane White studies the biogeochemical cycling of metals that are critical in emerging energy technologies but whose environmental behavior and impacts remain largely unknown. She is interested in metal transport and speciation in natural ecosystems, and its intersection with contaminant fate & transport, industrial ecology, and human health. Sarah Jane received her doctoral degree in Environmental Chemistry from MIT, and her bachelor’s degree in Chemistry from Princeton University. She held positions as a Postdoctoral Fellow and Research Associate at the Harvard School of Public Health while doing multidisciplinary research as an NSF Science, Engineering, and Education for Sustainability Fellow. She continued her research and taught in the Environmental Studies Program as a Visiting Associate Research Scholar at Princeton University before joining the U.S. Geological Survey as a Research Chemist in 2017. Presently Sarah Jane’s research focus is the cycling of indium, gallium, and germanium during the mining and processing of zinc ores (of which they are a byproduct), with a goal of understanding the full life cycle of these elements from ore formation, through mining and processing, to their subsequent behavior and potential health impacts when released to the environment.

Read Sarah Jane White’s Emerging Investigator Series article “atmospheric cycling of indium in the northeastern United States” and read more about her in the interview below:

Your recent Emerging Investigator Series paper focuses on atmospheric cycling of indium. How has your research evolved from your first article to this most recent article?

My first published article was about what causes Candida albicans, a typically-benign yeast that everyone has in their bodies, to switch to a virulent form that can cause significant problems in immunocompromised people.  That paper was a result of work that I did as a lab technician – my first job out of college.  After doing an undergraduate thesis in environmental chemistry, and not having taken any biology courses in college, I serendipitously had the opportunity to work in a molecular biology lab, and knew that the opportunity to better understand biology would enhance the environmental science that I was hoping to do in the future.  After that, I went back for a PhD in environmental chemistry, where I focused on contaminant fate and transport – for which biology is immensely important!  As my research interests have expanded even further to include human exposure to metals and subsequent impacts on health, this biology experience has proven invaluable. Now my work focuses on the environmental and anthropogenic cycling of elements like indium, that are critical to new energy technologies but whose environmental behaviors and human health impacts are poorly understood.

What aspect of your work are you most excited about at the moment?

I have recently begun doing some synchrotron-based x-ray absorption work to determine the speciation of germanium in mine wastes.  It has been exciting to learn a new technique that has powerful implications for understanding the mobility, bioaccessibility, and potential for recovery of a critical element from mine wastes.

In your opinion, what are the most important questions to be asked/answered in this field of research?

There are a dizzying number of chemicals and metals that we are exposed to on a daily basis, many of which have poorly characterized toxicity and environmental behavior.  I believe that it is essential for researchers to not only study the behavior and toxicities of these elements and compounds, but also find ways to predict their characteristics to protect human and organismal health.

What do you find most challenging about your research?

Juggling multiple projects at once, and finding sufficient time to invest in all of them.

In which upcoming conferences or events may our readers meet you?

I just returned from a workshop on the environmental behavior of technology-critical elements in Croatia, and don’t have conference travel planned until likely the AGU Fall Meeting in December.

How do you spend your spare time?

I spend most of my non-working time with my husband and two young kids.  We like to go on bike rides, hit wiffle balls in the backyard, play music, garden, go to farmers’ markets…

Which profession would you choose if you were not a scientist?

Baseball radio announcer?  Violin maker?  Physical therapist?

Can you share one piece of career-related advice or wisdom with other early career scientists?

Research is worthless unless people know about it.  For me, this means working to overcome perfectionist tendencies so that my work is published, even if not perfect.

 

 

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Emerging Investigator Series: Shantanu Jathar

Shantanu Jathar is an Assistant Professor in Mechanical Engineering and also an affiliate of the Energy Institute at Colorado State University. He leads the Laboratory for Air Quality Research (http://tinyurl.com/aerosol-csu) that performs research at the intersection of energy and the environment. By leveraging laboratory and field experiments and regional air quality models, his group studies the atmospheric evolution and properties of air pollutants arising from energy and combustion systems, all in the interest of addressing future energy and environmental policy. He has a Ph.D. from Carnegie Mellon University where he used numerical models and laboratory experiments to understand the atmospheric formation of organic aerosols from combustion sources. He worked as a post-doctoral scholar at the University of California, Davis where he worked on improving the treatment of particulate matter in air quality models used for regulatory purposes. Shantanu hails from the suburbs of Mumbai, India. He is married to Poorva (an electrical engineer) and is enjoying parenthood with two energetic sons. In his spare time, he likes to run, bike, hike, and play the bansuri (bamboo flute).

