Painting the mountains blue

Vera Thoss tells Elinor Richards about her bluebell business and research, using her car in her experiments and analysing whale vomit

Vera Thoss lying in bluebell fieldVera Thoss is an environmental chemistry lecturer at Bangor University, UK. Her research is based on ecological chemistry, which addresses processes mediated through specific compounds within ecosystems and environmental chemistry, which is concerned with the impact of human activities on the environment.

What inspired you to become a scientist?

It all started when I was 13 and I had my first chemistry lesson. I instantly took to the subject and from then my mind was made up. I was also curious and wanted to ‘understand the world’.

What attracted you to environmental science?

As a chemist, the choice was between synthetic and analytical chemistry. I chose analytical chemistry because it allows you to follow the environmental fate of natural or man-made compounds. Being allowed to spend time in the woods was a big bonus!

What projects are you working on?

Currently, my group is working on oil pollution, composting and plant-derived products. It seems a bit of a stretch but it is all part of carbon cycling: plants build precious molecules, most of the time these remain intact but may transfer into air, water or soil. Crude oil is the remnants of sunken forests. So in the end, all the chemistry comes from plants photosynthesising and creating complex fragrances, tastes and colours. It is fascinating.

What will be the next big breakthrough in your field?

To chemically separate plant material into multiple useable compounds, with environmentally benign techniques, using as little energy as possible and ideally producing no waste at all.

Which achievements are you most proud of?

My beautiful daughter.  Last year I organised the first ‘Plants as Providers of Fine Chemicals’ conference, which was very successful.  I also managed to measure picogram amounts of monoterpenes in three-week-old Scots pine seedlings before they were eaten by slugs.

You own a farm from which you run a business selling bluebells called Vera Bluebell. How did this come about?

I was always concerned about the availability of clean drinking water, and moving to a mountain farm near Snowdon in Wales was a strategic choice (it does rain a lot!). Realising that there was abundance of bluebells on the land was a chance discovery after a fire. I was aware of their unusual chemistry though and that was the starting point for Vera Bluebell. Bluebells are protected, which means a license is needed to work with them. There was a demand for wild bluebells as well. We have now been sustainably managing a wild bluebell population for over six years and it has been an interesting journey. I would love to see a bluebell derived extract being used in a commercial product.

What discoveries have you made during your research on bluebells?

Bluebell seeds have a high oil content and the oil has an unusual composition. Even though this is the first chemical assessment of Hyacinthoides non-scripta oil, the chemistry is not earth-shattering. The ecology aspects gave room for more discoveries, for example we found seed stores on the site, meaning that possibly voles or shrew have collected the seeds for storage. This has never been reported before.

Tell us about your bluebell conservation efforts and how your research can help.

We are hoping to show that bluebell seeds can be a source of fine chemicals. We obtain an oil of unusual composition from the seeds. The residue contains iminosugars, which may be of use in future medicines. I am hoping that the compounds isolated from bluebell seeds will be of commercial value, which in turn means that the conservation of bluebells pays for itself. We are hoping to paint the mountains and woodlands blue again.

You’re involved with projects called BEACON and PROBECO. What are these and what is your role in both projects?

BEACON is all about biorefining, obtaining different compounds from the same plant feedstock. There are different feedstocks investigated in BEACON ranging from perennial rye grass to ivy. My role is to analyse whole plant composition and organise the ‘ Plants as Providers of Fine Chemicals ‘  conference. The PROBECO project was about the influence of monoterpenes on ecosystem processes in Caledonian Scots pine forests. These are very rare ecosystems. Individual pine trees smell different and the forest served as a study site to investigate the role of specific monoterpenes. I was the scientist analysing the smell of thousands of pine trees and we came up with the chemodiversity hypothesis.

In 2007, you worked with Welsh company Used Tyre Distillation Research to produce novel products from used tyres, in particular oil for fuelling cars. What was your role in the research? I read that your car was used to test the fuel. What was the result?

Again my role was to analyse the products. The oil was a complex mixture and we did see some interesting compounds in it. The tyre oil was noticeably energy dense, giving faster acceleration to the car, which has survived the experiment well!

