Read NJC’s Themed Issue on Dendrimers

Thirteen reviews and eighteen original research works make up this Dendrimers II themed issue.

If you work with dendrimers, or are interested in learning more about these fascinating molecules, then don’t miss NJC‘s themed issue on dendrimers that has recently been published on-line (February 2012 issue).

Guest-edited by renowned expert Jean-Pierre Majoral, this Dendrimers II issue follows our highly successful first Dendrimers issue of July 2007. In his editorial prefacing this latest issue, Jean-Pierre defines the concept of “dendrimer space” (click to read it free)

The three short and topical Focus reviews look at dendrimers as bactericides, in biomedical applications and in neurodegenerative diseases. The ten longer Perspective reviews cover the synthesis and properties of dendrimers, materials that incorporate dendrimers, and a variety of applications of dendrimers in biology and medicine.

Eighteen original research works complete the issue. I’ve selected five of these contributions, highly ranked by the reviewers, as Hot Papers; these will be free to access during the month of February (just click on the DOIs below).

• 5 Hot Papers

The biodistribution of maltotriose modified PPI dendrimers, with particular attention to the BBB crossing, was studied in a collaboration of Polish and German groups, revealing that the dendrimers were able to enter rat’s important organs, including the brain.

“The biodistribution of maltotriose modified poly(propylene imine) (PPI) dendrimers conjugated with fluorescein—proofs of crossing blood–brain–barrier” by A. Janaszewska, B. Ziemba, K. Ciepluch, D. Appelhans, B. Voit, B. Klajnert and M. Bryszewska, New J. Chem., 2012, 36, 350-353. DOI: 10.1039/C1NJ20444K

The group of Rainer Haag (Freie Universität Berlin) looked at fluorous polyglycerol dendrons and dendrimers, which are used to form highly stable aggregates in the micro- to nanometer range in water.

Supramolecular behavior of fluorous polyglycerol dendrons and polyglycerol dendrimers with perfluorinated shells in water” by M. Zieringer, M. Wyszogrodzka, K. Biskup and R. Haag, New J. Chem., 2012, 36, 402-406. DOI: 10.1039/C1NJ20741E

Steven Zimmerman (University of Illinois at Urbana Champaign), in collaboration with Rainer Haag, used hyperbranched polyglycerols to solubilize perylenediimide (PDI) and improve its fluorescent properties.

“Synthesis and properties of fluorescent dyes conjugated to hyperbranched polyglycerols” by A. T. Zill, K. Licha, R. Haag and S. C. Zimmerman, New J. Chem., 2012, 36, 419-427. DOI: 10.1039/C1NJ20476A

In the contribution by Bertrand Donnio and colleagues at the IPCMS in Strasbourg, two libraries of segmented block co-dendritic supermolecules bearing semi-fluorinated chains and lipophilic poly(benzyl ether)-based wedges form unusual liquid crystalline mesophases, whose supramolecular organization is tuned by the dendritic connectivity of both compartments.

“Self-assembly and liquid-crystalline supramolecular organizations of semifluorinated block co-dendritic supermolecules” by I. Bury, B. Heinrich, C. Bourgogne, G. H. Mehl, D. Guillon and B. Donnio, New J. Chem., 2012, 36, 452-468. DOI: 10.1039/C1NJ20530G

A self-assembly strategy allowing the generation of homo- and hetero-nuclear metallodendritic materials is the result of a joint effort by several American groups at the University of Akron and Louisiana State University.

“Shape-persistent, ruthenium(II)- and iron(II)-bisterpyridine metallodendrimers: synthesis, traveling-wave ion-mobility mass spectrometry, and photophysical properties” by J.-L. Wang, X. Li, C. D. Shreiner, X. Lu, C. N. Moorefield, S. R. Tummalapalli, D. A. Medvetz, M. J. Panzner, F. R. Fronczek, C. Wesdemiotis and G. R. Newkome, New J. Chem., 2012, 36, 484-491. DOI: 10.1039/C2NJ20799K

Take a look at these hot papers while they are free to all, this month only!

• About the Covers

The paper by J.-L. Wang et al. is also the subject of the outside cover (shown at the top) featuring windmills and dendrimers, while the inside front cover (at right) illustrates the Perspective review by French researchers in Strasbourg and Lyon on dendrimers in medical imaging .

