Author Archive

Fall ACS Update: photocatalysis

There’s been lots of talks this week at the ACS about photocatalysis and water-splitting, across many different divisions and symposia – it seems to be a very ‘hot’ topic right now!

One highlight for me was a talk by Ryu Abe, who discussed his work on visible-light responsive photocatalysis for solar hydrogen production. He also covered his research about PEC water-splitting, using co-catalysts to improve stability.

Read Ryu Abe’s latest research in EES:

Fabrication of efficient TaON and Ta3N5 photoanodes for water splitting under visible light irradiation
Masanobu Higashi, Kazunari Domen and Ryu Abe
DOI: 10.1039/C1EE01878G

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Fall ACS Update: Alternative energy research

The Fall ACS meeting in Denver, USA is all about air, space and water – with a strong emphasis on alternative energy.

I saw two great talks this afternoon by EES Advisory Board member Dirk Guldi and Francisco Zaera about just that; artificial photosynthesis and TiO2 catalysis to be more precise!

The Carbon leaves: Artificial photosynthesis based on low dimensional carbons
Dirk M. Guldi
Yolk@Shell nanoarchitecture for Au/TiO2 catalysts
Ilkeun Lee, Ji Bong Joo, Yadong Yin, Francisco Zaera

Browse the EES themed issue on carbon nanostructures for energy published earlier this year which was Guest edited by Dirk Guldi: Carbon nanostructures

Professor Zaera discussed his research on TiO2 catalysts and highlighted his PCCP Perspective review article on nanostructured heterogeneous catalysts:

New nanostructured heterogeneous catalysts with increased selectivity and stability
Ilkeun Lee, Manuel A. Albiter, Qiao Zhang, Jianping Ge, Yadong Yin and Francisco Zaera
DOI: 10.1039/C0CP01688H

This review was featured in the 2011 PCCP themed issue on Controlled nanostructures for applications in catalysis – take a look today!

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Splitting seawater

An electrode to split seawater molecules to get hydrogen has been made by researchers in China.

Splitting seawater molecules is difficult, but as it’s more abundant than freshwater, it is desirable to do so. The BiVO4 photoanode splits the water at much higher photocurrent densities than previous methods (2.16 mAcm-2 compared to 1.0 mAcm-2) and at a low potential.

Read this ‘HOT’ Energy & Environmental Science paper today:

Solar hydrogen generation from seawater with a modified BiVO4 photoanode
Z Li, et al, Energy Environ. Sci., 2011
DOI: 10.1039/c1ee01812d

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High performance thermoelectric PbTe alloy semiconductors

PbTe is one of the most studied thermoelectric semiconductors because its alloys have the highest energy conversion efficiency.

The ‘HOT’ article from Energy & Environmental Science combines alloy scattering of phonons and resonant electronic levels to reach a high thermoelectric figure of merit in PbTeSe and PbTeS alloys. It is thought that thallium triggers formation of resonant electronic states in PbTe alloys’ valence bands that enhance the thermoelectric figure of merit.

Read the article in full:

Combining alloy scattering of phonons and resonant electronic levels to reach a high thermoelectric figure of merit in PbTeSe and PbTeS alloys
Christopher M. Jaworski, Bartlomiej Wiendlocha, Vladimir Jovovic and Joseph P. Heremans
Energy Environ. Sci., 2011, DOI: 10.1039/C1EE01895G

PbTe alloys

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How safe are lithium-ion batteries?

‘HOT’ article: testing the thermal stability of lithiated graphite

In this paper the kinetics of solid–electrolyte interface were successfully correlated to the safety of lithium-ion batteries using graphite anodes.

The results revealed that the thermal decomposition of the solid–electrolyte interface is the most easily triggered chemical reaction in lithium-ion cells and plays a critical role in determining the battery safety.

Read the Energy & Environmental Science article:

Multi-scale study of thermal stability of lithiated graphite
Zonghai Chen, Yan Qin, Yang Ren, Wenquan Lu, Christopher Orendorff, E. Peter Roth and Khalil Amine
Energy Environ. Sci., 2011, DOI: 10.1039/C1EE01786A

battery safety

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Hot article: Releasing 17.8 wt% H2 from lithium borohydride ammoniate

In this paper, Ping Chen et al. have shown the release of 17.8 wt% of hydrogen in 135–250 °C in a closed vessel, from the Co-catalyzed Li(NH3)4/3BH4.

The presence of the nanosized Co catalyst is shown to effectively promote the release of hydrogen.