In 2008, you had an odd request to analyse what was thought to be whale vomit (ambergris) on a North Wales beach. Why is whale vomit so important and what did you find?

I’ve had a few requests for the analysis of beach finds. Ambergris is sought after in the perfume industry, but we have yet to get our hands on some. Most samples were waxes or plastic, which possibly fell overboard, just aged in the sea.

What other odd things have you been asked to analyse?

Another nice in-house example for analysis was to trace a smell in the corridor back to its origin: we sampled air in the corridor outside my office and the terrible smell was found to be due to demolition work going on next door. If it stinks don’t automatically blame the chemists!

What do you do in your spare time?

I love gardening, farming and generally just being outdoors. I am an amateur bee keeper and enjoy spending time with my family.

Read the original article at Chemistry World, or Vera’s recent paper in the journal RSC Advances:

Triacylglycerol composition of British bluebell (Hyacinthoides non-scripta) seed oil
Vera Thoss, P J Murphy, Ray John Marriott and Thomas Wilson
DOI: 10.1039/C2RA20090B

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Dioxin 2012 Symposium

The 32nd International Symposium on Halogenated Persistent Organic Pollutants – Dioxin 2012

Cairns convention centre This year’s International Symposium on Halogenated Persistent Organic Pollutants will be held in Cairns, Australia, at the Cairns Convention Centre. The conference runs from 26-31 August 2012.

Each year, the International Dioxin Symposium provides an excellent opportunity for the presentation and discussion of the most current scientific research on POPs (Persistent Organic Pollutants) across all disciplines, including analytical and environmental chemistry, molecular biology, human health, risk assessment and risk management.

This year’s Symposium Chairs are Jochen Mueller and Caroline Gaus, from the National Research Centre for Environmental Toxicology (Entox) at the University of Queensland.

Cairns at nightA wide range of core topics on analytical and environmental chemistry, environmental and human toxicology, epidemiology, exposure assessment, as well as regulation, risk assessment and management will be covered. Dioxin 2012 will also feature discussion on important global and current regional issues, focusing on topics such as emerging contaminants, marine and eco-toxicology, and chemical regulation and policy. For more information on this exciting conference and details of how to register, please see the website.

In attendance at the conference will be Professor Beate Escher, Editorial Board Member and Associate Editor for the Journal of Environmental Monitoring. I’m sure she’d be delighted to meet you.

Important dates for your diaries:

Abstract submission opens – 7 March 2012
Registration – Now open
Abstract submission deadline – 14 May 2012
Notifications to submitters – 15 June 2012
Early bird registration closes – 22 June 2012

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Latest hot articles on understanding Cr(VI) generation in drinking water and the effect of organic matter on nanoparticle stabilisation

Dana Lindsay and colleagues at Manhattan College, USA, have conducted a study to better understand the rate and extent of carcinogenic CrVI generation following the disinfection of drinking water with chlorine.  Trace amounts of CrIII may be present in water supplies, but the extent to which this is oxidised to CrVI is poorly understood.  Lindsay and colleagues found that oxidation occurred within a matter of hours, and therefore could occur during water treatment plants, but plateaued at less than 100% conversion, even with relatively high doses of chlorine.

Oxidation of CrIII to CrVI during chlorination of drinking water
Dana R. Lindsay ,  Kevin J. Farley and Richard F. Carbonaro
J. Environ. Monit., 2012, Advance Article
DOI: 10.1039/C2EM00012A

Understanding the fate and transport of engineered nanoparticles in the environment is a key issue, this paper Jeffery Nason et al. have investigated the effect of natural organic matter on the stabilisation of nanoparticles in aquatic environments.  Their findings indicate that both the type and concentration of the organic matter, along with the ionic strength of the aquatic system are important factors in determining colloidal nanoparticle stability.

Effects of natural organic matter type and concentration on the aggregation of citrate-stabilized gold nanoparticles
Jeffrey A. Nason ,  Shannon A. McDowell and Ty W. Callahan
J. Environ. Monit., 2012, Advance Article
DOI: 10.1039/C2EM00005A

Both these papers are free to access for 4 weeks following a simple registration for individual users.