“Dendrimers in nuclear medical imaging” by C. Ghobril, G. Lamanna, M. Kueny-Stotz, A. Garofalo, C. Billotey and D. Felder-Flesch, New J. Chem., 2012, 36, 310-323. DOI: 10.1039/C1NJ20416E (available to subscribers only)

We invite you to browse the issue here, and if you are a subscriber, to read more about dendrimers from the world’s experts in the field. Enjoy!

Click to subscribe to NJC.

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Top ten most accessed articles in December

This month sees the following articles in New Journal of Chemistry that are in the top ten most accessed:-

One-pot hydrothermal synthesis of graphene quantum dots surface-passivated by polyethylene glycol and their photoelectric conversion under near-infrared light
Jianhua Shen, Yihua Zhu, Xiaoling Yang, Jie Zong, Jianmei Zhang and Chunzhong Li 
New J. Chem., 2012, 36, 97-101 DOI: 10.1039/C1NJ20658C  

Synthesis of a pyridyl-appended calix[4]arene and its application to the modification of silver nanoparticles as an Fe3+ colorimetric sensor
Junyan Zhan, Long Wen, Fajun Miao, Demei Tian, Xiaolei Zhu and Haibing Li 
New J. Chem., 2012, Advance Article DOI: 10.1039/C2NJ20776A  

Generation of metallosupramolecular polymer gels from multiply functionalized grid-type complexes
John George Hardy, Xiao-yu Cao, Jack Harrowfield and Jean-Marie Lehn 
New J. Chem., 2012, Advance Article DOI: 10.1039/C2NJ20898A  

Photophysical property trends for a homologous series of bis-ethynyl-substituted benzochalcogendiazoles
Benjamin A. Coombs, Benjamin D. Lindner, Robert M. Edkins, Frank Rominger, Andrew Beeby and Uwe H. F. Bunz 
New J. Chem., 2012, Advance Article DOI: 10.1039/C2NJ20847D  

MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak and Jana K. Vieth 
New J. Chem., 2010, 34, 2366-2388 DOI: 10.1039/C0NJ00275E

Porphyrin-functionalized Fe3O4@SiO2 core/shell magnetic colorimetric material for detection, adsorption and removal of Hg2+ in aqueous solution
Lei Sun, Yaoxian Li, Mingda Sun, Hengguo Wang, Shufei Xu, Chaoqun Zhang and Qingbiao Yang 
New J. Chem., 2011, 35, 2697-2704 DOI: 10.1039/C1NJ20307J  
Cπ interaction of non-hydrogen bond type
Zhenfeng Zhang, Hongbo Tong, Yanbo Wu and Guisheng Zhang 
New J. Chem., 2012, 36, 44-47 DOI: 10.1039/C2NJ20903A  

PEG-dendritic block copolymers for biomedical applications
Ana Sousa-Herves, Ricardo Riguera and Eduardo Fernandez-Megia 
New J. Chem., 2012, 36, 205-210 DOI: 10.1039/C2NJ20849K  

Piezofluorochromism and morphology of a new aggregation-induced emission compound derived from tetraphenylethylene and carbazole
Xie Zhou, Haiyin Li, Zhenguo Chi, Xiqi Zhang, Jianyong Zhang, Bingjia Xu, Yi Zhang, Siwei Liu and Jiarui Xu 
New J. Chem., 2012, Advance Article DOI: 10.1039/C1NJ20782B  

Ln(iii)-cored complexes based on boron dipyrromethene (Bodipy) ligands for NIR emission
Jung Ho Ryu, Yu Kyung Eom, Jean-Claude G. Bünzli and Hwan Kyu Kim 
New J. Chem., 2012, Advance Article DOI: 10.1039/C2NJ20786A 

Why not take a look at the articles today and blog your thoughts and comments below.

Fancy submitting an article to New Journal of Chemistry? Then why not submit to us today or alternatively email us your suggestions.

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Extended azaheterocycles: flat but not dull !

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NJC Hot Articles: now available as Advance Articles on the web.

New dyes for LCD color filters!

