EES Issue 1 of 2014 out now!

Graphical abstract: Front coverThe latest issue of EES is now online. You can read the full issue here.

The outside front cover features the paper Energy applications of ionic liquids by Douglas R. MacFarlane, Naoki Tachikawa, Maria Forsyth, Jennifer M. Pringle, Patrick C. Howlett, Gloria D. Elliott, James H. Davis, Masayoshi Watanabe, Patrice Simon and C. Austen Angell.

Constructing ionic highway in alkaline polymer electrolytes is the paper highlighted on the inside front cover by Jing Pan, Chen Chen, Yao Li, Lei Wang, Lisheng Tan, Guangwei Li, Xun Tang, Li Xiao, Juntao Lu and Lin Zhuang.

Issue 11 contains a number of excellent Opinion, Analysis, Review, Minireview and Perspective articles:

Electrochemical energy storage in a sustainable modern society
John B. Goodenough

Reflections on the topic of solar fuels
John Meurig Thomas

The renaissance of energy innovation
Jim Skea

Piezoelectric and ferroelectric materials and structures for energy harvesting applications
C. R. Bowen, H. A. Kim, P. M. Weaver and S. Dunn

Physics and chemistry of CdTe/CdS thin film heterojunction photovoltaic devices: fundamental and critical aspects
S. Girish Kumar and K. S. R. Koteswara Rao

Upgrading of lignin-derived bio-oils by catalytic hydrodeoxygenation
Majid Saidi, Fereshteh Samimi, Dornaz Karimipourfard, Tarit Nimmanwudipong, Bruce C. Gates and Mohammad Reza Rahimpour

Carbon capture and storage update
Matthew E. Boot-Handford, Juan C. Abanades, Edward J. Anthony, Martin J. Blunt, Stefano Brandani, Niall Mac Dowell, José R. Fernández, Maria-Chiara Ferrari, Robert Gross, Jason P. Hallett, R. Stuart Haszeldine, Graphical abstract: Inside front coverPhilip Heptonstall, Anders Lyngfelt, Zen Makuch, Enzo Mangano, Richard T. J. Porter, Mohamed Pourkashanian, Gary T. Rochelle, Nilay Shah, Joseph G. Yao and Paul S. Fennell

Energetic I–III–VI2 and I2–II–IV–VI4 nanocrystals: synthesis, photovoltaic and thermoelectric applications
Feng-Jia Fan, Liang Wu and Shu-Hong Yu

Lithium ion battery applications of molybdenum disulfide (MoS2) nanocomposites
Tyler Stephenson, Zhi Li, Brian Olsen and David Mitlin

Energy applications of ionic liquids
Douglas R. MacFarlane, Naoki Tachikawa, Maria Forsyth, Jennifer M. Pringle, Patrick C. Howlett, Gloria D. Elliott, James H. Davis, Masayoshi Watanabe, Patrice Simon and C. Austen Angell

The panoscopic approach to high performance thermoelectrics
Li-Dong Zhao, Vinayak P. Dravid and Mercouri G. Kanatzidis

Transparent paper: fabrications, properties, and device applications
Hongli Zhu, Zhiqiang Fang, Colin Preston, Yuanyuan Li and Liangbing Hu

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2nd International Conference on Clean Energy Science – oral abstract deadline approaching

2nd International Conference on Clean Energy Science (ICCES2) 13-16 April 2014, Qingdao, China

The oral abstract deadline for the 2nd International Conference on Clean Energy Science (ICCES2) is rapidly approaching so don’t miss your chance to take part in this important event and showcase your research alongside the following distinguished speakers:

  • Xinhe Bao
  • Guillermo Bazan
  • James Clark
  • Eric Diau
  • Shunichi Fukuzumi
  • Frederik Krebs
  • Changjun Liu
  • Rafael Luque
  • Doug MacFarlane
  • Ryong Ryoo
  • He Tian
  • Peng Wang
  • Shu-Hong Yu
  • Hua Zhang
  • Dongyuan Zhao

The oral abstract deadline is 5 January 2014. Submit an abstract today for your chance to present at this engaging event.

