HOT Article: Plasmonic response of electrified metal–liquid interfaces

This month we have a HOT article from the Chair of our Editorial Board, Paul Bohn. Together with his colleague Sean Branagan from the University of Notre Dame, US, they have been looking at thin Au films, patterned by focused ion beam (FIB) milling to contain an array of subwavelength nanopores, and how they exhibit enhanced optical transmission (EOT) via front–back resonance coupling. Click on the link below to read more.

Plasmonic response of electrified metal–liquid interfaces during faradaic and non-faradaic reactions by enhanced optical transmission
Sean P. Branagan and Paul W. Bohn
Analyst, 2012, Advance Article
DOI: 10.1039/C2AN35488H

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Top ten most accessed articles in May

This month sees the following articles in Analyst that are in the top ten most accessed:-

A colorimetric probe for the selective naked-eye detection of Pb(ii) ions in aqueous media

Jihye Park and Youngmi Kim
Analyst, 2012,137, 3246-3248    DOI: 10.1039/C2AN35253B

Quantum dot enabled detection of Escherichia coli using a cell-phone
Hongying Zhu, Uzair Sikora and Aydogan Ozcan
Analyst, 2012,137, 2541-2544    DOI: 10.1039/C2AN35071H

Nafion–CNT coated carbon-fiber microelectrodes for enhanced detection of adenosine
Ashley E. Ross and B. Jill Venton
Analyst, 2012,137, 3045-3051    DOI: 10.1039/C2AN35297D

Highly sensitive, selective, and rapid fluorescence Hg2+ sensor based on DNA duplexes of poly(dT) and graphene oxide
Jian Rong Zhang, Wei Tao Huang, Wan Yi Xie, Ting Wen, Hong Qun Luo and Nian Bing Li
Analyst, 2012,137, 3300-3305    DOI: 10.1039/C2AN35528K

DNA-templated silver nanoclusters–graphene oxide nanohybrid materials: a platform for label-free and sensitive fluorescence turn-on detection of multiple nucleic acid targets
Yu Tao, Youhui Lin, Zhenzhen Huang, Jinsong Ren and Xiaogang Qu
Analyst, 2012,137, 2588-2592    DOI: 10.1039/C2AN35373C

Easy dual-mode ambient mass spectrometry with Venturi self-pumping, canned air, disposable parts and voltage-free sonic-spray ionization
Nicolas V. Schwab ,  Andreia M. Porcari ,  Mirela B. Coelho ,  Eduardo M. Schmidt ,  Jose L. Jara ,  Jesui V. Visentainer and Marcos N. Eberlin
Analyst, 2012,137, 2537-2540    DOI: 10.1039/C2AN16312H

A novel di-triazole based peptide as a highly sensitive and selective fluorescent chemosensor for Zn2+ ions
Sambasivarao Kotha ,  Deepti Goyal (née Bansal) ,  Subhasree Banerjee and Anindya Datta
Analyst, 2012,137, 2871-2875    DOI: 10.1039/C2AN35222B

A facile and sensitive detection of pathogenic bacteria using magnetic nanoparticles and optical nanocrystal probes
Jinmyoung Joo ,  Changyong Yim ,  Donghoon Kwon ,  Jaejin Lee ,  Hwa Hui Shin ,  Hyung Joon Cha and Sangmin Jeon
Analyst, 2012, Advance Article    DOI: 10.1039/C2AN35369E

Upconversion nanoparticles in biological labeling, imaging, and therapy
Feng Wang ,  Debapriya Banerjee ,  Yongsheng Liu ,  Xueyuan Chen and Xiaogang Liu
Analyst, 2010,135, 1839-1854    DOI: 10.1039/C0AN00144A

Sensitive and selective detection of glutathione based on resonance light scattering using sensitive gold nanoparticles as colorimetric probes
Zhanguang Chen ,  Zhen Wang ,  Junhui Chen ,  Shaobin Wang and Xiaopeng Huang
Analyst, 2012,137, 3132-3137    DOI: 10.1039/C2AN35405E

Why not take a look at the articles today and blog your thoughts and comments below.

Fancy submitting an article to Analyst? Then why not submit to us today or alternatively email us your suggestions.

