HOT article: extracting pure CO2 from air

Using a combined temperature-vacuum swing (TVS) process which separates CO2 from atmospheric air, scientists from Switzerland have shown a stable performance over 40 consecutive adsorption/desorption cycles.

The adsorption/desorption cycles use a sorbent material made of diamine-functionalized commercial silica gel, and are performed under equilibrium and non-equilibrium (short-cycle) conditions. Therefore the CO2 capture capacity of the material can be determined over a wide range of pressures and temperatures.

Read this ‘HOT’ Energy & Environmental Science article today:

Separation of CO2 from air by temperature-vacuum swing adsorption using diamine-functionalized silica gel
Jan Andre Wurzbacher, Christoph Gebald and Aldo Steinfeld
Energy Environ. Sci., 2011, DOI: 10.1039/C1EE01681D

CO2 separation

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Hot article: high performance thermoelectric materials

This ‘HOT’ article experimentally demonstrates a successful combination of the complexity in the valence band structure with the addition of nanostructuring to create a high performance thermoelectric material.

nanostructuringRead the Energy & Environmental Science paper:

Combination of large nanostructures and complex band structure for high performance thermoelectric lead telluride
Yanzhong Pei, Nicholas A. Heinz, Aaron LaLonde and G. Jeffrey Snyder
Energy Environ. Sci., 2011, DOI: 10.1039/C1EE01928G

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HOT article: Li3N@C composites present full hydrogen release

H2 desorption

For the first time, Li3N@C composites are synthesized via the wet impregnation of mesoporous carbons with LiN3 solutions followed by a thermal treatment.

The resulting Li3N@C composites present excellent sorption kinetics and a full hydrogen release.

Read the paper:
Modification of the hydrogen storage properties of Li3N by confinement into mesoporous carbons
Rezan Demir-Cakan, Wan Si Tang, Ali Darwiche and Raphaël Janot
Energy Environ. Sci., 2011, DOI: 10.1039/C1EE01387D

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Tequila for your fuel tank

Researchers in the UK show that Agave – a plant used to make tequila and fibres for rope – is a handy alternative feedstock to corn or sugarcane in the production of bioethanol fuel.  

Bioethanol is a good clean fuel candidate as it only forms carbon dioxide and water during combustion and can be easily blended with crude oil to produce other fuels. However, the sustainability of large-scale biofuel production has recently been called into question because of mounting concerns over the impact on land and water resources. 

Now a team led by David King from the Low Carbon Mobility Centre at the University of Oxford has studied the viability of using Agave as an alternative feedstock because it can be grown in an arid environment. 

In the US, bioethanol is produced from corn, which is very water and fertiliser intensive and requires a significant amount of land. The result is a trade-off between feedstocks for the food markets and feedstocks for bioethanol production. In Brazil, bioethanol is produced using sugarcane. But again, land that could be used to grow food is needed to grow this and the question is: which is more important, food or fuel? 

Agave plants
‘Agave is a sort of cactus that grows in water restricted arid areas,’ says Oliver Inderwildi, one of the researchers. ‘This is essentially what we want – to produce fuel away from arable land.’ Inderwildi explains that the Agave feedstock, after harvesting, will be milled, cooked, fermented and then distilled – essentially using the same process as other ethanol production procedures. 

‘This is academic research in the very early stages,’ says Inderwildi. ‘However, there is no real shortage of desert land and lots of deprived areas are located on the edge of deserts, so this could be a method to utilise unused land and help rejuvenate deprived areas,’ he adds. 

‘There is no question this is a valuable first attempt at predicting the benefits of Agave-based biofuels,’ says Stephen Long, an expert in bioenergy from the University of Illinois at Urbana-Champaign, in the US. ‘But without systematic trials and measurements, the scale of the opportunity is unclear,’ he adds.

Inderwildi admits that there are still a few problems to iron out before Agave will be a commercially viable feedstock. ‘They are slow growing crops and up until now they have been harvested manually,’ he tells Chemistry World. ‘What you have at the moment is a labour issue and a yield issue, but we can work on increasing yields and automating the harvesting.’

