Archive for April, 2012

NJC issue 5 out!

We invite you to visit the May issue of NJC.

An article by Kazuyuki Kuroda and co-workers (Waseda University, Tokyo, Japan) features on this month’s front cover. In this publication, the authors report the synthesis of a novel air-stable spherosilicate oligomer that can be trimethylsilylated leading to further chemical modification or condensed upon thermal-treatment to afford molecularly ordered hybrids. This silicate oligomer is an attractive building block for the preparation of silica-based nanomaterials such as metallosilicates or mesostructured materials.

“A spherosilicate oligomer with eight stable silanol groups as a building block of hybrid materials”, Kazufumi Kawahara, Hiroki Tachibana, Yoshiaki Hagiwara and Kazuyuki Kuroda New J. Chem., 2012, 36, 1210-1217. DOI: 10.1039/C2NJ20953E (Paper).

 

The inside cover was produced by Monika Stolar and Thomas Baumgartner (University of Calgary, Canada), presenting a series of donor/acceptor functionalized π-conjugated materials, in which the donor component is a 3(6)-carbazole unit and the acceptor component a 2(6)-dithienophosphole species. The new chromophores display a desirable and reversible stimulus-responsive behaviour with a significant red shift of the absorption and emission wavelengths in the presence of acids.

“Synthesis and unexpected halochromism of carbazole-functionalized dithienophospholes”, Monika Stolar and Thomas Baumgartner New J. Chem., 2012, 36, 1153-1160. DOI: 10.1039/C2NJ40022G (Paper).

You can access and read the whole issue 5 here. Why not sign-up for our table of contents e-alerts today to receive NJC issues direct to your inbox?

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Top ten most accessed articles in March

This month sees the following articles in New Journal of Chemistry that are in the top ten most accessed:-

One-pot hydrothermal synthesis of graphene quantum dots surface-passivated by polyethylene glycol and their photoelectric conversion under near-infrared light 
Jianhua Shen ,  Yihua Zhu ,  Xiaoling Yang ,  Jie Zong ,  Jianmei Zhang and Chunzhong Li  
New J. Chem., 2012, 36, 97-101 DOI: 10.1039/C1NJ20658C    
 
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs) 
Christoph Janiak and Jana K. Vieth  
New J. Chem., 2010, 34, 2366-2388 DOI: 10.1039/C0NJ00275E    

One-step ultrasonic synthesis of fluorescent N-doped carbon dots from glucose and their visible-light sensitive photocatalytic ability 
Zheng Ma ,  Hai Ming ,  Hui Huang ,  Yang Liu and Zhenhui Kang  
New J. Chem., 2012, 36, 861-864 DOI: 10.1039/C2NJ20942J    

Preparation of graphene–TiO2 composites with enhanced photocatalytic activity 
Kangfu Zhou ,  Yihua Zhu ,  Xiaoling Yang ,  Xin Jiang and Chunzhong Li  
New J. Chem., 2011, 35, 353-359 DOI: 10.1039/C0NJ00623H     

Preparation of graphene supported nickel nanoparticles and their application to methanol electrooxidation in alkaline medium 
Ling-Rong Zhang ,  Jin Zhao ,  Meng Li ,  Hai-Tao Ni ,  Jin-Lei Zhang ,  Xiao-Miao Feng ,  Yan-Wen Ma ,  Qu-Li Fan ,  Xi-Zhang Wang ,  Zheng Hu and Wei Huang  
New J. Chem., 2012, 36, 1108-1113 DOI: 10.1039/C2NJ20690K     

“Janus” dendrimers: syntheses and properties 
Anne-Marie Caminade ,  Régis Laurent ,  Béatrice Delavaux-Nicot and Jean-Pierre Majoral  
New J. Chem., 2012, 36, 217-226 DOI: 10.1039/C1NJ20458K    

Multifunctional ligands in transition metal catalysis 
Robert H. Crabtree  
New J. Chem., 2011, 35, 18-23 DOI: 10.1039/C0NJ00776E     

