Archive for the ‘Hot Articles’ Category

Mercury levels in Korean seafood and copper nanoparticles for 1,2-DCA remediation on the cover of Issue 9

The impressive image on the outside front cover highlights a hot article from Hyo-Bang Moon and coworkers at Hanyang University, the National Fisheries Products Quality Inspection Service and the National Fisheries Research & Development Institute, Korea. Their study is the first to assess the methyl mercury residues and total mercury content in seafood consumed in Korea – an important constituent of the population’s diet.  Their research found Hg levels to be below the threshold intake levels suggested by international authorities and thus will provide a baseline for future monitoring and risk management.

Exposure assessment for methyl and total mercury from seafood consumption in Korea, 2005 to 2008
Hyo-Bang Moon, Sang-Jo Kim, Hyejin Park, Yun Sun Jung, Suuggyu Lee, Yun-Hee Kim and Minkyu Choi
J. Environ. Monit., 2011, 13, 2400-2405
DOI: 10.1039/C1EM10504C

The image on the inside front cover depicts another hot article from Hsing-Lung Lien at the National Tawain University with colleagues from the National University of Kaohsiung, Tawain. They have designed a zero-valent copper nanoparticles for the hydrodechlorination of 1,2-dichloroethane.

1,2-DCA is a raw material used in vinyl chloride monomer (VCM) and polyvinyl chloride (PVC) manufacturing processes, and improper handling has lead to groundwater contamination in many places. As 1,2-DCA can cause circulatory and respiratory failure, and is a suspected carcinogen, remediation technologies are needed to deal with this contaminant.  The authors hope their copper nanoparticles could be immobilised on the surface of reducing metals to form a reactive bimetallic structure for environmental remediation applications.

Catalytic hydrodechlorination of 1,2-dichloroethane using copper nanoparticles under reduction conditions of sodium borohydride
Chang-Chieh Huang, Shang-Lien Lo, Shin-Mu Tsai and Hsing-Lung Lien
J. Environ. Monit., 2011, 13, 2406-2412
DOI: 10.1039/C1EM10370A

Interested?  Why not view the rest of Issue 9?

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HOT: Designing monitoring studies for the developing world, dynamic zinc, trace aerosols in the tropics & blood changes during pregnancy

Jayakody Sumith and Kelly Munkittrick from the University of New Brunswick look at designing studies to assess the health of fish in developing countries, by applying methodology currently in use in monitoring programmes in Canada.

Study design considerations for assessing the health of fish populations impacted by agriculture in developing countries: a Sri Lankan case study
Jayakody A. Sumith and Kelly R. Munkittrick
J. Environ. Monit., 2011, 13, 2105-2123


By monitoring dissolved zinc in the Deûle river, Baghdad Ouddane from the University of Lille et al., uncovered rapid concentration changes in a short period of time, indicating the need to better characterize the dynamic behaviour of trace metals in the aquatic environments
and to revise water quality assessments.

Evidence of highly dynamic geochemical behaviour of zinc in the Deûle river (northern France)
Beatriz Lourino-Cabana, Gabriel Billon, Aurélie Magnier, Emilie Prygiel, Willy Baeyens, Jean Prygiel, Oyvind Mikkelsen and Baghdad Ouddane
J. Environ. Monit., 2011, 13, 2124-2133


Tatiana Dillenburg Saint’Pierre, Pontifical Catholic University of Rio de Janeiro, and colleagues investigate trace aerosols in the tropics, which have so far been poorly studied, increasing our understanding of the long range transport, composition and solubility of airborne particulates in this region.

Chemical composition, sources, solubility, and transport of aerosol trace elements in a tropical region
Adriana Gioda, Beatriz Silva Amaral, Isabela Luizi Gonçalves Monteiro and Tatiana Dillenburg Saint’Pierre
J. Environ. Monit., 2011, 13, 2134-2142


The changing concentrations of toxic and essential elements were examined in pregnant women by Jon Øyvind Odland and teams from the University of Tromsø, McMaster University and the Norwegian Institute for Air Research.

