Author Archive

Salting out artificial photosynthesis

Chemical engineers from the US have put forward a concept for a new type of artificial photosynthetic system to convert carbon dioxide into almost pure liquid ethanol fuel. It uses a saturated salt electrolyte, and, according to their calculations, the system would be capable of generating 15.27 million gallons of ethanol per year per square kilometre.

You can read the article written by William Bergius which was published recently by Chemistry World.

Read the original full article based on M R Singh and A T Bell, Energy Environ. Sci., 2016, DOI: 10.1039/c5ee02783g here.

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Status of Photoelectrochemical Water Splitting: Past, Present, and Future

EES are pleased to announce that the Status of Photoelectrochemical Water Splitting: Past, Present, and Future collection, organised by Shane Ardo (The University of California), is now online.

Photoelectrochemical water splitting represents a promising path toward renewable and economical hydrogen generation using sunlight and water as the only inputs. In order to rapidly advance this technology to market-ready status, “all hands on deck” are needed from the scientific and engineering communities.

The aim of this themed collection is to inform those in the photoelectrochemistry field of historical and notable research findings and demonstrations, and to discuss the opportunities and key barriers to achieving this ambitious goal.

The collection consists of five articles written by experts in the field, describing the current state-of-the-art demonstrations in solar water splitting, approaches to band-structure engineering of semiconductor materials for optimized performance, characterization on small length scales and fast time scales, and efficiency definitions.

Renewable hydrogen generation is a timely topic given the recent expansion of mass-produced, commercially available hydrogen fuel cell vehicles.  This, combined with environmental pressures to move toward a carbon-free energy supply, create an urgent need for rapid discovery, development, and growth of hydrogen generation technologies that are stable, efficient, inexpensive, and sustainable.

View the below articles or access the full collection here.


Particle suspension reactors and materials for solar-driven water splitting
David M. Fabian, Shu Hu, Nirala Singh, Frances A. Houle, Takashi Hisatomi, Kazunari Domen, Frank E. Osterloh and Shane Ardo
Energy Environ. Sci., 2015, 8, 2825-2850
DOI: 10.1039/C5EE01434D


Methods of photoelectrode characterization with high spatial and temporal resolution
Daniel V. Esposito, Jason B. Baxter, Jimmy John, Nathan S. Lewis, Thomas P. Moffat, Tadashi Ogitsu, Glen D. O’Neil, Tuan Anh Pham, A. Alec Talin, Jesus M. Velazquez and Brandon C. Wood
Energy Environ. Sci., 2015, 8, 2863-2885
DOI: 10.1039/C5EE00835B

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HOT Articles in EES

The following HOT articles have been highlighted by the reviewers of the articles as being particularly interesting or significant pieces of research. These are all free to access until 30/9/2015. The order they appear in the list has no meaning or ranking.


Sodium intercalation chemistry in graphite
Haegyeom Kim, Jihyun Hong, Gabin Yoon, Hyunchul Kim, Kyu-Young Park, Min-Sik Park, Won-Sub Yoon and Kisuk Kang
Journal Article
DOI: 10.1039/C5EE02051D, Paper

C5EE02051D GA


Broadband and ultrahigh optical haze thin films with self-aggregated alumina nanowire bundles for photovoltaic applications
Gumin Kang, Kyuyoung Bae, Minwoo Nam, Doo-Hyun Ko, Kyoungsik Kim and Willie J. Padilla
Journal Article
DOI: 10.1039/C5EE01757B, Communication

C5EE01757B GA


Functional integration of Ni–Mo electrocatalysts with Si microwire array photocathodes to simultaneously achieve high fill factors and light-limited photocurrent densities for solar-driven hydrogen evolution
Matthew R. Shaner, James R. McKone, Harry B. Gray and Nathan S. Lewis
Journal Article
DOI: 10.1039/C5EE01076D, Paper

C5EE01076D GA


Reducing the charging voltage of a Li–O2 battery to 1.9 V by incorporating a photocatalyst
Yang Liu, Na Li, Shichao Wu, Kaiming Liao, Kai Zhu, Jin Yi and Haoshen Zhou
Journal Article
DOI: 10.1039/C5EE01958C, Communication

C5EE01958C GA


Biomass oxidation to formic acid in aqueous media using polyoxometalate catalysts – boosting FA selectivity by in-situ extraction
Jenny Reichert, Birgit Brunner, Andreas Jess, Peter Wasserscheid and Jakob Albert
Journal Article
DOI: 10.1039/C5EE01706H, Paper

C5EE01706H GA


Balancing the bioeconomy: supporting biofuels and bio-based materials in public policy
Jim Philp
Journal Article
DOI: 10.1039/C5EE01864A, Opinion

C5EE01864A GA


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HOT Articles in EES

The following HOT articles have been highlighted by the reviewers of the articles as being particularly interesting or significant pieces of research. These are all free to access until 18/06/2015. The order they appear in the list has no meaning or ranking.