Read his latest Emerging Investigator Series “Oxidative Potential of Diesel Exhaust Particles: Role of Fuel, Engine Load, and Emissions Control” and find out more about him in the interview below:

Your recent Emerging Investigator Series paper focuses on oxidative potential of diesel exhaust particles and the role of fuel, engine load, and emissions control. How has your research evolved from your first article to this most recent article?

My first project, as a graduate student at Carnegie Mellon University nearly a decade ago, examined the influence of an updated treatment on the global distribution of organic fine particles in a climate model. This study was motivated by the need to reduce the large uncertainties linked to fine particles in climate models. Over the years, my research interests have broadened to think about the impacts of fine particles on human health. In this study, we probed how the oxidative reactivity (proxy for toxicity) of particles generated by a modern-day diesel engine varied as we changed the fuel and engine operation. We found that biodiesel and the use of an emissions control device (particle filter) significantly lowered the oxidative reactivity of diesel exhaust particles and we suspect that the reduced oxidative reactivity might be from lower soot emissions. Our work provides some evidence that wider adoption of biofuels and stricter regulations on diesel vehicles may reduce their harmful impacts on human health.

What aspect of your work are you most excited about at the moment?

It has to be wildfires. Wildfires are a growing concern in the western United States as rising temperatures have been linked to more frequent and bigger wildfires. Unlike burning fossil fuels in a controlled environment (think of the internal combustion engine), the variability in fuel and environmental conditions under which fires burn results in large variability in their emissions. As a result, there are large uncertainties surrounding the atmospheric evolution and impacts from wildfire emissions. We have a project supported through the National Oceanic and Atmospheric Administration (NOAA) where we are studying the atmospheric evolution of wildfire emissions in a controlled environmental chamber and using computer models trained on the laboratory data to predict the evolution in real wildfire plumes.

In your opinion, what are the most important questions to be asked/answered in this field of research?

Fine particles when inhaled deposit in our respiratory system and have been linked to lung and cardiovascular disease. However, little is understood about what properties of the particle — defined by their size and composition — are responsible for those diseases and how they might affect different individuals over different periods of time. This, I believe, is an open question and we are not going to figure the answer to this anytime soon.

What do you find most challenging about your research?

Very broadly, I study the sources and impacts of air pollution arising from energy and combustion sources. What I find most challenging with this research area is to keep abreast of the breadth and depth of topic areas it encompasses: physics, chemistry, biology, mathematics, engineering, statistics, public health, and more. Thankfully, the vastness is humbling and I rely on collaborations with some very smart people at Colorado State University and elsewhere to bring their expertise to the topic.

In which upcoming conferences or events may our readers meet you?

I usually don’t miss the annual American Association for Aerosol Research Conference (AAAR), which will be in Portland, OR this year in October. It’s the perfect place to get my scientific fix for fine particle research and catch up with collaborators and colleagues.

How do you spend your spare time?

My wife and I have a 5.5 and a 1.5 year old and we like to spend as much time as we can get with them when we are not working. Summers are the best because we spend a lot of time outdoors hitting the trails and pools.

Which profession would you choose if you were not a scientist?

I have thought about this question a lot and my answer hasn’t changed in a while. I would like to host and produce a science radio show, similar to Radiolab, that mixes physical and social sciences with personal stories. The one thing I would do differently would be to focus on geographies, cultures, and topics relevant to the developing world.

Can you share one piece of career-related advice or wisdom with other early career scientists?

The one thing I would tell early-career scientists is that don’t take any advice (including this one!) too seriously. Listen, but forge your own path. Don’t be afraid to make mistakes and don’t hold any regrets.

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Emerging Investigator Series – Karen Dannemiller

Karen C. Dannemiller, PhD is an Assistant Professor at Ohio State University with a joint appointment in Civil, Environmental, and Geodetic Engineering and Environmental Health Sciences. She also has a courtesy appointment in Microbiology. At Ohio State, she leads the Indoor Environmental Quality (IEQ) (https://ieq.engineering.osu.edu/) group and studies the indoor microbiome and indoor chemical exposures. In 2017, she was awarded the Denman Distinguished Research Mentor Award.