In this NJC hot paper the scientists in Korea (Jae Pil Kim and co-workers) report some new phthalocyanine and coronene derivatives designed for dye-based green liquid crystal display (LCD) color filters.  Their thermal stability, optical properties, and solubility as the colorant materials for color filters were also investigated.

In addition, the synthesized six PC dyes and a benzopyrelene dye were successfully applied to the LCD color filters and showed superior optical properties than conventional pigment-based color filters.

Synthesis and characterization of thermally stable dyes with improved optical properties for dye-based LCD color filters by Jun Choi, Se Hun Kim, Woosung Lee, Chun Yoon and Jae Pil Kim, New J. Chem., 2012, Advance Article.

How to reduce the molecular dinitrogen to ammonia?

The problem is a classic of inorganic chemistry and the authors of this NJC hot paper (Chinnappan Sivasankar and co-workers) propose an interesting hypothetical approach to hydrogenating the complex. In general these reactions are mediated by a series of protonation and reduction steps. In this theoretical study, the authors propose a new methodology to reduce the molecular dinitrogen to ammonia in [WF(PH2(CH2)2PH2)N2] complex using some  co-catalysts in organic solvents.

With the help of DFT calculations the thermodynamic feasibility has been studied in three organic solvents (heptane, toluene and THF). The thermodynamic barriers for all the fundamental steps in the proposed catalytic cycle revealed that N2 can be reduced by H2 in all proposed organic solvents and that toluene would be the better choice of solvent than THF and heptane.

Hydrogenation of dinitrogen to ammonia in [WF(PH2(CH2)2PH2)2N2] using H2: Insights from DFT calculations by Perumal Balu, Sambath Baskaran, Venu Kannappan and Chinnappan Sivasankar, New J. Chem., 2012, Advance Article, DOI: 10.1039/C2NJ20929B, Letter.

Interested in reading further? Why not download the full articles now, FREE to access for a period of 4 weeks!

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Hot article : Why chromium Cr3+-doping is a catastrophe for catalysis.

In this NJC paper, Jean-Marie Herrmann (Institute of Researches on Catalysis and Environment of Lyon, France) investigated the chromium-doping of titania to tentatively photo-sensitize titania in the visible region and demonstrated why this strategy has proven to be a disaster in terms of photocatalytic activity.

In this study, the author explained the photo-electrical behavior of a Cr3+-doped titania catalyst in comparison with pristine titania, the related strong inhibition of titania’s catalytic performances and generalized this detrimental effect to all kinds of cationic dopings, either of n-type and/or p-type.

Detrimental cationic doping of titania in photocatalysis: why chromium Cr3+-doping is a catastrophe for photocatalysis, both under UV- and visible irradiations Jean-Marie Herrmann New J. Chem., 2012, Advance Article DOI: 10.1039/c2nj20914d

Interested in reading further? Why not download the full article now, FREE to access for a period of 4 weeks!

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Top ten most accessed articles in November

This month sees the following articles in New Journal of Chemistry that are in the top ten most accessed:-

Large scale synthesis of carbon nanospheres and their application as electrode materials for heavy metal ions detection 
Keming Pan, Hai Ming, Yang Liu and Zhenhui Kang 
New J. Chem., 2012, 36, 113-118 DOI:10.1039/c1nj20756c 

The influence of ultrasound on porphyrin-based metallogel formation: efficient control of H- and J-type aggregations 
Youngje Cho, Ji Ha Lee, Justyn Jaworski, Sunhong Park, Shim Sung Lee and Jong Hwa Jung 
New J. Chem., 2012, 36, 32-35 DOI:10.1039/c1nj20781d 

Silica-supported single-site catalysts: to be or not to be? A conjecture on silica surfaces 
David Gajan and Christophe Copéret 
New J. Chem., 2011, 35, 2403-2408 DOI:10.1039/c1nj20506d 

Synthesis and characterization of 1,7-disubstituted and 1,6,7,12-tetrasubstituted perylenetetracarboxy-3,4:9,10-diimide derivatives 
Mathieu Queste, Cyril Cadiou, Bernard Pagoaga, Louis Giraudet and Norbert Hoffmann 
New J. Chem., 2010, 34, 2537-2545 DOI:10.1039/c0nj00240b 