Submit

Energy & Environmental Science (EES) is pleased to support the conference and Professor Thomas Jaramillo will give the 2013 Energy & Environmental Science Readers’ Choice Award Lecture at the conference.

Many of the high profile speakers have published some of their best work in Energy & Environmental Science:

Read a selection of their articles today:

Food waste as a valuable resource for the production of chemicals, materials and fuels. Current situation and global perspective
Carol Sze Ki Lin, Lucie A. Pfaltzgraff, Lorenzo Herrero-Davila, Egid B. Mubofu, Solhy Abderrahim, James H. Clark, Apostolis A. Koutinas, Nikolaos Kopsahelis, Katerina Stamatelatou, Fiona Dickson, Samarthia Thankappan, Zahouily Mohamed, Robert Brocklesby and Rafael Luque
DOI: 10.1039/C2EE23440H

Very high energy density silicide–air primary batteries
Hua Zhang, Xing Zhong, Jonathan C. Shaw, Lixin Liu, Yu Huang and Xiangfeng Duan
DOI: 10.1039/C3EE41157E

New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
Kendra P. Kuhl, Etosha R. Cave, David N. Abramc and Thomas F. Jaramillo
DOI: 10.1039/C2EE21234J

Flexible graphene–polyaniline composite paper for high-performance supercapacitor
Huai-Ping Cong, Xiao-Chen Ren, Ping Wang and Shu-Hong Yu
DOI: 10.1039/C2EE24203F

Highly active Pt–Fe bicomponent catalysts for CO oxidation in the presence and absence of H2
Hong Xu, Qiang Fu, Yunxi Yao and Xinhe Bao
DOI: 10.1039/C1EE02393D

All printed transparent electrodes through an electrical switching mechanism: A convincing alternative to indium-tin-oxide, silver and vacuum
Thue T. Larsen-Olsen, Roar R. Søndergaard, Kion Norrman, Mikkel Jørgensen and Frederik C. Krebs
DOI: 10.1039/C2EE23244H

Optimization of energy levels by molecular design: evaluation of bis-diketopyrrolopyrrole molecular donor materials for bulk heterojunction solar cell
Bright Walker, Jianhua Liu, Chunki Kim, Gregory C. Welch, Jin Keun Park, Jason Lin, Peter Zalar, Christopher M. Proctor, Jung Hwa Seo, Guillermo C. Bazan and Thuc-Quyen Nguyen
DOI: 10.1039/C3EE24351F

A facile approach for the synthesis of monolithic hierarchical porous carbons – high performance materials for amine based CO2 capture and supercapacitor electrode
Luis Estevez, Rubal Dua, Nidhi Bhandari, Anirudh Ramanujapuram, Peng Wang and Emmanuel P. Giannelis
DOI: 10.1039/C3EE40549D

Ordered mesoporous carbons and their corresponding column for highly efficient removal of microcystin-LR
Wei Teng, Zhangxiong Wu, Jianwei Fan, Hong Chen, Dan Feng, Yingying Lv, Jinxiu Wang, Abdullah M. Asiri and Dongyuan Zhao
DOI: 10.1039/C3EE41775A

High Seebeck coefficient redox ionic liquid electrolytes for thermal energy harvesting
Theodore J. Abraham, Douglas R. MacFarlane and Jennifer M. Pringle
DOI: 10.1039/C3EE41608A

Enveloping porphyrins for efficient dye-sensitized solar cells
Chin-Li Wang, Chi-Ming Lan, Shang-Hao Hong, Yi-Fen Wang, Tsung-Yu Pan, Chia-Wei Chang, Hshin-Hui Kuo, Ming-Yu Kuo, Eric Wei-Guang Diau and Ching-Yao Lin
DOI: 10.1039/C2EE03308A