Prior to her current position, Dr. Dannemiller graduated with honors in Chemical and Biochemical Engineering from Brown University and earned her MS, MPhil, and PhD at Yale University in Chemical and Environmental Engineering. During this time, she completed an internship at the California Department of Public Health in the Indoor Air Quality Program. She was also a Microbiology of the Built Environment Postdoctoral Associate at Yale University

Read Karen Dannemiller’s Emerging Investigator article “Degradation of phthalate esters in floor dust at elevated relative humidity” and find out more about her in the interview below:

Your recent Emerging Investigator Series paper focuses on the degradation of phthalate esters in floor dust at elevated relative humidity. How has your research evolved from your first article to this most recent article?

This paper has really allowed my work to come full circle.  My first research paper was on formaldehyde in the indoor environment, which was based on my work in the chemical engineering department at Brown University as an undergraduate.  During my PhD, I began to focus more on microbial exposures in the indoor environment.  This Emerging Investigator Series paper is so exciting because it combines my interest in both indoor chemistry and indoor microbiology by examining the interactions between these two systems.

What aspect of your work are you most excited about at the moment?

I direct the Indoor Environmental Quality Laboratory at Ohio State University, and I am excited about all the applications that we are discovering to which we can apply our research. It is so critical to understand the chemical and microbial processes occurring in the indoor environment, and this has important implications in many different systems.  These processes can be particularly important in influencing exposures of vulnerable populations, such as asthmatic children.  We also need a thorough understanding of chemical and microbial interactions in specialized, sensitive systems such as on the International Space Station.  I am most excited to have received grants from NIH, NASA, the Alfred P. Sloan Foundation, and other organizations to study these interactions.

In your opinion, what are the most important questions to be asked/answered in this field of research?

Right now, very little is known about the interactions between chemicals and microbes in the indoor environment.  There are a plethora of questions that need to be asked to gain even a basic understanding of what is happening around us on a daily basis.  These may have important implications for our health.

What do you find most challenging about your research?

One of the most challenging but also exciting aspects of my research are the unexpected surprises inherent in any scientific dataset, but especially rich microbial datasets.  Often, future grant proposals can result from novel associations discovered during data analysis.

In which upcoming conferences or events may our readers meet you?

The next conference I will attend will be AEESP in Tempe, AZ, May 14-16, 2019.  I am very excited to be giving the plenary talk on Thursday morning.

How do you spend your spare time?

I love spending time with my family.

Which profession would you choose if you were not a scientist?

If I were not a research scientist, I would be an environmental public health practitioner.  They apply scientific principles to help people reduce their harmful exposures.  I appreciate the hard, challenging work that they do everyday, especially in fields like mold remediation.

Can you share one piece of career-related advice or wisdom with other early career scientists?

I have been very lucky and very thankful to have some outstanding mentors throughout my career.  I would highly recommend that early career scientists find mentors to help them navigate different obstacles they may encounter.  Mentors are a great source of advice and inspiration.  They can also help you identify exciting opportunities

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6th European Conference on Environmental Applications of Advanced Oxidation Processes

No photo description available.The 6th European Conference on Environmental Applications of Advanced Oxidation Processes will take place in Portorož, Slovenia from 26th – 28th June 2019. The conference will bring together scientists, engineers and other environmental professionals to present their findings and discuss future trends and directions concerning various environmental applications of advanced oxidation processes (AOPs). The contributions will focus on the scientific and technological advances of AOPs for the remediation of water, air and soil contaminated with various recalcitrant compounds, either alone or in combination with other processes.

Registration is required for all participants and accompanying guests. Please complete and submit on-line the Registration Form  to the EAAOP-6 Secretariat. Use a separate form for each participant and accompanying guest. Register here

Early bird registration deadline: To take advantage of the reduced conference registration fees, register before or on 15 April 2019. Higher fees apply after 15 April 2019.

Plenary speakers 

Prof. Dr. Angelika Brückner

Prof. Dr. Kazunari Domen

Dr. Wolfgang Gernjak

Prof. Dr. Gianluca Li Puma

Keynote speakers

Dr. Isabel Oller Alberola

Dr Fernando Fresno

Prof. Dr. Josef Krýsa

Prof. Dr. Urška Lavrenčič Štangar

For more information about the conference, check out the event website here http://eaaop6.ki.si/ 

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Emerging Investigator Series: Elliott Gall

