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Improved cycling stability of silicon nanowire anodes

Energy & Environmental Science ‘HOT’ Communication

PEDOT-coated nanowires and the molecular structure of PEDOT

 

Yi Cui and co-workers have markedly improved the cycling stability of a silicon nanowire anode by coating it with a conducting polymer (PEDOT).

Charge-discharge cycling experiments showed that the polymer-coated nanowires retained 80% of their original capacity after 100 cycles, compared to only 30% capacity retention for bare nanowires.

It is thought that the improved retention is due to the polymer having a stabilising effect on the nanowires as they undergo the large volume changes that accompany the charge-discharge cycles. PEDOT may also help to maintain electrical connections between the wires that would otherwise be lost during cycling.

 

The authors believe that polymer coated anodes could potentially be used to improve the performance of lithium-ion batteries.

Read the Energy & Environmental Science Communication today:

Improving the cycling stability of silicon nanowire anodes with conducting polymer coatings
Yan Yao, Nian Liu, Matthew T. McDowell, Mauro Pasta and Yi Cui
Energy Environ. Sci.
, 2012, DOI: 10.1039/C2EE21437G

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Putting the cement industry in the calcium loop

Scientists in the UK have shown that two major industrial processes that generate large amounts of carbon dioxide could usefully be linked together to deliver significant savings in energy and CO2 emissions.

For several years researchers have investigated ways of capturing and concentrating CO2 from fossil fuel power stations so that it can be trapped, possibly in underground rock formations. One promising method involves reacting the flue gases with calcium oxide. The CO2 in the exhaust gas combines with CaO to form calcium carbonate, CaCO3. This can then be heated to drive off the CO2 at a much higher concentration. The process regenerates CaO, which can be used for further cycles. Typically flue gases contain around 15 per cent CO2, which can be concentrated to around 95 per cent through this ‘calcium looping’ process.

After repeated cycles the CaO undergoes morphological changes which reduce its efficiency for producing CaCO3. It has been suggested that this spent CaO could be used as a feedstock for the production of cement. The cement industry requires a large amount of CaO, which is produced by heating calcium carbonate in the form of limestone, which in turn produces significant CO2 emissions.

Cement works

Carbon dioxide emissions from cement manufacture can be greatly reduced using calcium looping technology

However, it has not been clear if the CaO derived from the calcium looping cycle would be suitable for cement manufacture. Now, Charles Dean, Denis Dugwell and Paul Fennell, from Imperial College London, have carried out laboratory scale tests that suggest that spent CaO sorbent from CO2 capture retains the appropriate chemistry for its inclusion in cement, with no detrimental properties to the final product.

‘If you take off a purge stream of calcium oxide from the calcium looping cycle, it should be possible to feed this directly into the cement works,’ says Fennell. ‘This would save about 50 per cent of the CO2 produced in production.’ The requirement for less energy to generate the CaO from limestone would also create significant cost savings. ‘We have shown for the first time that cement can be successfully produced from CaO previously used in the calcium looping cycle, thereby confirming a positive synergy between the two processes,’ says Fennell.

Hannah Chalmers of the University of Edinburgh in the UK is a member of the Scottish Carbon Capture and Storage research group. She says successful application of CO2 capture to cement manufacture could be an important part of global efforts to reduce greenhouse gas emissions. ‘This work includes important information for developing an understanding of the economic and environmental performance of CO2 capture from cement manufacture, which could be vital for successful development and deployment of this technology.’

Simon Hadlington

 

Read the full Energy & Environmental Science article today:

Investigation into potential synergy between power generation, cement manufacture and CO2 abatement using the calcium looping cycle

Charles C. Dean, Denis Dugwell and Paul S. Fennell
Energy Environ. Sci., 2011, Advance Article

DOI: 10.1039/C1EE01282G, Communication

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