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HOT articles in Analyst

Check out some of the HOT articles published so far this month in Analyst. These papers will be free to access for 2 weeks.

Dissociated neuronal culture expressing ionotropic odorant receptors as a hybrid odorant biosensor—proof-of-concept study
Norio Tanada, Takeshi Sakurai, Hidefumi Mitsuno, Douglas J. Bakkum, Ryohei Kanzaki and Hirokazu Takahashi
Analyst
, 2012, Advance Article
DOI
: 10.1039/C2AN35058K

Fluorescent probe mimicking multiple logic gates and a molecular keypad lock upon interaction with Hg2+ and bovine serum albumin
Arvind Misra, Priyanka Srivastava and Mohammad Shahid
Analyst
, 2012, Advance Article
DOI
: 10.1039/C2AN35561B

A new fluorescent and colorimetric probe for Cu2+ in live cells
Wei-Yong Liu, Hai-Ying Li, Bao-Xiang Zhao and Jun-Ying Miao
Analyst
, 2012, Advance Article
DOI
: 10.1039/C2AN35559K

Colorimetric recognition and sensing of nitrite with unmodified gold nanoparticles based on a specific diazo reaction with phenylenediamine
Jia Zhang, Cheng Yang, Xiaolei Wang and Xiurong Yang
Analyst
, 2012,137, 3286-3292
DOI
: 10.1039/C2AN35204D

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HOT Article: Forensic fingerprints

Agnieszka Banas and Mark Breese from the National University of Singapore, and colleagues from Singapore and the UK have discovered there is more to be revealed in fingerprints. The non-destructive technique of synchrotron radiation-based Fourier transform infra-red (SR-FTIR) micro-imaging has been used to explore the molecular chemistry within the microstructures of microscopic particles found within latent fingerprints. Fingerprints can be contaminated with all sorts of things that a person has come in contact with, like powders, creams, medications and high explosive materials.

Click on the link below to read more about this work.

Detection of microscopic particles present as contaminants in latent fingerprints by means of synchrotron radiation-based Fourier transform infra-red micro-imaging
A. Banas, K. Banas, M. B. H. Breese, J. Loke, B. Heng Teo and S. K. Lim
Analyst, 2012, Advance Article
DOI: 10.1039/C2AN35355E

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HOT Article: Detecting people in collapsed buildings

Mochalski & Amman et al., Analyst, 2012, 137, 3278

In the last few years there have been a number of large natural disasters, including the earthquakes in Haiti and Indonesia, and the earthquake and subsequent tsunami in Japan. These disasters result in devastation and the collapse of buildings and infrastructure in cities, town and villages. Search and rescue teams looking for survivors in the rubble currently use techniques like geophones, telescopic cameras, infrared (IR) cameras, or search dogs to locate survivors.  Paweł Mochalski, Anton Amann and a collaborative team from Poland, Austria and Greece have used headspace solid phase micro-extraction gas chromatography-mass spectrometry to study the biomarkers in urine, and looked at how the profile of 22 volatile species in urine changed when in contact with concrete and brick, in an attempt to signify human presence. Read about their interesting study below.

Permeation profiles of potential urine-borne biomarkers of human presence over brick and concrete
Paweł Mochalski, Agapios Agapiou, Milt Statheropoulos and Anton Amann
Analyst, 2012, 137, 3278-3285
DOI: 10.1039/C2AN35214A

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HOT articles in Analyst

Check out some of the HOT articles published so far this month in Analyst. These papers will be free to access for 2 weeks.