Dr. Elliott Gall is an assistant professor at Portland State University in the department of Mechanical and Materials Engineering. Dr. Gall’s research and teaching seeks to improve the sustainability of the built environment through an understanding of the intersection of indoor air quality, urban air pollution, and human exposure to air pollutants. Research areas include: i) laboratory and field studies of air pollutant transport and transformation, ii) air pollution exposure assessment through modeling and personal exposure studies, and iii) evaluation of building technology and design with respect to indoor environmental quality. Active research includes application of chemical ionization – time of flight – mass spectrometry to the study of indoor environments; a current focus is measurement of source, sink, and transformation processes from traffic related air pollution, wildfire emissions, and wood stove heating emissions. Dr. Gall is also studying the fate and transport of indoor ozone and other oxidants; he was acknowledged with the 2018 Yaglou Award from the International Society for Indoor Air Quality and Climate for his work on indoor ozone chemistry. Finally, an ongoing research area investigates and critically evaluates the impact of vegetation, e.g., green roofs and houseplants, on indoor and urban air quality.

Previously, Dr. Gall received a B.S.E in Environmental Engineering from the University of Florida, an M.S. degree in Environmental & Water Resources Engineering from the University of Texas, and his Ph.D. in Civil Engineering from the University of Texas. From 2013 to 2016, he was a postdoctoral researcher in Singapore as part of a joint research program between UC Berkeley, NUS, and NTU, where he studied indoor air quality of buildings in tropical climates. He has authored or co-authored nearly thirty peer-reviewed journal publications. His work at Portland State has been featured in local and national media, including The Atlantic, the Willamette Week, Oregon Public Broadcasting, and he has been interviewed on the nationally syndicated Top of Mind radio program. More information can be found at his lab group website, www.pdx.edu/green-building or on twitter @etgall

Read Elliott Gall’s Emerging Investigator article “Primary emissions, ozone reactivity, and byproduct emissions from building insulation materials” and find out more about him in the interview below:

Your recent Emerging Investigator Series paper focuses on primary emissions, ozone reactivity, and byproduct emissions from building insulation materials. How has your research evolved from your first article to this most recent article?

The major evolution from some of my earlier work is the analytical methods my lab uses in this study. We designed these experiments to be similar in scope to prior work testing building materials because we’re integrating a proton transfer reaction – time of flight – mass spectrometer (PTR-TOF-MS) into the effort. A major focus of my start-up at Portland State has been learning chemical ionization mass spec with an Ionicon PTR-TOF-MS, with which we have also been working with multiple ionizing reagents. This research was the first major, research-grade study that we conducted with the instrument. Prior to that, the lab team and I spent a great deal of time learning, reading, and running preliminary tests. It’s been a fascinating, and at times, frustrating, journey learning time of flight-mass spectrometry. With this effort completed, and more broadly our increasing capability with TOF-MS, I’m excited about where we can continue contributing to the field.

What aspect of your work are you most excited about at the moment?

Our work with time of flight-mass spectrometry, and the general trend towards real-time measurements in the field, is exciting. The ability to see information on the gas and particle species in air in real-time has been fascinating and, I think, will really enable important new approaches both in field and lab studies. I’m hopeful that we can use the dynamic information from our PTR-TOF-MS to both better understand physics and chemistry of indoor spaces and to develop automated, high-throughput methods that will let us scale out test matrices to include many more samples and with better replication. I’m also excited about bridging indoor and outdoor air quality issues. There’s been a general increase in attention to indoor air quality in the past decade or so, which is leading to exciting new developments in the field.

In your opinion, what are the most important questions to be asked/answered in this field of research?

I believe establishing better understanding of health effects associated with exposures to indoor sources air pollution would drive better research questions as well as enable better actions to be formulated and recommended or incorporated into building code. Understanding indoor air pollutant levels and dynamics is one part of this, but it will require more collaboration with health scientists and funding for larger-scale studies than have been conducted to date.

I also think better understanding of indoor air pollutant cycling, over short and long time frames, will improve understanding of air pollution exposures and also other routes of exposures like dermal uptake. There are high surface area to volume ratios indoors. There exist many knowledge gaps in understanding how these surfaces interact with indoor air and may act as reservoirs for air pollutants, or as transformation pathways, especially for their role in indoor reactions of nitrogen containing compounds and impacts on indoor radical species.

What do you find most challenging about your research?