Synthesis and characterization of 1,7-disubstituted and 1,6,7,12-tetrasubstituted perylenetetracarboxy-3,4:9,10-diimide derivatives 
Mathieu Queste ,  Cyril Cadiou ,  Bernard Pagoaga ,  Louis Giraudet and Norbert Hoffmann 
New J. Chem., 2010, 34, 2537-2545 DOI: 10.1039/C0NJ00240B     

Towards efficient polyoxometalate encapsulation in MIL-100(Cr): influence of synthesis conditions 
Jana Juan-Alcañiz ,  Maarten G. Goesten ,  Enrique V. Ramos-Fernandez ,  Jorge Gascon and Freek Kapteijn  
New J. Chem., 2012, 36, 977-987 DOI: 10.1039/C2NJ20587D     

Friedländer synthesis of polysubstituted quinolines and naphthyridines promoted by propylphosphonic anhydride (T3P®) under mild conditions 
Mouhamad Jida and Benoit Deprez  
New J. Chem., 2012, 36, 869-873 DOI: 10.1039/C2NJ21043F    

Why not take a look at the articles today and blog your thoughts and comments below.

Fancy submitting an article to New Journal of Chemistry? Then why not submit to us today or alternatively email us your suggestions.

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NJC in China: 1st Stop Hong Kong

Our group of 11 NJC Board members and editors arrived in Hong Kong at the beginning of the week for the first of 3 stops on our 2012 China tour. About half of us are China “virgins” so we are quite excited and are looking forward to the week that awaits us.

University of Hong Kong Professor of Chemistry, Vivian Yam and her group were our hosts; they did such a great job, taking care of us and making sure we didn’t get lost in the 3D topology of the University!

The first symposium was a full program of 14 presentations by NJC board members/editors and Hong Kong chemists. Listening to these, I was struck by the connections between talks that, at first glance, had no relationship. Some of these were:

  • ion channels (for biology and batteries by Dan Yang and Takashi Kato, respectively)
  • use of porous materials (Len Barbour and JN Moorthy)
  • the effects of aggregation (Kato again and Ben Zhong Tang)
  • separating similar species (Michael Scott and Moorthy)
  • fluorine containing systems (Odile Eisenstein and Peter Junk)
  • transaminases (Helen Hailes and Ling Peng)

At the end of a long day, Niamh O’ Connor and Jamie Humphrey (of the RSC Publishing office in Cambridge) hosted the board members, editors and Vivian Yam for a lovely dinner. While sipping a velvety Australian Shiraz wine provided by Vivian, we tasted Shanghai-style delicacies, to give us a fore-taste of our upcoming stop.

Left to right: Vivian Yam welcoming NJC members; Editor-in-chief Mir Wais Hosseini breaking the chicken; tea service. (Thanks to Debbie Crans for these photos.)

Thanks to Vivian and her team, all the participants, and the French Consulate of Hong Kong and Macau (who gave financial support) for making this event such a scientific success and a delight for all of us, who came such a long way!

Next stop: Shanghai!

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Meet our authors of the May issue of NJC

We are pleased to present a selection of our authors of the May issue of NJC. We thank each of them for accepting our invitation and having kindly taken some of their time to answer a few questions for us.

Our first author is Oana R. Luca who is a Graduate Student at Yale University (USA) in the group of Prof. Robert H. Crabtree. Her current research interests are mainly focused on electrocatalysis, more specifically the production and storage of H2. In her NJC paper, Oana and co-workers report on a Ni(II) complex with a redox-active pincer ligand which reduces protons effectively at a low overpotential in aqueous acidic conditions. A combined experimental and computational study provides mechanistic insights into an unusual putative catalytic cycle.

When asked what led to the publication of this article at NJC, Oana responds: “NJC is a forum for cutting-edge work in the chemical sciences”.

Out of the lab, Oana enjoys spending time with her friends, playing chess, reading and playing guitar. If Oana could not be a scientist, she would probably be a baker.

A tridentate Nickel pincer for aqueous electrocatalytic hydrogen production by Oana R. Luca, Steven J. Konezny, James D. Blakemore, Dominic M. Colosi, Shubhro Saha, Gary W. Brudvig, Victor S. Batista and Robert H. Crabtree, New J. Chem., 2012, 36, 1149-1152; DOI: 10.1039/C2NJ20912H.

