Author Archive

Analysis article: Liquid fuel from CO2 using solar-thermal energy

Liquid fuel from sunlight, CO2, and water addresses a critical energy security issue with favorable energy efficiency, environmental, and economic metrics.

This investigation establishes a methodology for identifying opportunities, comparison, and assessment of impact on the efficiency, lifecycle impact, and economics for advanced system designs.

Analysis:
Methanol production from CO2 using solar-thermal energy: process development and techno-economic analysis
Jiyong Kim, Carlos A. Henao, Terry A. Johnson, Daniel E. Dedrick, James E. Miller, Ellen B. Stechel and Christos T. Maravelias
Energy Environ. Sci., 2011, DOI: 10.1039/C1EE01311D

Methanol production from CO2 using solar-thermal energy

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Overcoming a challenge in lithium–air battery function – inspired by artificial blood

Lithium–air batteries’ discharge rates can be increased substantially by using perfluorinated compounds as oxygen carriers, say scientists from the US. They were inspired to make oxygen carriers similar to artificial blood substitutes.

One of the challenges of making Li–air batteries viable is down to increasing oxygen solubility and diffusion coefficient, which should increase the discharge rate.

The perfluorinated compounds increase the oxygen’s solubility in non-aqueous electrolytes, which leads to an increase in the diffusion-limited current of oxygen reduction on the gas diffusion electrode in the battery.

A 5 mA.cm-2 discharge rate was achieved, an improvement over previous devices, which were limited to 0.01–5 mA.cm-2.

Reference:
High Rate Oxygen Reduction in Non-aqueous Electrolyte with the Addition of Perfluorinated Additives
Y Wang, D Zheng, X-Q Yang and D Qu,
Energy Environ. Sci., 2011, DOI: 10.1039/c1ee01556g

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Floating platform uses sun energy to get salt from water

A team in Australia has used floating light-absorbing materials to build an improved solar device for desalination.

The materials consist of Fe3O4/C particles and can be used as an alternative to black plastic bubble sheets that are placed at the bottom of solar ponds to increase sunlight absorption. Existing bubble sheets increase evaporation by 10%, but these new materials increase evaporation by 230%.

Read the just published EES paper now: 

Solar Evaporation Enhancement Using Floating light-absorbing Magnetic Particles
Y Zeng, J Yao, B A Horri, K Wang, Y Wu, D Li and H Wang
Energy Environ. Sci., 2011, DOI: 10.1039/c1ee01532j

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Hot article: inexpensive film-Si photovoltaics

Two advances toward inexpensive film-Si photovoltaics on metal foils: large oriented Si grains grown epitaxially on RABiTS NiW foils and heteroepitaxial silicon solar cells.

Read the ‘HOT@ article today:

Heteroepitaxial film crystal silicon on Al2O3: new route to inexpensive crystal silicon photovoltaics
Charles W. Teplin, M. Parans Paranthaman, Thomas R. Fanning, Kirstin Alberi, Lee Heatherly, Sung-Hun Wee, Kyunghoon Kim, Frederick A. List, Jerry Pineau, Jon Bornstein, Karen Bowers, Dominic F. Lee, Claudia Cantoni, Steve Hane, Paul Schroeter, David L. Young, Eugene Iwaniczko, Kim M. Jones and Howard M. Branz
Energy Environ. Sci., 2011, DOI: 10.1039/C1EE01555A

Heteroepitaxial film crystal silicon on Al2O3

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HOT article: extracting pure CO2 from air

Using a combined temperature-vacuum swing (TVS) process which separates CO2 from atmospheric air, scientists from Switzerland have shown a stable performance over 40 consecutive adsorption/desorption cycles.

The adsorption/desorption cycles use a sorbent material made of diamine-functionalized commercial silica gel, and are performed under equilibrium and non-equilibrium (short-cycle) conditions. Therefore the CO2 capture capacity of the material can be determined over a wide range of pressures and temperatures.

Read this ‘HOT’ Energy & Environmental Science article today:

Separation of CO2 from air by temperature-vacuum swing adsorption using diamine-functionalized silica gel
Jan Andre Wurzbacher, Christoph Gebald and Aldo Steinfeld
Energy Environ. Sci., 2011, DOI: 10.1039/C1EE01681D

CO2 separation

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Hot article: high performance thermoelectric materials

This ‘HOT’ article experimentally demonstrates a successful combination of the complexity in the valence band structure with the addition of nanostructuring to create a high performance thermoelectric material.

nanostructuringRead the Energy & Environmental Science paper:

Combination of large nanostructures and complex band structure for high performance thermoelectric lead telluride
Yanzhong Pei, Nicholas A. Heinz, Aaron LaLonde and G. Jeffrey Snyder
Energy Environ. Sci., 2011, DOI: 10.1039/C1EE01928G

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HOT article: Li3N@C composites present full hydrogen release

H2 desorption

For the first time, Li3N@C composites are synthesized via the wet impregnation of mesoporous carbons with LiN3 solutions followed by a thermal treatment.