Indoor air studies (and air quality studies in general) are characterized by a very complex matrix of gas and particle-phase pollutants. Since I started at PSU, a majority of our research effort has been focused on developing lab capabilities to measure things (e.g. organics via the PTR-TOF-MS) in that matrix. We’ve set up the lab to a point where we can measure a range of key parameters of interest: particle size distributions, some approaches for particle composition, and organic and inorganics in the gas-phase. Especially given my position in a Mechanical Engineering department, there’s often student interest and excitement for development of automation, instrumentation, and other tools. The field as a whole has obviously made really important advancements in our understanding of air quality due to improvements in instrumentation. Collecting data is central to what we do, but I’d like to ensure we keep a balance of learning and incorporating methods for data generation and collection while not losing sight of designing studies for generalizable, lasting, and impactful knowledge. Part of that is accepting that you will likely never have all the information you want. I try to keep a sense of humor about the somewhat famous quote “All science is either physics or stamp collecting”, and use it as little reminder to try and think about what kind of information a particular effort is going to yield.

In which upcoming conferences or events may our readers meet you?

I’ll be at AAAR in October 2019 in Portland, OR and I plan to attend Indoor Air in Seoul in 2020.

How do you spend your spare time?

My wife and I were thrilled to be able to move to the Pacific Northwest for my work at Portland State. We spend our free time hiking and camping in all the fantastic mountains, coasts, and deserts that the area has to offer. The mountain biking opportunities in the area are world-class, and coming from Florida and Texas, I’ve been able to improve a lot as a mountain biker. While summer is a great time to get research done, the perfect weather (outside of our recent spate of wildfires) make it way too alluring to get outside. I’ve been kicking around an indoor air quality in camping tents study in my head as an excuse to bridge work and fun.

Which profession would you choose if you were not a scientist?

I can’t get enough time on a mountain bike, but I’ve also always been pretty cautious person, so I don’t think anyone would pay to see such unexciting riding – but maybe a guide or trainer? More likely, if I wasn’t a scientist I would probably pursue advocacy related to the environment and conservation – maybe cycling-based urban planning. So many win-wins (including for air quality!) if we could redesign our cities around bikes instead of cars.

Can you share one piece of career-related advice or wisdom with other early career scientists?

It’s an obvious one, but being active and intentional about time management. What you choose to spend your time on impacts every aspect of your career, and inevitably also much of your personal life. There’s no one-size-fits all answer to this, but in my opinion, it’s important to give time management consideration on a daily basis regarding tasks at hand, but also to dedicate time to for bigger picture thinking on a regular basis. It took me some time to appreciate just how long lead time initiating new research can be, and so what you do day to day now can impact what you will be working on years from now, who you are collaborating with, etc. Giving this thought regularly has helped me focus and be more effective, and also with that all too difficult task of declining opportunities, to ensure I’m working on things that I think will be productive and meaningful.

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Emerging Investigator Series – Akane Yamakawa

Akane Yamakawa completed her undergraduate studies at Kobe University, and graduate studies (master) at University of Tokyo, and PhD at Okayama University, Japan. Under the supervision of Dr. Katsuyuki Yamashita, she developed chemical separation of transition metals, and highly sensitive Cr isotopic measurement in meteorites using thermal ionization mass spectrometry. She spent one and a half years as a postdoctoral position, CO with Dr. Qing-zhu Yin in UC Davis at Geology Department. She is now a senior researcher at National Institute for Environmental Studies (NIES), Tsukuba, Japan, working in Fundamental Analytical Chemistry Section of Center for Environmental Measurement and Analysis. Her current researches focus on using isotope geochemistry to better understand emission sources and atmospheric behavior of mercury using Hg isotope, emission sources of long-range transport of particulate matter using Pb isotope, fish ecology using Sr isotopic measurement of otolith, etc. She also involves a project to create environmental reference materials at NIES.

Read Akane Yamakawa’s Emerging Investigator Series article “Investigation of Mercury Emission Sources Using Hg Isotopic Compositions of Atmospheric Mercury at the Cape Hedo Atmosphere and Aerosol Monitoring Station (CHAAMS), Japan” and read more about her in the interview below:

Your recent Emerging Investigator Series paper focuses on Mercury Emission Sources Using Hg Isotopic Compositions of Atmospheric Mercury. How has your research evolved from your first article to this most recent article?

I started my carrier as a Cosmochemist. I studied about the early evolution of solar system by Cr isotopic measurement of various meteorites. I learned all manners about research from Dr. Katsuyuki Yamashita, Okayama University. After postdoc, I extended my research field to geochemistry and environmental chemistry. Although the research fields are largely different, research philosophy does not change. About atmospheric mercury research, my previous paper is focusing on methodology of Hg isotopic measurement of gaseous elementary mercury, and I applied the method to this most recent article.

