Dalton Transactions Blog

During the months April – June, the following articles are in the Top Ten most accessed:-

Water oxidation catalysed by manganese compounds: from complexes to ‘biomimetic rocks’ 
Mathias Wiechen, Hans-Martin Berends and Philipp Kurz   
Dalton Trans., 2012,41, 21-31 
DOI: 10.1039/C1DT11537E     

Crystal structure and functional studies of an unusual l-cysteine desulfurase from Archaeoglobus fulgidus 
Yasuaki Yamanaka, Laura Zeppieri, Yvain Nicolet, Elodie N. Marinoni, Jaim S. de Oliveira, Masafumi Odaka, Dennis R. Dean and Juan C. Fontecilla-Camps 
Dalton Trans., 2013,42, 3092-3099 
DOI: 10.1039/C2DT32101G     

Facile synthesis and excellent recyclable photocatalytic activity of pine cone-like Fe₃O₄@Cu₂O/Cu porous nanocomposites 
Haisheng Wang, Yongan Hu, Yang Jiang, Lingguang Qiu, Haibin Wu, Ben Guo, Yuhua Shen, Yang Wang, Ling Zhu and Anjian Xie  
Dalton Trans., 2013,42, 4915-4921 
DOI: 10.1039/C2DT32290K     

Visible-light-induced WO₃/g-C₃N₄ composites with enhanced photocatalytic activity 
Liying Huang, Hui Xu, Yeping Li, Huaming Li, Xiaonong Cheng, Jixiang Xia, Yuanguo Xu and Guobin Cai   
Dalton Trans., 2013,42, 8606-8616 
DOI: 10.1039/C3DT00115F     

Molecular and electronic structures and photophysical properties of quadruply bonded dimetal complexes (M = Mo or W) supported by trans-arylethynylcarboxylate ligands where aryl = p-tolyl or 9-anthrancenyl 
Brian G. Alberding, Samantha E. Brown-Xu, Malcolm H. Chisholm, Judith C. Gallucci, Terry L. Gustafson, Vesal Naseri, Carly R. Reed and Claudia Turro   
Dalton Trans., 2012,41, 12270-12281 
DOI: 10.1039/C2DT31359F     

Hydrogen bonded anion ribbons, networks and clusters and sulfur–anion interactions in novel radical cation salts of BEDT-TTF with sulfamate, pentaborate and bromide 
Andrew C. Brooks, Lee Martin, Peter Day, Elsa B. Lopes, Manuel Almeida, Koichi Kikuchi, Wataru Fujita, Kota Sasamori, Hiroki Aktusue and John D. Wallis  
Dalton Trans., 2013,42, 6645-6654 
DOI: 10.1039/C3DT32430C     

Self-assembly and alterable relaxivity of an organic cation-encapsulated gadolinium-containing polyoxometalate 
Yinglin Wang, Shengyan Zhou, Daliang Kong, Haishan Yang, Wenqiang Chai, Ulrich Kortz and Lixin Wu 
Dalton Trans., 2012,41, 10052-10059 
DOI: 10.1039/C2DT30641G   
  
Chemistry and applications of metal complexes 
M. Amélia Santosa   
Dalton Trans., 2013,42, 5957-5959 
DOI: 10.1039/C3DT90038J     

Recent progress in the synthesis of inorganic nanoparticles 
C. N. R. Rao, H. S. S. Ramakrishna Matte, Rakesh Voggu and A. Govindaraj  
Dalton Trans., 2012,41, 5089-5120 
DOI: 10.1039/C2DT12266A     

Two high-connected metal–organic frameworks based on d10-metal clusters: syntheses, structural topologies and luminescent properties 
Xue-Zhi Song, Shu-Yan Song, Shu-Na Zhao, Zhao-Min Hao, Min Zhu, Xing Meng and Hong-Jie Zhang 
Dalton Trans., 2013,42, 8183-8187 
DOI: 10.1039/C3DT50687H     

Why not take a look at the articles today and blog your thoughts and comments below.

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Fabrication of high performance, multi-layered phosphorescent organic light-emitting diodes (PhOLEDs) is often done by vacuum deposition of small organic molecules which can be a lengthy and costly process. Solution processing (layers can either be coated or printed from solution) is a more viable technique in terms of cost. However when it is used to make multilayered devices the lower layer can be affected by the solvent from upper layers due to inter-miscibility. It would be better to have electron and hole transporter materials together in a single layered device.

Yan Huang, Zhiyun Lu and colleagues have reported two novel orange iridium(III) complexes. The complexes were synthesized by modifying the phenyl moiety of the parent complex, (bt)₂Ir(acac) (bt = phenylbenzothiazole, acac = acetylacetonate). The new complexes have good thermostability and film amorphism meaning that they were able to be tested in a solution-processed single layer PhOLED. Both complexes demonstrated higher luminescence and efficiency than the parent complex. The improved characteristics of the two new Ir(III) complexes mean that they are promising candidates for use in low cost fabrication of PhOLEDs for large area displays.

To find out more, read the full Dalton Transactions article:

Iridium(III) complexes with enhanced film amorphism as guests for efficient orange solution-processed single-layer PhOLEDs with low efficiency roll-off
Jun Dai, Kaifeng Zhou, Ming Li, Huiqin Sun, Yunqing Chen, Shijian Su, Xuemei Pu, Yan Huang and Zhiyun Lu
Dalton Transactions, DOI: 10.1039/C3DT50834J

Congratulations to Philip Power, who has been awarded the inaugural Dalton Distinguished Lectureship in recognition of his work on transition metal and main group chemistry.

Supported by Dalton Transactions, this lectureship is awarded yearly to an outstanding senior researcher in the field of inorganic chemistry. Besides providing recognition for high quality chemistry research, it also facilitates interaction between researchers in different institutions.

Philip will be presenting his lecture at University of California, Berkeley on the 7th February 2014.

Philip received his B.A. from the University of Dublin in 1974, and commenced on his PhD research at the University of Sussex under M.F. Lappert. After graduating in 1977, he spent two years working as a postdoctoral researcher in Stanford under R.H. Holm. In 1981, he started a faculty position at University of California, Davis, where he is currently a Professor.