Dana R. Lindsay
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NEW critical review: How to assess the environmental impact associated with fish farming wastes

Researchers in Spain present an interesting critical review focusing on ways to assess the impact of fish farming waste waters on the environment in which they are situated.

The group outline the important environmental contaminants to be considered, including particulate waste and treatment products. As most fish farms are located on rocky coasts, the authors highlight the need for tools that are not affected by strong hydrodynamics and a lack of sediment. The review evaluates the suitability of various experimental and analytical procedures that can be used to evaluate the contamination, possible trophic and toxic effects, and changes to the ecological integrity.

Designing an integrated environmental monitoring plan for land-based marine fish farms located at exposed and hard bottom coastal areas
C. Carballeira, J. Ramos-Gómez, M. L. Martín-Díaz, T. A. DelValls and A. Carballeira
DOI: 10.1039/C2EM10839A

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JEM article on the radioactive fallout from Fukushima featured in the press

An article recently published in the journal has featured in the press this week.  The paper, which looks at trace levels of radioactivity in air, water, and milk samples in the United States over several weeks following the disaster, has been mentioned in an article in the International Business Times.

The article found that while levels of certain cadmium, technetium and iodide radionucleotides were elevated, these levels were still ‘well below any level of public and environmental concern’.

Read the full discussion of the results here:

Radioactive fallout in the United States due to the Fukushima nuclear plant accident
P. Thakur, S. Ballard and R. Nelson
J. Environ. Monit., 2012, DOI: 10.1039/C2EM11011C

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GE-RSC International Symposium on Water Re-use

The GE CTC-RSC International Symposium on Water Reuse to be held at the GE China Technology Center in Shanghai on 19-20 April 2012 will feature a selection of lectures covering water reuse, including water treatment technology and materials, water reuse and water reclamation.

This meeting is free to attend and will feature leading international scientists including Dr John Barber (GE), Prof. Guang-Hao Chen (Hong Kong University of Science and Technology), Prof. Jiahui Shao (Shanghai Jiaotong University) and Prof. David Stuckey (Imperial College, UK), plus a poster session.

Deadlines:

  • Poster abstract submission is Monday 9 April, 2012
  • Registration is Monday 16 April, 2012

More information and details of how to register can be found on the website.

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Top ten most accessed articles in February

This month sees the following articles in the Journal of Environmental Monitoring that are in the top ten most accessed:

Quantitation of persistent organic pollutants adsorbed on plastic debris from the Northern Pacific Gyre’s “eastern garbage patch”
Lorena M. Rios, Patrick R. Jones, Charles Moore and Urja V. Narayan
J. Environ. Monit., 2010, 12, 2226-2236
DOI: 10.1039/C0EM00239A

Elevated antimony concentrations in commercial juices
Claus Hansen, Alexandra Tsirigotaki, Søren Alex Bak, Spiros A. Pergantis, Stefan Stürup, Bente Gammelgaard and Helle Rüsz Hansen
J. Environ. Monit., 2010, 12, 822-824
DOI: 10.1039/B926551A

Impact of agglomeration and different dispersions of titanium dioxide nanoparticles on the human related in vitro cytotoxicity and genotoxicity
Zuzana Magdolenova, Dagmar Bilaničová, Giulio Pojana, Lise M Fjellsbø, Alexandra Hudecova, Katarina Hasplova, Antonio Marcomini and Maria Dusinska
J. Environ. Monit., 2012, 14, 455-464
DOI: 10.1039/C2EM10746E

Bioaerosol exposure assessment in the workplace: the past, present and recent advances
Wijnand Eduard, Dick Heederik, Caroline Duchaine and Brett James Green
J. Environ. Monit., 2012, 14, 334-339
DOI: 10.1039/C2EM10717A

The devil is in the details (or the surface): impact of surface structure and surface energetics on understanding the behavior of nanomaterials in the environment
Imali A. Mudunkotuwa and Vicki H. Grassian
J. Environ. Monit., 2011, 13, 1135-1144
DOI: 10.1039/C1EM00002K

Pharmaceuticals and personal care products in effluent matrices: A survey of transformation and removal during wastewater treatment and implications for wastewater management
Rebekah L. Oulton, Tamar Kohn and David M. Cwiertny
J. Environ. Monit., 2010, 12, 1956-1978
DOI: 10.1039/C0EM00068J