The effect of anticancer drugs on seven cell lines monitored by FTIR spectroscopy
Allison Derenne, Magali Verdonck and Erik Goormaghtigh
Analyst, 2012, Advance Article
DOI: 10.1039/C2AN35116A

Ring-opening metathesis polymerization-derived large-volume monolithic supports for reversed-phase and anion-exchange chromatography of biomolecules
Rajendar Bandari and Michael R. Buchmeiser
Analyst, 2012, Advance Article
DOI: 10.1039/C2AN35193E

Facile magnetization of metal–organic framework MIL-101 for magnetic solid-phase extraction of polycyclic aromatic hydrocarbons in environmental water samples
Shu-Hui Huo and Xiu-Ping Yan
Analyst, 2012, Advance Article
DOI: 10.1039/C2AN35429B

Generating contrast in hyperpolarized 13C MRI using ligand–receptor interactions
Kayvan R. Keshari, John Kurhanewicz, Jeffrey M. Macdonald and David M. Wilson
Analyst, 2012, Advance Article
DOI: 10.1039/C2AN35406C

Micro- and nanostructures and their application in gas chromatography
M. Mittermüller and D. A. Volmer
Analyst, 2012, Advance Article
DOI: 10.1039/C2AN35184F

Characterization of microstructured fibre emitters: in pursuit of improved nano electrospray ionization performance
Xinyun Wu, Richard D. Oleschuk and Natalie M. Cann
Analyst, 2012, Advance Article
DOI: 10.1039/C2AN35249D

Switchable ‘on–off–on’ electrochemical technique for direct detection of survivin mRNA in living cells
Jing Liu, Hong Zhou, Jing-Juan Xu and Hong-Yuan Chen
Analyst, 2012, Advance Article
DOI: 10.1039/C2AN35463B

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Analyst Issue 14 now online!

Park & Hong et al., Analyst, 2012, 137, 3249

Issue 14 for Analyst has now gone online for you to have a look at. We have some wonderful and interesting covers this time.

On the front cover we have an image from Tai Hyun Park, Seunghun Hong and colleagues from Seoul National University, Seoul, Korea. They have developed a biosensor that works on the same principles as the canine nose and have used it in the detection of hexanal, which is an indicator of the oxidation of food and food quality.

A bioelectronic sensor based on canine olfactory nanovesicle–carbon nanotube hybrid structures for the fast assessment of food quality
Juhun Park, Jong Hyun Lim, Hye Jun Jin, Seon Namgung, Sang Hun Lee, Tai Hyun Park and Seunghun Hong
Analyst, 2012, 137, 3249-3254
DOI: 10.1039/C2AN16274A

Gupta et al., Analyst, 2012, 137, 3216

Tarkeshwar Gupta from the University of Delhi and co-workers from India and Germany have given us our inside front cover this issue. In their communication they have made an efficient sensor for ascorbic acid using a copper complex-based monolayer on glass. They hope this is a step forward in research in monolayer-based remote-sensing devices and wireless sensor fabrication.

“Turn on” electron-transfer-based selective detection of ascorbic acid via copper complexes immobilized on glass
Vikram Singh, Prakash Chandra Mondal, Jeyachandran Yekkoni Lakshmanan, Michael Zharnikov and Tarkeshwar Gupta
Analyst, 2012, 137, 3216-3219
DOI: 10.1039/C2AN16197D

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HOT articles in Issue 14

We have a number of HOT articles in this week’s latest issue of Analyst. With topics including urine-borne biomarkers, nerve agent detection, nanostructures for gas chromatography and a bioelectronic sensor based on a dog’s nose, this is a very HOT issue indeed! These papers will be free to access until July 4th.

Micro- and nanostructures and their application in gas chromatography
M. Mittermüller and D. A. Volmer
Analyst, 2012, 137, 3195-3201
DOI: 10.1039/C2AN35184F

“Turn on” electron-transfer-based selective detection of ascorbic acid via copper complexes immobilized on glass
Vikram Singh, Prakash Chandra Mondal, Jeyachandran Yekkoni Lakshmanan, Michael Zharnikov and Tarkeshwar Gupta
Analyst, 2012, 137, 3216-3219
DOI: 10.1039/C2AN16197D

A novel screen-printed electrode array for rapid high-throughput detection
Shuai Mu, Xiao Wang, Yuan-Ting Li, Yang Wang, Da-Wei Li and Yi-Tao Long
Analyst, 2012, 137, 3220-3223
DOI: 10.1039/C2AN35261C

Fluorogenic and chromogenic probe for rapid detection of a nerve agent simulant DCP
Wei-hui Wu, Jun-jun Dong, Xin Wang, Jian Li, Shao-hui Sui, Gao-yun Chen, Ji-wei Liu and Ming Zhang
Analyst, 2012, 137, 3224-3226
DOI: 10.1039/C2AN35428D