The resulting Li3N@C composites present excellent sorption kinetics and a full hydrogen release.

Read the paper:
Modification of the hydrogen storage properties of Li3N by confinement into mesoporous carbons
Rezan Demir-Cakan, Wan Si Tang, Ali Darwiche and Raphaël Janot
Energy Environ. Sci., 2011, DOI: 10.1039/C1EE01387D

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Tequila for your fuel tank

Researchers in the UK show that Agave – a plant used to make tequila and fibres for rope – is a handy alternative feedstock to corn or sugarcane in the production of bioethanol fuel.  

Bioethanol is a good clean fuel candidate as it only forms carbon dioxide and water during combustion and can be easily blended with crude oil to produce other fuels. However, the sustainability of large-scale biofuel production has recently been called into question because of mounting concerns over the impact on land and water resources. 

Now a team led by David King from the Low Carbon Mobility Centre at the University of Oxford has studied the viability of using Agave as an alternative feedstock because it can be grown in an arid environment. 

In the US, bioethanol is produced from corn, which is very water and fertiliser intensive and requires a significant amount of land. The result is a trade-off between feedstocks for the food markets and feedstocks for bioethanol production. In Brazil, bioethanol is produced using sugarcane. But again, land that could be used to grow food is needed to grow this and the question is: which is more important, food or fuel? 

Agave plants
‘Agave is a sort of cactus that grows in water restricted arid areas,’ says Oliver Inderwildi, one of the researchers. ‘This is essentially what we want – to produce fuel away from arable land.’ Inderwildi explains that the Agave feedstock, after harvesting, will be milled, cooked, fermented and then distilled – essentially using the same process as other ethanol production procedures. 

‘This is academic research in the very early stages,’ says Inderwildi. ‘However, there is no real shortage of desert land and lots of deprived areas are located on the edge of deserts, so this could be a method to utilise unused land and help rejuvenate deprived areas,’ he adds. 

‘There is no question this is a valuable first attempt at predicting the benefits of Agave-based biofuels,’ says Stephen Long, an expert in bioenergy from the University of Illinois at Urbana-Champaign, in the US. ‘But without systematic trials and measurements, the scale of the opportunity is unclear,’ he adds.

Inderwildi admits that there are still a few problems to iron out before Agave will be a commercially viable feedstock. ‘They are slow growing crops and up until now they have been harvested manually,’ he tells Chemistry World. ‘What you have at the moment is a labour issue and a yield issue, but we can work on increasing yields and automating the harvesting.’

The team at the Low Carbon Mobility Centre are also looking at other ways to produce biofuels from algae. ‘Fuels from algae can be used as diesel type fuels or kerosene,’ says Inderwildi. ‘Air New Zealand has already carried out a test flight using these fuels and performance is outstanding,’ he adds.

Even if Agave is used to produce our fuels in the future, tequila production or prices will be unaffected, according to Inderwildi.   ‘I’m not at all worried about the tequila supply in bars,’ he says.

Mike Brown

Read the Energy & Environmental Science article:

Life cycle energy and greenhouse gas analysis for agave-derived bioethanol
Xiaoyu Yan, Daniel K. Y. Tan, Oliver R. Inderwildi, J. A. C. Smith and David A. King, Energy Environ. Sci., 2011
DOI: 10.1039/c1ee01107c

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Tequila biofuel: EES paper featured in The Guardian

An Energy & Environmental Science article which analyses the use of agave (tequila) plants as a source of bio-ethanol has been featured in The Guardian today: Tequila gives new biofuel crops a shot

The work by scientists at the University of Oxford and The University of Sydney have shown that Agave – a plant used to make tequila – is an alternative feedstock to corn or sugarcane in the production of bioethanol fuel. They have studied the viability of using Agave as an alternative feedstock because it can be grown in an arid environment, away from arable land.

Bioethanol produced from corn and sugarcane is water and fertiliser intensive and requires a significant amount of land. The result is a trade-off between feedstocks for the food markets and feedstocks for bioethanol production.

Read the Energy & Environmental Science Analysis article:

Life cycle energy and greenhouse gas analysis for agave-derived bioethanol
Xiaoyu Yan, Daniel K. Y. Tan, Oliver R. Inderwildi, J. A. C. Smith and David A. King
Energy Environ. Sci., 2011, DOI: 10.1039/C1EE01107C

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The rise of the sodium ion battery: EES in C&EN

An Energy & Environmental Science Communication by Philipp Adelhelm and co-workers has been featured in an C&EN article Making Better Sodium-Ion Batteries.

The rise of the sodium ion battery: A nanostructured material has been used as an anode in a sodium ion battery for the first time and its performance is better than all carbon materials tested so far, say researchers from Germany.

Read the paper:

Room-temperature sodium-ion batteries: Improving the rate capability of carbon anode materials by templating strategies
S Wenzel, T Hara, J Janek and P Adelhelm, Energy Environ. Sci., 2011
DOI: 10.1039/c1ee01744f

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