Inside Cover Issue 20: Silicon is the link

Hans-Joachim Knölkner and colleagues reveal the link between this beautiful church in Dresden and β-isocomene: silicon

Find out more about this curious conection in this article and read about the total synthesis of the sesquiterpenes (±)-β-isocomene and (±)-isocomene via a Lewis acid promoted [3 + 2] cycloaddition of allyl-tert-butyldiphenylsilane.

This article will be free to access until 10th November

Organosilicon-mediated total synthesis of the triquinane sesquiterpenes (±)-β-isocomene and (±)-isocomene
Arndt W. Schmidt, Thomas Olpp, Elke Baum, Tina Stiffel and Hans-Joachim Knölker
Org. Biomol. Chem., 2010, 8, 4562-4568
DOI: 10.1039/C0OB00051E

Digg This
Reddit This
Stumble Now!
Share on Facebook
Bookmark this on Delicious
Share on LinkedIn
Bookmark this on Technorati
Post on Twitter
Google Buzz (aka. Google Reader)