H2 releaseRead the Energy & Environmental Science article today:

Releasing 17.8 wt% H2 from lithium borohydride ammoniate
Xueli Zheng, Guotao Wu, Wen Li, Zhitao Xiong, Teng He, Jianping Guo, Hua Chen and Ping Chen
Energy Environ. Sci., 2011, DOI: 10.1039/C1EE01480C

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EES biofuel article featured in The Times

An exciting Energy Environmental Science Anaylsis article about algae-derived biodiesel which ‘could be the answer to the fossil fuel crisis’ has been featured in The Times newspaper today.

Using a life-cycle analysis, King and colleagues evaluate whether algal biodiesel production can be a viable fuel source in the near future.

biofuel analysisRead the Energy Environmental Science article:

Life cycle energy and greenhouse gas analysis for algae-derived biodiesel
Tara Shirvani, Xiaoyu Yan, Oliver R. Inderwildi, Peter P. Edwards and David A. King
Energy Environ. Sci., 2011, DOI: 10.1039/C1EE01791H

Or read more about it on the Chemistry World Blog

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Algae-derived biodiesel flying high

Chemistry World Blog
Algae-derived biodiesel flying high
Posted by Elinor on Thu 11 Aug 2011

Two weeks ago, we read about agave as an alternative feedstock to corn or sugarcane in the production of bioethanol fuel in Mike’s story Tequila for your fuel tank. In it, Mike describes research by David King from the Low Carbon Mobility Centre at the University of Oxford and his team.

At the same time, King’s team has been busy putting research together to show that algae-derived biodiesel ‘could be the answer to the fossil fuel crisis’. Indeed, airlines have already been testing a range of biofuels in their planes, including algal-derived biofuels.

…Read the rest on the Chemistry World Blog

Journal Article:
Life cycle energy and greenhouse gas analysis for algae-derived biodiesel
Tara Shirvani, Xiaoyu Yan, Oliver R. Inderwildi, Peter P. Edwards and David A. King
Energy Environ. Sci., 2011, DOI: 10.1039/C1EE01791H

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Renewable energy could replace fossil fuels to heat US homes

US energy consumption study reveals that using renewable energy instead of fossil fuels to heat homes is viable.

An analysis on how the US uses thermal energy has revealed a perfect opportunity for renewable energy from geothermal and solar resources, say US scientists.

The study shows how renewable energy could provide a large fraction of the energy used for heating water and space at home that is currently supplied by high grade fossil fuels.

Read the Energy & Environmental Science article:

The thermal spectrum of low-temperature energy use in the United States
D B Fox, D Sutter and J W Tester
Energy Environ. Sci., 2011, DOI: 10.1039/c1ee01722e

thermal spectrum

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A solar torch to fit in your back pocket

In a real life display of the use of photovoltaics, a solar powered torch the size of a credit card has been developed by a team of scientists from Denmark, the Netherlands and the US. 

Organic and polymer solar cells (OPV) have reached a technological level where they can be produced commercially using roll-to-roll methods that are cost effective. Frederik Krebs, from the Technical University of Denmark, Roskilde, and colleagues have made a new device that combines 16 solar cells connected in series that are used to charge a battery that powers a white light emitting diode.    

Solar powered torch  Production required 35 steps, and combined the polymer solar cell with printed circuitry and flexible lithium polymer batteries. Tests were run on the lamp to determine its efficiency and study the effects of humidity and design on performance. 

This new pocket-sized flashlight was able to get a yield of 89 per cent and operated for hours at a time. Krebs explains: ‘Even if the flashlight is far from solving the world’s energy problem, it clearly demonstrates that polymer solar cells are capable of fairing outside the laboratory and can be made available to the public in an operational device.’ 

Until now, very few examples have been manufactured beyond a few units. This is the first time that a complex device has been commercialised at this scale – 10,000 units have already been made. Examples were even handed out at the most recent Large area Organic and Printed Electronics Conference (LOPE-C).

‘While the OPV powered lamp demonstrated in this work shows how this technology can be used in regions of the world where direct access to electricity by conventional sources is difficult, the methods developed will have a broader impact in the field of printable organic electronics in general,’ comments John Reynolds, an expert in conducting polymers from the University of Florida, US.

Krebs and his team are now tackling the next challenge, which is to make polymer solar cells with longer operational lifespans capable of working for years at a time in outdoor conditions.

Rebecca Brodie 

Read the journal article:

The OE-A OPV demonstrator anno domini 2011
Frederik C. Krebs, Jan Fyenbo, David M. Tanenbaum, Suren A. Gevorgyan, Ronn Andriessen, Bart van Remoortere, Yulia Galagan and Mikkel Jørgensen
Energy Environ. Sci., 2011
DOI: 10.1039/c1ee01891d

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