Archive for April, 2015

Membrane-less water splitting device

A water splitting electrolyser typically contains an ion-conducting membrane which separates the electrodes and keeps the oxygen and hydrogen apart, preventing explosion. However, these membranes are expensive and thus the development of a membrane-less electrolyser is an exciting advance. Researchers at Swiss Federal Institute of Technology Lausanne, led by Demetri Psaltis, have developed such a device by exploiting the Segré–Silberberg effect. The oxygen and hydrogen are kept separate as the distance between the two electrodes is less than a few hundred micrometres and they do not mix because lift forces in the narrow passage push them towards the wall they evolved from.This is a microfluidic device that provides promising proof-of-concept and the group are now attempting to scale up.

Want to know more?

Read the full article in Chemistry World by Isobel Marr.

Or, take a look at the original article which is free to access untill 1st June 2015:

A membrane-less electrolyzer for hydrogen production across the pH scale” by S. Mohammad H. Hashemi,  Miguel A. Modestino and Demetri Psaltis, DOI:10.1039/C5EE00083A

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Ultrasound test echos with battery charge

Measuring the charge within a battery can often involve the use of expensive equipment such as synchrotron light sources, which are not accessible to all researchers. However, scientists at Princeton University lead by Dr Daniel Steingart have developed a method of using ultrasound echoes to measure charge within a battery at different times, giving physical insight into a battery’s state. This ultrasomic imaging of what is happening inside a cell could prove to be useful commercially.

Want to know more?

Read the full article in Chemistry World by Osman Mohamed.

Or, take a look at the original article which is free to access untill 2nd June 2015:

Electrochemical-acoustic time of flight: in operando correlation of physical dynamics with battery charge and health by A. G. Hsieh, S. Bhadra, B. J. Hertzberg,  P. J. Gjeltema, A. Goy,  J. W. Fleischer and  D. A. Steingart, DOI: 10.1039/C5EE00111K.

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HOT Articles in EES

The following HOT articles have been highlighted by the reviewers of the articles as being particularly interesting or significant pieces of research. These are all free to access until 15/05/2015. The order they appear in the list has no meaning or ranking.

Positive onset potential and stability of Cu2O-based photocathodes in water splitting by atomic layer deposition of a Ga2O3 buffer layer
Changli Li, Takashi Hisatomi, Osamu Watanabe, Mamiko Nakabayashi, Naoya Shibata, Kazunari Domen and Jean-Jacques Delaunay
DOI: 10.1039/C5EE00250H, Paper

C5EE00250H GA

Toward the rational design of non-precious transition metal oxides for oxygen electrocatalysis
Wesley T. Hong, Marcel Risch, Kelsey A. Stoerzinger, Alexis Grimaud, Jin Suntivich and Yang Shao-Horn
DOI: 10.1039/C4EE03869J, Review Article

C4EE03869J GA

Tracking the structural arrangement of ions in carbon supercapacitor nanopores using in situ small-angle X-ray scattering
C. Prehal, D. Weingarth, E. Perre, R. T. Lechner, H. Amenitsch, O. Paris and V. Presser
Journal Article
DOI: 10.1039/C5EE00488H, Paper

C5EE00488H GA

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