A thermodynamic tank model for studying the effect of higher hydrocarbons on natural gas storage in metal–organic frameworks
Hongda Zhang, Pravas Deria, Omar K. Farha, Joseph T. Hupp and Randall Q. Snurr
DOI: 10.1039/C5EE00808E, Paper

C5EE00808E GA


Hydrogen or batteries for grid storage? A net energy analysis
Matthew A. Pellow, Christopher J. M. Emmott, Charles J. Barnhart and Sally M. Benson
DOI: 10.1039/C4EE04041D, Analysis

C4EE04041D GA


A quantitative analysis of the efficiency of solar-driven water-splitting device designs based on tandem photoabsorbers patterned with islands of metallic electrocatalyst
Yikai Chen, Ke Sun, Heather Audesirk, Chengxiang Xiang and Nathan S. Lewis
DOI: 10.1039/C5EE00311C, Paper

C5EE00311C GA


Metal–organic frameworks and their derived nanostructures for electrochemical energy storage and conversion
Wei Xia, Asif Mahmood, Ruqiang Zou and Qiang Xu
DOI: 10.1039/C5EE00762C, Review Article

C5EE00762C GA


You can’t have an energy revolution without transforming advances in materials, chemistry and catalysis into policy change and action
Geoffrey A. Ozin
DOI: 10.1039/C5EE00907C, Perspective

C5EE00907C GA


A simple spiro-type hole transporting material for efficient perovskite solar cells
Paramaguru Ganesan, Kunwu Fu, Peng Gao, Ines Raabe, Kurt Schenk, Rosario Scopelliti, Jingshan Luo, Lydia H. Wong, Michael Grätzel and Mohammad Khaja Nazeeruddin
DOI: 10.1039/C4EE03773A, Communication

C4EE03773A GA

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HOT Articles in EES

The following HOT articles have been highlighted by the reviewers of the articles as being particularly interesting or significant pieces of research. These are all free to access until 15/05/2015. The order they appear in the list has no meaning or ranking.

Positive onset potential and stability of Cu2O-based photocathodes in water splitting by atomic layer deposition of a Ga2O3 buffer layer
Changli Li, Takashi Hisatomi, Osamu Watanabe, Mamiko Nakabayashi, Naoya Shibata, Kazunari Domen and Jean-Jacques Delaunay
DOI: 10.1039/C5EE00250H, Paper

C5EE00250H GA

Toward the rational design of non-precious transition metal oxides for oxygen electrocatalysis
Wesley T. Hong, Marcel Risch, Kelsey A. Stoerzinger, Alexis Grimaud, Jin Suntivich and Yang Shao-Horn
DOI: 10.1039/C4EE03869J, Review Article

C4EE03869J GA

Tracking the structural arrangement of ions in carbon supercapacitor nanopores using in situ small-angle X-ray scattering
C. Prehal, D. Weingarth, E. Perre, R. T. Lechner, H. Amenitsch, O. Paris and V. Presser
Journal Article
DOI: 10.1039/C5EE00488H, Paper

C5EE00488H GA

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HOT Articles in EES

The following HOT articles have been highlighted by the reviewers of the articles as being particularly interesting or significant pieces of research. These are all free to access until 31/03/2015. The order they appear in the list has no meaning or ranking.

CO2-free electric power circulation via direct charge and discharge using the glycolic acid/oxalic acid redox couple

R. Watanabe, M.Yamauchi, M.Sadakiyo, R. Abe and T. Takeguchi
DOI: 10.1039/C5EE00192G

10.1039/C5EE00192G


Atomic scale enhancement of metal–support interactions between Pt and ZrC for highly stable electrocatalysts
Niancai Cheng,  Mohammad Norouzi Banis, Jian Liu, Adam Riese, Shichun Mu, Ruying Li, Tsun-Kong Sham and Xueliang Sun

DOI: 10.1039/C4EE04086D

10.1039/C4EE04086D


Novel scalable synthesis of highly conducting and robust PEDOT paper for a high performance flexible solid supercapacitor
Bihag Anothumakkool, Roby Soni, Siddheshwar, N. Bhangea and Sreekumar Kurungot

DOI: 10.1039/C5EE00142K

 DOI: 10.1039/C5EE00142K


Olivine LiFePO4: the remaining challenges for future energy storage
Jiajun Wang and  Xueliang Sun

DOI: 10.1039/C4EE04016C

10.1039/C4EE04016C


Anomalously large interface charge in polarity-switchable photovoltaic devices: an indication of mobile ions in organic–inorganic halide perovskites
Yong Zhao, Chunjun Liang, Huimin Zhang, Dan Li, Ding Tian, Guobao Li, Xiping Jing, Wenguan Zhang, Weikang Xiao, Qian Liu,  Fujun Zhang and  Zhiqun He