Changes in maternal blood concentrations of selected essential and toxic elements during and after pregnancy

Solrunn Hansen, Evert Nieboer, Torkjel M. Sandanger, Tom Wilsgaard, Yngvar Thomassen, Anna Sofia Veyhe and Jon Øyvind Odland
J. Environ. Monit., 2011, 13, 2143-2152

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HOT: tape measure for PAHs

Exposure to polycyclic aromatic hydrocarbons (PAHs) in the workplace is an issue of some concern due to the classification of several PAHs as carcinogens.  A significant amount of research into inhalation exposure has been carried out but relatively few methods are available to accurately evaluate levels of PAHs on the skin – an exposure route that is now attracting more interest.

In this HOT paper Ronny Kammer, Lund University, and colleagues have applied the relatively new technique of tape stripping to measure dermal exposure levels to PAHs. They were able to detect and determine exposure to pyrene and benzo(a)pyrene in volunteers, including 5 chimney sweeps, and conclude that dermal uptake of these compounds may occur after occupational exposure.

Download the article for the full details of this study – it’s free to access for 4 weeks:

Evaluation of a tape-stripping technique for measuring dermal exposure to pyrene and benzo(a)pyrene
Ronny Kammer, Håkan Tinnerberg and Kåre Eriksson
J. Environ. Monit., 2011, Advance Article
DOI: 10.1039/C1EM10245A

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Hot: aluminium in UK rivers

A national picture for river aluminium levels in England and Wales has been revealed by researchers at Lancaster University and the Centre for Ecology and Hydrology in Wallingford, UK. Aluminium can have toxic effects in rivers particularly in the Al3+ form and 54 river sites in rural, agricultural and urban locations were involved in the study.

The work by Paul Scholefield and colleagues showed, for example, that for mid Wales there are limited declines in aluminium following acidification recovery, and unexpected variations for organic and colloidal aluminium. Among other findings the study has highlighted the need for further investigation of the hydrogeochemical ecotoxicological relevance of colloidal aluminium.

Read the full article here

 

Aluminium in UK rivers: a need for integrated research related to kinetic factors, colloidal transport, carbon and habitat
Colin Neal, Philip Rowland, Margaret Neal, Helen P. Jarvie, Alan Lawlor, Darren Sleep and Paul Scholefield
J. Environ. Monit., 2011, Advance Article
DOI: 10.1039/C1EM10362H, Paper

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Reclaiming the wastelands: a strategy to prevent re-acidification and remove heavy metals from very acidic mine soil

On the cover of Issue 7 we have an arresting image of the barren and extremely acidic metalliferous mine wasteland at Dabaoshan Pyrite/Copper Mine, located in the north of the Guangdong Province, China.  It accompanies work from W. S. Shu et al., from Sun Yat-Sen University, Jishou University and Shaoguan Pb/Zn Smelter, demonstrating the effectiveness of the combination of the net acid generation test and bioassay assessment for developing a reclamation strategy for extremely acidic mine soils.

To read their conclusions on appropriate soil amendments download the full article – it’s free to access for 6 weeks:

Effectiveness of amendments on re-acidification and heavy metal immobilization in an extremely acidic mine soil
S. X. Yang, J. T. Li, B. Yang, B. Liao, J. T. Zhang and W. S. Shu
J. Environ. Monit., 2011, 13, 1876-1883

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HOT: pathogens in the water – methods for measuring Salmonella and other bacteria

The quality of our water is always a key environmental issue, but measuring pathogens in water sources can be tricky.  Instead, bacteria such as E. coli – which in themselves do not cause illness but are present alongside pathogens in contaminated water –  have historically been used as indicators of water quality.  This method has been criticised, and new technologies now enable quicker and easier detection of actual pathogens such as Salmonella.

In this hot paper, Alexandria Boehm‘s group at Stanford University have conducted the first study on the fate of non-seeded Salmonella and faecal bacterial indicators E. coli and enterococci in urban surface waters, specifically a creek in California with levels of E. coli that often exceed EPA limits. Surprisingly, the EPA has not yet set any Salmonella standards for drinking and recreational waters so these studies will be valuable in beginning to determine acceptable levels, as methodologies they have developed for monitoring the source and fate of the bacteria can be transferred to other water bodies.

