Archive for July, 2011

Dalton Transactions Younger Researchers Symposium: Abstract deadline this Friday

The abstract deadline for the Dalton Transactions Younger Researchers Symposium is on Friday (22nd July). If you want to present a poster prize, or be considered for the oral presentation you need to register before the end of the week.

The symposium in a great opportunity to meet postgraduates and postdocs working in inorganic and organometallic chemistry, and as registration is FREE of charge (accommodation and the conference dinner cost comes to just £67), this will be the best value meeting you attend all year!

How to submit an abstract:

  • Symposium delegates should register to attend the meeting by clicking on the ‘Registration‘ link on the meeting webpage (see the ‘In this section’ menu).
  • Delegates should then submit an abstract to present an oral or poster presentation by clicking on the ‘Call for Papers’ link on the meeting webpage (see the ‘In this section’ menu).

Registration for delegates who do not wish to present their work will remain open until 19th August.

Speakers include the 2010 Dalton Transactions Europe/Africa Lectureship Winner, Professor Karsten Meyer (
FAU University of Erlangen-Nuremberg), Dr Erwin Reisner (University of Cambridge) and Dr Michaele Hardie (University of Leeds). More information available at the event webpage.

Don’t miss out, register today!

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Dalton Transactions sponsors a poster prize at FEZA 2011

Dalton Transactions was delighted to sponsor a poster prize at the 5th International FEZA conference in Spain earlier in July.

The prize was awarded to Shusuke Okada and colleagues for their poster presentation on ‘Enhancement of catalytic activity in one-pot oxidation using Pd/SiO2@Ti containing mesoporous silica core-shell type catalyst.’

The presentation was based on the work done in Professor Hiromi Yamashita’s lab at Osaka University. Professor Yamashita’s team work on nano-sized ecomaterials such as photocatalysts. To find out more about their research, visit their website.

The conference was chaired by Avelino Corma and Fernando Rey from ITQ, and included plenary lectures from Ryong Ryoo, Ferdi Schüth, Christian Serre, Michael Tsapatsis and Jihong Yu. Find out more by visiting the Federation of European Zeolite Associations website.

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ICIQ Summer School on organometallic catalysis

The Institute of Chemical Research of Catalonia (ICIQ), Tarragonna, Spain, is running a summer school on organometallic catalysis next week.

The idea of the meeting is to bring together young researchers and distinguished chemists working in organometallic catalysis.

Dalton Transactions Managing Editor, Dr Jamie Humphrey,will be attending and speaking on how best to prepare an article for publication. Jamie will be joining a range of notable speakers including Profs Amos B. Smith III, John Hartwig, Paul Knochel and Polly Arnold. Visit the ICIQ Summer School webpage to find out more…

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Hot Article: Five-membered N,O-chelating metallacycles of early-transition metals

This Dalton Transactions Hot article investigates the intermolecular hydroamination of heteroatom-substituted allenes.

The addition of hydrogen-nitrogen bonds to carbon multiple bonds is an important reaction in organic synthesis, and here Laurel Schafter and Rashidat Oyinla from the University of British Columbia in Canada, use a transition metal catalyst to create five-membered N,O-chelating complexes.

Read the full article to find out more…

Intermolecular hydroamination of oxygen-substituted allenes. New routes for the synthesis of N,O-chelated zirconium and titanium amido complexes
Rashidat O. Ayinla and Laurel L. Schafer
Dalton Trans., 2011, DOI: 10.1039/C1DT10448A

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HOT article: Move over Pd

In this HOT article, Ribas and co-workers build on previous studies on the mechanism of Ullmann cross coupling reactions using a well-defined aryl-copper(III) complex. Fundamental mechanistic knowledge of these couplings is still scarce but is gaining renewed interest due to the cost and toxicity benefits in comparison to Pd-based methodologies for the synthesis of key intermediates in the pharmaceutical industry. The reactivity of well defined aryl–CuIII species in front of phenol-type nucleophiles was found to differ substantially from the reactivity with corresponding phenolates, and a significant enhancement was found to produce the same aryl–O coupling product. Mechanistic studies showed that easy deprotonation of coordinated secondary amines was responsible for the intense LMCT band at 545 nm; indeed, this pH-dependent reactivity of the pincer-like coordinated ligand somewhat enhanced its reactivity.