A bioelectronic sensor based on canine olfactory nanovesicle–carbon nanotube hybrid structures for the fast assessment of food quality
Juhun Park, Jong Hyun Lim, Hye Jun Jin, Seon Namgung, Sang Hun Lee, Tai Hyun Park and Seunghun Hong
Analyst, 2012, 137, 3249-3254
DOI: 10.1039/C2AN16274A

The effect of anticancer drugs on seven cell lines monitored by FTIR spectroscopy
Allison Derenne, Magali Verdonck and Erik Goormaghtigh
Analyst, 2012, 137, 3255-3264
DOI: 10.1039/C2AN35116A

Simultaneous electrochemical measurement of metal and organic propellant constituents of gunshot residues
Maika Vuki, Kwok-Keung Shiu, Michal Galik, Aoife M. O’Mahony and Joseph Wang
Analyst, 2012, 137, 3265-3270
DOI: 10.1039/C2AN35379B

Ring-opening metathesis polymerization-derived large-volume monolithic supports for reversed-phase and anion-exchange chromatography of biomolecules
Rajendar Bandari and Michael R. Buchmeiser
Analyst, 2012, 137, 3271-3277
DOI: 10.1039/C2AN35193E

Permeation profiles of potential urine-borne biomarkers of human presence over brick and concrete
Paweł Mochalski, Agapios Agapiou, Milt Statheropoulos and Anton Amann
Analyst, 2012, 137, 3278-3285
DOI: 10.1039/C2AN35214A

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Colorimetric recognition and sensing of nitrite with unmodified gold nanoparticles based on a specific diazo reaction with phenylenediamine
Jia Zhang, Cheng Yang, Xiaolei Wang and Xiurong Yang
Analyst, 2012, 137, 3286-3292
DOI: 10.1039/C2AN35204D

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HOT article: Monitoring chicken meat freshness by colorimetric sensor

Scientists in Spain used an array of 16 chromogenic indicators with different chemical recognition properties to follow the ageing of chicken stored in modified atmosphere packaging (MAP).

Many currently available methods to check meat spoilage are destructive, time-consuming, expensive and require qualified personnel. This means that they are fine for food safety inspections, but not suitable for use in shops or on every piece of packaged meat. Chromogenic sensors are cheap, versatile, can be printed on packaging and easily measured by cameras or the naked eye. The team observed characteristic colour fingerprints for each day of the study (which was carried out over 12 days) and gave clear differentiation at two-day intervals.

Once the 16-dye array had been successfully used, the team developed a simpler version based on just two dyes with three categories allowing differentiation between ‘fresh’, ‘beginning of decay’ and ‘non-fresh’. This shortened version could be printed on packaging and observed by the naked eye.

Monitoring of chicken meat freshness by means of a colorimetric sensor array
Analyst
, 2012,
DOI: 10.1039/C2AN35211G

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HOT article: Saliva sample collector for non-invasive health test

Monitoring volatile organic compound (VOC) levels in workers exposed to these compounds is important for their health. This is normally done by taking blood samples. However, scientists are looking towards using saliva samples instead, as a non-invasive technique.

Collecting saliva samples is done by either passive drool (in which the subject has to sit tight while their saliva drips off their lips into a collection vessel) or by chewing on a piece of cotton wool (which is then centrifuged to collect the saliva). But, neither technique can be used to detect VOCs in saliva.

Now, UK scientists at Loughborough University and Unilever R&D in the Wirral have come up with a new approach to overcome this problem. They carried out sampling of VOCs directly in the mouth using a polydimethylsiloxane sampler.

Although it takes 10 minutes to collect a sample, the team says that they are working towards reducing the time to one minute. The method could be combined with other VOC sampling methods – breath and skin analysis – they say.

Sampling and Characterisation of Volatile Organic Compound Profiles in Human Saliva Using a Polydimethylsiloxane Coupon Placed Within the Oral Cavity
Analyst, 2012, Accepted Manuscript
DOI: 10.1039/C2AN35432B

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