Preparation of graphene-TiO2 composites with enhanced photocatalytic activity 
Kangfu Zhou, Yihua Zhu, Xiaoling Yang, Xin Jiang and Chunzhong Li 
New J. Chem., 2011, 35, 353-359 DOI:10.1039/c0nj00623h 

Fluorescent carbon nanoparticles: electrochemical synthesis and their pH sensitive photoluminescence properties 
Haitao Li, Hai Ming, Yang Liu, Hang Yu, Xiaodie He, Hui Huang, Keming Pan, Zhenhui Kang and Shuit-Tong Lee 
New J. Chem., 2011, 35, 2666-2670 DOI:10.1039/c1nj20575g 

MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs) 
Christoph Janiak and Jana K. Vieth 
New J. Chem., 2010, 34, 2366-2388 DOI:10.1039/c0nj00275e 

Synthesis of surfactant-free self-assembled and size-controlled ZnS mesoporous nanospheres 
Qian Zhang, Wenyang Chi, Weiwei Zhang, Chunyan Lv and Jixue Li 
New J. Chem., 2012, 36, 119-124 DOI:10.1039/c1nj20727j 

One-pot hydrothermal synthesis of graphene quantum dots surface-passivated by polyethylene glycol and their photoelectric conversion under near-infrared light 
Jianhua Shen, Yihua Zhu, Xiaoling Yang, Jie Zong, Jianmei Zhang and Chunzhong Li 
New J. Chem., 2012, 36, 97-101 DOI:10.1039/c1nj20658c 

Porphyrin-functionalized Fe3O4@SiO2 core/shell magnetic colorimetric material for detection, adsorption and removal of Hg2+ in aqueous solution 
Lei Sun, Yaoxian Li, Mingda Sun, Hengguo Wang, Shufei Xu, Chaoqun Zhang and Qingbiao Yang 
New J. Chem., 2011, 35, 2697-2704 DOI:10.1039/c1nj20307j 

Why not take a look at the articles today and blog your thoughts and comments below.

Fancy submitting an article to New Journal of Chemistry? Then why not submit to us today or alternatively email us your suggestions.

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NJC Issue 1 out now !

We welcome you to NJC’s first issue of 2012. The new year gets off to a good start with the publication of high-quality, original and significant research works that display photosensitizers, dynamic combinatorial libraries, ab initio calculations, quantum dots, molecular magnets and much more.


The outside front cover highlights a contribution from Cristina Silva Pereira et al. (Universidade Nova de Lisboa, Portugal and Queen’s University of Belfast, UK) that was aimed at defining the mechanism of toxicity of alkyltributylphosphonium chlorides [P4 4 4 n]Cl (n = 1, 3–8, 10, 12 or 14) in conidia of the filamentous fungus Aspergillus nidulans. Systematic elongation of one of the alkyl substituents resulted generally in higher toxicity, as defined by their inhibitory and lethal effects. In this study, fluorescence microscopy is proposed as a direct method for assessing the impact of ionic liquids on the plasma membrane integrity. Data were complemented by microscopic evaluation of the conidia cell wall and morphology. The higher toxicity of phosphonium ionic liquids carrying long alkyl substituents is most likely due to their strong interaction with the conidia cellular boundaries.


“Unravelling the mechanism of toxicity of alkyltributylphosphonium chlorides in Aspergillus nidulans conidia”, Marija Petkovic, Diego O. Hartmann, Gabriela Adamová, Kenneth R. Seddon, Luís Paulo N. Rebelo and Cristina Silva Pereira, New J. Chem., 2012, 36, 56-63, DOI: 10.1039/C1NJ20470J.


NJC issue 1, 2012 inside front cover was produced by Dr Mike P. Coogan (Cardiff University, UK), Prof Lallan Mishra (Banaras Hindu University, India) and co-workers. In this research article, the authors describe the synthesis and study of a range of rhenium complexes appended through the axial pyridine ligand with groups known to direct cellular localisation. These complexes retain both their useful DNA binding and photophysical properties, while gaining the organelle specific-localisation desired. The imaging studies suggest that such complexes may be used as probes for oligonucleotides in specific cellular compartments (e.g. mitochondrial DNA). In addition, this study demonstrates that cellular localisation parameters are a vital consideration when designing probes to be applied in vivo.