DOI: 10.1039/C4EE04064C

10.1039/C4EE04064C


SnO2 nanocrystal-decorated mesoporous ZSM-5 as a precious metal-free electrode catalyst for methanol oxidation
Xiangzhi Cui,Yan Zhu, Zile Hua, Jingwei Feng,  Ziwei Liu, Lisong Chena and Jianlin Shi

DOI: 10.1039/C5EE00240K

10.1039/C5EE00240K


Hierarchical zigzag Na1.25V3O8 nanowires with topotactically encoded superior performance for sodium-ion battery cathodes
Yifan Dong, Shuo Li, Kangning Zhao, Chunhua Han, Wei Chen,  Bingliang Wang, Lei Wang, Boan Xu, Qiulong Wei, Lei Zhang, Xu Xua and Liqiang Mai

DOI: 10.1039/C5EE00036J

10.1039/C5EE00036J


CO2-free electric power circulation via direct charge and discharge using the glycolic acid/oxalic acid redox couple
R. Watanabe, M. Yamauchi, M. Sadakiyo, R. Abe and T. Takeguchi

DOI: 10.1039/C5EE00192G

10.1039/C5EE00192G


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Nanoporous methane storage – an impossible target?

Emma Stephen writes about an EES article in Chemistry World.


Is it possible to design a material to fulfil current methane storage goals? This is the question that a multi-disciplinary research team set out to answer by rapidly screening hundreds of thousands of possible methane storage materials in a computational study. Methane could reduce global dependence on oil so the search is on for nanoporous materials to act as fuel tanks for this tricky-to-store gas; but things are not looking promising.

C4EE03515A GA
Interested to find out more? Read the full article by Emma Stephen in Chemistry World.

Read the original article in Energy and Environmental Science:

The materials genome in action: identifying the performance limits for methane storage
Cory M. Simon, Jihan Kim, Diego A. Gomez-Gualdron, Jeffrey S. Camp, Yongchul G. Chung, Richard L. Martin, Rocio Mercado, Michael W. Deem, Dan Gunter, Maciej Haranczyk, David S. Sholl, Randall Q. Snurr and Berend Smit
Energy Environ. Sci., 2015, Advance Article
DOI: 10.1039/C4EE03515A, Perspective

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HOT Articles in EES

The following HOT articles have been highlighted by the reviewers of the articles as being particularly interesting or significant pieces of research. These are all free to access until 28th February 2015. The order they appear in the list has no meaning or ranking.


Microbial electrochemistry and technology: terminology and classification
Uwe Schröder, Falk Harnisch and Largus T. Angenent  
DOI: 10.1039/C4EE03359K, Perspective


A silole copolymer containing a ladder-type heptacylic arene and naphthobisoxadiazole moieties for highly efficient polymer solar cells
Zhiyun Zhang, Francis Lin, Hsieh-Chih Chen, Hung-Chin Wu, Chin-Lung Chung, Chien Lu, Shih-Hung Liu, Shih-Huang Tung, Wen-Chang Chen, Ken-Tsung Wong and Pi-Tai Chou  
DOI: 10.1039/C4EE03642E, Communication

C4EE03642E GA


Material descriptors for predicting thermoelectric performance
Jun Yan, Prashun Gorai, Brenden Ortiz, Sam Miller, Scott A. Barnett, Thomas Mason, Vladan Stevanović and Eric S. Toberer  
DOI: 10.1039/C4EE03157A, Paper


Understanding the rate-dependent J–V hysteresis, slow time component, and aging in CH3NH3PbI3 perovskite solar cells: the role of a compensated electric field
W. Tress, N. Marinova, T. Moehl, S. M. Zakeeruddin, Mohammad Khaja Nazeeruddin and M. Grätzel  
DOI: 10.1039/C4EE03664F, Paper


Polyoxometalate-functionalized nanocarbon materials for energy conversion, energy storage and sensor systems
Yuanchun Ji, Lujiang Huang, Jun Hu, Carsten Streb and Yu-Fei Song  
DOI: 10.1039/C4EE03749A, Review Article

C4EE03749A GA


Power-to-What? – Environmental assessment of energy storage systems
André Sternberg and André Bardow  
DOI: 10.1039/C4EE03051F, Analysis


Flexible graphene devices related to energy conversion and storage
Xiluan Wang and Gaoquan Shi  
DOI: 10.1039/C4EE03685A, Review Article


Light management in thin film silicon solar cells
F.-J. Haug and C. Ballif  
DOI: 10.1039/C4EE03346A, Review Article