Water-soluble mononuclear cobalt complexes with organic ligands acting as precatalysts for efficient photocatalytic water oxidation
Dachao Hong, Jieun Jung, Jiyun Park, Yusuke Yamada, Tomoyoshi Suenobu, Yong-Min Lee, Wonwoo Nam and Shunichi Fukuzumi
DOI: 10.1039/C2EE21185H

High-conversion-efficiency organic dye-sensitized solar cells: molecular engineering on D–A–π-A featured organic indoline dyes
Yongzhen Wu, Magdalena Marszalek, Shaik M. Zakeeruddin, Qiong Zhang, He Tian, Michael Grätzel and Weihong Zhu
DOI: 10.1039/C2EE22108J

For full details of how you can get involved in the 2nd International Conference on Clean Energy Science (ICCES2), please visit the dedicated webpage.

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Notes from the Non-Energy Sector: A Broad Model for Emissions Reduction

In a new broad analysis researchers model the impact of fossil fuels for non-energy purposes vs. lower-emission alternatives, such as the use of biomass.

In research and popular media, much attention is focused on the impact of fossil fuels used for energy purposes. In a new EES paper, researchers focus instead on the non-energy uses of fossil fuels, their impact, and lower-emissions alternatives. Non-energy uses are defined as “fuels that are used as raw materials […] and are not consumed as a fuel or transformed into another fuel,” and primarily include feedstock for chemical production of ethylene, methanol, and ammonia, and oil products like waxes and lubricants. Coal, gas, and oil usage for non-energy purposes currently account for up to 7% of global CO2 emissions.

In their paper, Daioglou et al. present a global model for emissions reduction in non-energy processes, called the Non-Energy Demand and Emissions Model, or NEDE. This model projects that the global demand of non-energy processes will more than double over the next 100 years. Their analysis explores the alternative of using biomass for feedstock chemical production, promoting fuel switching in climate policy, and post-consumer waste management such as mechanical recycling and cascading processes. By comparing current usage and feedstock substitution costs, and by projecting based on economic, population, and fuel price developments, the model predicts that substituting fossils fuels, particularly coal, with biomass for non-energy purposes could significantly reduce emissions. Post-consumer waste management processes are currently too inefficient to significantly reduce emissions; however, climate policy that promotes fuel switching through carbon taxation can help to implement emissions-reducing practices.

It is interesting that Daioglou et al. point out that there are currently a lack of broad studies on the emission reduction potential of using biomass in non-energy processes, as was apparently pointed out in the recent Special Report on Renewable Energy Sources of the Intergovernmental Panel on Climate Change. Speaking as someone outside of this field of research, I would say that lowering emissions of non-energy processes certainly takes a back seat in the media to the use of fossil fuels for energy purposes. While the relative impact of non-energy processes may seem small by comparison, if the NEDE model is correct then analyses such as this one will grow increasingly important. As the authors note, there is still much research to be done to determine if biomass is optimal for reducing emissions for non-energy purposes, but his broad analysis is certainly a good start.

Read more in the full EES article here:

Energy Demand and Emissions of the Non-Energy Sector
Vassilis Daioglou, Andre Faaij, Deger Saygin, Birka Wicke, Martin Patel and Detlef Peter van Vuuren
Energy Environ. Sci., 2013, Accepted Manuscript
DOI: 10.1039/C3EE42667J

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Transparent nanopaper for the next generation of renewable, flexible electronics

The next generation of flexible electronic devices will use transparent nanopaper, a flexible, renewable and tunable substrate that can be used in thin film resistors, organic light emitting diodes and organic photovoltaics.

Hybrid NFC nanopaper

Renewable, flexible paper electronics have been a tantalizing prospect for quite a while, yet they suffered from significant flaws including large surface roughness and high opacity.  New techniques have been developed to extract what is known as nanofibril cellulose (NFC) from natural wood fibers.  The paper that can be made from NFC has high transparency, extremely low surface roughness and good mechanical properties.  This review article covers fabrication techniques for nanopaper, optical and mechanical properties of the nanopaper, and devices constructed using electronics on transparent nanopaper.