The team at the Low Carbon Mobility Centre are also looking at other ways to produce biofuels from algae. ‘Fuels from algae can be used as diesel type fuels or kerosene,’ says Inderwildi. ‘Air New Zealand has already carried out a test flight using these fuels and performance is outstanding,’ he adds.

Even if Agave is used to produce our fuels in the future, tequila production or prices will be unaffected, according to Inderwildi.   ‘I’m not at all worried about the tequila supply in bars,’ he says.

Mike Brown

Read the Energy & Environmental Science article:

Life cycle energy and greenhouse gas analysis for agave-derived bioethanol
Xiaoyu Yan, Daniel K. Y. Tan, Oliver R. Inderwildi, J. A. C. Smith and David A. King, Energy Environ. Sci., 2011
DOI: 10.1039/c1ee01107c

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Tequila biofuel: EES paper featured in The Guardian

An Energy & Environmental Science article which analyses the use of agave (tequila) plants as a source of bio-ethanol has been featured in The Guardian today: Tequila gives new biofuel crops a shot

The work by scientists at the University of Oxford and The University of Sydney have shown that Agave – a plant used to make tequila – is an alternative feedstock to corn or sugarcane in the production of bioethanol fuel. They have studied the viability of using Agave as an alternative feedstock because it can be grown in an arid environment, away from arable land.

Bioethanol produced from corn and sugarcane is water and fertiliser intensive and requires a significant amount of land. The result is a trade-off between feedstocks for the food markets and feedstocks for bioethanol production.

Read the Energy & Environmental Science Analysis article:

Life cycle energy and greenhouse gas analysis for agave-derived bioethanol
Xiaoyu Yan, Daniel K. Y. Tan, Oliver R. Inderwildi, J. A. C. Smith and David A. King
Energy Environ. Sci., 2011, DOI: 10.1039/C1EE01107C

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The rise of the sodium ion battery: EES in C&EN

An Energy & Environmental Science Communication by Philipp Adelhelm and co-workers has been featured in an C&EN article Making Better Sodium-Ion Batteries.

The rise of the sodium ion battery: A nanostructured material has been used as an anode in a sodium ion battery for the first time and its performance is better than all carbon materials tested so far, say researchers from Germany.

Read the paper:

Room-temperature sodium-ion batteries: Improving the rate capability of carbon anode materials by templating strategies
S Wenzel, T Hara, J Janek and P Adelhelm, Energy Environ. Sci., 2011
DOI: 10.1039/c1ee01744f

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Hot Communication: paper supercapacitors

A simple solvent-free deposition method to fabricate flexible supercapacitors on cellulose paper using graphiteThe supercapacitors show stable long cycling performance and a high areal capacitance of 2.3 mF cm−2, which is much higher than the literature reported values. This solvent-free deposition technique represents a low cost, highly scalable and versatile fabrication method for integrated paper-based energy devices.

Read the Energy & Environmental Science Communication article:

Paper supercapacitors by a solvent-free drawing method
Guangyuan Zheng, Liangbing Hu, Hui Wu, Xing Xie and Yi Cui
Energy Environ. Sci., 2011, DOI: 10.1039/C1EE01853A

paper supercapacitor

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Poster Prizes at ICCDU XI

ICCDU winnerRSC Publishing was delighted to award three PhD Poster Prizes at the recent International Conference on Carbon Dioxide Utilization (ICCDU XI) held in June 2011, Dijon, France.

The winners were presented with RSC Prize certificates and either a free subscription to the journal or a financial award.

RSC Publishing journals will be awarding further Poster Prizes over the summer so watch this space!