1,2,4-Triazolium perfluorobutanesulfonate as an archetypal pure protic organic ionic plastic crystal electrolyte for all-solid-state fuel cells
Jiangshui Luo, Annemette H. Jensen, Neil R. Brooks, Jeroen Sniekers, Martin Knipper, David Aili, Qingfeng Li, Bram Vanroy, Michael Wübbenhorst, Feng Yan, Luc Van Meervelt, Zhigang Shao, Jianhua Fang, Zheng-Hong Luo, Dirk E. De Vos, Koen Binnemans and Jan Fransaer  
DOI: 10.1039/C4EE02280G, Paper


The materials genome in action: identifying the performance limits for methane storage
Cory M. Simon, Jihan Kim, Diego A. Gomez-Gualdron, Jeffrey S. Camp, Yongchul G. Chung, Richard L. Martin, Rocio Mercado, Michael W. Deem, Dan Gunter, Maciej Haranczyk, David S. Sholl, Randall Q. Snurr and Berend Smit  
DOI: 10.1039/C4EE03515A, Perspective


Bioelectrodes modified with chitosan for long-term energy supply from the body
S. El Ichi, A. Zebda, J.-P. Alcaraz, A. Laaroussi, F. Boucher, J. Boutonnat, N. Reverdy-Bruas, D. Chaussy, M. N. Belgacem, P. Cinquin and D. K. Martin  
DOI: 10.1039/C4EE03430A, Paper


β-cyclodextrin enhanced triboelectrification for self-powered phenol detection and electrochemical degradation
Zhaoling Li, Jun Chen, Jin Yang, Yuanjie Su, Xing Fan, Ying Wu, Chongwen Yu and Zhong Lin Wang  
DOI: 10.1039/C4EE03596H, Communication

Cooperative kinetics of depolarization in CH3NH3PbI3 perovskite solar cells
Luca Bertoluzzi, Rafael S. Sanchez, Linfeng Liu, Jin-Wook Lee, Elena Mas-Marza, Hongwei Han, Nam-Gyu Park, Ivan Mora-Sero and Juan Bisquert  
DOI: 10.1039/C4EE03171G, Communication
C4EE03171G GA

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HOT Articles in EES

The following HOT articles have been highlighted by the reviewers of the articles as being particularly interesting or significant pieces of research. These are all free to access until 31st January 2015. The order they appear in the list has no meaning or ranking.

Automated vehicles and electrification of transport
Gregory James
DOI: 10.1039/C4EE02229G, Opinion

C4EE02229G GA

Band engineering of high performance p-type FeNbSb based half-Heusler thermoelectric materials for figure of merit zT > 1
Chenguang Fu, Tiejun Zhu, Yintu Liu, Hanhui Xie and Xinbing Zhao  
DOI: 10.1039/C4EE03042G, Communication

C4EE03042G GA

Mechanistic insights into solar water oxidation by cobalt-phosphate-modified α-Fe2O3 photoanodes
Gerard M. Carroll, Diane K. Zhong and Daniel R. Gamelin  
DOI: 10.1039/C4EE02869D, Paper

C4EE02869D GA

Theory, practice and prospects of X-ray and neutron scattering for lignocellulosic biomass characterization: towards understanding biomass pretreatment
Gang Cheng, Xin Zhang, Blake Simmons and Seema Singh  
DOI: 10.1039/C4EE03147D, Review Article

C4EE03147D GA

Peanut shell hybrid sodium ion capacitor with extreme energy–power rivals lithium ion capacitors
Jia Ding, Huanlei Wang, Zhi Li, Kai Cui, Dimitre Karpuzov, Xuehai Tan, Alireza Kohandehghan and David Mitlin  
DOI: 10.1039/C4EE02986K, Paper

C4EE02986K GA

Adipic acid production from lignin
Derek R. Vardon, Mary Ann Franden, Christopher W. Johnson, Eric M. Karp, Michael T. Guarnieri, Jeffrey G. Linger, Michael J. Salm, Timothy J. Strathmann and Gregg T. Beckham  
DOI: 10.1039/C4EE03230F, Paper

C4EE03230F GA

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Register now for HOPV15

You are invited to participate in the International Conference on Hybrid and Organic Photovoltaics 2015, to be held in Rome, Italy, from 10-13 May 2015.

HOPV has been consolidated since 2009 as a unique forum for the advances in hybrid and organic photovoltaics. Now the 7th edition chaired by Prof. Filippo de Angelis and Prof. Mike McGehee, kindly invite you to present your latest research and participate in a major event in Rome, 10-13 May 2015. Of course the generous progress of perovskite solar cells will form a key part of the conference. The conference format is a full three days, multiple symposia meeting, with outstanding figures of the field as keynotes and invited speakers, and with also room for plenty of contributed talks by participant scientists and unlimited poster presentation.
 
Energy and Environmental Science is sponsoring three HOPV15 poster prize awards, with a first prize of 200 euros, second prize of 150 euros, and third prize of 100 euros.

HOPV15 banner

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