The release of engineered nanomaterials to the environment
Fadri Gottschalk and Bernd Nowack
J. Environ. Monit., 2011, 13, 1145-1155
DOI: 10.1039/C0EM00547A

The antibacterial effects of engineered nanomaterials: implications for wastewater treatment plants
Ndeke Musee, Melusi Thwala and Nomakhwezi Nota
J. Environ. Monit., 2011, 13, 1164-1183
DOI: 10.1039/C1EM10023H

Comparison of DNA extraction methodologies used for assessing fungal diversity via ITS sequencing
William R. Rittenour, Ju-Hyeong Park, Jean M. Cox-Ganser, Donald H. Beezhold and Brett J. Green
J. Environ. Monit., 2012, 14, 766-774
DOI: 10.1039/C2EM10779A

Biological monitoring versus air monitoring strategies in assessing environmental–occupational exposure
Marek Jakubowski
J. Environ. Monit., 2012, 14, 348-352
DOI: 10.1039/C1EM10706B

Why not take a look at the articles today and blog your thoughts and comments below.

Fancy submitting an article to JEM? Then why not submit to us today or alternatively email us your suggestions.

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The fate of titanium dioxide nanoparticles in soil on the cover of Issue 4

J. Environ. Monit. Cover Issue 4A hot article from Michael F. Hochella and colleagues Virginia Tech and Duke University is on the cover of our latest issue, describing their work to better understand the fate of TiO2 nanomaterials in soil, and their most likely route of entry into the environment.

Characterization and environmental implications of nano- and larger TiO2 particles in sewage sludge, and soils amended with sewage sludge
Bojeong Kim, Mitsuhiro Murayama, Benjamin P. Colman and Michael F. Hochella
J. Environ. Monit., 2012, 14, 1128-1136
DOI: 10.1039/C2EM10809G

Nanoparticles your thing? Have you seen the themed issue we published on Environmental Nanotechnology?

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Latest environmental news

Every month Mike Sharpe, MS Consulting & Research Ltd., UK, provides a roundup of the latest environmental news including recent EU and international legislation, environmental quality, chemical hazards and public and occupational health issues, as well as significant research activities.

Stroke risk from air pollution ‘rises in hours’Mike Sharpe discusses the latest environmental issues, including the conclusions of a study which links air pollution and an increased stoke risks.  Other public health issues discussed include air emissions of dioxins and the division between EU regulators and scientific experts on the adoption of the thresholds of toxicological concern (TTC) approach for chemical risk assessment.

Read the whole article which has much more news on recent environmental legislation and research.

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Latest hot articles in JEM on urban stormwater sampling and characterising titanium dioxide nanoparticles

C2EM10999A graphical abstractWilliam Selbig, Amanda Cox and Roger Bannerman discuss the development of a new water sample collection system, to improve representation of solids entrained in urban stormwater by integrating water-quality samples from the entire water column, rather than a single, fixed point. They report that development of this new depth-integrated sample arm (DISA) was able to mitigate stratification bias resulting in a more accurate representation of stormwater-borne solids than traditional fixed-point sample collection methods.

Verification of a depth-integrated sample arm as a means to reduce solids stratification bias in urban stormwater sampling
William R. Selbig, Amanda Cox and Roger T. Bannerman
DOI: 10.1039/C2EM10999A

C2EM10809G graphical abstractBojeong Kim and colleagues from Virginia Tech and Duke University have investigated the characterization and environmental implications of nano- and larger TiO2 particles in sewage sludge and soils amended with sewage. They examined the most likely route of engineered TiO2 particles entering the soil environment by using analytical electron microscopic techniques, and provided detailed information regarding their occurrence, fate and behaviour in the sewage sludge materials and in mesocosm soils that had been amended with biosolid products.

Characterization and environmental implications of nano- and larger TiO2 particles in sewage sludge, and soils amended with sewage sludge
Bojeong Kim, Mitsuhiro Murayama, Benjamin P. Colman and Michael F. Hochella
DOI: 10.1039/C2EM10809G

All our hot articles are free to access for four weeks following a simple registration for individual users.

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