Our next author is Mariano Venanzi, Associate Professor of Physical Chemistry at the University of Rome Tor Vergata (Italy). Mariano’s research interests focus on biotechnology, peptide materials and spectroscopy of biological molecules.

In this issue of NJC, Mariano has authored the article Glucosylated steroid-porphyrins as new tools for nanotechnology applications by R. Lettieri, D. Monti, Karel Zelenka, Tomáš Trnka, Pavel Drašar and M. Venanzi, New J. Chem., 2012, 36, 1246-1254; DOI: 10.1039/C2NJ20982A. “Porphyrins are versatile scaffolds that can be suitably engineered  for applications in different environments. The paper shows how the unique self-assembly properties of derivatized porphyrins can be exploited for forming complex supramolecular structures (mesoscopic aggregates, multilayer films, inclusion complexes in liposomes)”, explains Mariano who chooses NJC for publication of this article as “NJC is an authoritative journal edited by a prominent chemical society with a large readership”.

In his free time, Mariano loves spending time running, trekking and listening to music. If Mariano was not a scientist, he would have been a historian or a mystery fiction author.

Mark Moloney is Professor of Chemistry at the University of Oxford (UK).

His current research interest is synthetic organic chemistry in the areas of natural products, drug development and surface science.

In this NJC issue’s paper, Mark and co-workers describes the culmination of a large multidisciplinary project to demonstrate that the surface modification of materials can be used to control protein binding, and that this behaviour can be correlated with surface chemistry and with modern cheminformatic descriptors more normally used in the drug discovery process.

Post-Polymerisation Modification of Surface Chemical Functionality and its Effect on Protein Binding by Cleo Choong, J. S. Foord, Jon-Paul Griffiths, Emily M. Parker, Luo Baiwen, Meghali Bora and Mark G. Moloney, New J. Chem., 2012, 36, 1187-1200; DOI: 10.1039/C2NJ00002D.

NJC was chosen as a highly attractive home for this work because of its wide readership and the fact that it encourages genuinely interdisciplinary work.”

Walking, swimming and gardening are Mark’s favourite activities. If he could not be a scientist, Mark would love to run a small-holding specialising in rare animal breeds.

Closing this month’s author selection, Yuxin Zhao is PhD student at the Griffith University (Australia).

His current research interest are metal-based nanomaterials, carbon-based nanocomposites and dye-sensitized solar cells. He has authored in this NJC issue the paper A Flexible Chemical Vapor Deposition Method to Synthesize Copper@Carbon Core-shell Structured Nanowires and Study of Their Structural Electrical Properties by Yuxin Zhao, Juan Wang, Ying Zhang, Yanpeng Li and Zifeng Yan, New J. Chem., 2012, 36, 1255-1264; DOI: 10.1039/C2NJ40036G.

Out of the lab, Yuxin’s favorite activity is Chinese traditional painting and if he was not a scientist, he would be an artist in oriental traditional painting.

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Catalyst expert named to NJC Advisory Board

The Editors-in-Chief of NJC welcome 3 new members to the boards. Earlier this year Len Barbour of Stellenbosch University in South Africa and Takashi Kato of the University of Tokyo were appointed to the Editorial Board, while Davit Zargarian, at the University of Montreal in Québec, Canada, has joined the International Advisory Board.

In this post, I present Professor Davit Zargarian, who has been at the University of Montreal since 1993.

Davit Zargarian began his studies at the University of Toronto as an undergraduate in the group of Professor Martin Moskovits, working on the oxidation of ethylene. After his B. S. degree, he moved to the University of Waterloo to join the new organometallic chemistry/homogenous catalysis laboratory led by Professor Todd Marder. His M. S. studies centered on the preparation of Rh-alkynyl complexes. The University of Ottawa was his next home, where Davit prepared his Ph. D. thesis with Professor Howard Alper on the Ni- and Pd-catalyzed carbonylation of alkenes and alkynes. In 1991, Davit moved to the Scripps Institute for his first postdoctoral stint. After working on Os-catalyzed dihydroxylation of olefins in the group of Professor Barry Sharpless, Davit moved across the street to the San Diego campus of the University of California to work in the research group of Professor Don Tilley, studying the chemistry of Hf-silyl complexes.