“The importance of cellular localisation of probes: synthesis, photophysical properties, DNA interactions and cellular imaging properties of rhenium dppz complexes with known cellular localisation vectors”, Flora L. Thorp-Greenwood, Michael P. Coogan, Lallan Mishra, Niraj Kumari, Geeta Rai and Srikrishna Saripella, New J. Chem., 2012, 36, 64-72, DOI: 10.1039/C1NJ20662A.


You can access and read the whole issue available online at: NJC 2012, Issue 1. Leave us a comment and let us know what you think!


We wish you a happy new year 2012!

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NJC Hot Articles: our latest selection!

Check out NJC’s latest Hot Articles now available as Advance Articles on the web:


Dithiolene complexes as metallo-ligands

In this NJC Hot article Formigué and co-workers (research collaboration within France, Italy and Poland) describe the synthesis and behaviour of complexes between Ni(II) ion and crown ethers incorporating a dithiolene coordination motif. A nickel dithiolene complex substituted with crown ether cyclic moieties incorporating four O atoms, abbreviated as [Ni(S2O4)2]1,0, is isolated in its radical anionic (as Na+ salt) and neutral forms.

The results presented in this paper show that dithiolene complexes substituted with crown ether moieties, can be used as metallo-ligands toward 3d magnetic metal cations for the elaboration of more complex magnetic systems. This work opens new perspectives to the preparation of more complex magnetic structures applying a trivalent metal cations such as rare-earth cations as well as smaller crown-ether moieties.

Dithiolene complexes as metallo-ligands: a crown-ether approach by Alessia Famengo, Dalice Pinero, Olivier Jeannin, Thierry Guizouarn, Lidia Piekara-Sady and Marc Fourmigué; New J. Chem., 2012, Advance Article; DOI: 10.1039/C1NJ20870E, Paper


Purification of double-walled carbon nanotube macro-films

The authors of the next NJC Hot article, J. N. Wang and co-workers (China) present a new, interesting concept for macroscopic carbon nanotube films purification. They use thermal reduction using NH4Cl as reducing agent and gas-phase sublimation instead of liquid-phase purification with acids.

The most important advantage of this method over previous oxidation in acid is that nanotubes do not come into contact with potentially damaging acids, and thus the morphology and integrity of the macroscopic film are maintained.

Purification of double-walled carbon nanotube macro-films by Yun Chen, Shi Qing Xu and Jian Nong Wang; New J. Chem., 2012, Advance Article, DOI: 10.1039/C1NJ20866G, Letter



Glycodendrimers as functional antigens and antitumor vaccines

In this NJC Perspective article, Roy and Shiao (University of Montreal, Quebec, Canada) give an excellent and timely overview of the application of glycodendrimers in the field of actively pursued vaccine candidates against tumor associated carbohydrate antigens.

This perspective is composed of two parts, one describing the present state of the art of glycodendrimers, and another one presented all recent advances in glycoderived cancer vaccine. This article is part of the themed issue Dendrimers II, guest-edited by Jean-Pierre Majoral, to be out in the February issue of NJC.

Glycodendrimers as functional antigens and antitumor vaccines by Tze Chieh Shiao and René Roy; New J. Chem., 2012, Advance Article; DOI: 10.1039/C2NJ20873C; Perspective.

Interested in reading further?  Why not read by accessing the full article now!  This “Hot article” will be free to access for a period of 4 weeks.

If you have some of your own exciting, high impact research to publish then consider submitting your manuscript to NJCvia our online submission system.

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Presentation of NJC issue to Didier Astruc

Presentation of the October 2011 NJC issue to Prof. Didier Astruc took place during a symposium held in Bordeaux.

At the beginning of December I made the trip to Bordeaux to participate in a 2-day symposium that brought together many of the authors who contributed to the NJC issue in honor of Didier Astruc.

Former co-workers, current colleagues, friends from around the world were there, including Prof. Hiroshi Nishihara (who incidentally provided the artwork for the inside front cover to accompany his article in the October issue) and Dr. Yves Chauvin, who spoke at the presentation of this NJC issue to Didier.

From left to right: Yves Chauvin, Denise Parent, Didier Astruc, Jean-René Hamon

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Meet our Authors of the January issue of NJC

We are pleased to present a selection of our authors of the January issue of NJC. We thank each of them for accepting our invitation and having kindly taken some of their time to answer a few questions for us.