What aspect of your work are you most excited about at the moment?

I like to develop and use new techniques. I recently stayed at University of Pau, and learned highly sensitive Hg isotopic measurement. I was lucky to learn the cutting edge technology in this field.

In your opinion, what are the most important questions to be asked/answered in this field of research?

Environmental dynamics of mercury. Especially the interrelationship between atomic mercury and reactive mercury, and the mechanism of methylation-demethylation.

What do you find most challenging about your research?

In order to understand environmental dynamics of mercury, it is essential to have discussions with experts in various fields, and I have to identify my role. Hg isotopic measurement will be a tracer to understand environmental dynamics of atmospheric mercury. It requires many analytical challenges to assure the quality of the research.

In which upcoming conferences or events may our readers meet you?

I plan to present my resent work at AGU Fall Meeting 2019 (San Francisco).

How do you spend your spare time?

I love to spend my time with family. I especially like to play with my dogs. They make me smile. I also enjoy playing and watching tennis when I have spare time.

Which profession would you choose if you were not a scientist?

I have not thought about this question… Maybe tennis player…?

Can you share one piece of career-related advice or wisdom with other early career scientists?

Find your mentor or advisor. I was fortunate to meet Dr. Yamashita at undergraduate research project. He had many interesting collaboration works, and led me to participate in some researches. Although I was such like a C grade student, he did not give up teaching. If you find a wonderful mentor or advisor at an early stage of your career, he/she will bring you nice projects with nice collaborators. All you need to do is show your enthusiasm and effort, and keep your motivation high.

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Emerging Investigator Series: Laura Carter

Laura Carter is a University Academic Fellow at the University of Leeds, UK. Laura’s research focuses on understanding the fate and uptake of emerging contaminants in the natural environment, with particular focus on soil-plant systems.  Since completing her PhD at The University of York, Laura has spent time as a Risk Assessor at Unilever’s Safety and Environmental Assurance Centre (SEAC) and as a Postdoctoral Research Fellow at the Commonwealth Scientific Industrial Research Organisation (CSIRO) in Adelaide, Australia where she investigated the biological effects of pharmaceutical uptake into plants. From 2016 – 2018 Laura worked as a Postdoctoral Researcher at the University of York, UK where she contributed to the European iPiE project on the intelligent assessment of pharmaceuticals in the environment, developing soil sorption models and monitoring pharmaceuticals in river catchments. At the University of Leeds, Laura is currently working on projects to increase our understanding of the effects of pharmaceuticals on soil and plant health.

Read Laura’s Emerging Investigator article “Towards a framework for establishing the impacts of pharmaceuticals in wastewater irrigation systems on agro-ecosystems and human health” and find out more about her in the interview below:

Your recent Emerging Investigator Series paper focuses on the impacts of pharmaceuticals in wastewater irrigation systems on agro-ecosystems and human health. How has your research evolved from your first article to this most recent article?

The first publication from my PhD centred on exploring the role of chemical fate in the uptake of pharmaceuticals by plants. This involved pot experiments to consider the sorption, persistence and bioavailability of pharmaceuticals in soil systems and the influence of this on plant uptake. My research then moved on to explore the factors and processes, which control the fate and uptake of pharmaceuticals in terrestrial systems including the potential for pharmaceuticals to induce sub-lethal toxicity. Our recently published article takes a more holistic approach to considering pharmaceutical exposure in agro-ecosystems accounting for the complexity and connectivity between different sources and receptors. The proposed framework allows us to begin to piece together individual research outputs to quantify the agricultural and human health risks associated with pharmaceutical exposure in agro-ecosystems.

What aspect of your work are you most excited about at the moment?

I have recently started at the University of Leeds as a University Academic Fellow. I am excited about the opportunity to develop my own research group and an independent programme of research centred on exploring the fate and uptake of contaminants in terrestrial systems.

In your opinion, what are the most important questions to be asked/answered in this field of research?

As highlighted in our recent publication we are unable to currently assess the risk of pharmaceuticals in agro-ecosystems because we do not have a high level of understanding of many of the processes and compartments involved in the exposure of pharmaceuticals. Work is urgently needed to understand the fate and transport of pharmaceuticals in arable soils systems and the effects of chronic, low level exposure to these substances on microbes, invertebrates, plants, wildlife and humans. In addition, research pertaining to the fate, uptake and effects of pharmaceutical mixtures and metabolites is lacking.