Davit returned to Canada in 1993 to take up a position as Assistant Professor at the University of Montreal, where he learnt to teach inorganic and organometallic chemistry in French and moved up the ranks to become Full Professor in 2004. The Zargarian research group typically consists of a small group of enthusiastic students focused on the coordination and organometallic chemistry of first-row transition metals (primarily nickel) featuring ligands such as indenyls, bis- and tris(pyrazolyl)alkanes, and various types of pincer ligands. The main theme of their studies is homogeneous catalysis promoted by new complexes designed and synthesized by the group.

Davit has a message to address to the chemistry community worldwide: “I look forward to joining my colleagues on the international advisory  board in their efforts to strengthen New Journal Chemistry as a society publication that will contribute to the advancement of the chemical sciences. With the rapid worldwide growth of chemical research over the past two decades, it is incumbent on all of us to take steps to avoid fragmentation of our research results, strive to interpret the avalanche of new data being generated worldwide, and formulate this data into new knowledge that can be communicated to the research community and the society at large. In this spirit, I urge my fellow inorganic and organometallic chemists to consider publishing their latest research results in the form of articles and perspectives in NJC.”

We wish a warm welcome to Davit and look forward to a fruitful collaboration with him as a representative of the Canadian chemistry community.

 

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Meet Our Authors – April 2012

Faces behind the research: Learn more about some of our authors of the April issue of NJC and check out their latest entries.

Prof. Robert Bruce King is Regents’ Professor Emeritus at the University of Georgia, USA. He is currently directing a research program directing collaborators spread over three continents.  He works with large research groups in Romania at Babeş-Bolyai University (Cluj-Napoca) and in China at South China Normal University (Guangzhou) and Xihua University (Chengdu) where he has adjunct academic appointments.

His research interests are computational inorganic and organometallic chemistry. The paper to be published in NJC deals with using density functional theory to explore the chemistry of boronyl (BO) analogous of the simple metal carbonyls.  The work describes the interesting structures of Fe2(BO)2(CO)8 isoelectronic with the well-known dimanganese decacarbonyl.

“This paper is of broad interest to both inorganic and physical chemists, therefore a general journal such as NJC appeared to be the most suitable journal for this paper” commented Prof. King on choosing the NJC journal to publish this work.

When asking which scientific problem he would like to solve: “I am much more oriented towards exploring uncharted territory rather than solving specific problems.  Early in my career, I found the synthesis of new molecules exhibiting novel structural features to be very exciting.  Nowadays, I am particularly enthusiastic about generating new types of molecules in silico on the computer using well-established density functional theory methods arising from quantum chemistry”.

Binuclear iron boronyl carbonyls isoelectronic with the well-known decacarbonyldimanganese by Yu Chang, Qian-Shu Li, Yaoming Xie, R. Bruce King and Henry F. Schaefer III, New J. Chem., DOI: 10.1039/C2NJ20894F


Jana Juan-Alcañiz is a PhD student at the Delft University of Technology in the Netherlands. Jana is working in the field of heterogeneous catalysis and her current research interests are metal-organic frameworks as nanoreactors.

In their NJC paper, Jana and her colleagues focused on “a ship in a bottle” approach that has been followed to successfully encapsulate phosphotungstic acid in the metal-organic framework MIL-100(Cr). The influences of the synthesis conditions, like solvent effect or irradiation methods have been investigated to achieve efficient one-pot encapsulation maintaining the chemical nature of the guest species.

Solving the low efficiency of renewable energy sources is a scientific problem that Jana would like to solve.

Towards efficient polyoxometalate encapsulation in MIL-100(Cr): influence of synthesis conditions by Jana Juan-Alcañiz, Maarten G. Goesten, Enrique V. Ramos-Fernandez, Jorge Gascon and Freek Kapteijn, New J. Chem.DOI: 10.1039/C2NJ20587D

Our next author is Dr. Eliano Diana, an Associate Professor of General and Inorganic Chemistry at Faculty of Sciences M.F.N., University of Turin, Italy. His research interest centers on the evaluation of bond properties and intermolecular interactions in metal complexes by means of vibrational spectroscopies and computational modeling.