Further catalysis reading available for FREE at:
Aryl–O reductive elimination from reaction of well-defined aryl–CuIII species with phenolates: the importance of ligand reactivity
Alicia Casitas, Nikolaos Ioannidis, George Mitrikas, Miquel Costas and Xavi Ribas
Dalton Trans., 2011, Advance Article
DOI: 10.1039/C1DT10428D

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HOT article: Jahn-Teller distortion for modifying magnetic properties

In this HOT article, a detailed study of the impact of a Jahn-Teller distorted Cu(II) ion in the anti-ferromagnetically coupled ring, Cr7Cu, is reported. The Jahn-Teller distortions are identified using spectroscopic techniques and a theoretical characterization is also presented. The problem is important for molecular magnetism as the origin of Jahn-Teller related magnetic anisotropy and consequently the barrier for the spin reversal is single molecular magnets.

Read more about these interesting magnetic effects for FREE at:

Modification of the magnetic properties of a heterometallic wheel by inclusion of a Jahn–Teller distorted Cu(II) ion
Michael L. Baker, Stergios Piligkos, Alberto Bianchi, Stefano Carretta, David Collison, Joseph J. W. McDouall, Eric J. L. McInnes, Hannu Mutka, Grigore A. Timco, Floriana Tuna, Prabha Vadivelu, Høgni Weihe, Hans U. Güdel and Richard E. P. Winpenny
Dalton Trans., 2011, Advance Article
DOI: 10.1039/C1DT10547G

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Jonathan Nitschke announced as the 2011 Dalton Transactions European/African Lecturer

We are very pleased to announce that the 2011 Dalton Transactions European/African Lectureship has been awarded to Professor Jonathan Nitschke, based in the Chemistry Department at the University of Cambridge, UK.

Dr Jonathan Nitschke

Jonathan’s research output in terms of quality and quantity is extraordinary. In his first four years as an independent researcher, he published 16 papers on Cu(I) mediated assembly processes in high impact journals, a significant achievement when starting up an independent lab.  During his time at Cambridge University, he has focussed his research on how to manipulate complex mixtures of interchanging compounds, and the useful functions exhibited by these new systems. Read more about Jonathan’s research here.

Jonathan will be giving his Dalton Transactions Lecture at a number of conferences during the next 12 months.

Congratulations Jonathan!


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Hot Article: Zinc complexes that act against drug resistant cancers

This Dalton Transactions Hot article looks at the use of zinc complexes in cancer treatment. This exciting compound, made by Soumitra Choudhuri and colleagues, was found to act against drug resistant cancers.

Read the full article for FREE to find out more about this anticancer compound…

An in vitro and in vivo study of a novel zinc complex, zinc N-(2-hydroxyacetophenone)glycinate to overcome multidrug resistance in cancer Ruma Dey Ghosh, Satyajit Das, Avishek Ganguly, Kaushik Banerjee, Paramita Chakraborty, Avijit Sarkar, Mitali Chatterjee, Ashis Nanda, Kiran Pradhan and Soumitra K. Choudhuri
Dalton Trans., 2011, DOI: 10.1039/C1DT10501A

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Highest ever Immediacy Index for Dalton Transactions

The 2010 Journal Citation Reports have recently been published by Thomson ISI, and the immediacy index for Dalton Transactions was announced to be a record high value for the journal, leading the field with a value of 0.81!  Published alongside the more well known impact factors, the immediacy index is considered to be a measure of how topical and urgent the work in a journal is.

Dalton Transactions’ latest impact factor was also published, as 3.65, representing a more than 20% growth in impact factor over the last 5 years!

The Impact Factor for 2010 is calculated from the total number of citations given in 2010 to articles published in 2008 and 2009, divided by the number of articles published in 2008 and 2009.

The Immediacy Index for 2010 is calculated from the total number of citations given in 2010 to articles published in 2010, divided by the number of articles published in 2010.

We thank all our authors and referees who continue to supported the journal. Please visit our website to learn more about Dalton Transactions, or submit an article today.

Information about the latest impact factors for other RSC journals is available here.

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TCNE versus TCNQ in zwitterionic benzo quinonemonoimines

Since their first publication, zwitterionic benzo quinonemonoimines such as have attracted much attention, because of the remarkable electronic delocalization of their pi-system which forms two chemically connected but electronically separated 6pi-electron subunits. Their potential antiaromaticity is of theoretical interest, and the unique properties that such ligands may confer to their metal complexes extend to coordination chemistry, optical recording, homogenous catalysis and supramolecular chemistry.

In this Dalton Transactions Hot Article, Thomas Kauf and Pierre Braunstein compare the properties of TCNE and TCNQ zwitterionic benzoquinonemonoimine derivatives to find some interesting results. Be the first to read their communication here – free for you to view for 4 weeks:

Contrasting behaviour of TCNE and TCNQ zwitterionic benzoquinonemonoimine derivatives and coordination of a tricyanoethenyl substituent to Pd(0)
Thomas Kauf and Pierre Braunstein
Dalton Trans., 2011, Advance Article
DOI: 10.1039/C1DT10804B

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