Ultimately, it is not feasible to experimentally determine all the data we need to fill the identified knowledge gaps, so a key focus is the need to develop and validate models to predict the uptake of pharmaceuticals by non-target organisms. This will enable us to have a better understanding of the exposure of pharmaceuticals in terrestrial systems and provide basis for understanding any potential risk.

What do you find most challenging about your research?

I find translating results from laboratory experiments to understand the impacts of pharmaceuticals in our natural environment a particularly challenging aspect about my research. This is an inherently complex topic and trying to account for the complexity of environmental matrices across spatial and temporal scales, such as differences in soil properties, makes for a significant, yet interesting, challenge.

 In which upcoming conferences or events may our readers meet you?

I will be attending the 2019 Society of Toxicology and Environmental Chemistry (SETAC) conference in Helsinki where I will be presenting some recent work on the potential for pharmaceutical translocation to beehives.

How do you spend your spare time?

I love to spend my spare time exploring new places with my family; this usually involves a lot of ice cream and trying to keep up with my two-year-old son.

Which profession would you choose if you were not a scientist?

I am a naturally inquisitive person and wanted to pursue a career in journalism when I was at school but this soon changed to a passion to pursue a career in science.

Can you share one piece of career-related advice or wisdom with other early career scientists?

Pursue opportunities for multi-disciplinary collaboration to facilitate the sharing of expertise across complementary subject areas. This enables you to develop novel and interesting hypotheses. Some of my most interesting research has involved collaborating with plant biologists, analytical chemists and mathematical modellers.

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Proceedings from the 6th International conference on Emerging Contaminants (EmCon 2018), Oslo, Norway

Pernilla Carlsson, NIVA, Norway; Dana W.Kolpin, USGS, USA; Bjarne W. Strobel, University of Copenhagen, Denmark; Edward T. Furlong, USGS, USA; Thomas Borch, Colorado State University, USA; Rai Kookana, CSIRO, Australia; Edward P. Kolodziej, Washington State University, USA; Elisabeth Lie, NIVA, Norway; Bert van Bavel, NIVA, Norway; Kevin Thomas, NIVA, Norway and University of Queensland, Australia.

The 6th International conference on Emerging Contaminants (EmCon 2018) was held in Oslo, Norway in June 2018. This topical conference on emerging contaminants (ECs) was highly successful with around 140 participants including scientists, management, regulators, students, and industry attending the conference. Twenty-seven countries were represented at the conference, covering all continents except Africa and Antarctica with participants contributing 33 platform and 57 poster presentations of high quality during the event.

This single-track conference (i.e. all sessions were plenary) was organized with themes covering all aspects of emerging contaminant research, such as the occurrence of microplastics in the Artic and the removal of ECs during water treatment. For example, at one of the three keynote addresses, Katrin Vorkamp (University of Aarhus) shared a success story on how collaboration within the Arctic region on polychlorinated naphthalene’s led to their addition to the Stockholm Convention list. Other researchers at the meeting also discussed the presence of new contaminants in the Arctic, such as microplastics and personal care products, demonstrating the global transport of contaminants as well as contribution from local settlements and the need to include the Arctic when screening for ECs.

Environmental microplastics is clearly a popular and hot topic globally that was reflected in the number of talks and posters presented on these contaminants. During the meeting, we learned about the latest ideas and work on standardization of methods for monitoring microplastics and research across international borders. Inger Lise Nerland Bråte (Norwegian Institute for Water Research; NIVA) presented research on how the monitoring of blue mussels (Mytilus edulis) for microplastics can be used for sampling and can provide a standard comparison between different localities where present. Another researcher (Rachel Hurley; NIVA) presented a new project where the impact and uptake of microplastics from the use of biosolids in agriculture was under the spotlight. A poster by Bettina Liebmann (Environment Agency Austria) presented research documenting for the first time the presence of microplastics in human stool samples. This research went on to receive global media coverage later in 2018.

A keynote by Edward Kolodziej (Washington State University) brought to the audience’s attention the issue of Urban Stormwater Mortality Syndrome in Coho Salmon in the Western USA. Edward and his team used high-resolution mass spectrometry to identify a number of contaminants found in tire wear leachates as potentially responsible for the deleterious effects observed in these salmon. This was followed by additional informative presentations on the most recent developments in non-target analysis, demonstrating optimism within the EmCon community that this approach will be a crucial tool for identifying ECs in future research. For example, Marja Lamoree (Vrije Universiteit Amsterdam) utilized a non-target approach as part of a high-throughput effects-directed analysis approach to identify endocrine disrupters in Dutch surface waters.