To read more about their findings download the paper – it’s free to access for 4 weeks:

Sources and fate of Salmonella and fecal indicator bacteria in an urban creek
Lauren M. Sassoubre, Sarah P. Walters, Todd L. Russell and Alexandria B. Boehm
J. Environ. Monit., 2011, Advance Article
DOI: 10.1039/C1EM10213C

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HOT: Protecting the environment – with the right information

One of the jobs of an environmental regulatory body is to establish acceptable levels of containments in the ecosystem under its jurisdiction.  But can the data they are basing their decisions on be relevant when standard toxicity tests have been carried out on non-native species, or when tests have not been carried out across the whole ecosystem?

This Critical Review from Samantha Eslava Martins and Adalto Bianchini at the Federal University of Rio Grande, Brazil, presents the first database of toxicological tests performed with Brazilian aquatic species.  Brazil has a hugely varied ecosystem and by analysing the database they were able to identify large gaps in current research efforts – both geographical and in the species tested.

Such an approach could be easily adopted by other countries, and could be a valuable tool to help researchers understand where more information is needed or to help policy makers make more realistic decisions about the protection of the environment.

As with all our HOT articles, this one is also free to access for 4 weeks, so why not take a look:

Toxicity tests aiming to protect Brazilian aquatic systems: current status and implications for management
Samantha Eslava Martins and Adalto Bianchini
J. Environ. Monit., 2011, Advance Article
DOI: 10.1039/C0EM00787K

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HOT: REACHing better exposure models

Assessing exposure is an important aspect of complying with the EU REACH regulations.  In the pharmaceutical industry accurately determining occupational exposure to API can be difficult due to the nature of the pharmaceutical process.  There are modelling tools available to help give confident assessments of exposure, one of the most sophisticated of which is the Advanced REACH Tool (ART).

In this HOT paper Patricia McDonnell (National University of Ireland Galway) and colleagues from across Europe have optimised ART to model airborne exposure of workers in the pharmaceutical industry, by refining and validating the inhalable dust algorithm.

If you’re interested in evaluating exposure assessment models why not download the paper – it’s free to access for 4 weeks:

Validation of the inhalable dust algorithm of the Advanced REACH Tool using a dataset from the pharmaceutical industry
Patricia E. Mc Donnell, Jody M. Schinkel, Marie A. Coggins, Wouter Fransman, Hans Kromhout, John W. Cherrie and Erik L. Tielemans
J. Environ. Monit., 2011, 13, 1597-1606
DOI: 10.1039/C1EM10189G

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HOT: analysing a new insecticide exposure route for honey bees

Andrea Tapparo and colleagues at the University of Padua, Italy, have developed a fast method for analysing neonicotinoid insecticides using UHPLC-DAD.  The method was used to analyse the insecticide content of guttation drops on corn seedlings.  Guttation is the formation of xylem droplets on leaves – often confused with dew – and has recently been proposed as a mechanism for the exposure of detrimental doses of insecticide to honey bee populations.

This HOT article is featured on the front cover of Issue 6.  Why not download it today to read the results of this interesting study – it’s free to access for 6 weeks:

Rapid analysis of neonicotinoid insecticides in guttation drops of corn seedlings obtained from coated seeds
Andrea Tapparo, Chiara Giorio, Matteo Marzaro, Daniele Marton, Lidia Soldà and Vincenzo Girolami
J. Environ. Monit., 2011, 13, 1564-1568
DOI: 10.1039/C1EM10085H, Paper

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HOT: analysing effects of sampling techniques on the analyte

The last few decades has seen a huge increase in the amount of data we collect to monitor our environment.  But making sure we do so in a representative and comparable way is vital for extracting valuable information on what we are monitoring whether it be pollutants, contaminants or climate change.

In this HOT paper Thorsten Pohlert and colleagues from the Federal Institute of Hydrology have taken on the mammoth task of analysing the effect of sampling techniques for suspended matter in stream water in a 5 year dataset. They look at the effect that three different sampling devices – continuous-flow centrifuges, floating collectors and sedimentation tanks – have on the on subsequent particle-size distribution and concentration of total organic carbon and selected persistent organic pollutants.

Download the article to read their recommendations on the type of sampling technique that is most suitable for the nature of the sample and the analyte – it’s free to access for 4 weeks:

Effects of sampling techniques on physical parameters and concentrations of selected persistent organic pollutants in suspended matter
Thorsten Pohlert, Gudrun Hillebrand and Vera Breitung
J. Environ. Monit., 2011, Advance Article
DOI: 10.1039/C1EM10045A, Paper

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