Eliano’s contribution to this April issue of NJC reports the experimental data concerning atypical hydrogen bonds found in organometallic salts and tried to explicate it with a multidisciplinary approach.

When asking why did he decide to submit this work to NJC, Eliano answered: ”Because of the good quality of the Journal, the cross-disciplinary spread and the excellent editorial support”.

If Eliano could solve any scientific problem: “I’d eliminate the HIV virus”.

Blue and red shift hydrogen bonds in crystalline cobaltocinium complexes by Eliano Diana, Michele R. Chierotti, Edoardo M. C. Marchese, Gianluca Croce, Marco Milanesio and Pier Luigi Stanghellini, New J. Chem., DOI: 10.1039/C2NJ20760E

Dr. Sébastien FLOQUET holds an Associate Professor position at Institut Lavoisier de Versailles, University of Versailles, France. His research activity is currently concentrated on synthesis and characterization of polyoxo(thio)metalates.

In their NJC paper, Sébastien and his collegues highlight the liquid crystal properties of a famous nanoscale polyoxometalate, i.e. the “Keplerate” compound [Mo132O372(CH3COO)30(H2O)72]42- surrounded by 36 DODA+ cations. “In this field of research, the results we present here opens the route towards the formation of new mesomorphic phases based on very large inorganic clusters simply by ionic association with appropriate organic cations”.

New Journal of Chemistry is a European journal co-edited by RSC and the French CNRS. Futhermore NJC publishes articles focused on all domains of chemistry, the colored figures are free of charge and NJC possesses a good impact factor, which probably will increase in the future” explains why Sébastien and his colleagues consider that their work is particularly suitable for NJC.

“In my opinion, environmental and energetic problems constitute the main challenges for chemists today. The synthesis of highly efficient materials for hydrogen production, CO2 conversion or pollutant reduction are probably the most exciting challenges I would like to solve”.

Evidence of ionic liquid crystal properties for a DODA+ salt of the keplerate [Mo132O372(CH3COO)30(H2O)72]42− by Sébastien Floquet, Emmanuel Terazzi, Akram Hijazi, Laure Guénée, Claude Piguet and Emmanuel Cadot; New J. Chem., DOI: 10.1039/C2NJ20923C

We would like to thank to our authors for answering these questions for us and we appreciate their interest in publishing with us and look forward to seeing new submissions soon!

Why not submit your high impact research to us today or alternatively email us your suggestions.

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A facile strategy to prepare nitrogen and boron doped monolayer graphene from solid precursors.

In this NJC paper, Honglie Shen et al (Nanjing University of Aeronautics & Astronautics, China) report a facile strategy to prepare a nitrogen and boron doped monolayer of graphene from urea and boric acid as solid precursors.

This approach is shown to be efficient, producing graphene with excellent optical and electrical performances at relatively low cost.

Nitrogen and boron doped monolayer graphene by chemical vapor deposition using polystyrene, urea and boric acidNitrogen and boron doped monolayer graphene by chemical vapor deposition using polystyrene, urea and boric acid Tianru Wu,  Honglie Shen,  Lei Sun,  Bin Cheng,  Bin Liu and Jiancang Shen, New J. Chem., 2012, Advance Article DOI: 10.1039/C2NJ40068E

Interested in reading further? Why not download the full article now, FREE to access for a period of 4 weeks!

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South African chemist joins NJC Editorial Board

The Editors-in-Chief of NJC welcome 3 new members to the boards. Earlier this year Len Barbour of Stellenbosch University in South Africa and Takashi Kato of the University of Tokyo were appointed to the Editorial Board, while Davit Zargarian, at the University of Montreal in Québec, Canada, has joined the International Advisory Board. Len and Takashi will be participating in the 2012 NJC Symposia: New Directions in Chemistry, which will be held in Hong Kong, Shanghai and Beijing during the last week of April.

In this post I present Len Barbour, professor of chemistry at Stellenbosch University in South Africa.

Len completed his Ph.D. research in 1994 at the University of Cape Town, where he studied physico-chemical aspects of inclusion compounds under the direction of Professor Luigi Nassimbeni. He then moved to the University of Missouri-Columbia (UMC) to work as a postdoctoral fellow with Professor Jerry Atwood. Len continued at UMC as a Research Assistant Professor until 2003, at which time he moved back to South Africa to take up an Associate Professor position at Stellenbosch University. Len was promoted to Full Professor in 2005 and two years later was awarded a South African Research Chairs Initiative (SARChI) Chair in Nanostructured Functional Materials, a position that was recently renewed.