While researchers are still working to develop high throughput, low energy fabrication techniques for nanopapers, the currently developed techniques have already yielded paper with exciting properties.  The optical transparency of the nanopaper can be as high as 90%, and the amount of haze can be tuned to optimize for a variety of applications.  High haze is ideal for light scattering in photovoltaics and in screens for outdoor viewing, while low haze is optimal for high clarity screens for indoor viewing.  Nanopaper also has extremely low surface roughness (5 nm), high mechanical strength and low thermal expansion.

Organic LED made using transparent nanopaper

These physical and optical properties make nanopaper an ideal medium for the next generation of flexible electronics.  When coated with a conductive layer such as ITO, carbon nanotubes or silver nanowires, the conductivity of the nanopaper is high enough to allow it to be used in thin film transistors and organic LEDs.  Though not yet as efficient as plastic substrates, nanopaper can also be used to make organic photovoltaics with much higher efficiencies than those with paper substrates.  Finally, researchers have created a resistive touch screen from nanopaper – one that outperforms PET (polyethylene terephthalate) in sunny conditions.

Want to know more?  Check out the full article in EES today!

Transparent paper: fabrications, properties, and device applications

Hongli Zhu, Zhiqiang Fang, Colin Preston, Yuanyuan Li and Liangbing Hu

DOI: 10.1039/c3ee43024c

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Rewarding Excellence, Gaining recognition

Up to £5,000 prize money

The Royal Society of Chemistry’s Prizes and Awards recognise achievements by individuals, teams and organisations in advancing the chemical sciences. There are over 80 Prizes and Awards available covering all areas of the chemical sciences.

You still have time to make your nomination before the deadline on 15th January 2014

As well as the cash prize of up to £5,000 and an inscribed medal , all Prize and Award winners are given the opportunity to present their work to the wider community by giving lectures at several universities around the UK.

Prizes are available in the categories various categories, including Biosciences, Environment, Sustainability and Energy, Materials Chemistry, Physical Chemistry and Industry & Technology.

Please nominate someone or be nominated by a Royal Society of Chemistry member by visiting

http://www.rsc.org/ScienceAndTechnology/Awards/2014-RSC-Prizes-Awards.asp

The publicity associated with my RSC Award resulted in the increased recognition for all my great colleagues who contributed and supported this programme over the years.” Monica Papworth

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This week’s HOT articles

Take a look at this week’s selection! These articles are available free for a limited time: Graphical abstract: Use of potential determining ions to control energetics and photochemical charge transfer of a nanoscale water splitting photocatalyst

Use of potential determining ions to control energetics and photochemical charge transfer of a nanoscale water splitting photocatalyst
Rachel L. Chamousis and Frank E. Osterloh
DOI: 10.1039/C3EE42993H, Paper

A fast, inexpensive method for predicting overcharge performance in lithium-ion batteries
Susan A. Odom, Selin Ergun, Pramod P. Poudel and Sean R. Parkin
DOI: 10.1039/C3EE42305K, Paper

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Photophysical mechanisms for exceeding the Shockley-Queisser limit in solar energy conversion

Martina Congiu is a guest web-writer for Energy and Environmental Science. Martina is currently a Research Technician in Dr Henry Snaith’s group at the University of Oxford. During her free time from work, she loves cooking and cycling in the outskirts of Oxford.

Researchers are focused on novel solar cells designs with power conversion efficiencies that exceed the Shockely-Queisser limit. Hot carrier solar cells (HCSC) and multi-exciton generation (MEG) technology aim to reduce thermalization and band gap losses, which together account for >55% of the total absorbed solar energy.

Hot carrier equilibration and carrier multiplication in both molecular and nano materials are two photophysical mechanisms discussed in this paper for implementation in third generation photovoltaics.

