Homogeneous catalyst immobilization for record recyclability

In this NJC Letter, Janet Blümel and colleagues discuss the design of a linker scaffold that prevents the immobilized Rh catalyst from being deactivated by dimerization or contact with the support surface. Using a multipoint attachment approach, the authors show how the catalyst can be recycled for a record 30 times. 

New linker systems for superior immobilized catalysts, Björn Beele, Johannes Guenther, Melanie Perera, Michaela Stach, Thomas Oeser and Janet Blümel, New J. Chem. 2010, Advance article, DOI: 10.1039/C0NJ00482K

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