Our first author is Aharon Gendanken who is Professor of Chemistry at the Bar-Ilan University (Ramat-Gan, Israel). His current research interests are focused on nanochemistry. Sonochemistry is a method used in Aharon’s laboratory for synthesizing nanomaterials. One of the unique additional properties of the use of ultrasonic waves is the ability to create microspheres of proteins, starch, Chitosan, DNA and RNA in a one step short process. In his NJC paper, Aharon and co-workers examined whether they can apply this method to the preparation of Graphene Oxide spheres? The answer is yes, and the manuscript presents the technique.

“I think that NJC is treating very fairly papers that are submitted to the journal for publication. I have never experienced that the editors have rejected my paper before the refereeing process. After all the Editors in Chief and Assoc. Editors of a journal are great experts in science but the question is how wide is their knowledge? And many of their rejection are very questionable.”, says Aharon.

Outside of the lab, Aharon enjoys listening to Classical Music, and watching Sport on TV. He used to play soccer until 15 months ago and then hanged his shoes. If he could not be a scientific researcher, he would be a music conductor.

Graphene oxide microspheres prepared by a simple, one-step ultrasonication method by Matias Sametband, Ulyana Shimanovich and Aharon Gedanken, New J. Chem., 2012, 36, 36-39; DOI: 10.1039/C1NJ20738E, Letter.

Our next author is Cristina Silva Pereira, Assistant researcher at the Universidade Nova de Lisboa, (Lisbon, Portugal). Cristina’s research interests are centred on the understanding of fungal response to critical anthropogenic stresses, such as ionic liquids, and their potential utility for designing novel and environmentally friendly biotechnological processes.

In this issue of NJC, Cristina has authored the article Unravelling the mechanism of toxicity of alkyltributylphosphonium chlorides in Aspergillus nidulans conidia by Marija Petkovic, Diego O. Hartmann, Gabriela Adamová, Kenneth R. Seddon, Luís Paulo N. Rebelo and Cristina Silva Pereira, New J. Chem., 2012, 36, 56-63; DOI: 10.1039/C1NJ20470J, Paper. “A rapid method to detect the effects of industrially important ionic liquids in cellular boundaries of filamentous fungi conidia is proposed. After exposure to quaternary phosphonium ionic liquids carrying long alkyl substituents, severe membrane damage was almost immediately observed; this is known as baseline toxicity and exonerates the involvement of programmed cell death. ”, explains Cristina who chooses NJC for publication of this article as the NJC renders high interest for publishing multidisciplinary studies, with a chemical core, that cross borders of pure disciplines.

In her free time, Cristina loves spending time writing, reading and travelling to remote and uninhabited locations. If she could not be a scientist, she will be a writer.

Closing this month’s author selection, Mike Coogan is Senior lecturer at the Cardiff University UK (Cardiff, United Kingdom).

His current research interest is inorganic chemistry, specialising in the application of metal complexes in cell imaging and he has authored in this NJC issue the paper The importance of cellular localisation of probes: synthesis, photophysical properties, DNA interactions and cellular imaging properties of rhenium dppz complexes with known cellular localisation vectors by Flora L. Thorp-Greenwood, Michael P. Coogan, Lallan Mishra, Niraj Kumari, Geeta Rai and Srikrishna Saripella, New J. Chem., 2012, 36, 64-72; DOI: 10.1039/C1NJ20662A, Paper.

This paper shows that when designing probes for cell imaging the cellular uptake and localisation are vital parameters, which are often overlooked in favour of the purely analytical chemists’ approach of designing responsive molecules. They showed that rhenium dppz complexes which are known to act as DNA luminescence sensors can be tuned to highlight oligonucleotides in particular cell compartments (e.g. mitochondria) by tuning their localisation properties with additional ligands.

“I see NJC as a natural home for imaging studies which by their nature combine synthetic, analytical and biological chemistry, and so fit well with the interdisciplinary mission of this journal.”, says Mike.

Out of the lab, Mike’s favorite activity is walking in the hills. If he could not be a scientist, Mike will probably run a campsite – all the other options him though of such as naturalist are really scientists anyway and he don’t think you can be a professional hill-walker!

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