The prize winners at ICCDU were:

Energy & Environmental Science Award:
Isabel VILLAFÁN-VIDALES
Title: THERMOCHEMICAL CO2 SPLITTING BASED ON FE3O4/FEO REDOX REACTIONS USING CONCENTRATED SOLAR ENERGY
Stéphane ABANADES and H. Isabel VILLAFÁN-VIDALES (CNRS-PROMES, France)

Green Chemistry Award:
Stephanie WILSON
Title: COUPLING REACTIONS OF CO2 AND UNEXPLORED EPOXIDES : POLYCARBONATE VS. CYCLIC CARBONATE FORMATION
Stephanie WILSON and Donald J. DARENSBOURG (Department of Chemistry, Texas A&M University, USA)

Journal of Materials Chemistry Award:
Mohd Bismillah ANSARI
Ttle: TRIAZINE BASED POROUS FRAMEWORKS FOR METAL FREE CO2 ACTIVATION
Mohd Bismillah ANSARI and Sang-Eon PARK (Department of Chemistry, Inha University, Republic of Korea)

Energy & Environmental Science and Green Chemistry will also be publishing a special web-theme collection of articles from the ICCDU conference.

Sign-up to the free e-alerts and newsletter to hear about the latest research published on CO2 utilization.

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Hot article: MOFs for post-combustion CO2 capture

Representative metal–organic frameworks were investigated for use in a post-combustion CO2 capture system. High-temperature, low-pressure adsorption isotherms were measured and analyzed in order to probe the performance of these materials in a temperature swing adsorption cycle.

Read this ‘HOT’ Energy & Environmental Science article today:

Evaluating metal–organic frameworks for post-combustion carbon dioxide capture via temperature swing adsorption
Jarad A. Mason, Kenji Sumida, Zoey R. Herm, Rajamani Krishna and Jeffrey. R. Long
Energy Environ. Sci., 2011, DOI: 10.1039/C1EE01720A

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Nanorobots powered from beneath the skin

Science fiction comes to life with the latest nanodevice that sits underneath the skin and converts near-infrared (NIR) light energy into electrical power. This is a promising wireless electrical power source for biological nanorobots for use within the human body, say scientists in Taiwan.

The nanodevice is an organic photovoltaic device (OPV) designed by Fang-Chung Chen and his team from National Chiao Tung University, in Hsinchu. OPVs are more commonly known for their applications in solar cell technology converting sunlight into electricity. 

Here, Chen has developed an OPV device that uses NIR light, enabling the energy conversion to occur underneath the skins surface as biological tissues are highly transparent to NIR light. Made up of several layers; including indium tin oxide (ITO)-coated glass, anodic buffer, polymer/fullerene-mixed layer and calcium/aluminium cathode, the device is small, the shape of a fibre, and is ideal for a biological environment.

laser photovoltaic device

The device, the size of a fibre, converts NIR radiation from a laser into electrical power

To test their theory, Chen’s team covered the OPV device with a 3mm layer of porcine skin and fired a NIR laser on it at the maximum threshold tolerated by human skin. The team measured the OPV electrical output as 0.32µW, which is more than enough to drive many biological nanodevices at the same time – the typical power needed for one nanodevice is approximately 10nW.

Yang Yang, Director of the Nano Renewable Energy Center, at the University of California, Los Angeles in the US, says: ‘This is a very interesting and smart design, which will be potentially important and useful for medical applications.   Chen has created a new direction for OPVs.’

‘In addition to tissue repair or medical target identification, this OPV device could act as an energy source to trigger biomedical functions of the nanorobots, or more straightforward applications in neurostimulation,’ Chen tells Chemistry World. ‘Imagine that, with this approach, we might be able to use optical methods, non-intrusively, to trigger the electrical stimulation deep inside the body to inhibit pain or to control the disease directly,’ he adds.

Emma Shiells

Read the Energy & Environmental Science article:

Near-infrared laser-driven polymer photovoltaic devices and their biomedical applications
Jyh-Lih Wu, Fang-Chung Chen, Ming-Kai Chuang and Kim-Shih Tan
Energy Environ. Sci., 2011
DOI: 10.1039/c1ee01723c

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