While on one hand, per- and poly-fluorinated alkylated substances (PFASs) may no longer be considered as «emerging» contaminants. There has been a resurgence in PFASs research as the number of known PFAS and replacement compounds have increased (currently approaching 5,000 different compounds).  At the same time, we better understand the true prevalence of environmental exposures to PFASs, and mounting evidence show an ever-increasing number of potential environmental and human health effects. Paul Leahy (Environment Protection Authority Victoria) presented on the issue from a management and regulator’s perspective and how national environmental management plans are developed and used for regulation and also highlighted the importance of QA/QC work for high quality research and effective management. There were many excellent presentations at EmCon2018 focusing on the relation between sources and compound patterns and how regulation impacts compound profiles found in environmental samples. This is clearly documenting that PFAS is of high interest for researchers and regulators alike.

The list of ECs is continually evolving with new contaminants on the horizon with others having been previously identified but gaining ever greater environmental interest. One such example are salmon lice pesticides, where Steven J. Brooks (NIVA) discussed the bioaccumulation of teflubenzuron and emamectin benzoate in blue mussels. Sarah Hale (Norwegian Geotechnical Institute) talked about REACH registered compounds that are emerging as hazardous ECs in drinking water. The persistence, bioaccumulative and toxic (PBT) perspective may not always be efficient enough on targeting hazardous compounds in water. Sarah showed how a mobility criteria in addition to the set PBT criteria may help for further regulation and prioritization of drinking water contaminants. Summer time equates to higher use of UV-filter compounds in certain countries. An Australian study by Elissa O’Malley (University of Queensland) reported the global occurrence of UV compounds in surface waters. As UV compounds are, in general, directly related to sunscreen usage. Elissa reported that weather and latitude can be used as predictors for UV-filter compounds in the environment.

How we monitor the complexity of exposures to ECs in urban environments was the focus of a keynote by Alistair Boxall. A range of novel tools were presented that allow for the comprehensive monitoring of a multitude of exposures in urban environments in the future. A complementary approach worthy of consideration when assessing the exposure of populations is wastewater-based epidemiology. The approach was highlighted by Erik Emke (KWR Water Research) who estimated the quantity of illicit drugs consumed by festival visitors through measuring the levels of drug specific biomarkers in wastewater.

It has been challenging to select the highlights from such an exciting week and the EmCon2018 organizing committee were very pleased with the wide range of presentations, the high level of international representation of delegates and high quality of the science presented. We are very thankful to all of our sponsors, and especially our main sponsor Wellington and Norwegian Research Council. The EmCon 2018 conference would not have been possible without their support. ESPI has also kindly sponsored EmCon 2018.

We are already looking forward to the next EmCon conference, which is planned for the 21st-24th June 2021 in Seattle, USA. Welcome!

EmCon 2018 participants gathered in the conference venue

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Outstanding Reviewers for Environmental Science: Processes & Impacts in 2018

We would like to highlight the Outstanding Reviewers for Environmental Science: Processes & Impacts in 2018, as selected by the editorial team, for their significant contribution to the journal. The reviewers have been chosen based on the number, timeliness and quality of the reports completed over the last 12 months.

Dr Hans Peter Arp, Norwegian Geotechnical Institute

Dr  Jose Cerrato, The University of New Mexico

Dr  Satoshi Endo, Osaka City University

Dr Thorsten Hüffer,  University of Vienna

Dr Gerrad Jones, Oregon State University

Dr Linsey  Marr, Virginia Tech

Dr Xuejun Pan, Kunming University of Science and Technology

Dr Kim Parker, Washington University in St. Louis

Dr Christina Remucal, University of Wisconsin-Madison

Dr Joseph  Ryan, University of Colorado Boulder

We would like to say a big thank you to those individuals listed here as well as to all of the reviewers that have supported the journal. Each Outstanding Reviewer will receive a certificate to give recognition for their significant contribution.

We would also like to thank the Environmental Science: Processes & Impacts board and the Environmental Chemistry community for their continued support of the journal, as authors, reviewers and readers.

If you would like to become a reviewer for our journal, just email us at espi-rsc@rsc.org with details of your research interests and an up-to-date CV or résumé. You can find more details in our author and reviewer resource centre

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