Len’s research interests centre on structure-property relationships in molecular crystals. Properties of interest include porosity, nonlinear optics, and anomalous thermal expansion, with the main objective being to gain new insights into physical processes that occur at the molecular scale. Using a crystal engineering approach, the group carries out multifaceted studies that include the synthesis of molecular building blocks, crystallisation studies, kinetic and thermodynamic measurements, X-ray structure elucidation, computation and process engineering.  Methodology development is also a strong research theme within the group.

Of his nomination to the NJC Board, Len had this to say: “I was greatly honoured when asked to join the editorial board of the New Journal of Chemistry—an invitation that I accepted without hesitation. NJC has a longstanding record of publishing outstanding papers that cover a broad range of subdisciplines within chemistry, and I very much look forward to making meaningful contributions aimed at maintaining and even improving the journal’s profile.

We look forward to welcoming Len Barbour onto the Editorial Board of NJC at the upcoming Board meeting.

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Professor Takashi Kato appointed to NJC Editorial Board

The Editors-in-Chief of NJC welcome 3 new members to the boards. Earlier this year Len Barbour of Stellenbosch University in South Africa and Takashi Kato of the University of Tokyo were appointed to the Editorial Board, while Davit Zargarian, at the University of Montreal in Québec, Canada, has joined the International Advisory Board. Len and Takashi will be participating in the 2012 NJC Symposia: New Directions in Chemistry, which will be held in Hong Kong, Shanghai and Beijing during the last week of April.

In this post, I present Takashi Kato, who is a professor in the Department of Chemistry and Biotechnology of the School of Engineering at The University of Tokyo since 2000. His research focuses on the development of self-assembled functional materials including liquid crystals, gels, polymers, stimuli-responsive materials, nanostructured ion- and electron-active materials, and bio-inspired hybrids.

Takashi received his Ph.D. degree at the University of Tokyo in 1988. After his postdoctoral research at Cornell University with Professor Jean M. J. Frechet on supramolecular liquid crystals and polymers (1988-1989), he joined The University of Tokyo. Takashi is the recipient of numerous awards from a variety of organizations around the world: the Chemical Society of Japan Award for Young Chemists (1993), the Wiley Polymer Science Award (Chemistry, 2001), the 17th IBM Japan Science Award (Chemistry, 2003), the 1st JSPS Prize (2005), the Japanese Liquid Crystal Society (2008), Molecular Science Forum Lecture Professorship of the Institute of Chemistry, Chinese Academy of Science (2009), and the Society of Polymer Science, Japan (2010).

Takashi has published about 350 papers including original papers, reviews, and chapters of books. He is an Associate Editor of Polymer Journal (2002-present) and is also on several advisory boards, including those of two RSC journals—Journal of Materials Chemistry and Chemical Science.

“It is my great pleasure to join the Editorial Board of New Journal of Chemistry. Interdisciplinary fields relating to and surrounding chemistry and interdisciplinary fields in chemistry are becoming more important both to advance science and to resolve global issues. I believe New Journal of Chemistry is an excellent forum for this mission.”

With his vast experience in chemistry and in working with RSC Publishing, we are looking forward to having Takashi Kato’s input into NJC‘s editorial policy and his help for the promotion of the journal.

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Register for the China NJC Symposia

Are you interested in attending one of the 2012 NJC Symposia: New Directions in Chemistry?

(Full details can be found here and here.)

Then please register—it’s free, easy and only takes a minute!

Send an e-mail with the following information to njc ‘at’ univ-montp2.fr (replace ‘at’ with @)

  • your full name
  • your status (Ph.D. student, postdoc, researcher, professor)
  • your institution
  • which symposium you wish to attend: Hong Kong on April 23rd, Shanghai on April 25th or Beijing on April 27th

You can also click here to access a link to send an e-mail automatically to the editor.

Please register by April 15th!

Thank you for your interest and we look forward to meeting you soon…

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