Carrier-carrier scattering must be ensured to achieve high efficiency HCSC, as well as inefficient carrier-phonon scattering. The photon flux parameter is a challenge that still need to be addressed, but graphene and related two-dimensional materials seem to be promising.

Multi-exciton solar cells can offer an actual implementation especially for singlet fission in organic semiconductors, which have shown exceptional quantum efficiency of 200% and lots of potential for new molecule designs.

Interested in  better understanding this field? Read more in this Perspective article:

Exceeding the Shockley–Queisser limit in solar energy conversion
Cory A. Nelson, Nicholas R. Monahan and X.-Y. Zhu
DOI: 10.1039/C3EE42098A

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EES now features Altmetrics

 We are pleased to announce the inclusion of Altmetrics on EES.

With a constantly changing publishing landscape and changes to the way people use scientific literature, altmetrics is a measure that can monitor the level of conversation and interest in a particular piece of research at the article level. Thus altmetrics provides an additional modern metric for our authors to measure the impact of their work, rather than rely solely on citations and impact factor.

To view altmetrics on EES articles, use the Metrics tab as pictured below on the article landing page.

 

 

A press release from Altmetrics is available on our website.

What do you think? We are interested to hear your feedback on this new development and how you are utilising these new types of metrics. Please leave your comments below.

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This week’s HOT articles

Take a look at this week’s selection! These articles are available free for a limited time:Graphical abstract: Strongly coupled carbon nanofiber–metal oxide coaxial nanocables with enhanced lithium storage properties

Strongly coupled carbon nanofiber–metal oxide coaxial nanocables with enhanced lithium storage properties
Genqiang Zhang, Hao Bin Wu, Harry E. Hoster and Xiong Wen (David) Lou
DOI: 10.1039/C3EE43123A, Communication

Upgrading of lignin-derived bio-oils by catalytic hydrodeoxygenation
Majid Saidi, Fereshteh Samimi, Dornaz Karimipourfard, Tarit Nimmanwudipong, Bruce C. Gates and Mohammad Reza Rahimpour
DOI: 10.1039/C3EE43081B, Review Article

Human hair-derived carbon flakes for electrochemical supercapacitors
Wenjing Qian, Fengxia Sun, Yanhui Xu, Lihua Qiu, Changhai Liu, Suidong Wang and Feng Yan
DOI: 10.1039/C3EE43111H, Paper

Lithium and oxygen vacancies and their role in Li2O2 charge transport in Li–O2 batteries
J. B. Varley, V. Viswanathan, J. K. Nørskov and A. C. Luntz
DOI: 10.1039/C3EE42446D, Paper

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Scorched hair makes supercapacitors greener – EES article in Chemistry World

Researchers in China have used human hair to make a vital component of energy-storage devices. The discovery could lead to more efficient and environmentally-friendly replacements for traditional batteries.

Many batteries currently in use, such as the lead–acid batteries in cars, are heavy and bulky and rely on hazardous chemicals to store electrical charge. With increasing worldwide sales of mobile electronics, the environmental impact of batteries is receiving more attention and motivating research into supercapacitors, which can be made from sustainable carbon-based materials.

Unfortunately, these carbon materials are usually either difficult to manufacture or derived from fossil fuels. Now, however, Feng Yan and his team at Soochow University have used a simple carbonisation process to turn human hair – a common and renewable waste product – into carbon flakes suitable for use in supercapacitor electrodes.

Interested to know more? Read the full news article by Stephan McCarthy in Chemistry World here…

Read the article by Wenjing Qian et al. in EES:

Human Hair-Derived Carbon Flakes for Electrochemical Supercapacitors
Wenjing Qian, fFengxia Sun, Yanhui Xu, Lihua Qiu, Chang-Hai Liu, Sui-Dong Wang and Feng Yan
Energy Environ. Sci., 2013, Accepted Manuscript
DOI: 10.1039/C3EE43111H, Paper

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